01-05-2022 - Incoming SR - Super60 - Jee-Adv (2019-P1) - WTA-25 - Q.Paper
01-05-2022 - Incoming SR - Super60 - Jee-Adv (2019-P1) - WTA-25 - Q.Paper
PHYSICS:
Total
+Ve - Ve
Section Question Type No.of Qs mar
Marks Marks
ks
Sec – I(Q.N : 1 – 4) Questions with Single Correct Choice 3 -1 4 12
Sec – II(Q.N : 5 – Questions with Multiple Correct
4 -1 8 32
12) Choice
Sec – III(Q.N : 13 – Questions with Numerical Value
3 0 6 18
18) Answer Type
Total 18 62
CHEMISTRY:
Total
+Ve - Ve
Section Question Type No.of Qs mar
Marks Marks
ks
Sec – I(Q.N : 19 – 22) Questions with Single Correct Choice 3 -1 4 12
Sec – II(Q.N : 23 – Questions with Multiple Correct
4 -1 8 32
30) Choice
Sec – III(Q.N : 31 – Questions with Numerical Value
3 0 6 18
36) Answer Type
Total 18 62
MATHEMATICS:
Total
+Ve - Ve
Section Question Type No.of Qs mar
Marks Marks
ks
Sec – I(Q.N : 37 – 40) Questions with Single Correct Choice 3 -1 4 12
Sec – II(Q.N : 41 – Questions with Multiple Correct
4 -1 8 32
48) Choice
Sec – III(Q.N : 49 – Questions with Numerical Value
3 0 6 18
54) Answer Type
Total 18 62
PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
z0
gz gz
2 2
A) z 0e v
B) z 0e v
gz 2
3
gz
C) z 0 ln 2 D) z 0e v
v
3. A smooth string of uniform mass density is connected with two hanging blocks of masses
M and 2M after passing over the smooth massless pulleys P and Q. If the mass of the
string between P and Q is m (m<<M) and it’s length as shown. Find the time taken by a
transverse pulse generated at P to move between P and Q if the system is released from
rest at time t = 0 sec. [neglect the pulleys dimensions]
l
P Q
M 2M
3ml 3l 4M 4M
A) B) 2
4Mg g m m
3l 4M 4M 3
C) 2 D)
g m m g
4. A uniform rope with length L and mass m is held at one end whirled in a horizontal circle
with angular velocity . You can ignore the force of gravity on the rope. Find the time
required for a transverse wave to travel from one end of the rope to the other.
2 2 2
A) B) C) D)
2
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONE OR MORE than ONE
option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
5. A plane progressive wave is advanced in a medium along the +x –axis in the ground
frame of reference is represented by the equation y A sin t kx then which of the
following statements is/are correct?
A) When the observer is moving along the positive x axis with a uniform velocity
V0 V0 and starting from the origin then the wave equation in the observer’s frame of
k
reference is y A sin kV0 t kx .
B) When the observer is moving along the negative x-axis with a uniform velocity
V0 V0 and starting from the origin then the wave equation in the observer’s frame of
k
reference is y A sin kV0 t kx
C) When the observer is starting from rest from the origin with a uniform acceleration a 0
along the positive x-axis then the wave equation in the observer’s frame of reference
1
y A sin t ka 0 t 2 kx .
2
D) When the observer is starting from rest from the origin with a uniform acceleration a 0
along the positive x – axis then the wave equation in the observer frame of reference
y A sin t ka 0 t 2 kx .
6. A harmonic progressive wave produced by a distant source is travelling through your
vicinity and wavefronts that travel through your vicinity are vertical planes. Let +x
direction is to be east and +y direction be toward north. The wave function of wave is:
p x, y, t A cos k x x k y y t .
ky
A) Direction of wave propagation is at an angle cot 1 with + x axis
kx
ky
B) Direction of wave propagation is at an angle tan 1 with +x axis
kx
C) Wave speed is
kx ky
D) Wave speed is
k 2x k 2y
7. Consider a very small element of length dx in a string in which a plane progressive
travelling sinusoidal wave moves along the positive x-direction. Let the energy of this
element be E and let the rate of change of energy of this element be P. Then,
A) P is positive if the slope of the element and displacement of element from mean
position are both positive
B) P is negative if the slope of the element and displacement of element from mean
position are both negative
C) P is negative if the velocity of the element and displacement of element from mean
position are both negative
D) P is positive if the velocity of the element and displacement of element from mean
position are both positive
8. A string wave is represented by y A sin kx t . Snapshot of string at t = 0 is shown in
the diagram. Let R A , R B , R C & R D represent rate of change of mechanical energy of a small
element of string located at A, B, C & D respectively. Then choose the CORRECT option
2
(s) ; Assume A .
