EEDM Notes Unit-5
EEDM Notes Unit-5
Solid waste is the term used to describe non-liquid waste materials arising from domestic, trade,
commercial, agricultural, industrial activities and from public services. Wastes that arise from a
typical urban society comprise of garbage, rubbish (package materials), construction and
demolition wastes, leaf litter, hazardous wastes, etc. If not managed properly, these wastes can
have an adverse impact on the environment and public health arising from contamination of soil,
water and pollution of air and through spread of diseases via vectors living on waste. The
relationship between public health and the improper storage, collection and disposal of solid
wastes is quite clear. Because of their intrinsic properties, discarded waste materials are often
reusable and may be considered a resource in another setting. Ecological phenomena such as
water and air pollution have also been attributed to improper management of solid wastes
From the days of primitive society, humans and animals have used the resources of the earth to
support life and to dispose wastes. In those days, the disposal of human and other wastes did not
pose significant problems as the population was very small and the area of land available for the
assimilation of such wastes was large. However, today, serious consideration is being given
everywhere to this burgeoning problem of solid wastes. Rapid population growth and
uncontrolled industrial development are seriously degrading the urban and semi-urban
environment in many of the world's developing countries, placing enormous strain on natural
resources and undermining efficient and sustainable development.
Solid waste management has become a major environmental issue in India. The per capita of
MSW generated daily, in India ranges from about 100 g in small towns to 500 g in large towns.
The population of Mumbai grew from around 8.2 million in 1981 to 12.3 million in 1991,
registering a growth of around 49%. On the other hand, Municipal Solid Wastes generated in the
city increased from 3 200 tonnes per day to 5 355 tonnes per day in the same period registering a
growth of around 67% (CPCB 2000). This clearly indicates that the growth in Municipal Solid
Wastes in our urban centres has outpaced the population growth in recent years. This trend can
be ascribed to our changing lifestyles, food habits, and change in living standards. Municipal
Solid Wastes in cities is collected by respective municipalities and transported to designated
disposal sites, which are normally low lying areas on the outskirts of the city.
Now-a-days the concern for solid waste management has increased and government has created
lot of awareness among the public for proper separation of solid wastes at the source level itself,
so that it will become easier for treatment / disposal.
There are innumerable potential hazards due to the mismanagement of solid wastes. It has the
potential to pollute all the vital natural resources viz., land, water and air. Some of the hazards
caused by solid wastes are listed below:
Environmental pollution from waste leachates and gas evolving from dumped solid
waste
Air pollution from smoke by burning of waste and health hazards to the people
through inhalation of dust and smoke
Health hazards to waste workers and pickers through direct contact with waste.
Attraction and support of disease vectors (rodents and insects that carry and transmit
disease carrying micro-organisms)
Unaesthetic appearance
Poor living ambience
source reduction
onsite storage
processing techniques
disposal
The following flow chart describes the relationship between the key functional elements of a
solid waste management system
5.2.3 Collection
It includes not only the gathering of solid wastes and recyclable materials, but also the transport
of these materials, after collection, to the location where the collection vehicle is emptied. This
location may be a material processing facility, a transfer station, or a landfill disposal site.
Waste transformation is undertaken to reduce the volume, weight, size or toxicity of waste
without resource recovery. Transformation may be done by a variety of mechanical (eg
shredding), thermal (e.g. incineration without energy recovery) or chemical (e.g. encapsulation)
techniques.
5.2.6 Disposal
The final functional element in the solid waste management system is disposal. Today the
disposal of wastes by landfilling or uncontrolled dumping is the ultimate fate of all solid wastes.
A municipal solid waste landfill plant is an engineered facility used for disposing of solid wastes
on land or within the earth’s mantle without creating nuisance or hazard to public health or
safety, such as breeding of rodents and insects and contamination of groundwater.
food habits,
standard of living
seasons
The quantity of solid waste can be expressed in units of volume or in units of weight. The
advantage of measuring quantity in terms of weight rather than weight is that weight is fairly
constant for a given set of discarded objects, whereas volume is highly variable. Waste
generated on a given day in a given location occupies different volumes in the collection truck,
on the transfer station, in the storage pit or in a landfill. In addition, the same waste can occupy
different volumes in different trucks or landfills. Hence, its always preferable to express the
quantity of solid waste on weight basis.
The best method for estimating waste quantity is to install permanent scales at disposal facilities
and weigh every truck on the way in and again in the way out. At disposal facilities without
permanent scales, portable scales can be used to develop a better estimate of the weight of waste
being deliverd. Selected trucks are weighed and environmental engineers use the results to
estimate the overall weight of the waste stream. Weighing all trucks entering the disposal
facility is a tedious job and hence a method of truck selection must be done. A simple approach
will be to weigh every nth truck (for instance, every 4 th truck) that delivers waste to the facility.
This approach assume that the trucks weighed represent all trucks arriving at the facility. The
total waste taonnage can be estimate can be estimated with the following equation
W = T (w/t)
Where,
The quantity of solid waste is often expressed in kg per capita per day so that the waste streams
in different areas can be compared. The quantity is typically calculated with the following
equation
Q = 1000 T / 365 * P
Data on quantity variation and generation are useful in planning for collection and disposal
systems. Indian cities now generate eight times more municipal solid wastes than they did in
1947 because of increasing urbanization and changing life styles. Municipal solid wastes
generation rates in small towns are lower than those of metro cities, and the per capita generation
rate of municipal solid wastes in India varies in towns and cities. It was also estimated that the
total municipal solid wastes generated by 217 million people living in urban areas was 23.86
million t/yr in 1991, and more than 39 million ton in 2001. Waste generation rate in Indian cities
ranges between 200 - 500 grams/day, depending upon the region’s lifestyle and the size of the
city. The per capita waste generation is increasing by about 1.3% per year in India.
