SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.

Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_Elite, Target & LIIT-BTs JEE-MAIN Date: 24-03-2024
Time: 09.00Am to 12.00Pm GTM-29/26 Max. Marks: 300
KEY SHEET
PHYSICS
1) 2 2) 1 3) 3 4) 1 5) 1
6) 2 7) 1 8) 3 9) 4 10) 3
11) 1 12) 1 13) 1 14) 2 15) 2
16) 2 17) 2 18) 3 19) 1 20) 2
21) 18 22) 2 23) 22 24) 3 25) 5
26) 4 27) 8 28) 6 29) 35 30) 340

CHEMISTRY
31) 4 32) 3 33) 4 34) 3 35) 4
36) 4 37) 2 38) 2 39) 1 40) 4
41) 3 42) 4 43) 4 44) 3 45) 2
46) 3 47) 4 48) 3 49) 2 50) 2
51) 5 52) 6 53) 2 54) 25 55) 4
56) 10 57) 7 58) 5 59) 9 60) 5

MATHEMATICS
61) 3 62) 1 63) 4 64) 4 65) 3
66) 1 67) 2 68) 2 69) 1 70) 4
71) 1 72) 4 73) 1 74) 4 75) 3
76) 3 77) 2 78) 3 79) 1 80) 3
81) 5 82) 2 83) 2 84) 432 85) 7
86) 6 87) 1 88) 8 89) 10 90) 1

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SOLUTIONS
PHYSICS
1. When both the blocks are moving together in downward direction the required friction is
less than the limiting friction between the blocks.
 v v 
2. F   n1  n2 A
 1 h h  h1

dF h
 0  h1 
dh1 4

 V2
3. a a 
R

 V2 V2
a   a cos iˆ  a sin ˆj  cos iˆ  sin ˆj
R R
0 A
4. C1 
d
0 A 2 0 A C2 2
C2   
d d 2 d C1 1

2 
2E
5. I ... i 
R  r1  r2
E
But VA  VB  E  Ir2  0  I  .... ii 
r2
Comparing values of I from (i) and (ii)
E 2E
  R  r2  r1
r2 R  r1  r2
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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
I1
6. 4
I2
2 2
I max  I1  I 2  I max  2 I 2  I 2 
   
I min  I1  I 2  I min  2 I 2  I 2 

I max I max  I min 10 5 10

9   x=4
I min I max  I min 8 x 8
8. The work done by magnetic force is WB = 0, because, magnetic force is always

perpendicular to instantaneous displacement.

 
WE  qE . S  qE0ˆi . (x 0 ˆi  y0 ˆj)  qE0 x 0

The speed of particle at (x0, y0) is v  42  (3)2  5m / s

According to work – energy theorem,

1 1 1
W  T  mv2  mu 2 WE  WB  m52  0
2 2 2
25 25m 25
qE 0 x 0  m x0  
2 2qE 0 2E 0 

9. A body is fired from point P and strikes at Q inside a smooth circular wall (in horizontal
plane) as
Let v1 and v2 be the speed of the body before and after striking Q.
v1 sin   v2 cos  (as there is no friction so component of velocity along the tangential
direction remains same)
 
ev1 cos   v2 cos     (from coefficient of restitution equation)
2 
v2 sin 
e  tan 2 
v1 cos 

10 In forward bias diffusion of majority carriers takes place from pside to nside

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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
y
11. P   B
x
hrdg
12. T
2cos 
13. =

14.
Consider a cube of side ‘2a’ having same charge density as that of cube of side ‘a’.
If ‘V’ is the potential at the corner of a cube of side ‘a’ then potential at the center of
cube of side ‘2a’ is given by
V '  8V
Q
But V0 
a

 8Q 
V '  
 2a 
V'
 4
V0

V0
V 
2

15. KEmax = hν – hν0

16. e0  nB A  100  0.04  3  60  720V

e0 720
The maximum current drawn I max    1.44 A
R 500
hc 1 1 
17. By using   
     V0
e  0 

hc 1 1 
  
 
  4 .8
 …..(i)
e  0 

hc  1 1 
and 
 2  
  1 .6
 …..(ii)
e  0 

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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
1 1 
  
   4. 8
From equation (i) by (ii),  0 
  0  4  .
 1 1  1 .6
  
 2  
 0 

18. Conceptual
19. Conceptual
20. Small oscillation occurs relative to stationary axis passing through AB. DC perpendicular
to line passing through AB becomes length of equivalent pendulum.

