C HE M I S T R Y

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE
ST


INFORM AT IO
NO. 01
MOLE CONCEPT
Topic : Mole Calculation

1. 1 mole by definition represents same number of particles as :

16
(A) Number of atoms present in exactly 8 g of 8O isotope.

(B) Number of molecules in exactly 2 g of H2 gas.

16
(C) Number of atoms present in exactly 16 g of 8O isotope.

(D) Number of atoms present in exactly 12 g of 126 C isotope.

2. The weight of a molecule of the compound C6H12O6 is about :

(A) 180 g (B) 3 × 10–22 g (C) 22 × 10–23 g (D) 132 g

3. The mass of half mole of electrons is about : (Given : Mass of electron = 9.1 × 10–28 g)
(A) 0.546 mg (B) 0.273 mg (C) 1.092 mg (D) 4.55 mg

4. 39.4 kg of gold was recovered from a smuggler. The number of atoms of gold recovered are :
(A) 200 (B) 1.2044 × 1025 (C) 6.022 × 1025 (D) 1.2044 × 1026

5. The charge on 1 gram of Al3+ ions is : (e = magnitude of electronic charge)

1 1
(A) NAe coulomb (B) NAe coulomb
27 3
1
(C) NAe coulomb (D) 3 NAe coulomb
9

6. The number of atoms present in 0.5 g atoms of nitrogen is same as the atoms in :
(A) 24g of Mg (B) 8g of Oxygen gas (C) 32g of S (D) 12g of C

7. In which of the following pairs, do 1 g of each have an equal number of molecules ?

(A) N2O and CO (B) N2 and CO (C) N2O and CO2 (D) Both (B) and (C)

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8. The number of atoms in 4.25 g of NH3 is approximately :
(A) 1 × 1023 (B) 2 × 1023 (C) 4 × 1023 (D) 6 × 1023

9. Total number of neutrons present in 4 g of heavy water (D2O) is : (Where NA represents

Avogadro's number)
(A) 2.4 NA (B) 4 NA (C) 1.2 NA (D) 2 NA

10. In which of the following options, the molecules are correctly matched with their atomicity ?

(1) P4 (p) 7
(2) HNO3 (q) 6
(3) N2H4 (r) 5
(4) H2SO4 (s) 4

(A) (1 – s), (2 – r), (3 – p), (4 – q) (B) (1 – q), (2 – s), (3 – p), (4 – r)

(C) (1 – q), (2 – s), (3 – r), (4 – p) (D) (1 – s), (2 – r), (3 – q), (4 – p)

11. The atomic weight of an element is 'a'. If this element occurs in nature as a triatomic gas, then
the correct formula for the number of moles of gas in its 'w' g is :
3w w a
(A) (B) (C) 3wa (D)
a 3a 3w

12. 124 g of P4 will contain which of the following :

(1) 4 atoms of Phosphorus (2) 4NA atoms of Phosphorus
(3) NA molecules of Phosphorus (4) 1 molecule of Phosphorus
(A) 1 and 4 (B) 2 and 3 (C) 1 and 3 (D) 2 and 4

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 C HE M I S T R Y

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE
ST


INFORM AT IO
NO. 02
MOLE CONCEPT
Topic : Mole Calculation

1. Among the following samples, select the sample which contains maximum number of atoms.
(A) 4 gm of oxygen (B) 32 gm of sulphur
(C) 108 gm of silver (D) 2 gm atoms of nitrogen

2. A gaseous mixture contains oxygen and sulphur dioxide in the ratio of 1 : 4 by mass.
Therefore, the ratio of their respective number of molecules is :
(A) 1 : 2 (B) 1 : 4 (C) 2 : 1 (D) 4 : 1

3. Sulphur exist in different allotropic forms like S2, S6 and S8 etc. If equal moles of these three
forms are taken in separate containers, then the ratio of number of atoms present in them
respectively is :
(A) 1 : 3 : 4 (B) 1 : 1 : 1 (C) 12 : 4 : 3 (D) 4 : 3 : 1

4. Which of the following has least mass?

(A) 2 gram-atom of Nitrogen (B) 3 × 1023 atoms of Carbon
(C) 1 mole of Sulphur atoms (D) 7 g of Silver