1999 2025
A major fraction of urban municipal solid wastes in India is organic matter (51%). Recyclables
are 17.5 % of the municipal solid wates and the rest 31% is inert waste. It has to be understood
that this composition is at the dump and not the composition of the waste generated. The actual
percentage of recyclables discarded as waste in India is unknown due to informal picking of
waste which is generally not accounted. Accounting wastes collected informally will change the
composition of municipal solid wastes considerably and help estimating the total waste generated
by communities.
Waste composition varies with the socio-economic status within a particular community, since
income, for example, determines life style, composition pattern and cultural behavior.
The geographical location is related primarily to different climate that can influence both the
amount of solid wastes generated and the collection operation. For instance, substantial
variations in the amount of yard and garden wastes generated in various parts of India are related
to the climate. To illustrate, in the warmer southern areas, where the growing season is
considerably longer compared to the northern areas, yard wastes are collected in considerably
larger quantities and over a longer period of time.
Season
Seasons of the year have implications for the quantities and composition of certain types of solid
wastes. For example, the growing season of vegetables and fruits affect the quantities of food
wastes.
Collection frequency
A general observation is that in localities, where there are ultimate collection services, more
wastes are collected. Note that this does not mean that more wastes are generated. For example,
if a resident has access to only one or two containers per week, due to limited container capacity,
he or she will store newspapers or other materials in some specified storage area. However, the
same person will tend to throw them away, if there is access to unlimited container services. In
this latter situation, the quantity of waste generated may actually be the same but the quantity
collected, as it relates to the frequency of collection, is considerably different
Population diversity:
The characteristics of the population influence the quantity and composition of waste generated.
The amount of waste generated is more in low-income areas compared to that in high-income
areas. Similarly, the composition differs in terms of paper and other recyclables, which are
typically more in high-income areas as against low-income areas
20 to
Paper 1 to 4 % Low paper content indicates low calorific value
50%
The existence of salvaging and recycling operation within a community definitely affects the
quantity of wastes collected.
Public attitude
Significant reduction in the quantity of solid waste is possible, if and when people are willing to
change – on their own volition – their habits and lifestyles to conserve the natural resources and
to reduce the economic burden associated with the management of solid wastes.
Legislation
This refers to the existence of local and state regulations concerning the use and disposal of
specific materials and is an important factor that influences the composition and generation of
certain types of wastes.
In a nutshell, elements that relate to waste generation include land use characteristics, population
in age distribution, legislation, socio economic conditions, etc.
It is rather interesting to study the changes in the composition of waste in India in the past. The
following table gives the changing composition of Municipal Waste over the last two decades
and is attributed to the changing life styles and increasing consumerism.
% of Wet Weight
Component
1971-73 (40 cities) 1995 (23 cities)
Density
Density of waste, i.e., its mass per unit volume (kg/m 3), is a critical factor in the design of a solid
waste management system, e.g., the design of sanitary landfills, storage, types of collection and
transport vehicles, etc. To explain, an efficient operation of a landfill demands compaction of
wastes to optimum density. Any normal compaction equipment can achieve reduction in volume
of wastes by 75%, which increases an initial density of 100 kg/m3 to 400 kg/m3. In other words, a
waste collection vehicle can haul four times the weight of waste in its compacted state than when
it is uncompacted. Significant changes in density occur spontaneously as the waste moves from
source to disposal, due to scavenging, handling, wetting and drying by the weather, vibration in
the collection vehicle and decomposition
Moisture content
Moisture content is defined as the ratio of the weight of water (wet weight - dry weight) to the
total wet weight of the waste. Moisture increases the weight of solid wastes, and thereby, the cost
of collection and transport. In addition, moisture content is a critical determinant in the economic
feasibility of waste treatment by incineration, because wet waste consumes energy for
evaporation of water and in raising the temperature of water vapour. In the main, wastes should
be insulated from rainfall or other extraneous water. We can calculate the moisture percentage,
using the formula given below
The size distribution of waste constituents in the waste stream is important because of its
significance in the design of mechanical separators and shredder and waste treatment process.
This varies widely and while designing a system, proper analysis of the waste characteristics
should be carried out.
Calorific Value
Calorific value is the amount of heat generated from combustion of a unit weight of a substance,
expressed as kcal/kg. The calorific value is determined experimentally using Bomb calorimeter
in which the heat generated at a constant temperature of 25 OC from the combustion of a dry
sample is measured.
The physical properties that are essential to analyse of wastes disposed at landfills are:
Field capacity
The field capacity of municipal solid waste is the total amount of moisture which can be retained
in a waste sample subject to gravitational pull. It is a critical measure because water in excess of
field capacity will form leachate, and leachate can be a major problem in landfills. Field capacity
varies with the degree of applied pressure and the state of decomposition of the wastes.
Compressibility
It is the degree of physical changes of the suspended solids or filter cake when subjected to
pressure.
Chemical: Chemical characteristics include pH, Nitrogen, Phosphorus and Potassium (N-P-K),
total Carbon, C/N ratio, calorific value.
Toxic: Toxicity characteristics include heavy metals, pesticides, insecticides, Toxicity test for
Leachates (TCLP), etc.
Lipids
This class of compounds includes fats, oils and grease. Lipids have high calorific values, about
38000 kcal/kg, which makes waste with a high lipid content suitable for energy recovery
processes. Since lipids in the solid state become liquid at temperatures slightly above ambient,
they add to the liquid content during waste decomposition. They are biodegradable but because
they have a low solubility in waste, the rate of biodegradation is relatively slow.
Carbohydrates
Carbohydrates are found primarily in food and yard waste. They include sugars and polymers of
sugars such as starch and cellulose and have the general formula (CH 2O)X. Carbohydrates are
readily biodegraded to products such as carbon dioxide, water and methane. Decomposing
carbohydrates are particularly attractive for flies and rats and for this reason should not be left
exposed for periods longer than is necessary.
