PAINTING & COATING SPECIFICATION & PAINTING

APPLICATION PROCEDURE

CLEAN FUEL PROJECT ( CFP )

-15 New Tank Construction Work

TRC CONSTRUCTION PUBLIC

COMPANY LIMITED
 CONTENT

(I) GENERAL

 COMPANY PROFILE
( II ) GENERAL INSTRUCTION FOR PAINTING WORKS & PAINTING
SYSTEM (REFERRED TO PAINTING No.R1118111-00000-CI-SPC-00001)

 GENERAL INSTRUCTION FOR SURFACE PREPARATION & PAINTING

 INSTRUCTION FOR APPLICATION OF EPOXY & POLYURETHANE COATING
 PAINTING SPECIFICATION
 TECHNICAL DATA AND MATERIAL SAFETY DATA SHEET
 INSPECTION ACTIVITY OF PAINT SUPERVISOR
 INSPECTION REPORT
 PAINTING MATERIAL CONTROL
( III ) GENERAL INSTRUCTION FOR CHUGOKU

 CATALOG CHUGOKU
(I) GENERAL
This proposal cover the technical, requirement for painting works, coating procedure,
Chugoku technical data and application procedure

CLEAN FUEL PROJECT ( CFP )

-15 New Tank Construction Work

TRC CONSTRUCTION PUBLIC

COMPANY LIMITED
( II ) GENERAL INSTRUCTION FOR PAINTING WORKS
& PAINTING SYSTEM
 GENERAL INSTRUCTION FOR
SURFACE PREPARATION & PAINTING
SURFACE PREPARATION
In protection steel with paint, careful surface preparation is of almost importance.
If this surface preparation in neglected, the designed performance of paint will not be
ensured.
SURFACE PREPARATION OF BARE STEEL
(Pre-Fabrication Treatment)
1. Oil and grease will be removed by thinner- wiping after scraping firmly adhering
impurities off the surface.
2. Corrosive salt and sulphate on steel surface will be cleaned off by fresh water-washing
and then the surface will be dried with dry waste compressed air.
3. All milescale rust and foreign matter will be removed by shot grit or sand blasting.
Finally, the surface should be cleaned by blowing with compressed air.

S.S.P.C. STEEL STRUCTURE PAINTING COUNCIL

The kind and grade of treatment methods are specified in detail. The main items are as
follows :-
S.S.P.C.’s treatment methods and grade
Symbol Kind of treatment Corresponding SIS
SSPC-SP 1 Solvent cleaning
SSPC-SP 2 Hand tool cleaning St 2
SSPC-SP 3 Power tool cleaning St 3
SSPC-SP 4 Flame cleaning
SSPC-SP 5 White metal blast cleaning Sa 3
SSPC-SP 6 Commercial blast cleaning Sa 2
SSPC-SP 7 Brush off blast cleaning Sa 1
SSPC-SP 8 Pickling
SSPC-SP 9 Weather followed by blast cleaning
SSPC-SP 10 Near white blast cleaning Sa 2.5
[ SSPC-SP 2 (Hand tool cleaning) ]
The loose mill-scale, rust and other foreign material are removed by manual brushing, sanding,
scraping, chipping or other tools, or the combination of these methods.
[ SSPC-SP 3 (Power tool cleaning) ]
The loose mill-scale, rust and other foreign materials are removed by the power tools such as
disc-sander, tube cleaner, wire-foil, etc.
[ SSPC-SP 5 (White metal blast cleaning) ]
The all visual mill-scale, rust and other foreign materials are removed thoroughly by blasting
using wheel or nozzle with sand, grit, or shot.
[ SSPC-SP 6 (Commercial blast cleaning) ]
The all visual rust and trace of mill-scale on 2/3 areas of each 1 inch square on the surface are
removed thoroughly by blasting using wheel or nozzle with sand, grit or shot.
[ SSPC-SP 8 (Pickling) ]
The all mill-scale, rust and rust-scale are removed thoroughly by chemical reaction or electrolytic
solution or by combination of the two. On the treated surface, there are not remain any mill-
scale, rust or other foreign materials. At the same time, toxic acid or alkaline or contamination
should not remain.
[ SSPC-SP 10 (Near white blast cleaning) ]
The all oil, grease, contamination, mill-scale, rust, corroded materials and other foreign materials
are removed thoroughly by blasting using wheel or nozzle with sand, grit or shot.
The very slight cloud and scratches or discoloration due to rust stain or the slight residue of mill-
scale and oxide are permitted.
There is no visual residue on 95% areas of 1 inch square and very slight residue is accepted on
others area.

Specification and Grades of Primary surface preparation

The following standard and specifications are used worldwide as the standard for de-rusting.
1. SIS 055900 : SWEDISH STANDARD SIS 05 59 00
2. S.S.P.C. : STEEL STRUCTURES PAINTING COUNCIL
3. BS 4232 : BRITISH STANDARDS
4. ASTM A 123 : AMERICAN STANDARD FOR TESTING AND MATERIALS
5. ASTM A 153 : AMERICAN STANDARD FOR TESTING AND MATERIALS
-
PAINTING
1. WEATHER CONDITION
Full advantage should be taken of weather conditions to carry out painting whenever it
is favorable. Paint should be not applied on wet surface. Please do not apply
painting during raining. On the painting surface should be done at over 20°C and
below 85% R.H.. condition in Thailand. However, below 5°C some paint such as Alkyd
and Epoxy, slow down or stop the curing dramatically. Painting should not be carried
out when the surface temperature is less than 3°C above the dew point whether the
R.H. is below 90% R.H. Detail are mentioned in Structure for Application for Alkyd and
Epoxy coating.
2. PREPARATION & STORAGE
(a) Some painting components although perfectly stable at normal temperature will
react together at higher temperature causing thicking, etc. Some paint such as
water based paint should not be stored where temperature can become excessive.
(b)Shelf life of paint and if stored in normal condition.
Epoxy Paint = 12 months min., subject to reinspection
thereafter
Under normal condition temp. = 30ºC
(c) When paints are left standing, they very often tend to separate slightly. This is
caused by the different specific gravities of the ingredient. All paint must
therefore be carefully stirred and mixed until homogenized before using stirring
should be done from time to time in order to prevent such separation while
painting.
(d) Once opened some paint rapidly from a skin on the surface. Generally, the quick
drying types have this tendency, which is of course no fault of the paint but is due
to the natural process of drying. The skin must be removed before painting. This
precaution applied particularly when material sprayed for small particles of skin
should soon clog the gun.
(e) Most paints do not morally require adjustment under conditions of excessively high
or low temperature, a small amount of appropriate thinner do not exceed the
amount specified by the manufacture.
3. FILM THICKNESS
The dry film thickness of Shop Primer on a blasted steel surface should be measured
as follows :-
Place a smooth steel panel on blasted steel surface apply Shop Primer and measured
the dry film thickness on the steel panel and adequate electromagnetic thickness meter.
4. APPLICATION SPRAY
(a)Brush
The paint should be applied on the surface by lengthwise and crosswise
movements of the brush. Rough surface rivet heads, edges and angles should be
given special attention.
(b)Paint Roller
Cover the surface of the roller by spreading the paint. Paint at a slow and even
space up and down and cross. Do not spread the paint excessively. Particular
care should be taken when painting rivet heads and welding seams.
(c) Airless Spray
Most CHUGOKU products can be applied by spray. Which is more economic
method than conventional spray especially on large areas. The method is
quicker with less spill and the paint can be applied in thicker coats. The use of
airless spray require more of routine than conventional spray and great caution
must be exercised in handling the gun which works with very high pressure.

