BOLIVE
Bharat Panchal Sir
Organic Name
Reaction
Haloalkanes
a Bharat Panchal Sir
Haloarenes
# Reaction
ein
R-X NdT * R - + Nax
+
T 2 accone
a
a
<245-ce + Nal -
-
<245-J+NaC
Exa
Swarts Reaction Bharat Panchal Sir
R-F +AgX
ASE
-
R-X O
+
on
a
(15E+gB
6945-But Ag
->
on
a
Rule
·
Markos
->CH.-CH
CHc =
CHe +44
in e
cy- cn cFicMN
=
Eddls Y
e
Crs-on
Bharat Panchal Sir & - chloroprobal
Rule
·
Anti-Markolnikov's
-
+- Organic
UB
CY-CH=CHz + -
Peroxide
No No H
I Negative
Higher
hydroger
Bharat Panchal Sir CU,-C1-C,re
1. Bromoprobes
·
Wurtz Reaction
dr R- R
RteNa+X-R -
ether
2Nax
↑
dr
CansNa+c-CUs C1410
-
+ 2Nacl
other
Fittig Reaction
·
Na+ x-tn [ExE+awax
Bharat Panchal Sir
EteNa+c-
T
n) taNac
Wurtz-Fittg Reaction 2Nax
+x to
+
R-1*
emer
castNa
+ctE) t (Nz zE)
-
emer
+2NaU
Grignard Reagent
·
* avignard
R-X +
Mg the R-MgX
Reagent
, BU
CM53Bw +Mg emer
CeN5-Mg
Bharat Panchal Sir
should be prepared under
anguard reagent anhydrous condition
RMgX d
R -
on alcohol
uYc s
0
=
T
-
-
10
HgO+
rv R'MgX n--oU & alcohol
c = 0 T
-
ax1
R Vot
Ri
Ri * yo alson. I
C O - C-on
O
a ↓jpt bu
NHz
NC
·
Sandmeyer Reaction 1 x + NaNOctuc I
-
-M2 Br
nc
l Br Nc +
+ +
Bharat Panchal Sir
·
Gattermann Reaction
Br
-Nus -
ar
Powder
[ +N+ nc
Trick sand I salt stat
D.C
Doc of Catter Ian Powder Stal
·
Hunsdiecker Reaction
or Borodine Hunsdiecker Reachon
ora
r.com Bharat Panchal Sir
R-Bu +COn + AgBv
or t
Cans-cook
a
CU5-Br + COstAgBr
soycoraryis atthe
-> CO2+AgBr
·
Dow's Process
On
1 A
68ETR
-
Yo won, 10)
-
nenel
↑
culocobenzere
Bharat Panchal Sir
-
on
NOrFNOs
NortFNO
-
T
INo, x
NOW
Electrophilic substitution Reaction
of Halwarenes.
a th " +
k chloination
-
U
j- O
+nouspancs oppwor+ Nation
10) H50s->Asen
-
v
'No2
Y
Potsure
I + alre
XBharat
⑥
Panchal Sir -/
C
cyc Fm e
pchs
+
AICs
-
+ 1aho
C "Ch
Are
[
coCls
+ CHCOC
+1Acylation
I
X
10C43
Alcohol, Phenol
Bharat Panchal Sir
and Ethers
cid catalysed
A
Hydration of Allene
CNC =CHg +NO ACU e e
Bharat Panchal Sir
lf
CHy-CU= CHz HO
Chy-CH-c
+ - e
-
M. R
&at
B
one
⑭- re
Propan-e-o
&
lower
⑪ hydroge
oxidation Reaction
·
Hydro Bovation
-Indirect hydration of alleve
* A.M.R
*Bet.U.F
UrOz, OU- Bharat Panchal Sir
BzNG, FU-F
SH2=CHe >CH.-CU-
N.Or,OU- bu
i
BaNGs ToeITR
Chy-on on
CHe
=
-
I
CHy-CHL-CH
·
oxidation of Alcohol
-
PoCoC or CrOs
-10 alcohol ->
aldehyde
*
20 alcohol -a
kelore
alcohol Bharat Panchal Sir
on
O
0.C.C 1)
(Ny -c -
1 -
Cry-c-V
2. alcoh
anog
D
on as curian e
Grignard Reagent on
Carbonys componds.
·
⑭ UsOf
+RMgX
->YC
=> 0
(
O MY
= -
S
-
I ↑
s-on
ic =0
GoMsx Xcon Bharat Panchal Sir
R RMgX
I alcohol
nxc =0 T
-
YyOt
R- RMgX
c= 0 - 20 alcohol
n My Ot
& RMgY alcohol
x Se
0
=
R
·
Esterification Reaction
Econo
&-COORd
ester
cans-coo
no-chs I
Bharat Panchal Sir
↑
CN5-c-O
-
- tH2@
Metal probanoate
Bromination of Phenol
on
on
Br
Bu
15
->
+
3B02199) Yar +3nBr
2,4,6-Tribrom
Duenol (white opt
Bharat Panchal Sir
ou
1
oU
I CS
a
[3r +
Y
-
t BVz
10
Nitration of Phenol
On
on
C + SAN,
Ursorpone NOETFNOE
X(
cronc(
No
2.p, o-trinito [Pieric
acid)
Bharat Panchal Sir Phenol
OU On
ou
i
I A
+ UNU
(ag)
->
No + 101
You
Reimer Tiemann Reaction
or on
was
As
10
-
I ·
on, popco
*
0-hydroxy -> salicyldehyde ]
Kolbels Reaction benaldelyde
Bharat Panchal Sir
On
ou
I
A X cool
on LI
Naon
lo
- -Salicylic
O-hydroxy Arid)
benzoic acid
Kolbels reaction
Cumene Process (
Noone
ans
CH5 C
-
ref
x
-
+ Or
Bharat Panchal Sir
on
[5 + CYCOCUs
Williamson Synthesis
RSNCD
R.olNa
+ x-R -
R- 0-R* +
NaX
Ether
-alkyl Halide should be
primary
20 and so
alley Valide will undergo, dehydrohalo.