5. Which of the following has least mass?

(A) 2 gram-molecules of CO2 (B) 1.2044 × 1024 molecules of CH3COOH
(C) 3 moles of NH2CONH2 (D) 80 g of CaCO3

6. Which of the following contains the greatest number of atoms?

(A) 1 g of butane (C4H10) (B) 1 g of nitrogen (N2)
(C) 1 g of silver (Ag) (D) 1 g of water (H2O)

7. Cinnabar (HgS) is a prominent ore of mercury. How many grams of mercury are present in
464g of pure HgS.
(A) 200 g (B) 400 g (C) 160 g (D) None of these

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8. The number of F– ions in 2.1g AlF3 is (NA = 6  1023)
(A) 1.5  1022 (B) 6 1022 (C) 3 1022 (D) 4.5 1022

9. A gaseous mixture contains SO2 & CO2, average molecular mass of mixture may be :
(A) 64 (B) 44 (C) 54 (D) 70

10. An element is found in nature in two isotopic forms with mass numbers (A–1) and (A+3). If the
average atomic mass of the element is found to be A, then the relative abundance of the
heavier isotope in the nature will be :
(A) 66.6% (B) 75% (C) 25% (D) 33.3%

65 67
11. A hypothetical element Z exists in nature as two isotopes Z and Z with their relative
abundances 25% and 75% respectively. Then, the average atomic mass (in u) of element Z is
(A) 65.5 (B) 66 (C) 66.25 (D) 66.5

12. What is the ratio of weights of O2 and SO2, the mixture of which contains equal number of
molecules of each gas?
(A) 1 : 8 (B) 8 : 1 (C) 1 : 2 (D) 2 : 1

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 C HE M I S T R Y

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE
NO. 03


ST INFORM AT IO

MOLE CONCEPT
Topic : Mole Calculation

1. 360 amu of Glucose (C6H12O6) contains :

(A) 2 moles of glucose molecules (B) 24 hydrogen atoms
(C) 12 moles of carbon atoms (D) 2 glucose molecules

2. Equal mass of O2 and O3 gases contain the same number of :

(A) atoms (B) molecules (C) protons (D) moles of given species

3. If 42 g of an unknown gas X occupies a volume of 125 L at 0.3 bar pressure and 300 K
temperature, then the gas X could be :
(A) N2 (B) CO2 (C) CO (D) NO2

Comprehension-1 (4 & 5)
Consider a sample containing (NH4)2Cr2O7
4. Mass of nitrogen present in sample if mass of oxygen present is 11.2 g.
(A) 1.4 g (B) 2.8 g (C) 28 g (D) 14 g

5. Number of gm molecules of (NH4)2Cr2O7 present in the sample if mass of hydrogen obtained

from the sample is 2g.
(A) 0.25 NA (B) 0.25 (C) 0.125 NA (D) 0.125

Comprehension-1 (6 & 7)
In a container equal number of moles of ethene and sulphur dioxide gases are present at 760
mm Hg pressure and 546K temperature.
6. The ratio of carbon atoms to oxygen atoms present in container will be :
(A) 2 : 1 (B) 1 : 2 (C) 1 : 1 (D) 3 : 2

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7. If all ethene molecules are replaced by same number of molecules of ethyne, then molar
mass of the gaseous mixture will be
(A) 46 g (B) 45 g (C) 60 g (D) 32 g

8. Calculate mass of carbon in 0.01 mole of K4[Fe(CN)6]. Report your after dividing by 0.08.

9. What is the number of gram atoms of oxygen in 6.023 ×1024 CO-molecule.

10. A gaseous mixture contains SO3(g) and CH4(g) in 25 : 1 ratio by mass. What is ratio of total
number of atoms present in SO3(g) to total number of atoms present in CH4(g) in the mixture.

11. A gaseous mixture is composed of equal number of moles of CH4, C2H6 and C2H2. Determine
the average molecular mass of mixture (in amu).

12. Match the column :

Column-I Column-II

A 1 mole (NH4)2 CO3 p moles of carbon atom is less than 1

B 0.5 mole NH2 CONH2 q Mass of oxygen is greater than 16g in sample

at least two elements have same number of atoms in

C 1 mole C6H5N r
given sample

D 1 mole C9N6 s Number of neutron and protons are not same.

t moles of nitrogen atom is greater than 1.