Proteins
Proteins are compounds containing carbon, hydrogen, oxygen and nitrogen and consist of an
organic acid with a substituted amine group (NH2). They are found mainly in food and garden
wastes and comprise 5-10% of the dry solids in solid waste. Proteins decompose to form amino
acids but partial decomposition can result in the production of amines, which have intensely
unpleasant odours.
Natural fibres
This class includes the natural compounds, cellulose and lignin, both of which are resistant to
biodegradation. They are found in paper and paper products and in food and yard waste.
Cellulose is a larger polymer of glucose while lignin is composed of a group of monomers of
which benzene is the primary member. Paper, cotton and wood products are 100%, 95% and
40% cellulose respectively. Since they are highly combustible, solid waste having a high
proportion of paper and wood products, are suitable for incineration. The calorific values of
ovendried paper products are in the range 12000 – 18000 kcal/kg and of wood about 20000
kcal/kg, which compare with 44200 kcal/kg for fuel oil.
Non-combustibles:
This class includes glass, ceramics, metals, dust and ashes, and accounts for 12 – 25% of dry
solids.
Heating value
An evaluation of the potential of waste material for use as fuel for incineration requires a
determination of its heating value, expressed as kilojoules per kilogram (kJ/kg). The heating
value is determined experimentally using the Bomb calorimeter test, in which the heat generated,
at a constant temperature of 25°C from the combustion of a dry sample is measured. Since the
test temperature is below the boiling point of water (100°C), the combustion water remains in the
liquid state. However, during combustion, the temperature of the combustion gases reaches
above 100°C, and the resultant water is in the vapour form. While evaluating incineration as a
means of disposal or energy recovery, one has to consider the heating values of respective
constituents.
Ultimate analysis
This refers to an analysis of waste to determine the proportion of carbon, hydrogen, oxygen,
nitrogen and sulphur, and it is done to perform mass balance calculation for a chemical or
thermal process. Besides, it is necessary to determine ash fraction because of its potentially
harmful environmental effects, brought about by the presence of toxic metals such as cadmium,
chromium, mercury, nickel, lead, tin and zinc. One should note that other metals (e.g., iron,
magnesium, etc.) may also be present but they are non-toxic.
The following table shows an ultimate analysis of a typical municipal solid waste
Carbon 25-30
Hydrogen 2.5-6.0
Oxygen 15-30
Nitrogen 0.25-1.2
Sulphur 0.02-0.12
Ash 12-30
Proximate analysis
This is important in evaluating the combustion properties of wastes or a waste or refuse derived
fuel. The fractions of interest are:
moisture content, which adds weight to the waste without increasing its heating
value, and the evaporation of water reduces the heat released from the fuel;
ash, which adds weight without generating any heat during combustion;
volatile matter, i.e., that portion of the waste that is converted to gases before and
during combustion;
fixed carbon, which represents the carbon remaining on the surface grates as
charcoal. A waste or fuel with a high proportion of fixed carbon requires a longer
retention time on the furnace grates to achieve complete combustion than a waste or
fuel with a low proportion of fixed carbon.
The following table shows an proximate analysis of a typical municipal solid waste
Value (%)
Components
Range Typical
Moisture 15-40 20
Disposal is the final element in the solid waste mangement system. It is the ultimate fate of all
solid wastes, be the residential wastes collected and transported directly to a landfill site,
semisolid waste (sludge) from municipal and industrial treatment plants, incinerator residue,
compost or other substances from various solid waste processing plants that are of no further use
to society. It is, therefore, imperative to have a proper plan in place for safe disposal of solid
wastes, which involves appropriate handling of residual matter after solid wastes have been
processed and the recovery of conversion products/energy has been achieved.
Problems due to improper disposal of wastes
health hazards (e.g., residents in the vicinity of wastes inhale dust and smoke when the
wastes are burnt; workers and rag pickers come into direct contact with wastes, etc.);
pollution due to smoke;
pollution from waste leachate and gas;
blockage of open drains and sewers.
Hence it is very much imminent that safe disposal of solid wastes is important for safeguarding
both public health and the environment.
1. Open dumping
2. Composting
3. Land filling
4. Incineration
5. Gasification
6. Refuse-derived fuel
7. Pyrolysis
Open dumping
Open dumping is an illegal process, in which any type of the waste such as household trash,
garbage, tires, demolition/construction waste, metal or any other material dump at any location
like along the roadside, vacant lots on public or private property even in parks other than a
permitted landfill or facility. Open dumping poses a threat to human health and the environment
because it causes land pollution. In the developing countries, municipal solid waste is commonly
disposed off by discharge the waste in open dumps around 60-90%, which are environmentally
unsafe. Open dumping of nondegradable component like burning of plastic waste is added to
create air pollution and uncollected waste pose serious health hazards. As a result of illegal
dumping, land area such as property value may decrease and also put negative impact on the
scarcity of land in future
Composting
Composting is a natural biological process that carried out under controlled aerobic (requires
oxygen) or anaerobic conditions (without oxygen). Organic waste is biodegradable and can be
processed in the presence of oxygen or in the absence of oxygen using anaerobic digestion.
Anaerobic composting is not common because of the slow degradation rate and produce odorous
intermediate product. Anaerobic digestion however also produces methane gas which is an
important source of bio-energy.
Composting is an efficient method to break down organic materials into an end product which is
beneficial for soil and plants. Compost is used as an organic amendment to improve the physical,
chemical and biological properties of soil. Adding compost helps to increase the ability of the
soil to hold and release essential nutrients.
Composting has a long tradition particularly in rural India. Composting is difficult process
because the waste arrives in a mixed form and contains a lot of non-organic material. When
mixed waste is composted, the end product is of poor quality. The presence of plastic objects in
the waste stream is especially problematic, since these materials do not get recycled or have a
secondary market. In the absence of segregation, even the best waste management system or
plant will be rendered useless. In India, composting is used around 10-12% because composting
needs segregation of waste and sorting is not widely practiced
Landfills
A landfill is an area of land onto or into which waste is deposited. The aim is to avoid any
contact between the waste and the surrounding environment, particularly the groundwater.
