(Batches: e-SANKALP-2325 S1, T1 & P1)

IIT – JEE, 2325 Paper Code

101013
(CLASS XI)
Time: 2 Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.

B. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Numerical Value Questions, the answer to each
question is a Non-Negative Numerical Value. For each question, enter the correct numerical value
corresponding to the answer and each question carries +4 marks for correct answer. There is no
negative marking.

Enrolment No. :

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eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-2

PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.

1. A block of mass 2m is hanging at the lower end of a rope of mass m and length ,
the other end being fixed to the ceiling. A pulse of wavelength 0 is produced at the m, 
lower end of the rope. The wavelength of the pulse when it reaches the other end of
the rope is 2m

3
(A) 3 0 (B) 0
2
0
(C) 0 (D)
2

2. A sinusoidal wave is propagating along negative X–direction in a string stretched along X–axis. A
particle of string at x = 3 m is found at its negative extreme position and is having an acceleration
along positive y–direction at t = 2s. The amplitude of the wave, the wavelength and the angular
frequency of the wave are 0.5 m,  m and 6 rad/sec.The equation of the wave is
 
(A) y = 0.5 sin[6(t – 2) + 2(x – 3) + 3 ] (B) y = 0.5 sin[6(t – 2) – 2(x – 3) + 3 ]
2 2

(C) y = 0.5 sin[6(t) + 2(x) + 3 ] (D) none of these
2

3. The diagram shows a wave train of amplitude A at y

time t = 0 sec. The phase difference between the
oscillation of the particle at x = 0 and x = x1 is . The
particle at x = x1 is moving upward with velocity v1. x
Which of the following equations represent the wave
equation correctly?
X1

 tv   x v1 
(A) A sin  x  1  (B) A sin    t 
 A   1x A sin 
 x v1 
(C) A sin    t  (D) none
 x1 A cos  

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-3

2 2
4. Equation of a travelling wave is y  5e(–ax –bt – 2 abxt ) when x & y is in meter and t is in sec.
–2 –2
a = 25 m and b = 9 sec . Choose the incorrect statement.
(A) Travelling wave is propagated along (+) x direction.
(B) Travelling wave is propagated along (–) x direction.
(C) Speed of wave is 3/5 m/sec.
(D) Maximum displacement of particle is 5 m.

5. A transverse sinusoidal wave moves along a string in the positive x-direction at a speed of 10
cm/s. The wavelength of the wave is 0.5 m and its amplitude is 10 cm. At a particular time t, the
snap–shot of the wave is shown in figure. The velocity of point P when its displacement is 5 cm is
Figure:
y
P
x

3 3
(A) ĵ m/s (B)  ĵ m/s
50 50
3 3
(C) î m/s (D)  î m/s
50 50

6. In the given figure, a string of linear mass density m and length P Q

L, is stretched by a force F = (F0 kt)N, where F0 & k are
constant and t is time. At the time t = 0, a pulse is generated at
the end P of the string. As the pulse reaches the point Q, the L
force vanishes. The value of k in the above equation is
F = (F0 kt)N
2 F03 2 F03
(A) (B)
3L m 3L 2m
1 F03 1 F03
(C) (D)
3L m 3L 2m

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eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-4

SECTION – 2 : (One or More Than One Options Correct Type)

This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.

7. The figures represent two snaps of a travelling wave on a string of mass per unit length,  = 0.25
1
kg/m. The two snaps are taken at time t = 0 and at t  s. Then
24
y(mm) y(mm)

10 10
5 5

–5 x(m) –5 1 x(m)
–10 –10 1
t=0 t=24 s
Figure -1 Figure -2
(A) speed of wave is 4 m/s
(B) the tension in the string is 4 N

(C) the equation of the wave is y = 10 sin (x – 4t  )
6

(D) the maximum velocity of the particle  m/s
25

8. A horizontal stretched string fixed at two ends, is vibrating in its fifth harmonic according to the
equation y(x, t) = 0.01m sin [(62.8m 1)x] cos[(628s1)t]. Assuming  = 3.14, the correct
statement(s) is (are)
(A) The number of nodes is 5.
(B) the length of the string is 0.25 m.
(C) The maximum displacement of the midpoint of the string, from its equilibrium position is
0.01m.
(D) The fundamental frequency is 100 Hz.