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 ANSWER KEY
DPP-1
1. (D) 2. (B) 3. (B) 4. (D) 5. (C)
6. (B) 7. (D) 8. (D) 9. (D) 10. (D)
11. (B) 12. (B)
DPP-2
1. (D) 2. (A) 3. (A) 4. (B) 5. (D)
6. (A) 7. (B) 8. (D) 9. (C) 10. (C)
11. (D) 12. (C)
DPP-3
1. (BD) 2. (AC) 3. (AC) 4. (B) 5. (B)
6. (C) 7. (B) 8. 9 9. 10 10. 4
11. 24 12. A  q, s, t ; B  p, r, s ; C  s ; D  t

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 CHE MIS TRY

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE(MAIN + ADVANCED)

ST


NO. 04
MOLE CONCEPT
Topic : Percentage Based Calculation, Emperical Formula

1. The number of moles of compound (KHC2O4)0.95·H2C2O4 in its pure sample if sample contains
4 moles of oxygen atoms.

4 4
(A) 0.5 (B) 0.5 × 0.95 (C) (D)
(4  0.95  4) 0.95

2. An organic compound contains 8 % Oxygen and 4 % Sulphur by mass. Find the minimum
possible molecular weight of compound?
(A) 400 (B) 200 (C) 800 (D) 1600

3. An organic compound contains 14 atoms of carbon per molecule. If mass % of carbon in the
compound is 22.4 % then molecular mass of the compound will be
(A) 3000 (B) 750 (C) 12000 (D) 600

4. Silver has two naturally occuring isotopes, one of mass 107 amu and other of mass 109 amu.
Find fraction of abundances for these two isotopes. The atomic mass is 107.8 amu.

5. Calculate density of a gaseous mixture which consist of 3.01 × 1024 molecules of N2 and 32 g of
O2 gas at 3 atm pressure and 860 K temperature (Given : R = 1/12 atm L/mole. K)
(A) 0.6 g/L (B) 1.2 g/L (C) 0.3 g/L (D) 12 g/L

6. The vapour denisty of a mixutre containing NO2 and N2O4 is 27.6. The mole fraction of N2O4 in
the mixture is:
(A) 0.1 (B) 0.2 (C) 0.5 (D) 0.8

7. Density of dry air containing only N2 and O2 is 1.15 g/L at 740 mm of Hg and 300 K. What is %
composition of N2 by mass in the air ?
(A) 78 % (B) 85.5 % (C) 70.02% (D) 62.75%

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Paragraph for question nos. 8 to 10
Some faculty members of XYZ classes were trying to simplify a problem for students by mentioning
data explicitly about a gaseous mixture. Information given by them is as follow :
Faculty-1 : Mixture consist of three gases A, B and C.
Faculty-2 : Molar mass of B is twice of A & Molar mass of A is 4 times of C.
Faculty-3 : The gas that is neither heaviest nor lightest is 16% by mass.
Faculty-4 : Molar ratio of heaviest to lightest gas is 2 : 5.
Based on the above information, answer the questions that follows:

8. Which of the following options correctly represents gases A, B and C respectively?

(A) O2, CH4, He (B) CH4, O2, He (C) O2, SO2, He (D) O2, SO2, CH4

9. What is the molar ratio of A : B: C?

(A) 5 : 2 : 2 (B) 2 : 2 : 5 (C) 2 : 1 : 5 (D) 1 : 2 : 5

10. What would be the average molar mass of mixture.

[Assuming answer of above question to be correct.]

400
(A) gm (B) 12.5 gm (C) 15 gm (D) 20 gm
67

11. A compound contains only C, H, and N. Combustion of 70 mg of the compound produces 132 mg
CO2 and 54 mg H2O. What is empirical formula of compound?