L sin  L tan  2l
T  2  2 T  2
g cos  g g

z 2a 3x 1 y
21. z  a 2 x 3 y1 2   
z a x 2 y
z 1
a is constant  100  3  4%   12%   18%
z 2
GM V 800 1
22. V  1 
r V2 3200 2

23. X L  L  2  50  101  10 

1 1 100
XX    104 
C 2 50 
R  10
2
 100  2
Z   10    10  10
  
E 220
i   22 Amp
2 10
24. Current through load is 5mA
Current through series resistance is 14mA

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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
25. Area = V  at  0
26. Change in voltage/ change in current
de 2 105 m
27. e  l2  l1  100   8%
e 25 105 m
28. From graph P  V
PV 1 = constant (Polytrophic process)
P1 P2 P P
  0 2
V1 V2 V0 2V0
 P2  2 P0
For a polytrophic process
R
C  CV 
1 x
3 R
C  R  x  1
2 11
C = 2R
 Amount of heat supplied dQ  nCdT

 2 P 2V PV 
dQ  nC T2  T1   n  2 R   0 0  0 0 
 nR nR 
dQ  6 PV
0 0

29. The induced emf across inductor

 Ldi
e  5   1.0   5V
dt
As the current is decreasing the inductor can be replaced by a source of emf 5V in such a
manner so that it compensate the decreasing current. It to be like as shown in fig now by
loop rule
 Ri  e    Vab  0  or Vab  Ri    e  10  2  20  5  35V

V
30. f   V  4 Lf  340 m s
4L

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CHEMISTRY
31. conceptual

32. NCERT – 345

33.

 b b
Ca H b   a   O2  aCO2  H 2O
 4 2

 b b
1 ml  a   ml  aml ml
 4  2
 b
10 ml 10  a   ml  10aml '0ml '
 4
Volume absorbed by KOH  VCO2  20ml
 10a  20
a2
Volume absorbed by alkaline pyrogallol = 75 ml
VO2 reacted = 100 – 75 = 25
 b 10b
 10  a    25  5b  2
 4 4
34. Pinacole-pinacolone reaction
1) One of two – OH groups leaves which results in formation of more stable carbon
cation. In given compound – OMe is better stabilizing group
2) Relatively electron rich ring migration to form ketone
35. As we already mentioned that Hydrolysis of 3o alkyl halide is independent of
nucleophilic concentration.
36.
H 2 N  CH 2  COOH  Glycine   H 2 N  CH  COOH
|
CH 3
1. Gly – Gly 2. Gly – ala (+) 3. Gly – ala (–) 4. Ala (+) – Gly
5. Ala (–) – Gly 6. Ala (+) – Ala (+) 7. Ala (–) – ala (–) 8. Ala (+) – ala (–)
37. CONCEPTUAL
38. effective conc. of NaCl sol  0.1  2  0.2 M
effective conc. of BaCl2 soln  0.05  3  0.15M
  Nacl   Bacl2
 Solvent flows from BaCl2 to NaCl sol

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 Conc. BaCl2  & Conc. of NaCl 

39. In order to remove interfering ions (cyanides & sulphides)

40. CONCEPTUAL
41. Sol: Otherwise Na will react with water to liberate H 2
Na  H 2O  NaOH  H 2 
42. CONCEPTUAL
43.

44. Conceptual
45. Principle Fn. group= C  O (ester)
||
O
Side chain = OCH 3 (methoxy)
4 3 2 1
CH3  O  C H 2  C H 2  C H 2  C  O  C2 H5
||
O
Ethyl-4 –methoxy butanoate

