science coaching classes ,jintur

MH-CET CELL
Chemistry

es
Total Questions : 50 Total Marks : 50
Roll No.
08-Jul-2021
XII - A Div 10:00 AM To 12:00 PM

ss
This is to certify that, the entry of Roll No. has been correctly written and verified.

Candidate’s Signature MH-CET Chemistry Invigilator’s Signature

Note :
i) All Questions are compulsory

a
ii) Darken ( ) the appropriate circle(#) of the most correct option/response with black ball point pen.

1) Which of the following is CORRECT order of

boiling points? cl
Aldehydes, Ketones and Carboxylic Acids

A) Phenols B) Carboxylic acids

ng
C) Ethers D) Aldehydes
A) Ethanal < Propanal < Butanal < Pentanal
5) Which of the following will have lower boiling
B) Ethanal > Propanal > Butanal > Pentanal point than ethanoic acid? i. Propan-l-ol ii.
Propanone iii. Propanal
C) Butanal > Pentanal > Propanal > Ethanal
hi

A) Only I B) I and II
D) Ethanal < Butanal < Propanal < Pentanal
C) II and III D) I, II, III
2) Lower aliphatic carboxylic acids are
__________.
ac

6) Which of the following will have maximum

boiling point?
A) coloured liquids B) colourless liquids
A) Acetic acid B) Acetone
C) wax like solids D) gases
C) Propanal D) Propan-l-ol
co

3) Lower carboxylic acids are soluble in water due

to _____________. 7) When dry formaldehyde is required, it is
obtained by heating _________.
A) low molecular weight
A) formalin B) paraformaldehyde
B) hydrogen bonding
C) paraldehyde D) metaldehyde
e

C) dissociation into ions

8) Which of the following statements is
INCORRECT?
nc

D) dispersion forces

4) Which class of compounds shows H-bonding

even more than in alcohols?
 14) Which of the following compounds will NOT
A) The carbonyl carbon is nucleophilic in nature.
give the positive test for Tollens reagent?

B) Aldehydes are more reactive than ketones

A) Propanone B) Propanal
towards nucleophilic attack.

es
C) Ethanal D) Both (B) and (C)
C) Aromatic aldehydes are less reactive than
aliphatic aldehydes in nucleophilic addition 15) Ethanal on reacting with ammonical silver
reactions. nitrate forms

ss
D) The carbonyl carbon is electron deficient. A) CH3 − CH3 B) CH3 COO−
9) Which of the following is most reactive towards
C) CH3 COOAg D) CH3 COCH3
nucleophilic addition reactions?
16) Acetaldehyde on warming with Fehling solution

a
A) Formaldehyde B) Acetone gives a red precipitate of __________.

C) Benzaldehyde D) Acetaldehyde A) elemental copper B) cuprous oxide

10) Which of the following is least reactive towards
nucleophilic addition reactions?

A) Acetaldehyde B) Benzophenone clC) cupric oxide D) Cu(OH)2

17) Propanal + Fehling soluation → Red ppt.

Change in oxidation number of copper is from
ng
___________.
C) Benzaldehyde D) Acetone
A) +1 to +2 B) +2 to zero
11) Schiff"s reagent is _______________.
C) +2 to+1 D) +1 to+2
A) ammoniacal silver nitrate
hi

18) Acetone + [Fe(CN)5 NO]2− → Complex Colour of

B) resorcinol solution in dilute HCI the complex will be ____________.

C) alkaline CuSO4 stabilised by Roschelle salt A) silver B) magenta

ac

D) p-rosaniline hydrochloride solution in water C) blue D) red

decolourised by SO2
19) Acetaldehyde and acetone react with HCN to
12) Schiff reagent gives pink colour with form corresponding __________.
_____________.
co

A) cyanides B) nitriles
A) aldehydes B) ether
C) cyanohydrins D) nydrides
C) ketones D) carboxylic acid
20) Which of the following will give the addition
13) Which of the following does NOT turn Schiff"s product with NaHSO3 ?
reagent to pink?
e

A) CH3 OH B) CH3 COOH

A) Formaldehyde B) propanal
nc

C) CH3 COCH3 D) CH3 CH2 CI

C) Acetone D) Acetaldehyde
21) Compounds of general formula, are called
__________.
 26) Which of the following compounds does NOT
undergo haloform reaction?

A) Ethanol B) Propanal

es
C) Pentan-2-one D) Acetaldehyde
A) diesters B) acid anhydrides
27) Which of the following can be used to
C) hemiacetals D) ketals differentiate between ethanal and propanal?

ss
22) The product of the reaction between acetone
A) Ammoniacal AgNO3
and propylene glycol is ___________.
B) Fehling solution

C) I2 in presence of base

a
D) Schiff"s reagent

cl
28) In the formation of an aldol, α -carbon atom of
one aldehyde molecule attaches to
___________ of another adehyde molecule.