12. A compound whose empirical formula is XF3 consists of 65% F by mass. What is the atomic
mass of X?

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 CHE MIS TRY

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE(MAIN + ADVANCED)

ST


NO. 05
MOLE CONCEPT
Topic : Stoichiometry
1. Which of the following setups is correct to calculate the mass (in g) of KCIO3 produced from the
reaction of 0.150 moles of Cl2 ?
3Cl2 + 6KOH  5KCl + KClO3 + 3H2O
(A) 0.150 moles Cl2 × 1 mole KClO3 / 3 moles Cl2 × 122.5 g/1mole KClO3
(B) 0.150 moles Cl2 × 1 mole KClO3 / 3 moles Cl2 × 1 mole KClO3/122.5 g
(C) 0.150 moles Cl2 × 3 moles Cl2 / 1 mole KClO3 × 122.5 g/1 mole KClO3
(D) 0.150 moles Cl2 × 3 moles Cl2 / 1 mole KClO3 × 1 mole KClO3/122.5 g

2. How many litre of C7H16 will be required to react with 176 gm of oxygen. If density of C7H16 is
0.8 gm/L?
(A) 62.5 L (B) 40 L (C) 50 L (D) 80 L

3. For the following reaction if equal mass of A and B are taken :

A + 2B  C
Which of the following is correct? (MA and MB are molar masses of A and B respectively)
(A) If MA = 2MB , then none of the reactant will be left.

MA
(B) If MB > , then A will be limiting reagent.
2
(C) If MA = MB, then A will be limiting reagent
(D) All are correct

4. Calculate the mass of lime (CaO) obtained by heating 200 kg of 95% pure lime stone (CaCO3) :
(A) 104.4 kg (B) 105.4 kg (C) 212.8 kg (D) 106.4 kg

5. 2.0 g of a sample contains mixture of SiO2 and Fe2O3. On very strong heating, it leaves a residue
weighing 1.96 g. The reaction responsible for loss of mass is given below :
Fe2O3(s)  Fe3O4(s) + O2(g), (unbalance equation)
What is the percentage by mass of SiO2 in original sample ?
(A) 10% (B) 20% (C) 40% (D) 60 %

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6. For the reaction, 2Fe(NO3)3 + 3Na2CO3  Fe2(CO3)3 + 6NaNO3
initially 2.5 mole of Fe(NO3)2 and 3.6 mole of Na2CO3 are taken. If 6.3 mole of NaNO3 is obtained
then % yield of given reaction is:
(A) 50 (B) 84 (C) 87.5 (D) 100

Paragraph for question nos. 7 & 8

On a closed rigid vessel combustion of 2 moles of CH4 was carried out with 10 moles of O2.
At room temperature.

7. After combustion was complete what will be the vapour density of contents of vessel.
(A) 35 (B) 70 (C) 17.5 (D) 15.8

8. If 2 moles of N2 are added after combustions then what will be the change in vapour density of
contents of vessel. [Assume : N2 does not react with any gas]
(A) 2.1 (B) 4.2 (C) 2.93 (D) 0.7

9. Urea, NH2CONH2, is a nitrogen fertilizer that is manufactured from ammonia and CO2(g)
2NH3(g) + CO2(g)  NH2 CONH2(aq) + H2O(l)
What volume of ammonia at 27°C and 8.21 atm is needed to produce 900 g urea?

10. Carbon dioxide is end product of metabolism as shown :

C6H12O6 + O2  CO2 + H2O
Calculate daily production of CO2 (in grams) assuming each person consumes 5 × 102 gm
glucose perday and world's population is 3.6 billion.

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 CHE MIS TRY

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE(MAIN + ADVANCED)

ST


NO. 06
MOLE CONCEPT
Topic : Application of Stoichiometry
1. Consider the reaction :
P4(s) + F2(g)  PF3(g)
What mass of F2 is needed to produce 176 g of PF3 if the reaction has 80% yield.

2. Calculate average molar mass of mixture containing 128g O2(g), 16g H2(g) and 40g He(g).

3. For BaCl2·xH2O, if 2.1 gm of compound gives 2 gm of anhydrous BaSO4 upon treatment with
H2SO4. Then calculate value of 'x'.