Landfilling will usually not be done for the following waste streams in the municipal solid waste:
Biowaste/garden waste
Dry recyclables
Landfills minimise the harmful impact of solid waste on the environment by the following
mechanisms:
1. A liner system at the base and sides of the landfill which prevents migration of leachate
or gas to the surrounding soil.
2. A leachate collection and control facility which collects and extracts leachate from within
and from the base of the landfill and then treats the leachate.
3. A gas collection and control facility (optional for small landfills) which collects and
extracts gas from within and from the top of the landfill and then treats it or uses it for
energy recovery.
4. A final cover system at the top of the landfill which enhances surface drainage, prevents
infiltrating water and supports surface vegetation.
5. A surface water drainage system which collects and removes all surface runoff from the
landfill site.
6. An environmental monitoring system which periodically collects and analyses air,
surface water, soil-gas and ground water samples around the landfill site.
7. A closure and post-closure plan which lists the steps that must be taken to close and
secure a landfill site once the filling operation has been completed and the activities for
long-term monitoring, operation and maintenance of the completed landfill.
Incineration
Incineration is one of the waste treatment technologies that involve the combustion of organic
materials and other substances. This refers to the controlled burning of wastes, at a high
temperature (roughly 1200 – 1500°C), which sterilises and stabilises the waste in addition to
reducing its volume. Hence, Incineration waste treatment system is normally described as
‘thermal treatment’. Incinerator process converts the waste into bottom ash, particulates and heat,
which can be used to generate the electric power. The volume of ash is usually 10% of the
original volume of the waste. Finally, the ash is typically disposed off in the landfill site. In
developing countries, the use of incineration is in few amounts to around 1-5% respectively.
In India the incineration is a poor option as the waste consists mainly high organic material (40–
60%) and high inert content (30–50%) also low calorific value content (800–1100 kcal/kg), high
moisture content (40–60%) in MSW and the high costs of setting up and running the plants.
Gasification
This is the combustible part of raw waste, separated for burning as fuel. Various physical
processes such as screening, size reduction, magnetic separation, etc., are used to separate the
combustibles
Pyrolysis
This is the thermal degradation of carbonaceous material to gaseous, liquid and solid fraction in
the absence of oxygen. This occurs at a temperature between 200 and 900°C. The product of
pyrolysis is a gas of relatively high calorific value of 20,000 joules per gram with oils, tars and
solid burned residue.
As we all know, air is the most essential for our living. A person cannot survive for five minutes
without air. The important life controlling element, viz. air, sometimes becomes an enemy when
it gets polluted. Air pollution is nothing but a system where presence of any substance (solid,
liquid or gas) in the atmosphere in such a concentration that may or may tend to cause injuries to
human, crops or property and to the atmosphere itself. The substances which cause air pollution
are called as air pollutants.
The polluted air affects not only living beings but also non living things and has a deleterious
effect on mankind. Air pollution is a serious problem in many countries of the world. Centre for
Science and Environment (CSE) has observed that air pollution is the fifth leading cause of death
in India after high blood pressure, indoor air pollution, tobacco smoking and poor nutrition, with
about 620,000 premature deaths occurring from air pollution-related diseases. Like China, India
faces an unprecedented public health crisis due to air pollution. Half of the urban population
breathes air laced with particulate pollution that has exceeded the safety standards. As much as
one third of urban population is exposed to critical level of particulate pollution. Smaller cities
are among the most polluted in the country.
The green think tank released its own assessment and the global study's India specific data
during February 2013 warning that the number of premature deaths due to air pollution had
increased six fold over the last 10 years.
Air quality data generated by the Central Pollution Control Board (CPCB) for 2007 under the
National Air Quality Monitoring Programme (NAMP) presents deadly facts about air pollution
levels in Indian cities. CSE has analysed the official data to assess the state of air quality and
trend in Indian cities. The most widely monitored pollutants in India are particulate matter (PM),
nitrogen dioxide (NO2), sulphur dioxide (SO2), and on a limited scale carbon monoxide. Some
of the worst forms of air pollutions are found in Indian cities. The Central Pollution Control
Board (CPCB) considers air to be ‘clean’ if the levels are below 50 per cent of the prescribed
standards for pollutants. During 2007 only 2 per cent cities have low air pollution on the basis of
PM10. In about 80 per cent of cities (of a total of 127 cities/towns monitored under the NAMP) at
least one criteria pollutant exceeded the annual average ambient air quality standards. This has
serious public health implications. There are very few cities, which can be termed clean keeping
PM10 levels (respirable particulates) as criteria however over the years SO 2 levels have fallen
sharply in many cities but the NO2 levels are increasing in many cities.
In past few decades, there has been a large amount of hue and cry regarding the issue of earth
getting hotter and hotter year after year. This concept of global warming is predominantly
because of major changes in the human lifestyle. Generally, green house gases viz., Carbon
dioxide, methane, etc. in the lower atmosphere act as a shield in trapping some of the heat, as it
radiates back to the atmosphere from the Earth. Such gases because of their heat and warmth
have made survival for life on our mother Earth. But when the quantities of these green house
gases increases, excessive heat is generated and makes living almost impossible.
Continuous and excessive burning of fossil fuels increases carbon dioxide level
Large scale decomposition of organic matter in swamps, rice fields, live stock yards
has lead to increase in methane level
Level of Chloro Flouro Carbons (CFCs) increasing due to change in human life style
Acid rain
Rainfall through unpolluted environment is slightly acidic with its pH value ranging just less
than 7. However, when the environment is polluted with primary pollutants like SO x and
NOx gases, the resultant precipitation tends become more acidic. This acidity if because of the
formation of secondary pollutants like sulphuric acid and nitric acid due to the reaction of water
vapour with SOx and NOx gases. It has been specified that when the pH value of rainfall is less
than 5.6 or below, then the rain is specifically termed as acidic.