k
y
A) R A R B R C R D
B) R A and R B are positive, while R C and R D are negative
C) R B and R D are positive, while R A and R C are negative
D) R A and R C are positive, while R B and R D are negative
9. One end of a rope of length L is tied to the ceiling of a lift accelerating upwards with
acceleration 2g. The linear mass density of the string varies linearly from 0 to 0 from
bottom to top. A wave pulse is started at the free end of the rope
A) The velocity of pulse at a distance x from the free end of the rope is 3gx
B) The velocity of pulse at a distance x from the free end of the rope is 3gx / 2
C) The acceleration of pulse is 3g / 2
D) The time taken by a pulse to reach bottom to top is 8L / 3g
10. A transverse wave is travelling along a string from left to right . The adjoining figure
represents the shape of the string at a given instant . At this instant, among the following,
choose the correct statements(s)
A) Points D,E and F have upwards velocity.
B) Points A,B and H have downwards velocity.
C) Points C and G have zero velocity.
D) Points A and E have minimum velocity
11. A travelling transverse wave is propagating in a string consider an element of string
which is at it’s mean position or extreme position of oscillation. Which of the
following option(s) is/are CORRECT
A) KE is maximum at mean position B) KE is maximum at extreme position
C) PE is maximum at mean position D) PE is maximum at extreme position
12. A sinusoidal progressive wave is generated in a string. It’s equation is given by
y 2 mm sin 2 x 100t / 3 . The time when particle at x = 4 m passes through mean
position, will be ( x is in m and t is in second)
1 1 1 1
A) sec B) sec C) sec D) sec
150 12 300 100
SECTION – III
(NUMERICAL VALUE TYPE)
This section contains 6 questions. Each question is numerical value type. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded-off to second decimal place. (e.g. 003.2343, 6.250023, 7.000000, ‐0.33, ‐.30, 30.27000, ‐127.0030).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
13. The linear mass density of a wire AB which is under uniform tension T, varies linearly
from 1 to 2 with x co-ordinate. The length of the wire is L and it is clamped at both the
ends. The end A of the wire is placed at x = 0 and another end B of the wire is placed at x
= L. If a wave pulse is generated at point A (x = 0) then its observed that wave pulse
reaches the end B after a time of t 0 . It is given that t 0 is given by the expression
pL 3/2
2 1
3/2
14. A string wave is represented by y A cos kx t , what will be the ratio of mechanical
5 5 3
energy stored in the string between x to x and x to x at time t ;
k 4k 4k 2k 2
2
Assume A
k
15. The speed of longitudinal wave is 100 times, then the speed of transverse wave in a brass
wire. The Young’s modulus of brass is 1.0 1011 N / m 2 .Longitudinal stress in the wire is
N
x 107 . Find the value of x.
m2
16. A copper wire is held at the two ends by rigid supports. At 30C the wire is just taut, with
negligible tension. Find the speed of transverse waves in this wire at 10C
( 1.7 105 / C , Y 1.3 1011 N / m 2 , d 9 103 kg / m3 ).
The speed of transverse waves in this wire in m/s is:
(Give your answer in nearest integer)
17. A transverse wave of amplitude 0.50 mm and frequency 100 Hz is produced on a wire
stretched to a tension of 100 N. If the wave speed is 100 m/s, what average power is the
source transmitting to the wire? (Give your answer in mW, in nearest integer)
18. A harmonic transverse progressive wave is represented by y 4 mm sin 20 x 100t ;
6
where y (in mm) is displacement of medium particle from its mean position at x (in m), t
is time (in s). What will be the magnitude of acceleration (in m / s2 ) of medium particle
whose displacement from mean position is y =2 mm
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
CH 3Cl H 2 SO4 SO3 Cl2 H 3O KMnO4 / H NaOH CaO
AlCl3
A heat
B
AlCl3
C
heat
D
E
F. Find F
19.
COOH CH 3
Cl COOH
Cl Cl
Cl SO3 H
A) B) C) D)
O
O
O
NO2 BF4
20. Products.
The product that is least likely to be formed is
O
O
O
NO2
A)
O
O
O
B) NO2
O
O
O
ON
C) 2
D) Products given in options A,B and C are formed in equal percentages
21. Which of the following compounds undergo bromination by electrophilic aromatic
substitution reaction at the fastest rate ?