 Ea 1
46. slope    Ea  R
2.303R 2.303
PV
47. Temperature at ' a '  T0 
R
PV
 a  T0  0 0
R

At  C  TC  0
 2 P  4V0   8T
0
R
3
U  nCV  T f  Ti   R  8T0  T0 
2
21RT0
U   10.5 RT0
2
 2 HBr  g 
H 2  g   Br2  g  
48.
t 0 0 0 10 bar
x x  2x
t  teq x x 10  2 x

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2
10  2 x  10  2 x 10 10
KC  16 106  2
4  10 3   ;x   2.5  10 3
x x x 4  103
49. Diazonium ion acts as an electrophile in coupling reaction. The greater the electron-
withdrawing power. The Higher is the elcctrophilicity.
50.
The stronger base , the more is the nucleophilic character and vice versa

Hence, the nuclecophic character

51. (i), (ii), (iii), (iv), (vi).
52.
OH
Ph
Me3C 1.O3,Zn Me3C
Me3C 2.ex.PhMgBr Me C
3
3.H 3O Ph
OH

53. Paramagnetic : B2 , O2 , C21 , He2 , O2

Fractional BO : O2 , C 21 , He2
54. Conceptual
55. Conceptual
56. Conceptual
57. All compounds liberate oxygen
58.
2 HO COOH  Ca  OH  2 
 HO COO Ca  2 H 2O

Intial 2 m moles 0.5 m moles 0 0

After complete reacation 1 m moles 0 0.5 m moles

This is a buffer solution pH  pKa  log

conjugate base
 acid 
1
 5  log  pH  5
1
59. Conceptual
60.

48 1 1 
13.6   13.6  2  2   n  7; 7  2; n  5
49 1 n 
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MATHEMATICS
61. SOL: - required points are

A, B, C, D

D

C




 B

A

3 2 3  2 
62. PT Q8 P  A8 A2   
0 1 
3 3 
A3   
 
 3 n   3 8 
n
A    A 8  

 
   
  
iˆ ˆj kˆ
63. Sol:  2   3iˆ  4 ˆj  2kˆ
2 1 5

 10    iˆ   2  5  ˆj     4  kˆ  3iˆ  4 ˆj  2kˆ

   7;  2
b  3a   2  3  iˆ   1  6  ˆj   5  3  kˆ  4iˆ  5 ˆj  16kˆ
b  a  ˆj  2 kˆ
5  32 37
Projection of  b  3a  on  b  a   
5 5
64. 3, a, b, c in A.P
a  3 d b  3  2 d c  3  3d
3, a  1, b  1, c  9 are in G.P

a  1  3r b  1  3r 2 c  9  3r 2
a 1 b 1
r  2  d 2  3  4  2d   If d  2
3 a 1
r  0 a contradiction  d  4  3, 7,11,15 are in AP 1  2 a  b  c  11

 a1 b1 c1 
65. SOL: - Let A   a2 b2 c2 
 a3 b3 c3 

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0   c1  1 
A 0   c2   1   c1  1; c2  1; c3  2
1   c3   2 
1   c1  a1 
A 0   c2  a2   a1  2; a2  1; a3  1
   
1   c3  a3 
1   a1  b1  1 
A 1    a2  b2   1   b1  3; b2  2; b3  1
     
0   a3  b3  0
 2 3 1 
 A   1 2 1 
 1 1 2 
5 3 1
 A  3 I  1 1 1  0
1 1 1
 Given system of equations has a unique solution
288 5
66. SOL: - f ( x )  x 9  x  2304 x  2  0
5
f 1 ( x )  0  9 x 8  288 x 4  2304  0
 x8  32 x 4  256  0
 ( x 4  16) 2  0  x   2
Observe that f (2)  0  f ( x)  0 has only one real root
67. We have,
 xf '  x   f  x    x 2  2  d  f  x   2 
 2

  2      1  2 
 x   x  dx  x   x 
 on integrating, we get
f  x 2
 x   c; As f(1) = 1  c = -2
x x
3
2
 f  x    x  1  1  Area =  f  x  dx
0