Photochemical smog
Photochemical smog is a unique type of air pollution which is caused by reactions between
sunlight and pollutants like hydrocarbons and nitrogen dioxide. Although photochemical smog is
often invisible, it can be extremely harmful, leading to irritations of the respiratory tract and
eyes. In regions of the world with high concentrations of photochemical smog, elevated rates of
death and respiratory illnesses have been observed.
Ozone depletion
Ozone depletion is the most dreaded aspect of air pollution, having wide spread implications,
extending over the entire atmosphere. This problem is caused by the reduction of naturally
available ozone layer in the atmosphere. Scientists are also becoming aware of the possible
connection between ozone depletion and climate change due to global warming. The increased
concentrations of green house gases leading to warmer climate at the Earth’s surface, infact
causes cooling effect at altitudes where the ozone layer is found. This cooling of the stratosphere
enhances the chemical reaction that destroys the ozone, leading to further ozone depletion.
Chlorofluoro carbons (CFCs) are the chief agents of ozone destruction. They are largely used
and subsequently released in modern world, in refrigeration, air-conditioning, fire extinguishers.
These inert CFCs do not disintegrate in the lower atmosphere and do rise several kilometers up
into the stratosphere, where they release chlorine atoms in the presence of sunlight. Each
chlorine atom from CFCs then reacts with an ozone molecule forming Chlorine monoxide. The
Chlorine monoxide thus formed, reacts with another oxygen atom to form a new oxygen
molecule and a chlorine atom. The chlorine atoms, thus replenished can go on to break apart
thousands and thousands of more ozone molecules, leading to large scale ozone deficits. It has
been estimated that each atom of chlorine can destroy up to 1 lakh ozone molecules at a faster
rate than the gas is replenished naturally.
It refers to exposure to dust, fumes and gases to which an individual exposes himself when he
indulge himself in smoking
Natural Sources –Volcano, forest fire, dust storms, oceans, plants and trees
-Stationary sources
Area sources (Residential heating coal gas oil, on site incineration, open
burning etc.)
- Mobile sources
The agent causing pollution in air is termed as air pollutant. Air pollutants are broadly classified
into primary and secondary pollutants. This lesson deals with primary pollutants and their
properties.
Primary air pollutants
The atmosphere has hundreds of air pollutants from natural or from anthropogenic sources. All
such pollutants are called as primary pollutants
2. Carbon monoxide
3. Nitrogen oxides
4. Lead
5. Hydrocarbons
6. Radioactive substances
7. Hydrogen sulphide
Sulphur dioxide
Sulphur dioxide is an irritant gas, and when inhaled, affects our mucous membranes. It increases
the breathing rate and causes oxygen deficits in the body, leading to bronchial spasms. Patients
of asthma are very badly affected by this pollutant. Sulphur dioxide is also responsible for
causing acidity in fogs, smokes and in rains and hence is the major source of corrosion of
buildings and metal objects.
Burning of fuels
Carbon monoxide possesses about 200 times affinity for blood haemoglobin than oxygen.
Eventually, then inhaled, CO replaces O2 from the haemoglobin and form what is known as
carboxy-haemoglobin. This carboxy-haemoglobin is of no use for respiratory purposes, and
hence when about half of the haemoglobin of the blood is used up in forming carboxy-
haemoglobin, death becomes a certainty. Persons dying of carbon monoxide inhalations exhibit
characteristics bright pink colour of the flesh due to the presence of pink coloured carboxy-
haemoglobin in their bloods.
Carbon monoxide also affects the central nervous system, and is even responsible for heart
attacks, and high mortality rates.
Carbon monoxide chiefly originates from automobile exhausts, and is caused by incomplete
combustion of organic matter.
Oxides of Nitrogen
Nitric oxide and Nitrogen dioxide are found to be injurious to human health. Nitrogen dioxide is
more injurious than nitric oxide.
Eye and nasal irritations are the common problems caused by nitrogen dioxide. Also respiratory
discomfort occurs with brief exposure to NO2.
Hydrogen sulphide
It is a foul smelling gas with a typical odour of rotten egg. Exposure to hydrogen sulphide for
short periods may lead to loss of smell sense . This gas may also cause headaches,
conjunctivitis, sleepnessness and pain in the eyes. Its higher concentration may block oxygen
transfer and damage the nerve tissues. However, hydrogen sulphide is generally not found in
any trouble some concentrations in our atmosphere mainly because it is not emitted in
automobile exhausts.
Lead
Lead is mainly injected into the atmosphere through the exhausts of automobiles, particularly, by
automobiles running on petrol. The concentrations of lead in inhaled air, may cause irritation of
mucous membranes of nose, throat and lungs. Lead poisoning may also cause damage to gastro-
intestinal tracts, liver and kidney. It may also cause abnormalities in preganancy and fertility.
Lead poisoning is also found to be responsible for retarding mental growth in children.
Hydrocarbons
The compounds containing only hydrogen and carbon are hydrocarbons. Hydrocarbons are
chiefly released into the atmosphere by automobile exhausts. Substances like formaldehyde
cause irritation of eyes, skins and lungs and hence may be quite injurious to health
Radioactive isotopes
The radioactive isotopes viz., Strontium-90, Cesium-137 and Iodine-131 have been the main
products of atomic explosives and accidental discharges from atomic and nuclear reactors;
although, however, other isotopes may also be present. The serious health hazards caused by
such radioactive emissions are anemia, cancers, shortening of life spans and above all the genetic
effects, like sterility, embroyo defects, congenital malformations, etc. Radioactivity is notorious
for its delayed and long term evil effects on human health.
5.14 Types of secondary air pollutants and their properties
INTRODUCTION
This lesson deals with secondary air pollutants and their properties.
The primary pollutants often react with one another or with water vapour, in the presence of
sunlight to form entirely a new type of pollutants called / termed as secondary air pollutants.
These types of pollutants are the chemical substances, which are produced from the chemical
reactions of natural or anthropogenic air pollutants or due to their oxidation caused by the energy
of the sun.