4. Which statement is false for the balanced equation given below ?

CS2 + 3O2  2SO2 + CO2
(A) One mole of CS2 will produce one mole of CO2
(B) The reaction of 16 g of oxygen produces 7.33 g of CO2
(C) The reaction of one mole of O2 will produce 2/3 mole of SO2
(D) Six molecules of oxygen requires three molecules of CS2

5. 9 moles of “D” and 14 moles of E are allowed to react in a closed vesel according to given
reactions. Calculate number of moles of B formed in the end of reaction, if 4 moles of G are
present in reaction vessel. (Percentage yield of reaction is mentioned in the reaction)
Step-1 3D + 4E 
80%
 5C + A
Step-2 3C + 5G 
50%
 6B + F
(A) 2.4 (B) 30 (C) 4.8 (D) 1

6. Silver oxide (Ag2O) decomposes at temperature 300ºC yielding metallic silver and oxygen gas. A
1.60 g sample of impure silver oxide yields 0.104 g of oxygen gas. What is the per cent by mass
of the silver oxide in the sample ?
(A) 5.9 (B) 47.125 (C) 94.25 (D) 88.2

7. 2PbS + 3O2  2PbO + 2SO2

3SO2 + 2HNO3 + 2H2O  3H2SO4 + 2NO
According to the above sequence of reactions, how much H2SO4 will 1200 gm of PbS produce?
(Pb = 208)

8. During estimation of nitrogen present in an organic compound by Kjeldahl’s method, the ammonia
evolved from 0.5 g of the compound in Kjeldahl’s estimation of nitrogen, neutralized 10 mL of 1 M
H2SO4. Find out the percentage of nitrogen in the compound.

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 CHE MIS TRY

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE(MAIN + ADVANCED)

ST


NO. 07
MOLE CONCEPT
Topic : POAC And Stoichiometry
1. According to following reaction :
A + BO3  A3O4 + B2O3
The number of moles of A3O4 produced if 1 mole of A is mixed with 1 mole of B O3.
(A) 3 (B) 1 (C) 1/3 (D) 2/3

2. What is the maximum amount of nitrogen dioxide that can be produced by mixing 4.2 gm of
NO(g) and 3.2 gm of O2(g) ?
(A) 4.60 gm (B) 2.30 gm (C) 3.22 gm (D) 6.44 gm

3. A metal oxide has the formula M2O3. It can be reduced by hydrogen to give free metal and water.
0.1596 g of the metal oxide required 6 mg of hydrogen for complete reduction. The atomic weight
of the metal is
(A) 27.90 (B) 159.60 (C) 79.80 (D) 55.80

4. When 280 gm of ethylene polymerises to polyethylene according to the equation:

n (CH2 = CH2)  —(CH 2  CH 2 —

)n .
The weight and mole of polyethylene formed will be

280 28 10
(A) 280, 10 n (B) ,n (C) , 280 (D) 280,
n n n

5. NX is produced by the following steps of reactions

M + X2  MX2 ; M X2+ X2  M3X8 ; M3X8+ N2CO3  NX + CO2 + M3O4
How much M (Metal) is consumed to produce 206 gm of NX (Given at. wt. of M = 56, N = 23, X = 80)

7 14
(A) gm (B) (C) 56 (D) 42
4 3

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6. 5 moles of A, 6 moles of Z and mixed with sufficient amount of C to produce final product 'F'. Then
find the maximum moles of 'F' which can be produced. Assuming that the product formed can
also be reused. Reactions are: A + 2 Z  B ; B + C  Z + F
(A) 3 moles (B) 4.5 moles (C) 5 moles (D) 6 moles

7. 1.44 gram of Titanium (Ti) reacted with excess of O2 and produced 'x' gram of non-stoichiometric
compound Ti1.44O. The value of 'x' will be
(A) 2.77 gm (B) 3.77 gm (C) 1.77 gm (D) 3.0 gm

8. Number of moles of NH3 produced if 140 gm of N2 reacts with 40 gm of hydrogen.

[Given % yield of reaction is 50%]
(A) 12 (B) 10 (C) 5 (D) 6

9. A sample of acetone undergoes 40% dimerization. Then mole fraction of the dimer in the final
mixture is
(A) 0.16 (B) 0.75 (C) 0.4 (D) 0.25

10. Assertion : For the reaction producing Fe & CO2 by the reaction of Fe2O3 and C the ratioof
stoichiometric coefficients of Fe2O3 : Fe is 1 : 2.
Reason : During a chemical a reaction atoms can neither be created nor be destroyed.
(A) If both Assertion and Reason are CORRECT, and Reason is the CORRECT explanation of the
Assertion.
(B) If both Assertion and Reason are CORRECT, but Reason is not the CORRECT explanation of
the Assertion.
(C) If Assertion if CORRECT but Reason is INCORRECT.
(D) If Assertion is INCORRECT Reason is CORRECT.