CORRECT AND INCORRECT USE OF SPRAY GUN

5. CLEANING OF TOOLS
The tools should be cleaned immediately after use. This is particularly important when
working with quick drying or two components paints in using spray equipment. It
should be cleaned after use by flushing with and adequate thinner. Keep clean the
nozzles.
 INSTRUCTION FOR APPLICATION EPOXY &
POLYURETHANE COATING

CLEANING PRIOR TO PAINTING (Secondary surface preparation)

In surface preparation and cleaning of the surface, special attention should be given to the
welded parts and edges of steel construction. Dust, spatter, slag and etc. should be
removed.
1. Damaged part
Rusty parts should be cleaned by disc sander or other suitable method to the grade
SIS-St 3. Welding spatter, slag and other foreign matter should be removed by scraper,
scaling hammer or suitable tools. Areas burned by welding or other heat treatment,
including adjacent areas, should be cleaned by disc sander or suitable tools to SIS St
3. Welding parts should be cleaned by power brush or other suitable method.
2. Undamaged parts
Oil moisture, dust or other foreign matter should be removed by thinner, power brush,
disc sander, compressed air or vacuum cleaner, etc. After cleaning, a subsequent coat
should be applied as soon as possible.
MIXING OF MATERIALS
1. Mixing
Base and hardener should be mixed in the specified proportions and ensure a
homogeneous state. Since poor mixing may impair its drying property mixing should
be done by a pneumatic mixing machine or the like.
2. Thinning
Thinner may be added in spray application, but should never exceed the specification
amount.
3. Aging
When indicated necessary, the mixed materials should be aged longer than the
specified period before application. Insufficient aging causes blooming.

4. Pot life
The mixture should be used within the specified pot life.
PAINTING
Roller or Airless spray is most recommendable. With regard to spray application, cross
spraying (double spraying) is recommended to obtain uniform and specified film thickness. If
film thickness is found insufficient and additional seams, scallops, underside of longitudinal
should be touched up prior to spraying. In particular, underside of longitudinal must be
painted carefully, for it is difficult to obtain sufficient film thickness. Painting interval should
be kept as specified. If the painting interval is over than specified, the surface to be coated
should be roughened by sandpaper, disc sander or other adequate tools before application of
over coat.
CONTROL OF FILM THICKNESS
Film thickness should be controlled at the recommended mean value, unless otherwise
specified.
WEATHER CONDITION AND DRYING CONDITON
Generally, painting should be done at over 5°C and below 85% R.H. condition in Japan.
Painting should be not carried out when the surface temperature is less than 3°C above the
dew point, no mater what the R.H. is at the film.
PROTECTION OF PAINT FILM
1. Painted surface should be kept free from water or other liquid before drying through.
2. Painted surface should be kept free from welding sparkler dirt during and before touch-
free drying of the paint film.
3. Painted surface should be arranged to prevent possible damaged by foot-steps in tank’s
interior.
PRECAUTIONS FOR FIRE HAZARD AND HEALTH
1. Solvents are flammable, so attention must be given to prevent fire hazard. When painting
is carried out in confined spaces such as a tank’s interior, sufficient ventilation should
be provided during painting and during the drying process.

2. To prevent contamination of the skin by the paint, protective cream may be used for the
painters. Paint stain on skin, it should be wiped off by suitable thinner and then washed
by water
REPAIR METHOD
1. Repair method of small damaged portions.
(a) To remove the damaged parts by disc-sander at the damages parts with 20 mm.
to 50 mm. should be roughened by sand paper 100% of the precoated surface
should be roughened.
(b) Exposed parts of steel should be recoated by primer and these after Epoxy shall
be coated by brush.
DAMAGED PART
COATED FILM

PIPE BEFORE REPAIR PIPE AFTER REPAIR

2. Repair method of large damaged portion
Peel off spot producted by the lining film test & the damaged caused by other reasons shall
be cut off squarely, matching its portion with a sharp knife as shown below.

3. Next portion shall be enclosed about 20 mm. Larger by tapes from the cut off edge and the
enclosed previously lining film should be treated 100% with sandpaper.

20 mm.

The place where it

should be treated by
sand paper

20 mm.
4. The brush application should be preceded after completely finish the repair method
mentional above. It should be keep specified paint film thickness by brush paint
application. Paint will not be applied by spray, it will be required making surface roughness
with sand paper in advance.
 No.TH 6250
Jan' 20
GALBON S-HB
GALBON S-HB is an inorganic zinc coating, based on ethyl silicate and zinc dust type II per ASTM D-520.
It has zinc content by weight in the dry film 86%. It comforms to SSPC Paint No.20 Level 1 and ISO 12944-5.
It gives protection against corrosion prolonged weather resistance, good abrasion.
It also has continuous dry heat resistance up to 400°C and peak at 540°C for 1 hour.

TECHNICAL DATA
Type : Inorganic zinc silicate , high-build type
Recommended Use : As a protective coating outside of tank , pipe , steel structure , etc.
Mixing Ratio : Base : Zinc dust = 30 : 70 (by weight)
Colour : Grey
Flash Point : Base 14.5°C
VOC : 491 [g/litre] EPA method 24
Solid by Volume : 60.0 ± 2%
Coverage (Theoretical) : 0.08 - 0.14 l/m2 ; 12.0 - 7.06 m2/l
Wet Film Thickness : 3.33 - 5.67 mils ; 83 - 142 microns
Dry Film Thickness : 2.00 - 3.40 mils ; 50 - 85 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 75 microns) : Surface Dry 30 mins. 20 mins. 10 mins. 5 mins.
: Hard Dry 5 hrs. 4 hrs. 3 hrs. 2 hrs.
Painting Interval : Minimum 32 hrs. 20 hrs. 14 hrs. 6 hrs.
(at D.F.T. 75 microns) : Maximum 180 days 180 days 180 days 180 days
Pot Life : 10 hrs. 7 hrs. 5 hrs. 3 hrs.
Thinner : CMP-61
Method of Application : Airless spray, Brush is recommended for small touch up area.
Conditions of Application : Temperature 5 - 50°C
Humidity 50 - 95 % RH
For Airless spray
Tip No. GRACO 419 , 519
Paint output pressure 9.8 MPa.
Viscosity 10-12 sec. (Ford Cup No.4)
Thinning 0 - 5% by volume
Surface preparation : Surfaces must be clean and dry, remove dirt, dust, oil and all other
contaminants that could interfere with the adhesion of the next coat.
Steel : Recommend Blast cleaning to Sa 2½ (ISO 8501-1)
Anchor profile 30-65 µm are recommended for the highest performance.
Preceding Coats : Cerabond 2000
Subsequent Coats : Epicon series , Umeguard series , Silicon series , etc.
Packaging : Two pack product : 3.8 Litres / Gallon
Shelf life at 25°C : Base 6 months , Zinc dust 12 months , In unopened container
Note ; 1.Dry film thickness over 5.0 mils (125 microns) is not recommended.
2.Before applying the next coat, the paint film of GALBON S-HB must dry clean and free of zinc salts, etc.
3. Mist coat is required to minimize topcoat bubbling, thinning 30-40% is recommended.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
 No.TH 6174C
Jan' 20
UMEGUARD HS
UMEGUARD HS, surface tolerant paint, is a high solid modified epoxy paint and low VOC. It is a substantial
coating with excellent adhesion, impact and abrasion resistance properties and superior resistance to
water, oil and chemicals. It has excellent adhesion to the most substrate and may be applied over a wide range
of existing coatings. It is suitable for application to corrode areas where optimum pre-treatment is
not practical.