There are two main reasons for making distinction between primary and secondary air
pollutants. First, in order to perform and interpret atmospheric chemical research, one must
distinguish between primary and secondary air pollutants. The second reason is that emission
controls can only be effectively treated at primary anthropogenic air pollutants, their formation
process must be understood and somehow interrupted. Controlling the air concentrations of
primary anthropogenic pollutants is much easier than controlling the concentrations of secondary
pollutants. The distinction between primary and secondary air contaminants is not always clear,
as the same chemical can either be directly emitted into or formed by reactions in the air.
As secondary air pollutants are mainly formed by chemical reactions, and chemical reactions
usually produce products that are less reactive than their reactants, it would be convenient to
assume that secondary pollutants are more inert than primary pollutants. In many cases, it is
true. However, as sunlight drives many atmospheric reactions, additional energy can be found in
some secondary pollutants.
Sulphuric acid
Ozone
Formaldehyde
Peroxy-acetyl-nitrate (PAN)
Sulphuric acid
It is formed by the simple chemical reaction between sulphur dioxide and water vapour, and is
much more toxic pollutant than sulphur dioxide having far reaching effects on environment since
it causes acid rain.
Ozone
Ozone is a primary example of a very reactive secondary air pollutant. Thus photoactivation can
produce highly reactive products. The peak concentration of ozone is built late in the day, after
the sun has had time to drive their formation.
Since ozone has been generally found to occur in the highly motorized areas, particularly during
day time, it is believed that it is produced by the photochemical reaction of hydrocarbons and
nitrogen oxide. Possibility of formation of such photochemical smog is quite high in places
where number of plying automobiles is too high and where inversion smog conditions prevail in
the atmosphere.
The presence of ozone gas in the air may cause irritation in the respiratory tract, reaching much
deeper into the lungs than the oxides of sulphur.
Formaldehyde
Formaldehyde is an organic chemical that is very prevalent in our environment. It has colorless
gas with a pungent odor from a family of gases called aldehydes. Commonly known as a
preservative in medical laboratories and mortuaries, formaldehyde is also found in other products
such as chemicals, particle board, household products, glues, permanent press fabrics, paper
product coatings, fiberboard and plywood. It is a sensitizing agent that can cause an immune
system response upon initial exposure. It is also a suspected human carcinogen that is linked to
nasal cancer and lung cancer. Formaldehyde exposure is most common through gas-phase
inhalation.
Peroxy-acetyl-nitrate (PAN)
Peroxyacetyl nitrate, or PAN, is an oxidant more stable than ozone. Hence, it is better capable of
long-range transport than ozone. It serves as a carrier for oxides of nitrogen (NOx) into rural
regions and causes ozone formation in the global troposphere.
The formation of PAN on a secondary scale becomes an issue when ethanol is used as an
automotive fuel. Acetaldehyde emissions increase, which subsequently react in the atmosphere
to form smog. Whereas ethanol policies solve domestic oil supply problems, they drastically
exacerbate air quality conditions
Peroxy acetyl nitrate irritates the eyes resulting in blurred vision and eye fatigue. It decreases
vital capacity due to decrease in both inspiratory capacity and expiratory reserve volume.
Air pollutants have a deleterious impact on both living and non-living beings. In this lesson, you
will be learning about the effects of air pollution on living and non-living beings
Effect of Acid rain
When an air pollutant, such as sulphuric acid combines with the water droplets that make up
clouds, the water droplets become acidic. When those droplets fall to the ground as rain or snow,
the acidity of the water can have damaging effects on the environment. When acid rain falls over
an area, it can kill trees and harm animals, fish, and other wildlife. Acid rain destroys the leaves
of plants. When acid rain infiltrates into soils, it changes the chemistry of the soil making it unfit
for many living things that rely on soil as a habitat or for nutrition. Acid rain also changes the
chemical properties of the lakes and streams that the rainwater flows into, harming fish and other
aquatic life.
Air pollutants called chlorofluorocarbons (or CFCs) destroy ozone molecules in the stratosphere.
This has left places in the layer where the ozone is thin. These areas of thin ozone are
called ozone holes. The ozone layer, located in the stratosphere layer of Earth’s atmosphere,
shields our planet from the Sun’s ultraviolet radiation. Ultraviolet radiation causes skin cancer
and damages plants and wildlife.
Ozone molecules in the troposphere damage lung tissues of animals and prevent plant respiration
by blocking the openings in leaves, called stomata, where respiration occurs. Without sufficient
respiration, a plant is not able to photosynthesize at a high rate and will not be able to
grow. Ozone is also able to enter the stomata and decay plant cells directly.
Our planet is currently warming much more rapidly than expected because of
additional greenhouse gasses that are released into the atmosphere from air pollution. When fuels
are burned, some of the pollutants released, such as carbon dioxide, are greenhouses gasses.
Through the process of photosynthesis, plants convert carbon dioxide into oxygen and use the
carbon to grow larger. However, the amount of carbon dioxide released by burning fuels is far
greater than plants can convert. Cutting down forests exacerbates the problem
The health effects vary greatly from person to person. High-risk groups such as the
elderly, infants, pregnant women, and sufferers from chronic heart and lung diseases
are more susceptible to air pollution.
Exposure to air pollution can cause both acute (short-term) and chronic (long-term)
health effects.
Acute effects are usually immediate and often reversible when exposure to the
pollutant ends. Some acute health effects include eye irritation, headaches, and
nausea.
Chronic effects are usually not immediate and tend not to be reversible when
exposure to the pollutant ends. Some chronic health effects include decreased lung
capacity and lung cancer resulting from long-term exposure to toxic air pollutants.
Effects on human respiratory system
Both gaseous and particulate air pollutants can have negative effects on the lungs.
Solid particles can settle on the walls of the trachea, bronchi, and bronchioles.
Continuous breathing of polluted air can slow the normal cleansing action of the
lungs and result in more particles reaching the lower portions of the lung.