and
give alkene genation
Cou
Bharat Panchal Sir
Cals-OM+(15t ->
Cgus--Cel
Aldehyde, Ketones
Bharat Panchal Sir
Acid
and Carboxylic
Rosenmund Reduction
Acid chloride the s Aldehyde
Basod
I
anon
:
so,
R-c-n +H thr
ur
Bharat Panchal Sir
<xi at He was
&
so (a-a-n
Demaldehyde
Stephen's Reduction
cyguide->Aldehyde
Ho
R CEN
-
+ a(n) R-(n
+UU
N4 =
imir
R-CUO
CgH5-CEN+2TH) A CaM5-CHINU
+UC
tory of
Bharat Panchal Sir
Els-cno+NUs
-
aldehyde
Etard Reaction
CH3 CUS
H + cad ->
[
Bharat Panchal Sir
Gattermann Koch Reaction
in
the
· Friedal Craft Alkylation
·
Cause on
there
Friedal Craft Aclation
Bharat Panchal Sir COCUs
+ecod [
Friedal craft formulation
·
CUD
i + wou F
·
Friedal Craft Benzoylahv Co-1.
i 40 Fo
+ I
Friedel Craft Acylation
Bharat Panchal Sir
oK ec HeC
Reduction
*
Clemmensen
&
1)
In-Ug
CVy-c-U - CHy-CMs
uc
&
Crs-"-chs S
In-Ug
nc
CHy-CHe-CHs
Wolf-Kishner Reduction
Bharat Panchal Sir
Cns--N N-NHw
H
- CUy-CUs
kou, glycol
&
NN-NHw
CHr-c-CUs -
CUy-CHc-Cy
KOU,glycol
Wolft-Kisher Reduction
Bharat Panchal Sir
Adol Condensation Rou
-hydrogen
dil. Nor
chs-EC+A'CO-cy-s-cut
del.
Naou
Bharat Panchal Sir
ch-ce+C-Fo Naon
&
c
cy-
cc =
=
is
But-2-en-1-al
Cross Aldo) Condensation Reaction
cho-c=0 +cus-codon <ns-p=CU-F
(rj c=
+
-p
c
=
-
Bharat Panchal Sir
is
+
CUs-S=CH R
-
Cs ( cx
C
↑ =
-
=
-
h
Cannizzaro Reaction
- Carbonyl group have no a-hydrogen
*Conc. Naov
2ucho+
Naon(onc) ->
netzou+ nCoona
Bharat Panchal Sir
&((x(no) + No
concil-
*CHon+<1-100 Na
Benys Sod.
alcohol Benzoate
Decarboxylation Rey
CaO
RoloNaon -> Q-U
+Na.co,
cust+Naon-Bharat
CaO
Panchal Sir
CHb +Na,COs
HoV2 Reaction
&HELL VOLUARD ZELINSKY Ryn]
H
n -a-coon
⑭- oc +o0n.onto d
-
e
up
Bharat Panchal Si
C O
Red P
Hd-coon +Ur - O'C-coo
be
&0x
be -
-
x
cus-coon +ar* Ca-coon
cry-cu2-coon +Ck edp (U-CH-coon
*
~
Hofmann Ammonolysis Rx
H
Y
(245 Crn-iM+sense
u -
NM +
->
C2H5
T
->
CaMs-N-GNx +(Us ->CeNs-N-CMs
"Ne
(15-c
+
Bharat Panchal Sir
[Canst,N+ cl
=
99Hofmann Bromamide
Degradation
R-CNH + Bro + 9kOU I Q-NHL
Ampe
Amide
Cus-
Nte + Br+nkOU I
CaM5-NHw
Bharat Panchal Sir
<NMr + Brz taNaon
<0xNHct
Gabriel phthalimide synthesis
GNkon-KotINK⑳ + 1-X
Sopcon NR + 24.0 - 1,I
Bharat Panchal Sir
TQ-NU
F
only aliphatic lamine
can be
-
prepared from
thes
metod
· Aromatic amines can't be prepared from
this meter
Carbyl Amine Reaction
R-NM +
casK01-
R- NC + 3U10 +3KU
Bharat Panchal Sir
<Ex- Ni + ca
K0* T
340 +3Ke
+
Nc
--
Diazotization Reaction
NHz NC
I
O.SOC -
↓+ n0No+n -
I
-
& I
Beneer
Aviline
Diazoniu
Bharat Panchal Sir culovde
Coupling Reaction
*Ma.No on -> <5Nite-on
+hy
Bharat Panchal Sir
<x Nn-NH-
FoxN.-<5-Nte
Coupling Reaction
Thank Bharat Panchal Sir
you
(n -
x+ 2Na+ c- C4
emer
