NO-TOX2®

Safety Data Sheet

Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 06/15/2015 Supersedes: 10/01/2014 Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Trade name : NO-TOX2®
Product name : PROPYLENE GLYCOL/ALCOHOL
Product form : Mixture
Product code : NA1993
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : De-icant for compressed airlines. Not for human or animal consumption.
1.3. Details of the supplier of the safety data sheet

Tanner Systems, Inc

625 - 19th Avenue N.E
P.O. Box 488
St. Joseph, MN 56374, U.S.A.
Telephone: FACTORY, 800-461-6454
Email: [email protected]
Website: www.tannersystems.com

1.4. Emergency telephone number

Emergency number : CHEMTREC, 800-424-9300 (24 Hours)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 4 H227
Eye Irrit. 2B H320
2.2. Label elements
GHS-US labelling
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H227 - Combustible liquid
H320 - Causes eye irritation
Precautionary statements (GHS-US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking
P264 - Wash hands, forearms and face thoroughly after handling
P280 - Wear eye protection, protective gloves, protective clothing
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P337+P313 - If eye irritation persists: Get medical advice/attention
P370+P378 - In case of fire: Use dry extinguishing powder, carbon dioxide (CO2) to extinguish
P403+P235 - Store in a well-ventilated place. Keep cool
P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or
collection site except for empty clean containers which can be disposed of as non-hazardous
waste
2.3. Other hazards
Other hazards not contributing to the : None under normal conditions.
classification
2.4. Unknown acute toxicity (GHS US)
No data available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable

3.2. Mixture
Name Product identifier %
1,2-Propylene glycol (CAS No) 57-55-6 40 - 70
Ethyl alcohol (CAS No) 64-17-5 1-5
2-Amino-2-methyl-1-propanol (CAS No) 124-68-5 0.5 - 1.5
Boric acid (H3BO3), compound with 2-aminoethanol (CAS No) 26038-87-9 0.1 - 1

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Safety Data Sheet
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Name Product identifier %

Boric acid (H3BO3), compound with 1-amino-2-propanol (CAS No) 26038-90-4 0.1 - 1

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if breathing is affected. If breathing is difficult, supply oxygen.
First-aid measures after skin contact : IF ON SKIN (or clothing): Remove affected clothing and thoroughly wash all exposed skin with
mild soap water. If irritation develops or persists, seek medical attention.
First-aid measures after eye contact : IF IN EYES: Immediately flush with plenty of water. Remove contact lenses if present and easy
to do so. If pain, blinking, or irritation develops or persists, seek medical attention. Continue
rinsing.
First-aid measures after ingestion : IF SWALLOWED: rinse mouth thoroughly. Do not induce vomiting without advice from poison
control center or medical professional. Get medical attention if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes eye irritation.
Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : May cause skin irritation.
Symptoms/injuries after eye contact : Causes eye irritation.
Symptoms/injuries after ingestion : May cause gastrointestinal irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Dry chemical. Carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Combustible liquid.
Explosion hazard : Under fire conditions closed containers may rupture or explode.
Reactivity : No dangerous reactions known under normal conditions of use.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Do not dispose of fire-fighting water in the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Evacuate area. Ventilate area. Keep upwind. Stop leak. No flames, no sparks. Eliminate all
sources of ignition. Spill should be handled by trained clean-up crews properly equipped with
respiratory equipment and full chemical protective gear (see Section 8).

6.1.1. For non-emergency personnel

Protective equipment : Wear Protective equipment as described in Section 8.
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Wear suitable protective clothing, gloves and eye or face protection. Approved supplied-air
respirator, in case of emergency.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Avoid release to the environment. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or
streams. Small quantities of liquid spill: take up in non-combustible absorbent material and
shovel into container for disposal. Prevent entry to sewers and public waters.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Place
in a suitable container for disposal in accordance with the waste regulations (see Section 13).
Exclude sources of ignition and ventilate the area.