TECHNICAL DATA
Type : Mastic epoxy modified , high solid , self priming type
Recommended Use : Repair existing paint film and other new steel structure
Mixing Ratio : Base : Hardener = 85 : 15 (by volume) , 90 : 10 (by weight)
Colour : As specified
Flash Point : Base = 27°C Hardener = 27°C
VOC : 125 [g/litre] EPA method 24
Solid by Volume : 90.0 ± 2%
Coverage (Theoretical) : 0.06 - 0.22 l/m2 ; 18.0 - 4.50 m2/l
Wet Film Thickness : 2.22 - 8.89 mils ; 56 - 222 microns
Dry Film Thickness : 2.00 - 8.00 mils ; 50 - 200 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 100 microns) : Surface Dry 12 hrs. 6 hrs. 3 hrs. 2 hrs.
: Hard Dry 24 hrs. 12 hrs. 8 hrs. 5 hrs.
Painting Interval : Minimum 24 hrs. 12 hrs. 8 hrs. 5 hrs.
(at D.F.T. 100 microns) : Maximum - - - -
Pot Life : 5 hrs. 4 hrs. 3 hrs. 1.5 hrs.
Thinner : CMP-31
Method of Application : Airless spray , Roller , Brush
Conditions of Application : Temperature Minimum 10°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 621 , 623
Paint output pressure 14.7 - 17.7 MPa.
Viscosity 1.5 - 2.0 Pa.s
Thinning 0 - 15 % by volume
Preceding coats : Adge wide range of existing coating.
Subsequent coats : Wide range of any coating such as , Epoxy , Polyurethane , Alkyd , etc.
Packaging : Two pack product per set ; 3.785 Litres / Gallon , 18.925 Litres / Drum
Shelf life at 25°C : Base 24 months , Hardener 24 months , In unopened container
Note ; As the nature of epoxy coatings, UMEGUARD HS can not avoid chalking, yellowing and fading on sunlight exposure.
Maximum recoat time is limited. The surface must be clean, dry surface free of chalk, etc.
Safety period should be coated within 30 days interval.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
 No.TH 5512
Jan' 20
UNY MARINE HS
UNY MARINE HS, based on acrylic polyol and non-yellowing polyisocyanates resin, has excellent
gloss retention, durability and chemical resistance, etc. It is suitable for protection of tank , tower, bridge
and other steel structures.

TECHNICAL DATA
Type : Acrylic aliphatic polyurethane paint (non-yellowing), high solid
Recommended Use : Finish coat of Epoxy system for bridge, chemical plant oil tank
and steel structures, etc.
Mixing Ratio : Base : Hardener = 80 : 20 (by volume) , 5 : 1 (by weight)
Colour : White , as specified
Flash Point : Base = 23.5°C Hardener = 29°C
VOC : 430 [g/litre] EPA method 24
Solid by Volume : 61.0 ± 2%
Coverage (Theoretical) : 0.07 - 0.12 l/m2 ; 15.3 - 8.1 m2/l
Wet Film Thickness : 2.62 - 4.92 mils ; 66 - 123 microns
Dry Film Thickness : 1.60 - 3.00 mils ; 40 - 75 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 40 microns) : Surface Dry 2 hrs. 1 hr. 30 mins. 15 mins.
: Hard Dry 14 hrs. 8 hrs. 7 hrs. 4 hrs.
Painting Interval : Minimum 6 hrs. 4 hrs. 2 hrs. 1 hr.
(at D.F.T. 40 microns) : Maximum - - - -
Pot Life : 8 hrs. 7 hrs. 6 hrs. 4 hrs.
Thinner : CMP-41
Method of Application : Airless spray , Roller , Brush
Conditions of Application : Temperature Minimum 5°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 715 , 813
Paint output pressure 12 - 15 MPa.
Viscosity 25 - 35 sec. (Ford Cup No.4)
Thinning 0 - 15 % by volume
Preceding coats : Epicon HB-CL, Epicon HB-NP, Epicon Undercoat , Epicon F-HS ,
Umeguard HS , Umeguard HS Silver, Univan HS , etc.
Subsequent coats : -
Packaging : Two pack product per set ; 3.785 Litres / Gallon , 18.925 Litres / Drum
Shelf life at 25°C : Base 24 months , Hardener 24 months , In unopened container

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
 No.TH 6037C
Jan' 20
EPICON T-800 HS-GF
EPICON T-800 HS-GF is a high-build type epoxy phenolic glass flake coating.
It is suitable as a protective coating for piping and tank. It has the following adventages ;
1. Excellent temperature resistance up to 230 °C
2. Excellent physical properties such as adhesion, toughness, abrasion resistance and
wet/dry cycling condition resistance.
3. Excellent thermal shock resistance.

