Thermodynamics Assignment

1. ∆𝑈 = 𝑞 + 𝑤, is mathematical expression for 8. For the reaction of one mole of zinc dust with one
(1) first law of thermodynamics mole of sulphuric acid in a bomb calorimeter, ∆𝑈
(2) second law of thermodynamics and 𝑤 correspond to
(3) third law of thermodynamics (1) ∆𝑈 < 0, 𝑤 = 0 (2) ∆𝑈 < 0, 𝑤 < 0
(4) zeroth law of thermodynamics (3) ∆𝑈 > 0, 𝑤 = 0 (4) ∆𝑈 > 0, 𝑤 > 0

2. Two litres of an ideal gas at a pressure of 10 atm 9. If enthalpy of an overall reaction 𝑋 → 𝑌 along one
expands isothermally into a vacuum until its total route is ∆𝑟 𝐻 and ∆𝑟 𝐻1 , ∆𝑟 𝐻2 , ∆𝑟 𝐻3 … representing
volume is 10 litres. How much heat is absorbed and enthalpies of reactions leading to same product Y
how much work is done in the expansion? then ∆𝑟 𝐻 is
(1) 10 J, 10 J (2) 8 J, 10 J (1) ∆𝑟 𝐻 = ∆𝑟 𝐻1 + ∆𝑟 𝐻2 + ∆𝑟 𝐻3 …
(3) 18 J, 0 J (4) 0 J, 0 J (2) ∆𝑟 𝐻 = ∆𝑟 𝐻1 × ∆𝑟 𝐻2 × ∆𝑟 𝐻3 …
(3) ∆𝑟 𝐻 = ∆𝑟 𝐻1 + ∆𝑟 𝐻2 − ∆𝐻3 …
3. If the heat change at constant volume for ∆𝑟 𝐻1 ×∆𝑟 𝐻2 ×∆𝑟 𝐻3
decomposition of silver oxide is 80.25 kJ, what will (4) ∆𝑟 𝐻 = 2
be the heat change at constant pressure?
3
(1) 80.25 kJ (2) 80.25 kJ 10. In the reaction: 𝑆 + 𝑂2 → 𝑆𝑂3 + 2𝑥 kcal and
2
(3) < 80.25 kJ (4) 160.50 kJ 1
𝑆𝑂2 + 𝑂
2 2
→ 𝑆𝑂3 + 𝑦 kcal, heat of formation of
4. Consider the given diagram for 1 mole of a gas X 𝑆𝑂2 in kcal is
and answer the following question. (1) (𝑥 + 𝑦) (2) (𝑥 − 𝑦)
(3) (2𝑥 + 𝑦) (4) (2𝑥 − 𝑦)

