Crystal Diffraction
Crystal Diffraction
2. **In X-ray diffraction, what phenomenon occurs when X-rays strike a crystal lattice at a
specific angle?**
a) Reflection
b) Refraction
c) Absorption
d) Transmission
**Answer: a) Reflection**
4. **Which experimental method involves using a stationary crystal and allows the
observation of multiple diffraction orders simultaneously?**
a) Laue method
b) Rotating crystal method
c) Powder method
d) Single crystal method
**Answer: c) The lattice formed by the Fourier transform of the real lattice**
4. When X-ray are incident on an atom, they make an electronic cloud move.
a) True
b) False
8. If the angle of incidence is 30°, then the wavelength for first-order spectrum is equal to
__________
a) d
b) 2d
c) d/2
d) d/3
9. If X-ray of wavelength 100 Å is incident on an atom at an angle of 90°, then what should
be the value of d for first-order sepctrum?
a) 30 Å
b) 40 Å
c) 50 Å
d) 60 Å
1. In which case can the rotating crystal method for determining crystal structure be used?
a) Single crystal
b) Polycrystalline
c) Fine-grained polycrystalline
d) Cold worked crystals
2. What is the resultant image formed for very fine grains in the Laue back reflection
method?
a) Few clear spots
b) Large number of spots
c) Continuous rings
d) Irregular spots
14. The angle between [111] and [11⎯2] directions in a cubic crystal is (in degrees)
(a) 0 (b) 45 (c) 90 (d) 180
15. Miller indices of the line of intersection of (⎯1⎯11) and (110) are
(a) [110] (b) [101] (c) [10⎯1] (d) [⎯110]
18. For c coordination number of four, anion sits at the center of ……..where corners are
occupied by
cations
(a) Cube (b) Tetrahedron (c) Triangle (d) Octahedron
**1. Which of the following statements is TRUE about the reciprocal lattice?**
**Answer:** (b) The reciprocal lattice is obtained by taking the Fourier transform of the
real lattice.
**Explanation:** The reciprocal lattice is a mathematical construct that reveals the allowed
wavevectors for diffraction from a crystal. It's essentially the Fourier transform of the real
lattice, where points in the real lattice correspond to waves in the reciprocal lattice.
**2. What is the relationship between the spacing of points in the reciprocal lattice and the
real lattice?**
**Answer:** (b) They are inversely proportional. Smaller unit cell in the real lattice leads to
a larger unit cell in the reciprocal lattice, and vice versa.
**Answer:** (d) The symmetry of the real lattice. The arrangement of atoms in the real
lattice dictates the allowed wavevectors and hence the symmetry of the reciprocal lattice.
**4. Which of the following points in the reciprocal lattice corresponds to a direction where
diffraction is NOT allowed?**
**Answer:** (c) A point inside the Brillouin zone. Only points on the edges and faces of the
Brillouin zone, which represent allowed wavevectors, can lead to diffraction.
**5. What is the relationship between the reciprocal lattice vector K and the direction of
diffracted waves?**
(a) K points in the direction of the incident wave.
(b) K points in the direction of the scattered wave. (Correct)
(c) K is perpendicular to both the incident and scattered waves.
(d) K has no relation to the direction of waves.
**Answer:** (b) K points in the direction of the scattered wave. The reciprocal lattice
vector K encodes the direction and phase of the diffracted waves.
**6. How does the reciprocal lattice help us understand X-ray diffraction?**
**Answer:** (b) It predicts the angles at which X-rays are diffracted. By analyzing the
points in the reciprocal lattice that satisfy Bragg's Law, we can determine the angles at
which X-rays will be diffracted from the crystal.
**7. What is the relationship between the reciprocal lattice and Brillouin zone?**
**Answer:** (b) The Brillouin zone is a subset of the reciprocal lattice. It represents the
region of the reciprocal lattice where unique wavevectors exist for the crystal lattice.
**8. How can the reciprocal lattice be used to study neutron diffraction?**
**Answer:** (b) The band structure of a crystal, which describes the allowed energy levels
for electrons, can be understood by analyzing the reciprocal lattice and its Brillouin zone.
The periodic nature of the lattice translates to specific wavevectors and gaps in the
electronic states.