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 CHE MIS TRY

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE(MAIN + ADVANCED)

ST


NO. 08
MOLE CONCEPT
Topic : Concentration Terms
1. Molarity of aqueous NaOH solution will be, if mole fraction of NaOH in the solution is 0.5.
[Given : density of pure NaOH = 4 gm/ml]
(A) 76.92 (B) 35.71 (C) 68.96 (D) 26.46

2. Decreasing order (first having highest & then others following it) of mass of pure NaOH in each of
the aqueous solution
(i) 50 gm of 40% (w/w) NaOH (ii) 50 gm of 50% (w/v) NaOH [dsoln. = 1.2 gm/ml]
(iii) 50 gm of 20 M NaOH [dsoln. = 1 gm/ml]
(A) (i), (ii), (iii) (B) (iii), (ii), (i)
(C) (ii), (iii), (i) (D) all contain same wt. of NaOH

3. If ratio of mole fraction of solute to solvent is unity, what would be % by wt. (concentration of
solute) (M solute = molecular mass of solute, M solvent = M molecular mass of solvent)
M solute
(A) × 100 (B) 50%
(M solute  M solvent)

M solute
(C) 66.67 % (D) × 100
M solvent

4. 20 ml of CaCl2 solution is mixed with 30 ml of 0.1 M-AlCl3 solution. If the resulting solution has
chloride ion concentration equal is 0.34 M, the concentration of CaCl2 solution added is
(A) 0.2 M (B) 0.7 M (C) 0.4 M (D) 0.1 M

5. The legal limit for human exposure to CO in the work place is 35 ppm. Assuming that the
density of air is 1.3 g/L, how many grams of CO are in 1.0L of air at the maximum allowable
concentration?
(A) 4.55 ×10–5 gm (B) 3.5 ×10–5 gm (C) 2.69 ×10–5 gm (D) 7.2 ×10–5 gm

6. Arrange in increasing order of Molarity of solute in following solutions considering water as solvent.
(i) 224 gm/lit. KOH (ii) 11.2% w/v KOH (iii) 5m KOH (d = 0.64 gm/ml)
(A) (ii) < (iii) < (i) (B) (iii) < (ii) < (i) (C) (iii) < (i) < (ii) (D) (i) < (ii) < (iii)

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7. Statement -1 : For a very dilute solution molality & molarity are always approximately equal
Statement -2 : Mass of solution is always approximately equal to mass of solvent for a very dilute
solution.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is false, statement-2 is true.
(D) Statement-1 is true, statement-2 is false.

ω
8. Statement-1: For a very dilute aqueous solution "ppm" is approximately equal to " % × 104"
v
Statement-2 : Mass of solution is always equal to volume of a very dilute solution.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

9. Statement -1 :Density of air (containing N2 and O2 gas) is greater than that of sample of air
(containing N2, O2 & SO2 gas) at same T and P.
Statement -2 : Molecular mass of added gas is greater than N2 & O2 both.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is false, statement-2 is true.
(D) Statement-1 is true, statement-2 is false.

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 CHE MIS TRY

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE(MAIN + ADVANCED)