N
A) B) H
NH
NH
C) D) O
22. The decreasing order of reactivity towards electrophilic substitution reaction of the
following compounds.
Aniline Chlorobenzene Nitrobenzene Cyanobenzene is
(1) (2) (3) (4)
A) 1 > 3 >4>2 B) 4 >1 >3 >2 C) 1 >2 >4>3 D) 4 >2 >1 >3
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONE OR MORE than ONE
option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
23. Which of the following reaction(s) is (are) least likely to take place through Friedel-craft’s
acylation as per expectation?
NH2
CH(CH 3)2
CH3CH2COCl CH 3CH 2COCl
AlCl3
AlCl 3
A) B)
CH3
Br
O
C
CH 3CH 2COCl CH(CH3) 2 CH 3CH 2COCl
AlCl 3 AlCl 3
C) D) O 2N
24. Consider the reactions
Cl
(I)
AlCl3
Cl
and (II) O N2 H4
AlCl3 OH–
The INCORRECT statement(s) among the following is (are):
A) Major products of both reactions are same
B) In major Product of (I) benzene ring is activated for EAS but in (II) it is deactivated
C) Major products of both reactions are different but stereo isomers
D) Major products of both reactions are different but structural isomers
25. Correct statement(s) regarding substitution in benzene ring is (are)
A) Among halogens fluorine is the least deactivating group.
B) Halogens direct the incoming electrophile to ortho and para positions during
electrophilc substitution reactions of halobenzenes
C) Halogens are activating groups as they are +R groups.
D) Halobenzenes react at a faster rate than benzene towards nitration.
26. Which of the following is(are) correct statement(s)? (H,D,T are isotopes of hydrogen)
A) If the rate determining step (RDS) involves removal of proton then C6H6 reacts faster
than C6D6
B) The rate of nitration – C6H6> C6D6> C6T6
C) The rate of sulphonation C6H 6> C6D 6> C6T6
D) Bond energy of C H C D C T
27. The major product (D) in the following reaction sequence is
O
Cl
Zn(Hg) / HCl Br2 / h alC
(CH 3)3KOH
COK
A B C D major
AlCl 3
A) B)
C) D)
28. Which of the following will undergo nitration faster than benzene:
A) B)
O
Cl
NH-C-CH3
C) D)
29. The major product of the following reaction is
OH
CH3
CH3 HF/BF3
CH3
CH3
CH3 CH3
CH3
A) CH3 B) CH3
CH3
CH3
CH3
CH3
CH3 CH3
C) D)
BF3
+ FCH2CH2Br Product
30.
The predominant product is :
CH2CH2F CH2CH2Br
A) B)
CH3
C) D)
SECTION – III
(NUMERICAL VALUE TYPE)
This section contains 6 questions. Each question is numerical value type. For each question, enter the correct numerical value (in decimal notation,
truncated/rounded-off to second decimal place. (e.g. 6.250023, 7.000000, ‐0.33, ‐.30, 30.27000, ‐127.0030).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
31. The number of compounds among the following , which undergo Friedel –
Crafts acylation is
CHO CH3 NH2 Cl
(ix)
32. How many of the following compounds are less reactive than chlorobenzene
towards nitration?
CH3
OH NMe2
O CH3
F NO2 O O
CN CHO OMe
Br
Br2 , h
33. Cx H y organic compound A
monobromination Product Enantiomeric pair
A doesn’t decolourize
bromine water or Bayer’s Reagent but can form three isomeric mono bromo derivatives (including major
as well as possible minor products) different yields on heating with Br2 / Fe through electrophilic aromatic
substitution. What can be the minimum number of carbon atoms possible for the organic
compound A?
34. From which position does NO2+ replace predominantly a H from the following
compound?