= 6 (square units)
2 1
x
x
68. Let I   e dx … (1)
1
2

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2 x 1
1  1 
Put x  and adding, we get 2 I   e x  1   dx
y 1  x2 
2
1  1 2  1
 x  
 x  1   x  
 x 1 
 e  1  2 
dx   e 1  2  dx
1  x  1  x 
2

 1
Put  x    t  2I  2e e  2  I  e e  1
 x
 
69. Given e  x  tan15o  e 2 x  tan15o  a (Let) then

 1 
 e2 nx
n0 1  a  a  a  ....  1  a 
2 3


 
n 2 nx 1  a  a 2  a 3  ....  1 
  1 e  
n 0 1 a 


1 a 1 2  3
 
3 3 1
 3
 
1 a 1 2  3 3 1  
70. f ( 1  0)  2  3  1
y=2x+3

y=k-2x
y

x
-1 O

f (1)  1  k  2  1  k  1
a  b  68  44  48  60
71. Mean=  55  a  b  110
6
 2
Variance= 
xi  x 
  2 2 2 2
55  a    55  b   13  11  7 2  52
 194
n 6
 a 2  b 2  110 a  b  5250  a 2  b2  6850
 
After solving (1)& (2), we get a  75 & b  35  3a  b  225  35  260
72. Sol:
A B
x  y  13 6
6. 3
3
yz7 2.
1

x  z  12 9 C

z 3
x9
y4

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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
    9  17
    4  15
      13  30
  9;   2;   6
73. A   a, b   R  R : a  5  1, b  5  1
Let a  5  x , b  5  y
Set A contains all points inside x  1, y  1

B  a,b   R  R : 4  a  6 2 2
 9  b  5   36 
set B contains all points inside or on
 x  12  y 2  1
9 4
  1, 1 lies inside the ellipse
Hence A  B .


 
   
 2,0  2,0 
 


74. 1  log 2   cos x   log 2 cos3x  0 … (1)

Necessary condition
cos x  0    5 
n  x  , 
cos3x  0  2 6 
Now, (1)
 2cos x.cos3 x  1  8cos 4 x  6cos 2 x  1  0
  4 cos 2 x  1 2 cos 2 x  1  0
1 1  2 3 
  cos x    x   , 
2 2  3 4
75.
x  y  z  number of numbers = 9C3
x  y  z  number of numbers = 9C2
x  y  z  number of numbers = 9C2
x  y  z  number of numbers = 9
total numbers = 9C3  9 C2  9 C2  9  165

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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
        
76.  
r  xa  yb  z a  b dot product with a, b , a  b we get
4x  y  2
x y 8
3z  4 3
4
x  2, y  10, z 
3
77. SOL: -

 2t 2 24t 2 
B  0,  
 3 t2  9 
 

 2t 2 
 4t , A
 3 
 
S  0,6 


Equation of AB Is

2t 2 6t
y  ( x  4t )
3 9  t2

2t 2 24t 2
Put x  0 then, y 
3 9  t2

4t 2 24t 2
6 2
  lim 3 t  9  48  6  32  86
t6 3 3 3
x
78. f ( x) 
1  x2
1  x2
f ' ( x) 
2

1  x2 
x  , f ( x)  0
x  , f ( x )  0

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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
1 1
At x  1, and  1, f ( x ) takes and
2 2
79. 2x  3 y

3y
x  3, 6,......2 y; y  2, 4....66
2

n  66

80. CONCEPTUAL
 20  5t 
81. Sol: C  , t  D  s,0 
 4 
1
 5  s  t  5
2
2
 20  5t
2 
CD    s   t2
 4 
2
 10  5t 
      t 2
 t  4 
100 41
 2  t 2  25  5 41  25
t 16
1  1  1 1 1 1
82. Sol: Outcomes are   d  ,   d  ,..., 10 times , ,..., 10 times,  d ,  d ,...,
4  4  4 4 4 4
10 times
1 1  1
Mean =   30  
30  4  4
Variance of the outcomes is,
2 2 2
1 2 1  1  1 1   1
   xi2   x 
2
   d   10     10    d   10  
30 30  4   4 4   16
4 1  1  1
  30   20d 2  
3 30  16  16
4 1 2 1
   d2   d2  2  d  2
3 16 3 16
x
2 tan 1
r  2 f 2r  2  lim 2 1  2
 