ST


NO. 09
MOLE CONCEPT
Topic : Concentration Terms And Dilution Mixing
1. The molality of a H2O2 solution of density 1.068 gm/ml is '2m'. The only incorrect concentration
of the same solution is
(A) Molarity = 2 M (B) Volume strength = '22.4 vol'
(C) 6.8 % (w/v) (D) 6.8 % (w/w)
2. 20 ml of CaCl2 solution is mixed with 30 ml of 0.1 M-AlCl3 solution. If the resulting solution has
chloride ion concentration equal is 0.34 M, the concentration of CaCl2 solution added is
(A) 0.2 M (B) 0.7 M (C) 0.4 M (D) 0.1 M
3. 150 ml of a solution containing 5 millimoles of A (special gravity = 1.2) is mixed with 250 ml of
another solution containing 10 millimoles of A (special gravity = 1.4). If on mixing the density of the
5 .3
solution becomes gm/ml then what will be molarity of A in the final solution.
4 .5
1 3 1 4
(A) M (B) M (C) (D)
30 80 20 85
4. For a solution concentration can be expressed as 16% w/w as well as 20% w/v. What will be
density of solution?
(A) 1.25 gm/lit. (B) 0.8 gm/lit. (C) 1.25 gm/ml (D) 0.8 gm/ml
5. For a sequential reaction, NH3  N2 + H2 .....(i) ; H2 + O2  H2O .....(ii)
What will be the amount of water which will be obtained if 5 moles of NH3 is mixed with 3 moles
of O2 & % yield of 1st & 2nd reaction is 50% & 80% respectively?
(A) 3 moles (B) 2.5 mole (C) 2 moles (D) 2.4 moles
6. A sample of clay contains 60% Silica & 15 % water. The sample is heated such that the partially
dried sample contains 66 % Silica. What will be % of water in partially dries sample?
(A) 10% (B) 6.5 % (C) 12 % (D) 14 %
7. If 200 ml of 0.1 M Na2SO4 is mixed with 100 ml of 0.2 M Na3PO4 solution. Molarity of Na+ in the
final solution, if final solution has density 1.2 gm/ml.
(A) 0.196 M (B) 0.33 M (C) 0.5 M (D) None of these
8. If in a sample of oleum, mole fraction of SO3 is 0.5. Label the oleum sample
(A) 109 % (B) 110.11 % (C) 104.5 % (D) 114.22
9. 90 gm glucose is dissolved in 410 gm water to get a solution. The concentration of solution is
900 50
(A) %( w / w ) (B) 18 % (w/w) (C) m (D) 1.0 m
41 41
10. 25 ml of a solution containing HCl and H2SO4 required 10 ml of 1M NaOH solution for complete
neutralization. 20 ml of the same acid mixture on being treated with excess of AgNO3 gives
0.1435 gram of AgCl. If molarity of HCl is 'x' and that of H2SO4 is 'y'.
Report your answer as (x + y) × 1000.

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 CHE MIS TRY

DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE(MAIN + ADVANCED)

ST


NO. 10
MOLE CONCEPT
Topic : Application of Concentration Terms
1. The vapour density of a gaseous mixture of non-reactive gases 'A' and 'B' is 40. If the molar
mass of gas 'A' is 20 gm/mol and the mixture contains the gases in 2 : 3 volume ratio, then the
molar mass of gas 'B' is :
160
(A) (B) 40 (C) 120 (D) 60
3
2. Statement-1 : One molar aqueous solution may be one molal.
Statement-2 : The molality of a solution depends upon the mass of the solution whereas molarity
depends on volume of solution.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
3. The density of 2m-aqueous H2O2 solution is 1.068 gm/ml. Which of the following is/are correct
concentration(s) of this solution, in different units?
(A) Molarity = 2M (B) Volume strength = '22.4 V'
250
(C) %(w/v) = 6.8 (D) Mole-fraction of water =
259
4. A solution of H2O2 is labelled as 44.8 V. Which of the following concentration terms representing
the solution will also be correct. (dsoln. = 2.136 gm/ml)
4
(A) 4 molar (B) 2 molal (C) 13.6 % w/v (D) X H 2O2 = 1000
4
18
5. 500 ml of 2M AlCl3 solution is mixed with 200 ml of 5.85 % w/v NaCl solution and 300 ml of
w
50% BaCl2 solution (d = 2.08 gm/ml). Calculate molarity of Cl– in the final solution .
w

9
6. The mole fraction of glucose in an aqueous solution is . The molality of solution is
109
7. Calculate the molarity of H+ ions obtained by mixing 200 ml of 0.5 M H2SO4 solution
(dsolution = x gm / ml); 100 ml of 0.7 M HNO3 solution (dsolution= 1.2 x gm / ml) and 100 ml of 0.3
M HCl solution (dsolution = 1.3 x gm /ml) such that density of final solution is 1.5 x gm /ml.

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