TECHNICAL DATA
Type : Epoxy phenolic glassflake coating, high-build
Recommended Use : Tank outside, insulated pipe, other steel structures, etc.
Mixing Ratio : Base : Hardener = 86 : 14 (by volume) , 90 : 10 (by weight)
Colour : Grey , Light Grey , Reddish Brown
Flash Point : Base = 27°C Hardener = 33°C
VOC : 361 [g/litre] EPA method 24
Solid by Volume : 75.0 ± 2%
Coverage (Theoretical) : 0.13 - 0.20 l/m2 ; 7.50 - 5.00 m2/l
Wet Film Thickness : 5.33 - 8.00 mils ; 133 - 200 microns
Dry Film Thickness : 4.00 - 6.00 mils ; 100 - 150 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 150 microns) : Surface Dry 2.5 hrs. 1.5 hrs. 30 mins. 15 mins.
: Hard Dry 24 hrs. 12 hrs. 8 hrs. 6 hrs.
Painting Interval : Minimum 24 hrs. 16 hrs. 14 hrs. 8 hrs.
(at D.F.T. 150 microns) : Maximum 30 days 30 days 30 days 30 days
Pot Life : 7 hrs. 5 hrs. 3 hrs. 1.5 hrs.
Thinner : CMP-31
Method of Application : Airless spray , Roller , Brush
Conditions of Application : Temperature Minimum 5°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 631 , 635
Paint output pressure 14.7 - 17.7 MPa.
Viscosity 1.0 - 1.5 Pa.s
Thinning 0 - 15 % by volume
Recommended Surface- : Steel : Blast cleaning to Sa 2½ (ISO 8501-1)
preparation Anchor profile 60-90 µm are recommended for the highest performance.
Preceding coats : -
Subsequent coats : Epicon T-800 HS-GF , etc.
Packaging : Two pack product per set ; 3.785 Litres / Gallon , 18.925 Litres / Drum
Shelf life at 25°C : Base 24 months , Hardener 24 months , In unopened container
Note ; 1.Even if discolouration occures under the sunshine, this is not an indication of a change in film resistance to the cargo.
2.In confined spaces such as tank insides, ventilation is required during application and curing to removed solvent vapour
and promote curing.

The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
 No.TH 6037T
Jan' 20
EPICON T-800
EPICON T-800 is a high-build type epoxy phenolic coating, has excellent physical properties
such as adhesion, toughness, abrasion resistance as well as chemical resistance to salt water,
fresh water , petroleum products, crude oil, alkalis and weak acids. It is suitable as a protective coating
for tank interiors and this product has conformed to MIL-PRF-4556F, EI 1541

TECHNICAL DATA
Type : Epoxy phenolic tank coating, high-build
Recommended Use : Product carrier tank , Chemical tank, etc.
Mixing Ratio : Base : Hardener = 84 : 16 (by volume) , 88 : 12 (by weight)
Colour : White , Light grey, Dark grey
Flash Point : Base = 38°C Hardener = 34°C
VOC : 335 [g/litre] EPA Method 24
Solid by Volume : 63.0 ± 2%
Coverage (Theoretical) : 0.12 - 0.24 l/m2 ; 8.40 - 4.20 m2/l
Wet Film Thickness : 4.76 - 9.52 mils ; 119 - 238 microns
Dry Film Thickness : 3.00 - 6.00 mils ; 75 - 150 microns
Drying Time : Temperature 10°C 20°C 30°C 40°C
(at D.F.T. 100 microns) : Surface Dry 2.5 hrs. 1.5 hrs. 45 mins. 30 mins.
: Hard Dry 24 hrs. 14 hrs. 8 hrs. 6 hrs.
Painting Interval : Minimum 24 hrs. 18 hrs. 16 hrs. 8 hrs.
(at D.F.T. 100 microns) : Maximum 30 days 30 days 30 days 30 days
Pot Life : 7 hrs. 5 hrs. 3 hrs. 2 hrs.
Thinner : CMP-31
Method of Application : Airless spray , Roller , Brush
Conditions of Application : Temperature Minimum 10°C
Humidity Maximum 85% RH
For Airless spray :
Tip No. GRACO 619 , 621
Paint output pressure 14.7 - 17.7 MPa.
Viscosity 1.0 - 1.5 Pa.s
Thinning 0 - 15 % by volume
Recommended Surface- : Steel : Blast cleaning to Sa 2½ (ISO 8501-1)
preparation Anchor profile 60-90 µm are recommended for the highest performance.
Preceding coats : Epicon T-800 Holding Primer , Epicon T-800
Subsequent coats : Epicon T-800
Packaging : Two pack product per set ; 3.785 Litres / Gallon , 18.925 Litres / Drum
Shelf life at 25°C : Base 24 months , Hardener 24 months , In unopened container
Note ; 1.Maximum painting interval may be shorter or longer depending on actual work environment such as humidity,
temperature, dry film thickness, ventilation. For further information, please contact our technical service.
2.Generally, epoxies will be chalking, yellowing, and discolouring on exposure to sunlight.
3.Before subsequent coat application, all chalks (if existed) should be removed.
4.In confined spaces such as tank insides, ventilation is required during application and curing to removed
solvent vapour and promote curing.
5.The coating should not be exposed to oil, chemical until fully cured.
6.First loading is recommended after painted 5-7 days.
The information given in this sheet is effective at the date shown above and subject to revision from time to time without notice.
 Revision Date - 18/05/2020

SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : GALBON S-HB , BASE
Product No. : TH 6250
Product Type : Ethyl Silicate paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Skin sensitizer 1 May cause an allergic skin reaction.
Specific target organ toxicity (single exposure) 3 May cause drowsiness or dizziness.
Specific target organ toxicity (repeated exposure) 2 May cause damage to organs through prolong exposure.
Aspiration toxicity 2 May be fatal if swallowed and enters airways.
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H302 : Harmful if swallowed.
H305 : May be harmful if swallowed and enters airways.
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye irritation.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H373 : May cause damage to organs through prolonged or repeated exposure cause the hazard.
ENVIRONMENT
H402 : Harmful to aquatic life.
H412 : Harmful to aquatic life with long lasting effects.

Page 1 / 8
 Revision Date - 18/05/2020

PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
RESPONSE/FIRST AID MEASURES
IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.
IF ON SKIN
P302+P352 : Wash with plenty of soap and water.
P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.
IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Ethyl Silicate 78-10-4 30 - 40
2 1-Methoxy-2-Propanol 107-98-2 20 - 30
3 Ethanol 64-17-5 5 - 10
4 Xylene 1330-20-7 1-5
5 Ethylbenzene 100-41-4 0.1 - 0.3

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use

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recognised skin cleanser. Do not use solvents or thinners.

Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
: Refer to protective measures listed in sections 7 and 8.

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6.2. Environmental precautions

: Do not allow to enter drains or watercourses.
: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4. Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.
: Always keep in containers of same material as the original one.
: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.
: Prevent unauthorised access.
: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Ethyl Silicate - 1000 ppm
1-Methoxy-2-Propanol 100 ppm 50 ppm
Ethanol - 1000 ppm
Xylene 150 ppm 100 ppm
Ethylbenzene - 20 ppm

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.07 - 1.17
Colour : Clear
Odour : Smell of solvent
Solubility : Insoluble in water

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Explosion limits : LEL% 1.8 : UEL% 12.3

Vapour pressure : 1940 Pa at 20°C
Autoignition temperature : 432°C
Flash point : 14.5°C

10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.
Substance name LD50 Oral LD50 Dermal LC50 Inhalation
Ethyl Silicate 6270 mg/kg,Rat 5860 mg/kg,Rabbit 10-16 mg/kg,Rat
1-Methoxy-2-Propanol 4016 mg/kg,Rat >13300 mg/kg,Rabbit 54.6 mg/l,Rat
Ethanol >2000 mg/kg,Rat >2000 mg/kg,Rat >8000 mg/kg,Rat
Xylene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 29 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17.8 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

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STOT - single exposure:

Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects

Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Ethyl Silicate EC50/48h >75 mg/l (Daphnia magna), LC50/96h >245 mg/l (Brachydanio rerio), IC50/72h - Not available
1-Methoxy-2-Propanol EC50/48h 23300 mg/l (Daphnia magna), LC50/96h 6812 mg/l (Leuciscus Idus), IC50/72h - Not available
Ethanol EC50/24h >100mg/l (Daphnia magna), LC50/96h - Not available, IC50/72h - Not available
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available
Ethylbenzene EC50/48h 1.8-2.4 mg/l (Daphnia magna), LC50/96h 12.1 mg/l (Pimephales promelas), IC50/72h - Not available

12.2 Mobility in soil

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Soil/water partition coefficient (KOC) : Not available

Mobility : Not available

13. DISPOSAL CONSIDERATIONS

Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III

Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : GALBON S-HB , ZINC DUST
Product No. : TH 6250
Product Type : Zinc dust for Ethyl Silicate paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement
Flammable liquids 2 Flammable solid
Serious eye damage / eye irritation 2A Causes serious eye damage
Respiratory sensitizer 1 May cause allergy or breathing difficulties if inhaled
Acute hazards to the aquatic environment 1 Very Toxic to aquatic life
Long-term hazards to the aquatic 1 Very Toxic to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H228 : Flammable solid.
HEALTH
H319 : Causes serious eye irritation.
H334 : May cause allergy or asthma symptoms or breating difficulties if inhaled
ENVIRONMENT
H400 : Very Toxic to aquatic life
H410 : Very Toxic to aquatic life with long lasting effects
PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
RESPONSE/FIRST AID MEASURES
IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.
IF ON SKIN
P302+P352 : Wash with plenty of soap and water.

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P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.
IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Zinc Powder (Stabilised) 7440-66-6 90 - 100
2 Zinc Oxide 1314-13-2 0.1 - 0.5

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects

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: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
: Refer to protective measures listed in sections 7 and 8.
6.2 Environmental precautions
: Do not allow to enter drains or watercourses.
: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4 Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.

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: Always keep in containers of same material as the original one.

: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2 Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.
: Prevent unauthorised access.
: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Zinc Powder (Stabilised) - -
Zinc Oxide 2 mg/m3 10 mg/m3

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate

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respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ x ] Solid [ ] Liquid [ ] Paste [ ] Powder
Density : 6.7 - 7.2
Colour : Grey
Odour : Odorless
Solubility : Insoluble in water
Explosion limits : LEL% - : UEL% -
Vapour pressure : 1 mmHg at 487°C
Autoignition temperature : 460°C
Flash point :-

10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in

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the eye may cause irritation and soreness with possible reversibledamage.
Substance name LD50 Oral LD50 Dermal LC50 Inhalation
Zinc Powder (Stabilised) >2000 mg/kg,Rat Not available Not available
Zinc Oxide >5000 mg/kg,Rat Not available Not available

Skin corrosion/irritation:
Conclusion/Summary on mixture : No specific data.

Serious eye damage/irritation:

Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:

Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects

Inhalation : No specific data.
Ingestion : No specific data.
Skin contact : No specific data.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data
Ingestion : No specific data
Skin contact : No specific data.
Eye contact : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : No specific data

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 Revision Date - 18/05/2020

Conclusion/Summary
General : No specific data
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Zinc Powder (Stabilised) EC50/48h - Not available, LC50/96h - Not available, IC50/72h - Not available
Zinc Oxide Ac. EC50/72h - 0,17 mg/l (Algae - Selenastrum Capricornutum), Ac. LC50/48h - 98 ug/l Daphnia
magna/Neonate <24u ; Ac. LC50/96h - 1,1 tot 2,5 ppm Oncorhynchus mykiss ; Chr. NOEC/48h - 0,4 mg/L
Daphnia magna/Neonate, IC50 - Not available

12.2 Mobility in soil

Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS

Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Environmentally hazardous Environmentally hazardous Environmentally hazardous
substance, solid, n.o.s. substance, solid, n.o.s. substance, solid, n.o.s.
UN number 3077 3077 3077
Transport hazard class 9 9 9
Hazard Label

Packing group III III III

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Environmental hazard No Yes No

Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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 Revision Date - 18/05/2020

SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : UMEGUARD HS , BASE
Product No. : TH 6174C
Product Type : Epoxy paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Skin sensitizer 1 May cause an allergic skin reaction.
Specific target organ toxicity (single exposure) 3 May cause drowsiness or dizziness.
Specific target organ toxicity (repeated exposure) 2 May cause damage to organs through prolong exposure.
Aspiration toxicity 2 May be fatal if swallowed and enters airways.
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H302 : Harmful if swallowed.
H305 : May be harmful if swallowed and enters airways.
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye irritation.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H373 : May cause damage to organs through prolonged or repeated exposure cause the hazard.
ENVIRONMENT
H402 : Harmful to aquatic life.
H412 : Harmful to aquatic life with long lasting effects.

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PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
RESPONSE/FIRST AID MEASURES
IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.
IF ON SKIN
P302+P352 : Wash with plenty of soap and water.
P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.
IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Epoxy Resin 25068-38-6 25 - 35
2 Xylene 1330-20-7 1-5
3 Iso-butanol 78-83-1 0.1 - 1.0
4 Ethylbenzene 100-41-4 0.1 - 0.5
5 Silicon dioxide 14808-60-7 20 - 30

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use

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recognised skin cleanser. Do not use solvents or thinners.

Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
: Refer to protective measures listed in sections 7 and 8.

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6.2. Environmental precautions

: Do not allow to enter drains or watercourses.
: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4. Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.
: Always keep in containers of same material as the original one.
: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.
: Prevent unauthorised access.
: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Epoxy Resin - -
Xylene 150 ppm 100 ppm
Iso-butanol 100 ppm 75 ppm
Ethylbenzene - 20 ppm
Silicon dioxide - -

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.55 - 1.65
Colour : Various
Odour : Smell of solvent
Solubility : Insoluble in water

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Explosion limits : LEL% 1.8 : UEL% 12.3

Vapour pressure : 1940 Pa at 20°C
Autoignition temperature : 432°C
Flash point : 27°C

10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.
Substance name LD50 Oral LD50 Dermal LC50 Inhalation
Epoxy Resin >15000 mg/kg,Rabbit 23000 mg/kg,Rabbit Not available
Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat 29 mg/l,Rat
Iso-butanol 2460 mg/kg,Rat 3400 mg/kg,Rabbit >24 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit >17.8 mg/l,Rat
Silicon dioxide Not available Not available Not available

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

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STOT - single exposure:

Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects

Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Epoxy Resin EC50/48h 1.8 mg/l (Daphnia magna), LC50/96h 2 mg/l (Oncorhynchus mykiss), IC50/8h >42,6 mg/l (Bacteria)
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available
Iso-butanol EC50/48h 1439 mg/l (Daphnia magna), LC50/96h 1430 mg/l (Pimephales promelas), IC50/72h 1250 mg/l (Algae)
Ethylbenzene EC50/48h 1.8-2.4 mg/l (Daphnia magna), LC50/96h 12.1 mg/l (Pimephales promelas), IC50/72h - Not available
Silicon dioxide EC50/48h - Not available, LC50/96h - Not available, IC50/72h - Not available

12.2 Mobility in soil

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Soil/water partition coefficient (KOC) : Not available

Mobility : Not available

13. DISPOSAL CONSIDERATIONS

Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III

Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : UMEGUARD HS , HARDENER
Product No. : TH 6174C
Product Type : Epoxy paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 1 Causes serious eye damage
Skin sensitizer 1 May cause an allergic skin reaction
Specific target organ toxicity (single exposure) 3 May cause drowsiness or dizziness
Specific target organ toxicity (repeated exposure) 2 May cause damage to organs through prolong exposure
Aspiration toxicity 2 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H302 : Harmful if swallowed.
H305 : May be harmful if swallowed and enters airways
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H318 : Causes serious eye damage.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H373 : May cause damage to organs through prolong or repeated exposure cause the hazard.
ENVIRONMENT
H402 : Harmful to aquatic life.
H412 : Harmful to aquatic life with long lasting effects.

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PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
RESPONSE/FIRST AID MEASURES
IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.
IF ON SKIN
P302+P352 : Wash with plenty of soap and water.
P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.
IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Polyaminoamide 68410-23-1 85 - 95
2 Xylene 1330-20-7 5 - 10
3 Ethylbenzene 100-41-4 0.2 - 0.3
4 2,4,6-Tris (Dimethyl Amino Methyl) Phenol 90-72-2 0.5 - 1.0

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.

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Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
: Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions

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: Do not allow to enter drains or watercourses.

: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4. Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.
: Always keep in containers of same material as the original one.
: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.
: Prevent unauthorised access.
: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

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Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Polyaminoamide - -
Xylene 150 ppm 100 ppm
Ethylbenzene - 20 ppm
2,4,6-Tris (Dimethyl Amino Methyl) Phenol - -

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 0.93 - 0.98
Colour : Clear Brown
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 1000 Pa at 20°C

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Autoignition temperature : 432°C

Flash point : 27°C

10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.
Substance name LD50 Oral LD50 Dermal LC50 Inhalation
Polyaminoamide >2000 mg/kg,Rat >2000 mg/kg,Rat Not available
Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat 29 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17.8 mg/l,Rat
2,4,6-Tris (Dimethyl Amino Methyl) Phenol 200-2000 mg/kg,Rat >2000 mg/kg,Rat Not available

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:

Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:

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Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects

Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Polyaminoamide EC50/48h - Not available, LC50/96h - Not available, IC50/72h - Not available
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available
Ethylbenzene EC50/48h 1.8-2.4 mg/l (Daphnia magna), LC50/96h 12.1 mg/l (Pimephales promelas), IC50/72h - Not available
2,4,6-Tris (Dimethyl Amino Methyl) Phenol EC50/48h - Not available, LC50/96h - Not available, IC50/72h - Not available

12.2 Mobility in soil

Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS

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Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III

Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : UNY MARINE HS , BASE
Product No. : TH 5512
Product Type : Polyurethane paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Respiratory sensitization 1 May cause allergy or asthma symptoms or
breathing difficulties if inhaled
Skin sensitizer 1 May cause an allergic skin reaction
Specific target organ toxicity (single exposure) 3 May cause drowsiness or dizziness
Specific target organ toxicity (repeated exposure) 2 Liver, central nervous system,kidney
Aspiration toxicity 1 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H302 : Harmful if swallowed.
H305 : May be harmful if swallowed and enters airways.
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye damage.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.

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H370 : Cause damage to organs.

H372 : Cause damage to organs through prolong or repeated exposure cause the hazard.
H373 : May cause damage to organs through prolonged or repeated exposure cause the hazard.
ENVIRONMENT
H402 : Harmful to aquatic life.
H412 : Harmful to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P240 : Ground/bond container and receiving equipment.
P241 : Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 : Use only non-sparking tools.
P243 : Take precautionary measures against static discharge.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.

RESPONSE/FIRST AID MEASURES

IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.

IF ON SKIN
P302+P352 : Wash with plenty of soap and water.
P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.

IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.

IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
CRITERIA
No. Substance name CAS No. W.t (%)
TLV LD50
1 Xylene 1330-20-7 10 - 20

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2 Low Boiling point Naphtha 64742-95-6 1-2

3 Naphtha (Petroleum),Hydrotreated Heavy 64742-48-9 1-2
4 N-Butyl Acetate 123-86-4 5 - 10
5 Polymethyl Methacrylate 9011-14-7 45 - 55
6 Hydroxyphenyl-Benzotriazole Derivatives 104810-48-2 0.1 - 1

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.

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Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
: Refer to protective measures listed in sections 7 and 8.
6.2 Environmental precautions
: Do not allow to enter drains or watercourses.
: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4 Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.
: Always keep in containers of same material as the original one.
: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration

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higher than the occupational exposure limits.

: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2 Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.
: Prevent unauthorised access.
: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Xylene 150 ppm 100 ppm
Low Boiling point Naphtha - 19 ppm
Naphtha (Petroleum),Hydrotreated Heavy - 197 ppm
N-Butyl Acetate 200 ppm 150 ppm
Polymethyl Methacrylate 150 ppm 100 ppm
Hydroxyphenyl-Benzotriazole Derivatives - -

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)

Personal protection equipment

Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.

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Eyeware should comply with an approved standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.15 - 1.30
Colour : Various
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 370 Pa at 20°C
Autoignition temperature : 296°C
Flash point : 23.5°C

10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversible damage.

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Substance name LD50 Oral LD50 Dermal LC50 Inhalation

Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat 29 mg/l,Rat
Low Boiling point Naphtha 3592 mg/kg,Rat 3160 mg/kg,Rat 6193 mg/l,Rat
Naphtha (Petroleum),Hydrotreated Heavy >5000 mg/kg,Rat >5000 mg/kg,Rabbit >5 mg/l,Rat
N-Butyl Acetate 10760 mg/kg,Rat 9683 mg/kg,Rabbit >20 mg/l,Rat
Polymethyl Methacrylate >2000 mg/kg,Rat >700 mg/kg,Rat 10 mg/l,Rat
Hydroxyphenyl-Benzotriazole Derivatives >5000 mg/kg,Rat >2000 mg/kg,Rat 5.8 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no test data available.

Serious eye damage/irritation:

Conclusion/Summary on mixture : Causes eye irritation.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : May cause allergy.

Germ cell mutagenicity:

Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:

Conclusion/Summary on mixture : Cause damage to organs.

STOT - repeated exposure:

Conclusion/Summary on mixture : Cause damage to organs.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects

Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data.
Ingestion : No specific data.
Skin contact : Adverse symptoms may include the following: irritation, redness.
Eye contact : Adverse symptoms may include the following: irritation, watering, redness.