11. What will be the heat of reaction for the following

reaction? Will the reaction be exothermic or
endothermic?
𝐹𝑒2 𝑂3(𝑠) + 3𝐻2(g) → 2𝐹𝑒(𝑠) + 3𝐻2 𝑂(𝑙)
∆𝑓 𝐻°(𝐻2 𝑂, 𝑙) = −285.83 kJ mol−1 ,
The process 𝐴 → 𝐵 represents ∆𝑓 𝐻°(𝐹𝑒2 𝑂3 , 𝑠) = −824.2 kJ mol−1
(1) isobaric change (2) isothermal change (1) −824.2 kJ mol−1 , exothermic
(3) adiabatic change (4) isochoric change (2) +33.3 kJ mol−1 , endothermic
5. Consider the following reaction: (3) −33.3 kJ mol−1 , exothermic
1 (4) +824.2 kJ mol−1 , endothermic
𝐶𝑂(𝑔) + 𝑂2(g) → 𝐶𝑂2 (g)
2
How are ∆𝑈 and ∆𝐻 related for the reaction? 12. Hess’s law is applicable for the determination of
(1) ∆𝐻 = ∆𝑈 − 0.5𝑅𝑇 heat of
(2) ∆𝐻 = ∆𝑈 − 𝑅𝑇 (1) transition (2) formation
(3) ∆𝐻 = ∆𝑈 + 0.5 𝑅𝑇 (3) reaction (4) all of these
(4) ∆𝐻 = ∆𝑈 − 1.5𝑅𝑇
13. The het of combustion of ethane and benzene is
6. The value of ∆𝑈 for the reversible isothermal −1560 and −3268 kJ mol−1 respectively. Which
evaporation of 90 g water at 100 °𝐶 will be of two has higher efficiency as fuel per gram and
(∆𝐻𝑒𝑣𝑎𝑝 of water = 40.8 kJ mol−1, 𝑅 = what is the amount of heat produced per gram?
8.314 J K −1 mol−1) (1) Benzene, 41.9 kJ g −1 (2) Ethane, 52 kJ g −1
−1
(1) 4800 kJ (2) 188.494 kJ (3) Benzene, 78 78 kJ g (4) Ethane, 30 kJ g −1
(3) 40.8 kJ (4) 125.03 kJ
14. Which of the following relationships is not correct?
7. 200 joules of heat was supplied to a system at (1) ∆𝐻 = ∆𝑈 + ∆𝑛g 𝑅𝑇
constant volume. It resulted in the increase in (2) ∆𝐻𝑠𝑢𝑏 = ∆𝐻fussion + ∆𝐻vap
temperature of the system from 298 to 323 K. What (3) ∆𝐻𝑟 ° = ∑ 𝐻°𝑓(𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡𝑠) − ∑ 𝐻°𝑓(products)
is the change in internal energy of the system?
(4) ∆𝐻°𝑟 = ∑ 𝐵. 𝐸. of reactants − ∑ 𝐵. 𝐸. of
(1) 400 J (2) 200 J
products
(3) 50 J (4) 150 J
NEET-FINISHING-TOUCH-2024/Chemistry/Thermodynamics Assignment
15. The enthalpy of solution of sodium chloride is 21. Dissolution of ammonium chloride in water is an
4 kJ mol−1 and its enthalpy of hydration of ions is endothermic reaction, yet it is a spontaneous
−784 kJ mol−1. What will be the lattice enthalpy of process. This is due to the fact that
sodium chloride? (1) ∆𝐻 is −𝑣𝑒, ∆𝑆 is −𝑣𝑒
(1) +780 kJ mol−1 (2) ∆𝐻 is −𝑣𝑒, ∆𝑆 is +𝑣𝑒
(2) +394 kJ mol−1 (3) ∆𝐻 is +𝑣𝑒, ∆𝑆 is +𝑣𝑒 and ∆𝐻 < 𝑇∆𝑆
(3) +788 kJ mol−1 (4) ∆𝐻 is +𝑣 and ∆𝐻 > 𝑇∆𝑆
(4) +398 kJ mol−1
22. For a reaction: 𝑋 → 𝑌 + 𝑍
16. Match the column I with column II and mark the Absolute entropies are 𝑋 = 120 J K −1 mol−1 ,
appropriate choice. 𝑌 = 213.8 J K −1 mol−1and 𝑍 = 197.9 J K −1 mol−1.
Column I Column II What will be the entropy change at 298 K and 1
(A) CH4(g) + 2O2(g) (i) ∆𝑠𝑜𝑙 H° atm?
→ CO2(g) + 2H2 O (1) 291.7 J K −1 (2) 255 J K −1
(3) 213.8 J K −1 (4) 257.3 J K −1
(B) H2(g) → 2H(g) (ii) ∆lattice 𝐻°
(C) NaCl(s) (iii) ∆𝑐 𝐻° 23. Which of the following statements regarding Gibb’s
→ Na+(g) + Cl
−
energy change is correct?
𝑁𝑎𝐶𝑙(𝑠) (1) If ∆𝐺 is negative (< 0), the process is non-
(D) (iv) ∆bond H°
+ − spontaneous
→ 𝑁𝑎(𝑎𝑞) + 𝐶𝑙(𝑎𝑞)
(2) If ∆𝐺 is positive (> 0), the process is
(1) (A) → (iv), (B) → (iii), (C) → (i), (D) → (ii) spontaneous.
(2) (A) → (ii), (B) → (i), (C) → (iv), (D) → (iii) (3) If ∆𝐺 is negative (< 0), the process is
(3) (A) → (i), (B) → (ii), (C) → (iii), (D) → (iv) spontaneous
(4) (A) → (iii), (B) → (iv), (C) → (ii), (D) → (i) (4) If ∆𝐺 is positive (> 0), the process is in
equilibrium.
17. For which of the process, ∆𝑆 is negative?
(1) H2 (g) → 2H(g) 24. For a reaction to be spontaneous at any temperature,
(2) N2(g,1 atm) → N2 (g,8 atm) the conditions are
(1) ∆H = +ve, ∆S = +ve
(3) 2SO3 (g) → 2SO2 (g) + O2 (g)
(2) ∆H = −ve, ∆S = −ve
(4) C(diamond) → C(graphite) (3) ∆H = +ve, ∆S = −ve
(4) ∆H = −ve, ∆S = +ve
18. The change in energy on freezing 1.0 kg of liquid
water at 0°C and one atm is (Given energy of 1 25. What is the entropy change when 1 mole oxygen
fusion of ice = 6.03 kJ mol−1 at 0°C) gas expands isothermally and reversibly from an
(1) 235 kJ kg −1 (2) 450 kJ kg −1 initial volume of 10 L to 100 L at 300 K?
(3) −335 kJ kg −1
(4) −235 kJ kg −1 (1) 19.14 J K −1 (2) 109.12 J K −1
−1
(3) 29.12 J K (4) 10 J K −1
19. In general, for exothermic reactions to be
spontaneous 26. Which of the following statements is not correct?
(1) temperature should be high (1) For a spontaneous process, ∆𝐺 must be negative.
(2) temperature should be zero (2) Enthalpy, entropy, free energy etc. are state
(3) temperature should be low variables.
(4) temperature has no effect (3) A spontaneous process is reversible in nature.
(4) Total of all possible kinds of energy of a system
20. Which of the following expressions regarding is called its internal energy.
entropy is not correct? 27. For a reaction, 𝑃 + 𝑄 → 𝑅 + 𝑆. The value of ∆𝐻° is
𝑞
(1) ∆𝑆system = 𝑇 −30 kJ mol−1 and ∆𝑆 is −100 J k −1 mol−1. At
(2) ∆𝑆system = ∆𝑆𝑡𝑜𝑡𝑎𝑙 + ∆𝑆surrounding what temperature the reaction will be at
(3) ∆𝑆 = Sfinal − Sinitial equilibrium?
(4) ∆𝑆𝑡𝑜𝑡𝑎𝑙 = ∆𝑆system + ∆𝑆surrounding (1) 27 °C (2) 52 °C
(3) 30 °C (4) 45 °C