Damage to the lungs from air pollution can inhibit this process and contribute to the
occurrence of respiratory diseases such as bronchitis, emphysema, and cancer.
Effect of different air pollutants on living beings
Carbon monoxide
CO (carbon monoxide) combines with haemoglobin to lessen the amount of oxygen that enters
our blood through our lungs. The effect of carbon monoxide leads to headaches, reduced mental
alertness, heart attack, cardiovascular diseases, impaired fetal development, death.
Sulphur dioxide
It can oxidize and form sulphuric acid mist. Thus, presence of sulphur dioxide is responsible for
causing acidity in rains and hence causes corrosion of metal objects and buildings. SO2 in the
air leads to diseases of the lung and other lung disorders such as wheezing and shortness of
breath. Sulphur dioxide also causes eye irritation, chest tightness.
Nitrogen dioxide
Eye and nasal irritations are the common problems caused by nitrogen dioxide. Nitrogen
dioxide also results in respiratory infections, irritation of the lung and respiratory symptoms
(e.g., cough, chest pain, difficulty breathing).
Ozone
Exposure to Ozone leads to eye and throat irritation, coughing, respiratory tract problems,
asthma, lung damage.
Lead
Lead is responsible to anemia, high blood pressure, brain and kidney damage and neurological
disorders. Prolonged exposure can cause damage to the nervous system, digestive problems, and
in some cases cause cancer. It is especially hazardous to small children.
Particulate matter
Presence of particulate matter leads to eye irritation, asthma, bronchitis, lung damage, cancer,
heavy metal poisoning, cardiovascular effects.
Volatile compounds can cause irritation of the eye, nose and throat. In severe cases there may be
headaches, nausea, and loss of coordination. In the longer run, some of them are suspected to
cause damage to the liver and other parts of the body.
Formaldehyde
Exposure to formaldehyde causes irritation to the eyes, nose and may cause allergies
Annual Average* 50 20
Sulphur Dioxide (SO2), μg/m3
24 hours** 80 80
Annual Average* 40 30
Oxides of Nitrogen as (NO2) ,
μg/m3
24 hours** 80 80
8 hours 2 2
Carbon Monoxide (CO) ,
mg/m3
1 hour 4 4
* Annual arithmetic mean of minimum 104 measurements in a year at a particular site taken
twice a week 24 hourly at uniform intervals
The CPCB has evolved a format for preparation of action plans, which has been circulated to all
State Pollution Control Boards/Committees. The action plans emphasize identification of sources
of air pollution, assessment of pollution load and adoption of abatement measures for identified
sources. Setting up interdepartmental task force for implementation of city specific action plan
has also been suggested.
In order to control vehicular pollution, a road map has been adopted as per the schedule proposed
in Auto Fuel Policy, which includes use of cleaner fuels, automobile technologies and
enforcement measures for in use vehicles through improved Pollution Under control (PUC)
certification system. As per the Auto Fuel Policy, Bharat Stage-II norms for new vehicles have
been introduced through out the country from first April, 2005. However, EURO-III equivalent
emission norms for all new vehicles, except 2-3 wheelers, have been introduced in 11 major
cities from April 1, 2005. To meet Bharat Stage-II, EURO-III and EUROIV emission norms,
matching quality of petrol and diesel is being made available.
The damage caused by disasters is immeasurable and varies with the geographical location,
climate and the type of the earth surface/degree of vulnerability. At times there can be disasters
where there is no loss of human life and at times these can also cause a huge loss of life and
property. This influences the mental, socio-economic, political and cultural state of the affected
area. A disaster can be caused by human activities or due to some natural changes. Disasters are
events that are unpredictable most of the times. It is important for any government, state or
community to manage disasters by being prepared for it in advance. The government provides
legislation, allocates resources and does the rational planning and sustainable development.
Disaster management and planning is a key part of government work and an issue to be taken up
seriously by the concerned authorities.
Effects of Disaster
A disaster is an event of sudden calamity causing disruption in normal routing and causing a lot
of destruction depending upon the intensity of the disaster. Generally, disaster has the following
effects in the concerned areas:
Types of Disasters
Disasters are inevitable; there is no country that is immune from disaster, though vulnerability to
disaster varies. Generally, disasters are of two types – Natural Disasters and Manmade Disasters.
Based on the devastation caused and intensity of the disaster, these are further classified into
major/minor natural disaster and major/minor manmade disasters. Some of the disasters are
listed below:
Natural Disasters:
Natural disasters are generally unpredictable types of disasters and the destruction caused by
these depends upon the intensity of the disasters. These disasters include floods, hurricanes,
earthquakes and volcano eruptions that can have immediate impacts on human health, as well as
secondary impacts causing further death and suffering from floods causing landslides,
earthquakes resulting in fires, tsunamis causing widespread flooding and typhoons sinking
ferries. Majorly the cause of these disasters is the change in climate as well as the movements
inside the earth like moving of tectonic plates or lava. Depending upon the intensity as well as
the destruction caused these can be classified as:
Major Natural Disasters: Major natural disasters include the events of the high-
intensity earthquake, floods, cyclone, flash floods, some major landslides and event of
draught. These disasters generally cause a high loss of life and property and also lead to
displacement of a lot of people from their shelters. Generally, these disasters pose a major
threat to the developmental projects as well as the infrastructure of a particular area.
Preparedness against these disasters should be on the top of the priority list.
Minor Natural Disasters: Cold wave, heavy rains causing disruption in normal life, heat
wave, thunderstorms, mudslides, some minor landslides and low-intensity earthquakes
can be few cases of minor natural disasters. These disasters do not cause much loss in the
terms of human life as well as property. Though, if care is not taken then these can prove
to be fatal for human beings. There is generally not much need for disaster preparedness
at the community level but this kind of disaster requires personal preparedness and
awareness against these disasters. For example, there can’t be disaster preparedness for
heat-wave or cold wave at the community level; it is our own responsibility to take care
of ourselves in the event of severe cold and heat.
