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Chemistry Assignment 5 Class 11

This document contains 20 multiple choice and short answer questions related to redox reactions and oxidation numbers in chemistry. Some key topics covered include identifying oxidation states of elements in compounds, classifying reactions as redox or non-redox, balancing redox equations, and explaining properties of oxidizing and reducing agents.

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Nayan Shah
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103 views

Chemistry Assignment 5 Class 11

This document contains 20 multiple choice and short answer questions related to redox reactions and oxidation numbers in chemistry. Some key topics covered include identifying oxidation states of elements in compounds, classifying reactions as redox or non-redox, balancing redox equations, and explaining properties of oxidizing and reducing agents.

Uploaded by

Nayan Shah
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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PP5/CHEM11 /23-24

DELHI PUBLIC SCHOOL VADODARA


Academic Session 2023 -24
Practice paper 5

Subject : Chemistry (043) Class: XI


_______________________________________________________________________________________
1. The oxidation number of Cr in Cr(CO)6 is —————–

(a) 0 (b) +2 (c) -2 (d) +6

2. In the reaction:

2Ag + 2H2SO4 → Ag2SO4 + 2H2O + SO2

Sulphuric acid acts as:


(a) Oxidising agent (b) Reducing agent
(c) Catalyst (d) Acid as well as oxidant

3. H2O2 changes Cr2O72- ion to CrO5 in an acidic medium, the oxidation state
of Cr in CrO5 is
(a) +6 (b) +5 (c) -10 (d) +3

4 H2SO4 acts as a strong oxidising agent. In which of the reaction, is it not acting as an
oxidising agent?
(a) C + 2H2SO4 → CO2 + 2SO2 + 2H2O

(b) CaF2 + 2H2SO4 → CaSO4 + 2HF

(c) S + 2H2SO4 → 3SO2 + H2O

(d) Cu + 2H2SO4 → CuSO4 + SO2 + 2H2O

5 Assertion : In a reaction
Zn(s) + CuSO4 (aq) → ZnSO4(aq) + Cu(s)
Zn is a reductant but itself get oxidized.
Reason: In a redox reaction, oxidant is reduced by accepting electrons and reductant is
oxidized by losing electrons.
(a) Assertion is correct, reason is correct; reason is a correct explanation for assertion.
(b) Assertion is correct, reason is correct; reason is not a correct explanation for assertion
(c) Assertion is correct, reason is incorrect
(d) Assertion is incorrect, reason is correct.

6 Assign oxidation number to the underlined elements in the following species:


(a) Na2S2O8 (b) MnO42- (c) Na2Cr2 O4 (d) ClO4- (e) CrO5 (f) K2SO3

(g) K[Co(CO)4]

7 Identify the substance oxidized and reduced, also identify oxidizing and reducing agents in

the following reactions:

(a) Na2SO3 + Cl2 + H2O Na2SO4 + HCl

(b) 2Cu2+ +4I−→2CuI + I2

(c) 2Cu2+ + CH3CHO + 5OH- CH3COO- + 3H2O + Cu2O

(d) I2 + 5Cl2 + 6H2O 2HIO3 + 10HCl

8 Write the formula for the following compounds;

(a) Tin(IV) chloride (b) Copper(II) oxide

(c) lead (IV) Oxide (d) Iodine (VII) fluoride

9 Balance the following equations of the reactions by any one method:

(a) Cl2+ NaOH NaCl + NaClO3 + H2O

(b) MnO2 + HCl MnCl2 + Cl2 +H2O

(c) Cr2O72- + H+ + I- I2 + Cr+3 + H2O

(d) Fe(OH)2(s) + H2O2 Fe(OH)3(s) + H2O (in basic medium)

(e) P4 + NaOH + H2O NaH2PO2 + PH3

(f) MnO4- + S2O32- + H2O MnO2 + SO42- + OH-

10 MnO4-2 disproportionates in acidic medium but MnO4- does not. Explain.

11 Distinguish between oxidation number and valency.

12 Calculate the number of electrons lost or gained during the following reactions :

(a) Fe + H2O Fe3O4 + H2 (b) AlCl3 + K Al + 3KCl

13 Explain why :

(a) HNO3 acts only as oxidant while HNO2 act both as oxidant and reductant?

(b) AgF2 is unstable and act as an oxidizing agent?

(c) ClO3- , ClO,-, and ClO2- undergo disproportionation but ClO4- does not?

(d) Nitric acid is an oxidising agent and reacts with PbO, but it does not react
with PbO₂.
(e) Fluorine does not show a disproportionation reaction?
14 The reaction:

Cl2(g) + 2OH– (aq) → CIO– (aq) + Cl– (aq) + H2O(l)


represents the process of bleaching. Identify and name the species that bleaches the
substances due to their oxidising action.

15 Identify the type of redox reaction:


(a) P4 + NaOH + H2O NaH2PO2+ PH3

(b) 3Mg(s)+N2(g) ΔMg3N2(s)

(c) Cl2 + Br- Br2 + Cl-


16 What are the maximum and minimum oxidation number of nitrogen? Give one example
each.
17 Write a balanced chemical equation for the following reactions:

(a) Permanganate ion (MnO4–) reacts with sulphur dioxide gas in an acidic medium to
produce Mn2+ and hydrogensulphate ion.
(b) Reaction of liquid hydrazine (N2H4) with chlorate ion (CIO3–) in basic medium
produces nitric oxide gas and chloride ion in a gaseous state.
(c) Dichlorine heptaoxide (Cl2O7) in gaseous state combines with an aqueous solution of
hydrogen peroxide in acidic medium to give chlorite ion (ClO2–) and oxygen gas.

18 Which of the following are redox reactions and which are not?.Explain.
(a) NaCl + KNO3 → NaNO3 + KCl
(b) CaC2O4 + 2HCl → CaCl2 + H2C2O4
(c) MnO−4 + C2O2−4 + H+ → Mn2+ + CO2 + H2O
(d) Mg(OH)2 + 2NH4Cl → MgCl2 + 2NH4OH
(e) Zn + 2AgCN → 2Ag + Zn (CN)2

19 A compound contains atoms of three elements -A, B & C. If the oxidation number of A is
+2, B is +5 and that of C is -2 . Find the possible formula of the compound.

20 All decomposition reactions are not redox reactions. Give justification.

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