9. Shape of string transmitting wave along x-axis at

some instant is shown. Velocity of point P is
v = 4 cm/s and   tan1(0.004)
(A) Amplitude of wave is 2 mm
(B) Velocity of wave is 10 m/s
(C) Max acceleration of particle is 80 2 cm/sec2
(D) Wave is traveling in –ve x-direction

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-5

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).

10. Two strings AB and BC of equal length are connected as

C
shown to a 10kg block through an inextensible string QP.  Q
A B
AB and BC both are made of same material, whose density
is 8000 kg / m3 . The entire arrangement is kept in an
elevator accelerating upwards with acceleration 2 m/s2. Find
the minimum number of loops in the string AC if joint B is a P
10kg
25
node. Cross sectional area of BC is mm2 and that of AB
24
is 25/6 mm2 .

11. A uniform string is clamped at x = 0and x = Land is vibrating in its fundamental mode. Mass per
unit length of the string is , tension in it is T and the maximum displacement of its midpoint is A..
Assume A to be small so that changes in tension and length of the string can be ignored. The
k2 A 2 T
total energy stored in the string is . Find the value of k.
L

12. A transverse wave is traveling in the +ve x-direction according to the equation
y = 2sin[100t  x/50], where x and y are in cm.
The ratio of the maximum velocity that a particle can have to the velocity of wave propagation is

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eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-6

PART II : CHEMISTRY
SECTION – 1: (Only One Options Correct Type)
This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.
1. Which of the following molecules is (are) chiral?

H
CH3 H
H H3C
Cl H
O
C
H Br CH(CH3)2 H
O
(I) (II) (III) (IV)
(A) I and II (B) III and IV
(C) I, II and III (D) I, II and IV

2. Which of the following pairs of compounds is a pair of enantiomers?

Br Br

(A) (B)
Cl Cl
Cl Cl

(C) (D)
Cl Cl Cl Cl
3. Which of the following molecules is/are chiral?

OH
Br H Br H H COOH
Cl OH
HO H
COOH
(I) (II) OH (III)
(A) I (B) II
(C) III (D) I, II

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-7

4. Which of the following statements best describes the stereochemical relationships of compound I,
II and III shown below?
CHO
CHO CHO
H H
H H H H
H3C H
H CH3 H CH3
H CH3
H3C H H CH3
H H
H H H H
CHO
CHO CHO
(I) (II) (III)
(A) All compounds are chiral
(B) I and II are meso compounds
(C) I and II are diastereomers, and III is a meso compound
(D) I and II are enantiomers
5. Which of the following is the enantiomer of the compound shown below?
H
Me Br
Br H
Me OH

Et
Me H
H Br Me Br
H Br H Br
(A) (B)
HO Me Me OH
Et Et
H H
Br Me Br Me
Br H H Br
(C) (D)
HO Me Et Me

Et OH

6.

(I) (II)
If number of monochloro derivative of (I) are x and number of dibromo derivative of (II) are y, then
x and y are:
(A) 3, 11 (B) 4, 11
(C) 4, 10 (D) 4, 11

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eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-8

SECTION – 2: (Multi Correct Choice Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.
7. Which of the following is/are correct relationship for given compounds:
OH Cl H
H H OH
CH2OH COOH CH2OH
HOOC HOH2C OHC
Cl H H
H HO Cl
(I) (II) (III)
(A) I and II are enantiomers of each other
(B) II and III are identical to each other
(C) I and II are diastereomers of each other
(D) I and III are identical to each other
8. Which of the following is/are correct statement for the given compound?
Cl Cl

C C

Cl Cl
(A) Total number of stereoisomers are 7.
(B) Total number of enantiomeric pairs are 2.
(C) Total number of meso compounds are 5.
(D) Total number of diastereomer pairs are 5.
9. Which of the following statements are correct regarding the following molecule:
H3C CH CH
C CH2
H3C CH CH
(A) Total number of stereoisomers are 3.
(B) Total number of optically active isomers are 2.
(C) Total number of optically inactive isomer are 2.
(D) Total number of geometrical isomers are 3.

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-9

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
10. The following compounds may exist as two or more stereoisomers.
Me
(a) C  CH3 CHCl  4
C CHCO 2H
(b)
Me
If number of stereoisomers of (a) are x, stereoisomers of (b) are y, then calculate x + y.

