tL compl * followinww wo Give a gi < Hmple chomical Hest to distinguish between renzaldehyde and ethanal, Writo the main product in the following reaction i) CH3~c_— -~cooc,n, © it coe) "aH Giy ‘The resistance of 0.05 M CH,COOH solution is found to be 100 ohm. If the cell constant is 0.0354 em’*, calculate the molar conductivity of the acetic acid solution. State Faraday’s first law of electrolysis. How much charge in Faraday is required for the reduction of 1 mol of Maj to Mn?" ? 24325 OR The conductivity of 0.0025 molL 1 acetic acid is 5-25 x 10° S em“, Calculate its degree of dissociation if Ajy for acetic acid is 390 S cm” mol *. Write anode, cathode and overall reaction of lead storage 342=5 battery.SECTION ¥ f for the followings of aldehydes is ) hydrogen atoms o Write the products in the following reactions: CocHs Seer ea cocl @ + (CHg),Cd —> ? + CdCl, Give a simple chemical test to distinguish between ethanoic acid and ethanal. 2424125 OR Draw structure of the 2,4-dinitrophenylhydrazone of benzaldehyde. Arrange the following in increasing order of their reactivity towards HCN: CHCOCHg,, (CH),C — COCHg , CH;CHO magnesium bromide to benzoic How can you convert phenyl acid? P.T.O.newer the following questions ‘On what basis can we say that Cu is a transition element but Zn is @ not ? (Atomic number : Cu Why do transition elements show variety of oxidation states ? ® Why do BY... ,, values show irregular trend from Vanadium @ @ to Zine? How is the variability in oxidation states of transition metals 2x1=2 different from that of the non-transition elements ? OR 4 ‘ Ae Fi 7 ae Of the d” species, Cr is strongly reducing while Mn°* is strongly oxidizing. Why ? (Atomic number : Cr = 24, Mn = 25) Complete the following ionic equation : 2Mn0; + HzO +1- —> 2i _ what an @ ne the polysaccharide which is known a» ‘animal starch’. Wh je ealled ‘animal starch! ? ae or fo. © Neme the isomers of glucose which tn the eyete form difer only in the configuration of the — OH group at C ~ 1 Presence of which funetional group was detected when 2x1=2 a glucose reacted with Bro water ? Transition metals have incomplete d-subshell either in neutral atom or in their ions. The presence of partly filled d-rbitals in their atoms makes transition elements different from that of the non-transition elements. with partly filled d-orbitals, these elements exhibit certain characteristic 3 such as display of a variety of oxidation states, formation of properties qoloured ions and entering into complex formation with a variety of ion metals and their compounds also exhibit catalytic ligands, The transiti metals are very properties and paramagnetic behaviour. The transition F ° ation of the Ea. values hard and have low volatility. An examin: shows the varying trends : ened ied her P10, 419 3-12" Yay ag _ The vAPOUN Proon vapour PPOSSUTO of electrolyte AB 19-50 moten of the solvent at sun jation of solute An), * iss00 al qo rate of @ EaseoUS reaction triples when temperature is ineroaned 25. from 17°C 10 27°C: Calculate the energy of activation for this reaction. 3 | given | 2908 = 19-15 JK mol, tog 3 = 0.484 26, Cateolate emf of the following cel a: ga (@) | 222" (0-1 M) || Sn?* (0-001 M) | Sn (s) Given: Blgrtran=—OTEV> BBt47oq=—O14V [Jog 10 = 1] "a7, write the structures ofA, B and © in the following reactions 2x13 4 2 KCN i 2 (a) CHg- CHz—Br ——>A OH NaOH + Br, a > Partial hydrolysis NO, VAD 45 sconce aa ay aoe)pefine the Following to Pe a le linkawe ‘ a Basential amino aca ‘a pest order reaction has a rate constant 1.25 1-9 yt Aes eACtADE Lace to reduce vo 2 a a frog 2 = 0:901, TOS = 04771, tog 4 = 0:6021 1 ‘gx solution of glucose (molar mass = 180 & mot") is isotonte with 25% A AAiption of an voknown organic substance. Calculate the moleevtar samignt ofthe unkown organic substance, ; SECTION € ve the equations of reactions forthe preparation of:(any three) 31-3 {q) Phenol from chlorobenzene (y) Salicylaldehyde from phenol (e, 2Methoxyacetophenone from anisole (@_ Pieric acid from phenol Give reasons for the following : 3x1=3 13. Chlorine is ortho/para directing in electrophilic aromatic (a) substitution reactions, though chlorine is an electron withdrawing group. (b) Racemic mixture is optically inactive, ore readily than n-propyl chloride. pmpceetatetet PTO. < (©) Allyl chloride is hydrolysed m 2 Bawertion (A)? Aniline in n weaker ba AEA! Aniline is renonarcn stl prc | jusertion (AD Vite ie n(R): Vitamin C ia water #6 readily excreted in urine: jon (A): Ammonolynia of alkyl halides involves reaction between FI gy nalido ccd eitiancll¢ wolvtion of ammonta, pean (I: AMON of alk ainly produces secondary veion (A): Aniline docs not undergo Friedel-Crafts reaction fe Feledel-Crans reaction is a nucleophilic substitution ease” reaction. SECTION B ) Which one of the following pairs of substances undergoes Syl a 4 reaction faster and why ? CH,-CH,-CHz-Cl OR CH, =CH-CH,-Cl ) Write the major product in the following : cl G)_ NaOH, 443 K ? Gi) HY NOg 2x1=2 (a) What is lanthanoid contraction ? Actinoid contraction is greater from element to element than lanthanoid contraction. Why ? 