**10. What are some limitations of using the reciprocal lattice concept?**
**Answer:** (a) The reciprocal lattice assumes a perfect, periodic crystal structure.
Deviations from perfect order, such as defects or impurities, can affect the accuracy of
predictions based on the ideal lattice.
**1. For diffraction to occur, which of the following is NOT a necessary condition?**
(a) The wavelength of light must be comparable to the size of the aperture or obstacle.
(b) The light source must be at a finite distance from the aperture or obstacle.
(c) The light source must be monochromatic (single wavelength). (Correct)
(d) The wavefront of the light must be coherent (constant phase relationship).
**Answer:** (c) While monochromatic light simplifies analysis, diffraction can occur with
polychromatic light, just with a broader and less defined pattern.
**2. In single-slit diffraction, the intensity maximum on either side of the central bright
fringe occurs at an angle θ, given by:**
(a) θ = λ/d
(b) θ = sin⁻¹(λ/d)
(c) θ = tan⁻¹(λ/d) (Correct)
(d) θ = 2λ/d
**Answer:** (c) This corresponds to the first diffraction minimum formula, where λ is the
wavelength of light and d is the slit width.
**3. The diffraction pattern observed on a screen behind a circular aperture will be:**
**Answer:** (c) Circular aperture produces Airy's disc pattern with central bright maximum
surrounded by bright and dark rings due to constructive and destructive interference.
**4. In a diffraction grating, the separation between two diffraction maxima for the same
order (n) and different wavelengths (λ₁ and λ₂) is given by:**
**Answer:** (c) This shows the dependence of angular separation on both wavelength
difference and grating spacing (d).
**5. Which of the following factors does NOT affect the spacing between diffraction
fringes?**
**Answer:** (c) While the shape can affect overall pattern shape, the spacing between
fringes mainly depends on wavelength and distance.
Answer: (b) Ewald's method excels at calculating the electrostatic potential in crystals,
especially for large lattices, by converting a slowly converging real-space sum into a rapidly
converging reciprocal-space sum with an additional term.
Q What is the key advantage of using Ewald's method compared to direct summation in
real space?
Answer: (d) Ewald's method shines for large lattices where direct summation becomes
computationally expensive and suffers from slow convergence. The method cleverly splits
the sum into two parts, one converging quickly in reciprocal space and the other easily
evaluated in real space.
Q Which quantity in Ewald's method relates to the wavevector of a plane wave in the
crystal?
(a) The lattice constant of the crystal.
(b) The Madelung constant for the specific lattice.
(c) The radius of the Ewald sphere used in the calculation.
(d) The reciprocal lattice vector K. (Correct)
Answer: (d) The reciprocal lattice vector K plays a crucial role in Ewald's method. It defines
the wavevector of a plane wave within the crystal lattice and governs its properties, such as
momentum and direction.
Q What factor in Ewald's method primarily influences the convergence of the calculation?
Answer: (d) The Ewald sphere radius significantly impacts the convergence of the
calculation. A carefully chosen radius balances the accuracy and computational cost by
effectively separating the rapidly converging and slowly converging parts of the sum.
Answer: (b) The Brillouin zone is more than just a geometrical space; it holds deep physical
meaning. It defines the unique wavevectors allowed within the crystal lattice, and points
outside the zone correspond to folded-back equivalent states.
Answer: (d) The Brillouin zone inherits its symmetry directly from the underlying crystal
lattice. The arrangement of atoms in the unit cell dictates the allowed wavevectors and
their relationships, shaping the symmetry of the Brillouin zone.
Q What physical significance do points on the edge of the Brillouin zone hold?
Answer: (b) Points on the edge, or faces, of the Brillouin zone hold special importance. They
represent high-symmetry directions within the reciprocal lattice, where specific wavevector
properties lead to interesting phenomena like band edge states and critical points in band
structures.
**1. In reciprocal space, the spacing of lattice points for a given lattice is:**
**Answer:** (b) This key relationship reveals how tightly packed a real-space lattice
translates to a more spread-out or compressed reciprocal lattice and vice versa.