11. Find out the total number of stereoisomers of the given following compound.
Cl

Cl CH CH C CH CH Cl

H
12. Total number of monochlorinated product of R-3-methylhexane are:

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eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-10

PART III : MATHEMATICS

SECTION – 1: (Only One Options Correct Type)

This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.

1. There are seven letters L1, L2, L3, L4, L5, L6 and L7 and six envelopes E1, E2, E3, E4, E5, E6
corresponding to first six letters. The total number of ways if none of the letters goes to its correct
envelope, even letters goes to even envelopes. Odd letters goes to envelopes other that E4 and
E6 and all the envelopes except E2 contains exactly one letter is, N. If N = 2 + 4, where   z,
then  is equal to _____
(A) 8 (B) 9
(C) 10 (D) 11

2. The number of isosceles triangle with integer sides if no side exceeds 2014, then which of
following is incorrect
(A) (1007)2 if equal sides do not exceed 1007
(B) 2(1007)2 if equal sides exceed 1007
(C) 3(1007)2 if equal sides have any length  20014
(D) (2014)2 if equal sides have any length  2014

3. The number of ways to place 11 identical balls in three distinct boxes so that any two boxes
together will contain more balls than third one is
(A) 13C2 (B) 13C10 – 3 7C2
13 7
(C) C2 – 3 C2 (D) 14C2 – 3 8C2

4. Consider a set {1, 2, 3, . . . ., 100}. The number of ways in which a number can be selected from
the set so that it is of the form xy, (where x, y,  N and  2), is
(A) 12 (B) 16
(C) 5 (D) 11

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-11

5. Number of words can be formed using all the letters of the work ‘HIPHIPHURRAY’ in which all
H’s lie somewhere between R’s is
(A) (198)7! (B) (99)7!
(C) (99)8! (D) (198)8!

6. The number of n digit numbers formed by using digits {1, 2, 3} such that if 1 appears, it appears
even number of times
1 n
(A) 2n + 1 (B)
2
3 1  
1 n 1 n
(C)
2

3 1  (D)
2
2 1  
SECTION – 2: (Multi Correct Choice Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.

10  2
 1 22 102 
7. Let P   n    .....   then which of the following is/are correct?
1  n 2  n
n 1  10  n 
(A) 2P is perfect square (B) 2P is divisible by 112
(C) Number of divisors of 2P is 9 (D) The remainder when 2P is divided by 6 is 1

8. x1, x2, x3 are three real numbers satisfying the system of equations
x1 + 3x2 + 9x3 = 27, x1 + 5x2 + 25x3 = 125 and x1 + 7x2 + 49x3 = 343, then which of the following
options are correct
x1  x 2
(A) number of divisors of x1 + x3 is 16 (B) is a prime number
2
(C) x3 – x2 is a prime number (D) x1 + x2 + x3 is square of an integer

9. The number of codes of 20 digits which can be formed using digits 0, 1, 2, 3, 4 such that
difference of consecutive digit is one is N, then
(A) total number of positive integers which divides N is 40
(B) N is divisible by 38
(C) N is divisible by 7
(D) the number of ordered pair (a, b) such that a  b = N and a, b  I+ and gcd (a, b) = 1 is 4

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eSANKALP2325S1, T1 & P1-PCM-Paper-(101013)-12

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).

10. In a tournament each player played exactly one game against each of the other players. In each
game the winner was awarded 1 point, the loser got 0 points, and each of the two players earned
1/2 point if the game was a tie. After the completion of the tournament, it was found the exactly
half of the points earned by each player were earned in games against the ten players with the
least number of points. (In particular, each of the ten lowest coring players earned half of her/his
points against the other nine of the ten). What was the total number of players in the tournament?

11. In a sequence of coin tosses one can keep a record of the number of instances when a tail is
immediately followed by a head, a head is immediately followed by a head, etc. We denote these
by TH, HH etc. For example, in the sequence HHTTHHHHTHHTTTT of 15 coin tosses we
observe that there are five HH, three HT, two TH and four TT subsequences. How many different
sequences of 15 coin tosses will contain exactly two HH, three HT, four TH and five TT
subsequences?

12. A mail carrier delivers mail to the nineteen houses on the east side of Elm Street. The carrier
notes that no two adjacent houses ever get mail on the same day, but that there are never more
than two houses in a row that get no mail on the same day. How many different patterns of mail
delivery are possible?

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