1+1=2 OR b) Why do transition metals have high enthalpy of atomization ? 12 Which element of 3d-series has lowest enthalpy of atomization? 1+L 1 ANNAN PI.ayy Anwortion (A) ah eae Pig deme ae Ri. Assertion of alkyl halid ™ RBS hate tases Vitamin © in wator soluble and ra reason (PO: Aniline does not undergo Friedel-Crafts reaction, A tion (A): reason (FR): Friedel-Crafts reaction is a nucleophilic substitution reaction. SECTION B (e) Which one of the following pairs of substances undergoes Sy1 reaction faster and why ? CHs-CH,-CH,-Cl OR CH,=CH-cH,_cl Write the major product in the following ; cl (b) (i) NaOH, 443K, @H : oe 2x1=2 ) What is lanthanoid contraction ? Actinoid contraction is greater from element to element than lanthanoid contraction, Why ? 1+1=2 OR Why do transition metals have high enthalpy of atomization ? Which element of 3d-series has lowest enthalpy of atomization? 1+1=2 oul Daweh PTO.i Fora z0F0 Order reaction As producte, 4, aw Ee wo 2 L © AL o ie where (Alp = initial concentration of the reactant, lc = rate constant ine relative lowering of vapour pressure of an aqueous solution containing non-volatile solute is 00225. The mole fraction of the non-volatile solute is w 080 (p) 0°728 oo 015 @) 0-0225 a } For questions number 13 t0 16, to statements are given — one labelled (A) and the other labelled as Reason (R). Select the correct as Assertion ansuer to these questions from the codes (A), (B), (C) and (D) as given below. (A) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A), *(B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A). (CG) Assertion (A) is true, but Reason (R) is false. (D) Assertion (A) is false, but Reason (R) is true. 9 wien vn unernraniy PT.O (2/3-121CO with the molecular formula ©; A compar strong oxidizing ay formula is CsHgO,, CH ~CH,~0 w (B) CHs—CH-c én (©) Clg ~ CH, ~ CH, - OH (p) None of the above on mixing 10 mL of acetone with 50 ml. of chloroform, the total volume of the solution will be _ (a) <60mL (By > 60 mL @ =60mL (p) = 100 mL ‘The unit of cell constant is ohm em! a) (B) ohm! (© om™ (D) ohm™! cm” mot * For a certain reaction R ——> products, a plot of log {R] vs. time gives a straight line with a slope of — 1-25 s . The order of the reaction is : (A) One (B) Zero (©) Two (D) Fractional 7 annoniannsrnnntte 12/3-12 ey1¢ of the following hybrid ntaten i "© masocinted with low spin Which comple (a spd ays (spd? (p) a?sp® utanenitrile may be prepared by heating : (a) _ propyl chloride with KON putyl chloride with KCN B) propyl alcohol with KON © (p) _ butyl aleohol with KCN Which of the following is most acidic ? CH,OH, OH “ o ®) oa OH OH © Oo ©) QO NO, (CH) CH — 0 ~ CH, reacts with HI to give : (CH,),CH — OH + CH, - OH (A) (B) (CH )gCH - OH + CH; -1 (C) (CH),CH-1 + CH3—-OH (D) (CH3)gCH-I + CHg-1 5 vaiwannnwncnowenaniwy ——_PT.O. 3-12, fa ae > nstructions © ipltowing instructions carefully and follows them vestion paper contains 33 questions. ALL questions are eompulxory, jection A, B, C, D and E. ‘questions, Each e aes a * a duestion paper is divided into five sections ~ ction A—questions number 1 to 16 are multiple choice type Sp, ston carrie X mart Sen B_ questions number 17 to 21 are very short answer type questions 2 marks. ts roe Bach Y ach question carrie 5. By Lotion C — questions number 22 t0 28 are short answer type questions § % Inestion carries 3 marks Mm Suestions number 29 and 30 are case-bas ed questions. Each )section D Vuestion carries 4 marks ISection E — questions number 31 to 95 are long anewer type questions. Each 5 marks. the question paper. However, an. internal question carries There is no overal choice has been pro i Kindly note that there #: candidates. ators is not allowed. ‘ons in all the sections except Section A. 11 choice given in for Visually Impaired wided in few questi s a separate question paper Use of caleulc j SECTION A letions no. 1 to 16 are Multiple Choice type Questions, carrying 1 mark ‘ 16x 1=1€ t order for the increasing oxidizing power in 8d series of The correct transition elements is : MnOq < Cr,07 < VO3 (A) (B) Cr03” < VO3 < Mn0z (©) VO} < Cr,07 < MnO; @) VO} < MnO; < C107" en)gl* is: ‘The type of isomerism shown by the complex [CoCly( (A) Linkage isomerism (B) Geometrical isomerism (C) Coordination isomerism (D) Ionization isomerism AeA AANA 1 12