**2. For a simple cubic (SC) lattice with lattice constant a, which vector represents a
reciprocal lattice point?**
(a) (0, 0, 0)
(b) (a/2, a/2, a/2)
(c) (2π/a, 0, 0) (Correct)
(d) (a, 0, a/2)
**Answer:** (c) In reciprocal space, wavevectors are scaled versions of real-space lattice
vectors. For SC, reciprocal lattice vectors have components that are 2π divided by the
corresponding real-space lattice constants.
**3. Compared to the SC lattice, the reciprocal lattice points for a BCC lattice are:**
**Answer:** (a) Due to the additional atom at the body center in BCC, there are more
reciprocal lattice points compared to SC, resulting in a denser packing in reciprocal space.
**4. Which direction in the reciprocal lattice of an FCC lattice corresponds to a high-
symmetry direction?**
(a) [1, 0, 0]
(b) [1, 1, 1] (Correct)
(c) [0.5, 0.5, 0.5]
(d) All directions are high-symmetry in FCC.
**Answer:** (b) The [1, 1, 1] direction, also known as the face diagonal, is a high-symmetry
direction in FCC because it connects corners of the unit cell, representing important
wavevector properties in the band structure.
**Answer:** (a) The Brillouin zone, representing unique wavevectors in the lattice, directly
reflects the symmetry of the real-space lattice. Hence, SC has a cubic Brillouin zone.
(a) Cube.
(b) Tetrahedron.
(c) Octahedron. (Correct)
(d) Dodecahedron.
**Answer:** (c) The additional symmetry element in BCC, a fourfold rotation axis along
body diagonals, leads to an octahedral Brillouin zone.
(a) Cube.
(b) Tetrahedron.
(c) Octahedron.
(d) Dodecahedron. (Correct)
**Answer:** (d) FCC lattice boasts the highest symmetry among the three, resulting in a
dodecahedral Brillouin zone with 12 faces reflecting its high degree of symmetry.
**8. Points on the edge of the Brillouin zone for any lattice correspond to:**
**Answer:** (c) Edges and faces of the Brillouin zone represent high-symmetry directions
where interesting phenomena like band edge states and critical points occur.
Absolutely! Here are the next 7 MCQs on the reciprocal lattice for SC, BCC, and FCC lattices
with answers:
**10. X-ray diffraction patterns depend on:**
**Answer:** (c) The interaction of X-rays with the periodic arrangement of atoms in the
crystal, represented by both real-space and reciprocal-space lattice characteristics,
determines the diffraction pattern.
**11. Which lattice type generally exhibits more diffraction peaks in its X-ray diffraction
pattern?**
**Answer:** (c) The higher atomic density and additional high-symmetry directions in FCC
lead to a richer reciprocal lattice and consequently, more pronounced and diverse
diffraction peaks compared to SC and BCC.
**Answer:** (c) Unlike X-rays, neutrons interact differently with different elements,
allowing for direct observation of both heavy and light atoms within the crystal lattice
through their specific contributions to the diffraction pattern.
**Answer:** (c) The allowed and forbidden wavevector states within the Brillouin zone
directly influence the electronic band structure of a material, impacting its conductivity,
band gaps, and other electronic properties.
**14. The size of the Brillouin zone for a given lattice is affected by:**
**Answer:** (d) The Brillouin zone is an intrinsic property of the crystal lattice; its size and
shape are solely determined by the real-space lattice symmetry and are independent of
external factors like temperature, pressure, or probing radiation.
**Answer:** (b) The reciprocal lattice primarily provides information about the allowed
and forbidden wavevector states within the crystal, which hold significant implications for
the band structure, electronic properties, and potential phenomena like Bragg diffraction.