Delayed and immediate effects and also chronic effects from short and long term exposure.
: Short term exposure
Potential immediate effects : No specific data.
Potential delayed effects : No specific data.
: Long term exposure

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Potential immediate effects : No specific data.

Potential delayed effects : No specific data.
Potential chronic health effects : Not available.

General : Once sensitized, a severe allergic reaction may occur when

subsequently exposed to very low levels.

Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Other information : Not available.

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available
Low Boiling point Naphtha EC50/48h 3.2 mg/l (Daphnia Magna), LC50/96h 9.2 mg/l (Oncorhynchus mykiss), IC50/72h - Not available
Naphtha (Petroleum),Hydrotreated Heavy EC50/48h >1000 mg/l (Daphnia magna), LC50/96h >1000 mg/l (Oncorhynchus mykiss), IC50/72h - Not available
N-Butyl Acetate EC50/48h 44 mg/l (Daphnia magna), LC50/96h 18 mg/l (fish), IC50/72h 674.7 mg/l (Algae)
Polymethyl Methacrylate EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available
Hydroxyphenyl-Benzotriazole Derivatives EC50/48h 4.0 mg/l (Daphnia magna), LC50/96h 2.8 mg/l (Oncorhynchus mykiss), IC50/72h - Not available

12.2 Mobility in soil

Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS

: Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
: Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
: Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
: Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
: Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product.

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Paint Paint Paint

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UN number 1263 1263 1263

UN class 3 3 3
Hazard Label

Packing group III III III

Environmental hazard Yes Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation.

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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : UNY MARINE HS , HARDENER
Product No. : TH 5512
Product Type : Polyurethane paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement Hazard
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Respiratory sensitization 1 May cause allergy or asthma symptoms or
breathing difficulties if inhaled
Skin sensitizer 1 May cause an allergic skin reaction
Specific target organ toxicity (single exposure) 3 May cause drowsiness or dizziness
Specific target organ toxicity (repeated exposure) 2 Liver, central nervous system,kidney
Aspiration toxicity 1 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H302 : Harmful if swallowed.
H305 : May be harmful if swallowed and enters airways.
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye damage.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.

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H370 : Cause damage to organs.

H372 : Cause damage to organs through prolong or repeated exposure cause the hazard.
H373 : May cause damage to organs through prolonged or repeated exposure cause the hazard.
ENVIRONMENT
H402 : Harmful to aquatic life.
H412 : Harmful to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P240 : Ground/bond container and receiving equipment.
P241 : Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 : Use only non-sparking tools.
P243 : Take precautionary measures against static discharge.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.

RESPONSE/FIRST AID MEASURES

IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.

IF ON SKIN
P302+P352 : Wash with plenty of soap and water.
P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.

IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.

IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
CRITERIA
No. Substance name CAS No. W.t (%)
TLV LD50
1 Xylene 1330-20-7 30 - 40

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2 N-Butyl Acetate 123-86-4 5 - 10

3 TDI 28182-81-2 55 - 65

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

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5.1 Extinguishing media

: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
: Refer to protective measures listed in sections 7 and 8.
6.2 Environmental precautions
: Do not allow to enter drains or watercourses.
: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4 Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.
: Always keep in containers of same material as the original one.
: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.

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: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2 Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.
: Prevent unauthorised access.
: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Xylene 150 ppm 100 ppm
N-Butyl Acetate 200 ppm 150 ppm
TDI 0.05 ppm 0.02 ppm

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)

Personal protection equipment

Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied

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once exposure has occurred.

For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 0.95 - 1.05
Colour : Clear Liquid
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.8 : UEL% 12.3
Vapour pressure : 1000 Pa at 20°C
Autoignition temperature : 432°C
Flash point : 29°C

10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversible damage.

Substance name LD50 Oral LD50 Dermal LC50 Inhalation

Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat 29 mg/l,Rat
N-Butyl Acetate 10760 mg/kg,Rat 9683 mg/kg,Rabbit >20.0 mg/l,Rat
TDI >2500 mg/kg,Rat >2000 mg/kg,Rat 0.390 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.

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: Method: Additivity approach, no test data available.

Serious eye damage/irritation:

Conclusion/Summary on mixture : Causes eye irritation.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : May cause allergy.

Germ cell mutagenicity:

Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:

Conclusion/Summary on mixture : Cause damage to organs.

STOT - repeated exposure:

Conclusion/Summary on mixture : Cause damage to organs.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects

Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data.
Ingestion : No specific data.
Skin contact : Adverse symptoms may include the following: irritation, redness.
Eye contact : Adverse symptoms may include the following: irritation, watering, redness.

Delayed and immediate effects and also chronic effects from short and long term exposure.
: Short term exposure
Potential immediate effects : No specific data.
Potential delayed effects : No specific data.
: Long term exposure
Potential immediate effects : No specific data.
Potential delayed effects : No specific data.
Potential chronic health effects : Not available.

General : Once sensitized, a severe allergic reaction may occur when

subsequently exposed to very low levels.

Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.

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Fertility effects : No known significant effects or critical hazards.

Other information : Not available.

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available
N-Butyl Acetate EC50/48h 3.2 mg/l (Daphnia Magna), LC50/96h 9.2 mg/l (Oncorhynchus mykiss), IC50/72h - Not available
TDI EC50/48h >1000 mg/l (Daphnia magna), LC50/96h >1000 mg/l (Oncorhynchus mykiss), IC50/72h - Not available

12.2 Mobility in soil

Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS

: Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
: Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
: Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
: Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
: Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product.

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
UN class 3 3 3
Hazard Label

Packing group III III III

Environmental hazard Yes Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

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16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation.

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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : EPICON T-800 HS-GF , BASE
Product No. : TH 6037C
Product Type : Epoxy Phenolic paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Skin sensitizer 1 May cause an allergic skin reaction.
Specific target organ toxicity (single exposure) 3 May cause drowsiness or dizziness.
Specific target organ toxicity (repeated exposure) 2 May cause damage to organs through prolong exposure.
Aspiration toxicity 2 May be fatal if swallowed and enters airways.
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H302 : Harmful if swallowed.
H305 : May be harmful if swallowed and enters airways.
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye irritation.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H373 : May cause damage to organs through prolonged or repeated exposure cause the hazard.
ENVIRONMENT
H402 : Harmful to aquatic life.
H412 : Harmful to aquatic life with long lasting effects.

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PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
RESPONSE/FIRST AID MEASURES
IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.
IF ON SKIN
P302+P352 : Wash with plenty of soap and water.
P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.
IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Epoxy Resin 25036-25-3 25 - 30
2 Xylene 1330-20-7 15 - 20
3 MIBK 108-10-1 3-5
4 Iso-butanol 78-83-1 2-4
5 Silicon Dioxide 14808-60-7 25 - 30
6 Ethylbenzene 100-41-4 0.1 - 0.3

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact

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: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.

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: Refer to protective measures listed in sections 7 and 8.