A) α -hydrogen atom
ng
23) X + CH3 MgCI → Ethanol Identify X .
B) α -carbon atom
A) Formaldehyde B) Acetaldehyde
C) carbonyl carbon atom
C) Acetone D) Propanal
hi

D) β -carbon atom
24) The main product formed when acetaldehyde is
treated with phenylhydrazine is ____________. 29) Ethanal undergoes aldol condensation to form
__________.
ac

A) CH3 CH2 NHC6 H4 NH2

A) butane B) but-2-ene
B) CH3 CH = N − NH − C6 H5
C) but-2-enal D) butanal
C) H2 NCH2 CH2 CH2 C6 H4 NH2
30) Crossed aldol condensation product of
co

benzaldehyde and Y is 4-phenylbut-3-en-2-one.

D) CH3 CH = N − CH2 − C6 H5 Y is ____________.
25) Cyclohexanone + X → Semicarbazone of
cyclohexanone The structure of X is A) acetone
___________.
B) acetophenone
e

A) NH2 − NH2
C) phenyl acetaldehyde
B) NH2 − NH − CONH2
nc

D) 2-methylcyclohexanone .
C) NH2 − OH
31) Cannizzaro reaction does NOT take place with
__________.
D) NH2 − NH − C6 H5
 37) In Clemmensen reaction, ketone gives
corresponding ___________.

A) alcohol B) hydrocarbon

es
32) Cannizzaro reaction is given by ___________.
C) carboxylic acid D) ether
A) formaldehyde B) acetone
38) Ethane can be obtained from acetaldehyde in
one step by _____________.
C) acetaldehyde D) butanal

ss
33) Cannizzaro reaction is given by __________. A) CrO3

A) propanal B) Zn − Hg+ conc. HCI

B) 3-methylbutanal C) acidified K2 Cr2 O7

a
C) ethanal D) LiAIH4 + ether

D) p-methoxybenzaldehyde

34) Cannizzaro reaction of benzaldehyde yields

____________. cl
39) Ethyl methyl ketone can be reduced to n-butane
by ____________.

A) Etard reaction
ng
A) acetophenone B) phenylmethanol B) Wolf-Kishner reduction

C) cyclohexanol D) benzophenone C) Stephen reaction

35) Cross Cannizzaro reaction of formaldehyde and D) Friedel-Craft"s acylation

benzaldehyde yields ____________.
hi

40) Benzaldehyde undergoes ___________ to give

A) benzyl alcohol and formic acid m-nitrobenzaldehyde.
ac

B) benzoic acid and formic acid A) electrophilic substitution

C) benzene and ethanol B) electrophilic addition

D) phenol and formic acid C) nucleophilic substitution

co

36) Which of the following on oxidation by acidified D) nucleophilic addition

dichromate forms a carboxylic acid having less
number of carbon atoms? 41) In CH3 COOH and HCOOH, HCOOH will be
__________.
A) Formaldehyde
A) less acidic B) equally acidic
B) Butan-2-one
e

C) more acidic D) basic

C) 3-Phenylprop-2-enal
42) Arrange the following acids in order of their
nc

decreasing acidity. i CH3 COOH ii

D) Hexanal
CHCH(CI)CH2 COOH, iii CCI3 CH2 COOH
 48) Carboxylic acid reacts with ammonia resulting
A) iii > ii> i B) iii > i> ii
in the formation of ___________.

C) ii > iii> i D) i > ii> iii

A) amine B) imine C) oxime D) amide

es
43) Which of the following is most acidic?
49) When acetic acid is heated with P2 O5 it gives
____________.
A) Acetic acid
A) acetyl oxide B) acetic anhydride
B) Benzoic acid

ss
C) acetyl oxime D) acetyl amide
C) p-Methoxybenzoic acid
50) A and B are respectively ____________.
D) p-Nitrobenzoic acid

44) R − COOH + NaHCO3 → R − COONa + H2 O

a
+CO2 ↑ The above reaction is showing the
___________ property of carboxylic acid. A) ethane and sodium carbonate

A) acidic

C) oxidizing
B) basic

D) reducing

45) Identify the CORRECT statement from the

clB) methane and sodium carbonate

C) n-propane and sodium carbonate

ng
D) n-butane and sodium carbonate
following.

A) Aqueous solution of water soluble compounds

containing -COOH and phenolic -OH group
turns blue litmus red.
hi

B) Both carboxylic acid and phenol answer the

sodium bicarbonate test.
ac

C) Ester test of carboxylic acids gives a foul

smelling compound.

D) NaHCO3 does not react with water insoluble

carboxylic acids.
co

46) Reaction between a carboxylic acid and alcohol

in presence of conc. H2 SO4 will give a/an
__________.

A) acid anhydride B) secondary alcohol

e

C) alkane D) ester

47) Acetic acid reacts with PCI5 to give _________.

nc

A) acetyl chloride B) acetyl amide

C) acetic anhydride D) acetal

 Answer Sheet

Chemistry : Aldehydes, Ketones and Carboxylic Acids

Total Questions : 50 Total Marks : 50

es
1 A 2 B 3 B 4 B 5 D 6 A 7 B 8 A 9 A 10 B 11 D 12 A
13 C 14 A 15 B 16 B 17 C 18 D 19 C 20 C 21 D 22 B 23 A 24 B

ss
25 B 26 B 27 C 28 C 29 C 30 A 31 B 32 A 33 D 34 B 35 A 36 B
37 B 38 B 39 B 40 A 41 C 42 A 43 D 44 A 45 A 46 D 47 A 48 D
49 B 50 A

a
cl
ng
hi
ac
co
e
nc