**Answer:** a. 1
3. **In the reciprocal lattice of a Body-Centered Cubic (BCC) lattice, where is the first
Brillouin zone centered?**
a. At the origin
b. At the body center
c. At the face center
d. At the corner
4. **What is the relationship between the lattice constant of a crystal and the spacing
between reciprocal lattice points?**
a. Directly proportional
b. Inversely proportional
c. No relationship
d. Quadratically proportional
5. **For a Face-Centered Cubic (FCC) lattice, how many lattice points are there in the
reciprocal lattice?**
a. 1
b. 2
c. 4
d. 8
**Answer:** c. 4
6. **Which of the following lattice types has a more complex reciprocal lattice structure?**
a. Simple Cubic (SC)
b. Body-Centered Cubic (BCC)
c. Face-Centered Cubic (FCC)
d. All have the same complexity
7. **In the reciprocal lattice, the planes perpendicular to the (100) direction in the direct
lattice correspond to which Miller indices?**
a. (100)
b. (010)
c. (001)
d. (111)
**Answer:** c. (001)
8. **What is the relationship between the volume of the unit cell in direct space and the
volume of the unit cell in reciprocal space?**
a. Directly proportional
b. Inversely proportional
c. No relationship
d. Quadratically proportional
9. **In the reciprocal lattice of a BCC lattice, what is the shape of the first Brillouin zone?**
a. Spherical
b. Cubic
c. Tetrahedral
d. Octahedral
**Answer:** d. Octahedral
10. **For a crystal with a larger direct lattice constant, what happens to the spacing
between reciprocal lattice points?**
a. Increases
b. Decreases
c. Remains the same
d. Becomes zero
**Answer:** b. Decreases
11. **Which lattice type has the most symmetrical reciprocal lattice?**
a. Simple Cubic (SC)
b. Body-Centered Cubic (BCC)
c. Face-Centered Cubic (FCC)
d. All have the same symmetry
12. **In the reciprocal lattice, what does the position of a reciprocal lattice point
represent?**
a. Position of an atom in the crystal
b. Wave vector of a plane wave
c. Energy level of an electron
d. Magnetic moment
13. **For a SC lattice, what is the relationship between the lattice constant 'a' and the
reciprocal lattice vector 'b'?**
a. \( b = \frac{1}{a} \)
b. \( b = 2\pi a \)
c. \( b = \frac{2\pi}{a} \)
d. \( b = a^2 \)
**Answer:** c. \( b = \frac{2\pi}{a} \)
15. **For an FCC lattice, what is the ratio of the lengths of the sides of the first Brillouin
zone in the reciprocal lattice?**
a. 1:1:1
b. 2:2:1
c. 1:1:2
d. 1:2:2
**Answer:** d. 1:2:2
2. **For a Simple Cubic (SC) lattice, how many lattice points are there in the reciprocal
lattice?**
a. 1
b. 2
c. 4
d. 8
**Answer:** a. 1
3. **What is the relationship between the lattice constant 'a' of a crystal and the spacing
between reciprocal lattice points for a SC lattice?**
a. Directly proportional
b. Inversely proportional
c. No relationship
d. Quadratically proportional
**Answer:** b. Cubic
5. **Which of the following statements is true regarding the symmetry of the reciprocal
lattice of a SC crystal?**
a. It has higher symmetry than the direct lattice.
b. It has lower symmetry than the direct lattice.
c. It has the same symmetry as the direct lattice.
d. Symmetry is not relevant in reciprocal space.
6. **In the reciprocal lattice, what is the significance of a reciprocal lattice point?**
a. It represents the position of an atom in the crystal.
b. It represents a specific energy level of an electron.
c. It defines the allowed momentum states for electrons in the crystal.
d. It indicates the magnetic moment of the crystal.
**Answer:** c. It defines the allowed momentum states for electrons in the crystal.
7. **For a crystal with a larger direct lattice constant, what happens to the spacing between
reciprocal lattice points?**
a. Increases
b. Decreases
c. Remains the same
d. Becomes zero
**Answer:** b. Decreases
8. **What is the relationship between the lattice constant 'a' and the reciprocal lattice
vector 'b' for a SC lattice?**
a. \( b = \frac{1}{a} \)
b. \( b = 2\pi a \)
c. \( b = \frac{2\pi}{a} \)
d. \( b = a^2 \)
**Answer:** c. \( b = \frac{2\pi}{a} \)
9. **In the reciprocal lattice of a SC lattice, where is the first Brillouin zone centered?**
a. At the origin
b. At the body center
c. At the face center
d. At the corner
10. **What is the primary purpose of using reciprocal lattice in solid-state physics?**
a. To study crystallographic planes
b. To calculate lattice constants
c. To analyze momentum states of electrons
d. To determine crystal density
2. **For a Body-Centered Cubic (BCC) lattice, how many lattice points are there in the
reciprocal lattice?**
a. 1
b. 2
c. 4
d. 8
**Answer:** a. 1
3. **What is the relationship between the lattice constant 'a' of a crystal and the spacing
between reciprocal lattice points for a BCC lattice?**
a. Directly proportional
b. Inversely proportional
c. No relationship
d. Quadratically proportional
4. **In the reciprocal lattice of a BCC lattice, what is the shape of the first Brillouin zone?**
a. Spherical
b. Cubic
c. Tetrahedral
d. Octahedral
**Answer:** d. Octahedral
5. **Which of the following statements is true regarding the symmetry of the reciprocal
lattice of a BCC crystal?**
a. It has higher symmetry than the direct lattice.