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Safety Data Sheet
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

6.4. Reference to other sections

No additional information available

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Avoid contact with skin, eyes and clothing. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not breathe
vapours. Use only in well-ventilated areas. Ensure proper electrical grounding procedures are
in place. When opening drum give bung no more than one (1) turn and stop. Allow pressure to
vent before proceeding.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container closed when not in use. Store in a dry, cool and well-ventilated place. Keep
away from ignition sources. Use only D.O.T. approved containers.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

1,2-Propylene glycol (57-55-6)

Remark (ACGIH) OELs not established
Remark (OSHA) OELs not established

Ethyl alcohol (64-17-5)

ACGIH STEL (ppm) 1000 ppm
OSHA PEL (TWA) (mg/m³) 1900 mg/m³
OSHA PEL (TWA) (ppm) 1000 ppm

2-Amino-2-methyl-1-propanol (124-68-5)
Remark (ACGIH) OELs not established
Remark (OSHA) OELs not established

Boric acid (H3BO3), compound with 2-aminoethanol (26038-87-9)

Remark (ACGIH) OELs not established
Remark (OSHA) OELs not established

Boric acid (H3BO3), compound with 1-amino-2-propanol (26038-90-4)

Remark (ACGIH) OELs not established
Remark (OSHA) OELs not established
8.2. Exposure controls
Appropriate engineering controls : Provide ventilation designed for combustible atmospheres. Provide adequate general and local
exhaust ventilation. Use process enclosures, local exhaust ventilation, or other engineering
controls to control airborne levels below recommended exposure limits. Use explosion-proof
equipment with flammable materials. Ensure adequate ventilation, especially in confined areas.
Personal protective equipment : Gloves. Protective goggles.

Hand protection : Use gloves chemically resistant to this material when prolonged or repeated contact could
occur. Gloves should be classified under Standard EN 374 or ASTM F1296. Suggested glove
materials are: Neoprene, Nitrile/butadiene rubber, Polyethylene, Ethyl vinyl alcohol laminate,
PVC or vinyl. Suitable gloves for this specific application can be recommended by the glove
supplier.
Eye protection : Wear eye protection, including chemical splash goggles and a face shield when possibility
exists for eye contact due to spraying liquid or airborne particles.
Skin and body protection : Wear long sleeves, and chemically impervious PPE/coveralls to minimize bodily exposure.
Respiratory protection : Use NIOSH-approved dust/particulate respirator. Where vapor, mist, or dust exceed PELs or
other applicable OELs, use NIOSH-approved respiratory protective equipment.

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Safety Data Sheet
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Pink.
Odor : Slight alcohol.
Odor Threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 75 °C (167°F)
Flash point : 64.9 °C (150°F) [Method: TCC]
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density @ 20°C (69°F) : 1.02
Density : No data available
Solubility in water : 100 %
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
No dangerous reactions known under normal conditions of use.
10.2. Chemical stability
Stable under recommended handling and storage conditions (see section 7).
10.3. Possibility of hazardous reactions
None known.
10.4. Conditions to avoid
Sparks. Heat. Open flame. Ignition sources.
10.5. Incompatible materials
Oxidizing agents.
10.6. Hazardous decomposition products
Carbon dioxide. Carbon monoxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

1,2-Propylene glycol (57-55-6)

LD50 oral rat 20000 mg/kg
LD50 dermal rabbit 20800 mg/kg
ATE CLP (oral) 20000.000 mg/kg bodyweight
ATE CLP (dermal) 20800.000 mg/kg bodyweight

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Safety Data Sheet
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Ethyl alcohol (64-17-5)

LC50 inhalation rat (mg/l) 124.7 mg/l/4h
2-Amino-2-methyl-1-propanol (124-68-5)
LD50 oral rat 2900 mg/kg
LD50 dermal rabbit > 2000 mg/kg
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Ethyl alcohol (64-17-5)

IARC group 1 - Carcinogenic to humans
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : May cause skin irritation.
Symptoms/injuries after eye contact : Causes eye irritation.
Symptoms/injuries after ingestion : May cause gastrointestinal irritation.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : No information available.