Man-made Disasters:
These are the disaster generally taking place due to human activities and human negligence and
can lead to a lot of destruction in the terms of life and property. At times these are really fatal
and sometimes these could be a minor event of an emergency and can be handled at the
personal level. At most of the times, these take place due to human negligence and hence are
unpredictable most of the times, however, the events of wars, attacks etc are predictable
disasters. The loss taking place due to these disasters depends upon the intensity of these
disasters. These can be classified as:
Major Man-made Disaster: Some major man-made disasters may include the events of
forest-fires, event of wars, nuclear attack, major fires, industrial accidents as well as the
event of building collapsing or accidents at construction sites causing a lot of loss and
damage. Generally, the events leading to human negligence such as industrial accidents,
events of fires and construction accidents are unpredictable and cause a major loss in the
terms of life and infrastructure. Some major events of industrial fires have been reported
in past years that have led to the death of a lot of workers and reported a huge loss of
material and machinery. It is advised to have an emergency preparedness for evacuation
in the events of an emergency and also industrial units should be vigilant and install all
the safety gears as well equipment such as fire extinguishers and emergency alarms in the
plant.
Minor Man-made Disasters: Some events of train or road accidents, minor household
fire, food poisoning, minor industrial accidents, events of looting, terrorist attacks or
event of a fire at shops etc resulting mostly out of personal negligence is termed as minor
man-made accidents. These do not lead to a high loss of life through loss of property may
be evident in such cases. Personal awareness and caution can help you avert such
incidents as well as to escape unhurt in case of such disasters. Hence it is advised to be
cautious and vigilant to avoid such incidents.
Disaster Preparedness
Disaster preparedness or disaster management activities are aimed to minimize loss of life and
damage in the event of a disaster. Disaster management forces can help by removing people and
property from a threatened location and by facilitating timely and effective rescue, relief and
rehabilitation at the place of disaster. Preparedness is the only way of reducing the impact of
disasters as most of the disasters are unpredictable and even if predicted, there is not much time
to act. Community-based preparedness and management should be a high priority in physical
therapy practice management. Also, it should be the main agenda of the government to appoint a
proper department dealing with the disaster management and preparedness. Every municipality
must have a disaster management plan as part of its Integrated Development Plans, according to
the Municipal Systems Act. The local authorities should be empowered to act as soon as possible
in the event of a disaster. It may take time to get relief and rescue operation to start, so in the
meantime, it is the role of Municipal disaster management team to provide rescue work as soon
as disaster strikes. Disaster Management has four phases namely:
Mitigation: Mitigation can be defined as the effort to reduce the loss of life and property
in the event of a disaster by lessening the impact of disasters. Mitigation is taking action
now before the next disaster to reduce human and financial consequences later.
Mitigation involves analyzing risk, reducing risk and ensuring against risk. Personal
mitigation is a key to national preparedness. Individuals and families train to avoid
unnecessary risks. This includes an assessment of possible risks to personal/family health
and to personal property. Effective mitigation at the time of disaster requires that we all
understand local risks, address the hard choices, and invest in long-term community well-
being. Without mitigation actions, we jeopardize our safety, financial security, and self-
reliance. For effective mitigation, coordination, planning, and mock activities are very
important. Disasters can happen at any time and anyplace; their human and financial
consequences are hard to predict, preparedness is the only solution.
Rescue: Disaster can strike any place at any time. The response phase of an emergency
may commence with search and rescue but in all cases, the focus will quickly turn
to fulfil the basic humanitarian needs of the affected population. The assistance may be
provided by national or international agencies and organizations but it is the role of local
bodies to act as soon as possible. Effective coordination of disaster assistance is often
crucial, particularly when many organizations respond and local emergency management
agency capacity has been exceeded by the demand or diminished by the disaster itself.
Rescue operation involves providing medication to those hurt and taking people out of
the affected area and debris in the events of earthquake and floods etc. There are various
rescue teams at national and state level which come into action as soon as disaster strikes.
But it is also better if local authorities are also trained as they have the best knowledge
about the geographical location and other local conditions.
Relief: This is a coordinated multi-agency response to reduce the impact of a disaster and
its long-term results. Relief operation starts as soon as disaster strikes and the
main emphasis is laid on providing injured with medication and providing food as well as
clean drinking water to the people. Relief activities include rescue, relocation, providing
food and water, preventing disease and disability, repairing vital services such as
telecommunications and transport, providing temporary shelter and emergency health
care. It is very important to provide relief operation as soon as possible to minimize the
number of causalities and to provide relief for injured. The relief workers are trained in
basic first aid and medication and are also given training on
maintaining coordination even in the event of a crisis. The relief operation is best
supported only when carried out as a teamwork and all the members of the
team should coordinate well with each other and also support one another without any
discrepancy.
Rehabilitation: As soon as disaster strikes the first thing that comes to mind is relief and
rescue operations. Once emergency needs have been met and the initial crisis is over, the
people affected and the communities that support them are still vulnerable and it is time
to start rehabilitation activities. Rehabilitation activities include rebuilding infrastructure,
health care, and other basic necessities. These should blend with development activities,
such as building human resources for health and developing policies and practices to
avoid similar situations in the future. The immediate goal of the rehabilitation phase is to
bring the affected area back to some degree of normalcy and to get back to the normal
situation as soon as possible. During reconstruction, it is recommended to consider the
location or construction material of the property and it should not be hurried rather
reconstruction should be done properly and effectively.
Disaster management aims to reduce the occurrence of disasters and to reduce the impact of
those that cannot be prevented. The government White paper and Act on Disaster Management
define the roles of Local Authorities as well as Provincial and National government in disaster
management. Disaster management forces come into action as soon as a disaster strikes and help
out in the relief, rescue and rehabilitation process. These are trained individuals and are given
extensive training to perform in the event of a disaster or a natural calamity and they work as a
team to reduce the loss of life and helping the locals getting back to normal life.