NEET-FINISHING-TOUCH-2024/Chemistry/Thermodynamics Assignment
28. Match the following columns and mark the
appropriate choice.
Column-I Column-II
(A) Exothermic (i) ∆𝐻 = 0, ∆𝑈
=0
(B) Spontaneous (ii) ∆𝐺 = 0
(C) Cyclic process (iii) ∆𝐻 is
negative
(D) Equilibrium (iv) ∆𝐺 is
negative
(1) (A) → (ii), (B) → (iii), (C) → (i), (D) → (iv)
(2) (A) → (iv), (B) → (i), (C) → (iii), (D) → (ii)
(3) (A) → (i), (B) → (ii), (C) → (iv), (D) → (iii)
(4) (A) → (iii), (B) → (iv), (C) → (i), (D) → (ii)

29. The equilibrium constant for a reaction is 10. What

will be the value of ∆𝐺° at 300 K?
(1) − 5.74 kJ (2) −574 kJ
(3) + 11.48 kJ (4) + 5.74 kJ

30. Which is the correct relationship between ∆𝐺° and

equilibrium constant 𝐾𝑝 ?
(1) 𝑘𝑝 = −𝑅𝑇 log ∆𝐺° (2) 𝑘𝑝 = [𝑒/𝑅𝑇]∆𝐺°
(3) 𝑘𝑝 = −∆𝐺°/𝑅𝑇 (4) 𝑘𝑝 = 𝑒 −∆𝐺°/𝑅𝑇

Answer Key
Q 1 2 3 4 5 6 7 8 9
A 1 4 2 4 1 2 2 1 1
Q 10 11 12 13 14 15 16 17 18
A 4 3 4 2 3 3 4 2 3
Q 19 20 21 22 23 24 25 26 27
A 3 2 3 1 3 4 1 3 1
Q 28 29 30
A 4 1 4

NEET-FINISHING-TOUCH-2024/Chemistry/Thermodynamics Assignment