2-Amino-2-methyl-1-propanol (124-68-5)
LC50 fishes 1 190 mg/l 96 hr Lepomis macrochirus
EC50 Daphnia 1 193 mg/l 48 hr Daphnia magna
ErC50 (algae) 520 mg/l 72 hr Desmodesmus subspicatus
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available

12.5. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste treatment methods : Do not discharge to public wastewater systems without permit of pollution control authorities.
No discharge to surface waters is allowed without an NPDES permit.
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Refer to current EPA
regulations. Do not allow the product to be released into the environment.

SECTION 14: Transport information

Ground (US DOT) : NA1993 Combustible liquid, n.o.s., 3, III
:
Water (IMDG) : NA1993 Combustible liquid, n.o.s., 3, III
Air (IATA) : NA1993 Combustible liquid, n.o.s., 3, III

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Safety Data Sheet
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

14.3 Additional Information

Other information : No supplementary information available.
Overland Transport
No additional information available
Transport by sea
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.

Air transport
Not classified for transport by air

SECTION 15: Regulatory information

15.1. US Federal regulations
NO-TOX2®
All chemical substances in this product are listed in the EPA (Environment Protection Agency) TSCA (Toxic Substances Control Act) Inventory
Methyl alcohol CAS #: 67-56-1
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Section 302 (EHS) TPQ lb
Section 304 EHS RQ lb
CERCLA RQ 5000 lb
Section 313 Listed on US SARA Section 313
C.I. Food Red 15 CAS #: 81-88-9
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Section 302 (EHS) TPQ lb
Section 304 EHS RQ lb
CERCLA RQ lb
Section 313 Listed on US SARA Section 313

15.2. International regulations

CANADA
NO-TOX2®
Contains a substance not specified on the DSL (Domestic Substances List) or NDSL (Non-Domestic Substances List):
2-(methylamino)-2-methyl-propanol (27646-80-6) at < 0.1%
2-(methylamino)-2-methyl-propanol CAS#: 27646-80-6 < 0.1%

15.3. US State regulations

California Proposition 65
This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer and/or reproductive
toxicity
Ethyl alcohol (64-17-5)
U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significance risk level
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity -
Female Male
No Yes No No

Methyl alcohol (67-56-1)

U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significance risk level
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity -
Female Male
No Yes No No

C.I. Food Red 15 (81-88-9)

U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significance risk level
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity -
Female Male
Yes No No No

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NO-TOX2®
Safety Data Sheet
Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

1,2-Propylene glycol (57-55-6)

U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List

Ethyl alcohol (64-17-5)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List

Methyl alcohol (67-56-1)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List

2-Amino-2-methyl-1-propanol (124-68-5)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List

C.I. Food Red 15 (81-88-9)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List

SECTION 16: Other information

Indication of changes : Revision 1.0: New SDS Created.
Revision date : 06/15/2015
Other information : Author: NMR.

NFPA health hazard : 1 - Exposure could cause irritation but only minor residual
injury even if no treatment is given.
NFPA fire hazard : 2 - Must be moderately heated or exposed to relatively high
temperature before ignition can occur.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.

HMIS III Rating

Health : 1
Flammability : 2
Physical : 0
Personal Protection :

The above information is believed to be accurate and represents the best information currently available to us. Users should make their own
investigations to determine the suitability of the information for their particular purposes. This document is intended as a guide to the appropriate
precautionary handling of the material by a properly trained person using this product. Tanner Systems, Inc makes no representations or
warranties, either express or implied, including without limitation any warranties of merchantability, fitness for a particular purpose with the respect
to the information set forth herein or the product to which the information refers. Accordingly, Tanner Systems, Inc will not be responsible for
damages resulting from use of or reliance upon this information.

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