H
N
1
O
2
3 4
5 8
6 7
35. The number of moles of electrons transferred per mol of toluene when it is
converted into benzoic acid is X . The number of moles of electrons transferred
per mol of nitrobenzene when it is converted into Aniline is Y then the value of
X Y ____
36. Molecular weight of the organic compound (in grams) formed on treating benzene with
excess of Chlorine in the presence of anhydrous AlCl3 is ____
(Atomic Weights: C=12, H=1, Cl=35.5, Al=27)
MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
37. If the lines 2x+3y+1=0 , 6x+4y+1=0 intersect the co-ordinate axes in 4 points, then the
circle passing through the points is
A) 12x 2 12y2 8x 7y 1 0 B) 12x 2 12y2 8x 7y 1 0
C) 12x 2 12y2 8x 7y 3 0 D) x 2 y2 4x y 3 0
38. The number of points a 1,a , where a is an integer lying inside the region bounded by the
circles x 2 y2 2x 1 0 and x 2 y2 2x 17 0 , is
A) 2 B) 4 C) 1 D) 0
39. Consider 3 non collinear points A,B,C with coordinates 0, 6 , 5,5 1,1 respectively.
Equation of a line tangent to the circle circumscribing the triangle ABC and passing
through the origin is
A) 2x-3y = 0 B) 3x+2y = 0 C) 3x-2y = 0 D) 2x+3y = 0
2 2
40. A triangle ABC is inscribed in the circle x y 25 . If the coordinates of B and C are
3, 4 and 4,3 respectively, then BAC can be equal to :
A) B) C) D)
4 2 3 6
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONE OR MORE than ONE
option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
41. Equation of Circle(s) touching X-axis at a distance 3 units from the origin and having an
intercept of length 2 7 units on Y-axis can be
A) x2 y 2 6 x 8 y 9 0 B) x2 y 2 6 x 7 y 9 0
C) x 2 y 2 6 x 8 y 9 0 D) x2 y 2 6 x 7 y 9 0
42. Given two points A 1,3 and B 3,5 . Let S be the locus of point(s) P such that
APB , then which of the following option(s) is/are correct ?
2
A) S will satisfy the equation x 1 x 3 y 3 y 5 0
B) 2 x y 2 is a normal to S at some point on it.
C) From the point O 0, 0 , two tangents are drawn to S. Q and R are point of contacts of
1
tangents with S, then circumcentre of the triangle OQR is , 2
2
D) 2 x y 1 0 is a tangent to S
43. The equation of the circle passing through (1,2), (2,4) and (6,7) is x 2 y 2 2 gx 2 fy c 0 .
Then equation of the circle through
A) 2, 1 , 4, 2 and 7, 6 is x 2 y 2 2 gy 2 fx c 0
B) 2,1 , 4, 2 and 7, 6 is x 2 y 2 2 gy 2 fx c 0
2 2
C) 0,1 , 1,3 and 5, 6 is x 1 y 1 2 g x 1 2 f y 1 c 0
D) 2, 4 , 4,8 and 12,14 is x 2 y 2 4 gx 4 fy 4c 0
44. Given curve xy 3 x 2 y 13 intersects the line 2 x 3 y 1 at A and B. And given points
P ( 2, 4) and Q (4,8) .Then, which of the following Option(s) is/are correct?
A) APB is acute angle B) AQB is acute angle
C) APB is obtuse angle D) AQB is obtuse angle
3
45. Given circle x 2 y 2 4 3 2 ,three points A , B , C taken on the given
6 10 3
circle where P means point P
6 2 cos ,
6 2 sin .Tangents at A,B intersect at
D, and tangents at B and C intersect at E and tangents at C and A intersect at F, then
which of the following options is/are not true?
A) Perimeter of triangle DEF is 2 24 8 units
49. ABCD is a square of unit area. A circle is tangent to two sides of ABCD and passes
through exactly one of its vertices. The radius of the circle is r , then the value of r 2
is
50. Tangents are drawn to x 2 y 2 16 from P 0, h . These tangents meet X-axis at A and B. If
the area of PAB is minimum, then value of h 2 is
51. If the tangents are drawn from any point on the line x+y = 3 wherever possible to the
circle x 2 y 2 9 , then the chord of contact passes through the fixed point a, b then
ab
52. If eight distinct points can be found on the curve x y 1 such that from each point two
mutually perpendicular tangents can be drawn to the circle x 2 y 2 a 2 then the range of
1 1
a is , , where ___ . is G.I.F
53. Tangents are drawn from external point P (6,8) to the circle x2 y 2 r 2 . Then the radius
r of circle such that area of triangle formed by the tangents and chord of contact is
maximum is
54. If the radius of the circumcircle of the triangle TPQ, where PQ is chord of contact
corresponding to point T with respect to circle x 2 y 2 2 x 4 y 11 0 is 6 units, then
minimum distance of T from the director circle of the given circle is d , then the value of
d 4 2 is