83. f  r   lim
x 0 x r 2r n
 2r
84. Now,  a  c  e  g    b  d  f   11x
And a  b  c  d  e  f  g  31
Case (i)

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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
a  c  e  g  21 and b  d  f  10
b  d  f  10   b, d , f   1, 2,7 1,3,6 
Total number of cases  2  3! 4!  228
Case (ii)
a  c  e  g  10 and b  d  f  21
 b, d , f    6,7,8 possible number of cases   3! 4!  144
Finally, total number of cases  432
85.    3
f  n  2   k. f  n   f  n  2
  
  n  2   n  2  k  n   n   n 2   n  2 
 1   1 
 

 k  n  n   n   2  2    n  2  2 
   

  is a root of x 2  3 x  1  0
  2  3  1  0
1 1
    3  2  2  7
 
2 1
Similarly   2  7

 
 k  n  n   n  7   n  7 
 k=7
86. We have, f  x   2 x3  3  2  p  x 2  12 px  ln 16  p 2  

Now, f '  x   6 x 2   2  p  x  2 p 
 f '  x   0  x  2, p
As, f  x  has exactly one local maxima and one local minima
So, p  2
Also, 16  p 2  0
 p 2  16  0
  p  4  p  4   0
 4  p  4
 The possible integral values of p are 3, 2, 1,0,1,3
87. Sol: On differentiating both sides with respect to x we get
x  cos x  sin x  g  x   e x  1  xe x  e x
 1  xg 1  x   g  x    xg  x  e x
 
ex 1 x 2 2
1  e  e x
 1

  e x  1 x  cos x  sin x   g  x   e x  1  xe x   x  e x  1 g 1  x   g  x   e x  1  xe x 

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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
1
 g  x   cos x  sin x
 g  x   sin x  cos x  c
   3 
 g   2  c 1 g   1
2   4 
5 2
88.
4
 
cos 2 x  cos4 x  sin 4 x  cos6 x  sin 6 x  2

5
  
 cos2 2 x  1  2sin 2 x cos2 x  1  3cos2 x sin 2 x  2
4

5 2
cos 2 x  5sin 2 x cos2 x  0
4
5 2 5
cos 2 x 
2 4
1
cos2 2 x   2cos 2 2 x  1
2
1 + cos 4x = 1
cos 4 x  0, as0  x  2
As 0  4 x  8
  3 5 7 9 11 13 15 
4x   , , , , , , , 
8 8 8 8 8 8 8 8 
89. if last digit is 8 (last digit matches only)………..8

First place can be filled by 9 ways

Second………………………………10 ways

Third……………………………………9 ways

7 (cannot come at tens place)

No. of ways  9 10  9  810

Similarly if last two digits are 78 only

Then nos.  9  9  81

If last 3 digits matches then

Favorable no’s = 8

So favorable cases  810  81  8  1  900

Total cases = 9000

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 SRI CHAITANYA IIT ACADEMY, INDIA 24-03-24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-29/26_KEY &SOL’S
900 1
Probability  
9000 10
90. A   2, 2,1 , B  1, 2, 2 , C   2,1, 2

AB   2  12   2  2 2  1  2 2  1 0 1  2

BC  2 , CA  2


 2 1 2 2  2 1 1 2  2 
O , . 
 3 3 3 
5 5 5
O  , , 
3 3 3
3 3 
m   , , 2 
2 2 
h1  Om  h2  h3
2 2 2
5 3 5 3 5 3 1 1 1
Om               
3 2 3 2 3 2 36 36 9
1
  h2  h3
6
1 1 1
 
2 h12  h22  h32  2      1
6 6 6

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