b. It has lower symmetry than the direct lattice.
c. It has the same symmetry as the direct lattice.
d. Symmetry is not relevant in reciprocal space.
6. **In the reciprocal lattice, what is the significance of a reciprocal lattice point?**
a. It represents the position of an atom in the crystal.
b. It represents a specific energy level of an electron.
c. It defines the allowed momentum states for electrons in the crystal.
d. It indicates the magnetic moment of the crystal.
**Answer:** c. It defines the allowed momentum states for electrons in the crystal.
7. **For a crystal with a larger direct lattice constant, what happens to the spacing between
reciprocal lattice points?**
a. Increases
b. Decreases
c. Remains the same
d. Becomes zero
**Answer:** b. Decreases
8. **What is the relationship between the lattice constant 'a' and the reciprocal lattice
vector 'b' for a BCC lattice?**
a. \( b = \frac{1}{a} \)
b. \( b = 2\pi a \)
c. \( b = \frac{2\pi}{a} \)
d. \( b = a^2 \)
**Answer:** c. \( b = \frac{2\pi}{a} \)
9. **In the reciprocal lattice of a BCC lattice, where is the first Brillouin zone centered?**
a. At the origin
b. At the body center
c. At the face center
d. At the corner
10. **What is the primary purpose of using reciprocal lattice in solid-state physics?**
a. To study crystallographic planes
b. To calculate lattice constants
c. To analyze momentum states of electrons
d. To determine crystal density
2. **For a Face-Centered Cubic (FCC) lattice, how many lattice points are there in the
reciprocal lattice?**
a. 1
b. 2
c. 4
d. 8
**Answer:** c. 4
3. **What is the relationship between the lattice constant 'a' of a crystal and the spacing
between reciprocal lattice points for an FCC lattice?**
a. Directly proportional
b. Inversely proportional
c. No relationship
d. Quadratically proportional
4. **In the reciprocal lattice of an FCC lattice, what is the shape of the first Brillouin
zone?**
a. Spherical
b. Cubic
c. Tetrahedral
d. Octahedral
**Answer:** b. Cubic
5. **Which of the following statements is true regarding the symmetry of the reciprocal
lattice of an FCC crystal?**
a. It has higher symmetry than the direct lattice.
b. It has lower symmetry than the direct lattice.
c. It has the same symmetry as the direct lattice.
d. Symmetry is not relevant in reciprocal space.
6. **In the reciprocal lattice, what is the significance of a reciprocal lattice point?**
a. It represents the position of an atom in the crystal.
b. It represents a specific energy level of an electron.
c. It defines the allowed momentum states for electrons in the crystal.
d. It indicates the magnetic moment of the crystal.
**Answer:** c. It defines the allowed momentum states for electrons in the crystal.
7. **For a crystal with a larger direct lattice constant, what happens to the spacing between
reciprocal lattice points?**
a. Increases
b. Decreases
c. Remains the same
d. Becomes zero
**Answer:** b. Decreases
8. **What is the relationship between the lattice constant 'a' and the reciprocal lattice
vector 'b' for an FCC lattice?**
a. \( b = \frac{1}{a} \)
b. \( b = 2\pi a \)
c. \( b = \frac{2\pi}{a} \)
d. \( b = a^2 \)
**Answer:** c. \( b = \frac{2\pi}{a} \)
9. **In the reciprocal lattice of an FCC lattice, where is the first Brillouin zone centered?**
a. At the origin
b. At the body center
c. At the face center
d. At the corner
**Answer:** a. At the origin
10. **What is the primary purpose of using the reciprocal lattice in solid-state physics?**
a. To study crystallographic planes
b. To calculate lattice constants
c. To analyze momentum states of electrons
d. To determine crystal density