6.2. Environmental precautions
: Do not allow to enter drains or watercourses.
: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4. Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.
: Always keep in containers of same material as the original one.
: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.
: Prevent unauthorised access.

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: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Epoxy Resin - -
Xylene 100 ppm 100 ppm
MIBK 100 ppm 100 ppm
Iso-butanol - 20 ppm
Silicon Dioxide - -
Ethylbenzene - 20 ppm

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 1.25 - 1.50

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Colour : Various
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.4 : UEL% 12.3
Vapour pressure : 1940 Pa at 20°C
Autoignition temperature : 427°C
Flash point : 27°C

10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.
Substance name LD50 Oral LD50 Dermal LC50 Inhalation
Epoxy Resin >2000 mg/kg,Rabbit >2000 mg/kg,Rabbit Not available
Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat 29 mg/l,Rat
MIBK 2080 mg/kg,Rat >2000 mg/kg,Rabbit 8.2-16.4 mg/l,Rat
Iso-butanol 2460 mg/kg,Rat 3400 mg/kg,Rabbit >24 mg/l,Rat
Silicon Dioxide Not available Not available Not available
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rat 17.8 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

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Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:

Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects

Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Epoxy Resin EC50/48h >100 mg/l (Daphnia magna), LC50/96h >100 mg/l (Leuciscus idus), IC50/72h - Not available
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available

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MIBK EC50/48h 170 mg/l (Daphnia magna), LC50/96h 505 mg/l (Pimephales promelas), IC50/16h >100 mg/l
(Scenedesmus subspicatus)
Iso-butanol EC50/48h 1439 mg/l (Daphnia magna), LC50/96h 1430 mg/l (Pimephales promelas), IC50/72h 1250 mg/l (Algae)
Silicon Dioxide EC50 - Not available, LC50 - Not available, IC50 - Not available
Ethylbenzene EC50/48h 1.8-2.4 mg/l (Daphnia magna), LC50/96h 12.1 mg/l (Pimephales promelas), IC50/72h - Not available

12.2 Mobility in soil

Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS

Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III

Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : EPICON T-800 HS-GF , HARDENER
Product No. : TH 6037C
Product Type : Epoxy Phenolic paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 1 Causes serious eye damage
Skin sensitizer 1 May cause an allergic skin reaction
Specific target organ toxicity (single exposure) 3 May cause drowsiness or dizziness
Specific target organ toxicity (repeated exposure) 2 May cause damage to organs through prolong exposure
Aspiration toxicity 2 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H302 : Harmful if swallowed.
H305 : May be harmful if swallowed and enters airways
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H318 : Causes serious eye damage.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H373 : May cause damage to organs through prolong or repeated exposure cause the hazard.
ENVIRONMENT
H402 : Harmful to aquatic life.
H412 : Harmful to aquatic life with long lasting effects.

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PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
RESPONSE/FIRST AID MEASURES
IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.
IF ON SKIN
P302+P352 : Wash with plenty of soap and water.
P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.
IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Xylene 1330-20-7 25 - 30
2 Ethylbenzene 100-41-4 0.2 - 0.3
3 Iso-butanol 78-83-1 5 - 10

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation

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: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2. Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
: Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
: Do not allow to enter drains or watercourses.

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: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4. Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.
: Always keep in containers of same material as the original one.
: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.
: Prevent unauthorised access.
: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures

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: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Xylene 150 ppm 100 ppm
Ethylbenzene - 20 ppm
Iso-butanol - -

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 0.90 - 1.00
Colour : Clear Brown
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.2 : UEL% 10.9
Vapour pressure : 2900 Pa at 20°C
Autoignition temperature : 432°C
Flash point : 33°C

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10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.
Substance name LD50 Oral LD50 Dermal LC50 Inhalation
Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat 29 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17.8 mg/l,Rat
Iso-butanol 2460 mg/kg,Rat 3400 mg/kg,Rabbit >24 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:

Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

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Potential acute health effects

Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available
Ethylbenzene EC50/48h 1.8-2.4 mg/l (Daphnia magna), LC50/96h 12.1 mg/l (Pimephales promelas), IC50/72h - Not available
Iso-butanol EC50/48h 1439 mg/l (Daphnia magna), LC50/96h 1430 mg/l (Pimephales promelas), IC50 1250 mg/l (Algae)

12.2 Mobility in soil

Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS

Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.

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Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III

Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : EPICON T-800 , BASE
Product No. : TH 6037T
Product Type : Epoxy paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 2A Causes serious eye irritation
Skin sensitizer 1 May cause an allergic skin reaction.
Specific target organ toxicity (single exposure) 3 May cause drowsiness or dizziness.
Specific target organ toxicity (repeated exposure) 2 May cause damage to organs through prolong exposure.
Aspiration toxicity 2 May be fatal if swallowed and enters airways.
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H302 : Harmful if swallowed.
H305 : May be harmful if swallowed and enters airways.
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye irritation.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H373 : May cause damage to organs through prolonged or repeated exposure cause the hazard.
ENVIRONMENT
H402 : Harmful to aquatic life.
H412 : Harmful to aquatic life with long lasting effects.

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 Revision Date - 16/01/2021

PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
RESPONSE/FIRST AID MEASURES
IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.
IF ON SKIN
P302+P352 : Wash with plenty of soap and water.
P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.
IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Epoxy Resin 25036-25-3 25 - 35
2 Xylene 1330-20-7 15 - 20
3 Ethylbenzene 100-41-4 0.1 - 0.3
4 Silicon dioxide 14808-60-7 20 - 35
5 Iso-butanol 78-83-1 1-5
6 Methyl Isobutyl Ketone 108-10-1 1-5

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact

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 Revision Date - 16/01/2021

: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.
Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

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: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
: Refer to protective measures listed in sections 7 and 8.
6.2 Environmental precautions
: Do not allow to enter drains or watercourses.
: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4 Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.
: Always keep in containers of same material as the original one.
: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2 Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.

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: Prevent unauthorised access.

: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Epoxy Resin - -
Xylene 150 ppm 100 ppm
Ethylbenzene - 20 ppm
Silicon dioxide - -
Iso-butanol 100 ppm 75 ppm
Methyl Isobutyl Ketone 75 ppm 50 ppm

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder

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 Revision Date - 16/01/2021

Density : 1.35 - 1.45

Colour : Various
Odour : Smell of solvent
Solubility : Insoluble in water
Explosion limits : LEL% 1.4 : UEL% 12.3
Vapour pressure : 1940 Pa at 20°C
Autoignition temperature : 427°C
Flash point : 38°C

10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.
Substance name LD50 Oral LD50 Dermal LC50 Inhalation
Epoxy Resin >2000 mg/kg,Rat >2000 mg/kg,Rat Not available
Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat 29 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rat 17.8 mg/l,Rat
Silicon dioxide Not available Not available Not available
Iso-butanol 2460 mg/kg,Rat 3400 mg/kg,Rat >24 mg/l,Rat
Methyl Isobutyl Ketone >2080 mg/kg,Rat >2000 mg/kg,Rat 8.2 - 16.4 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:

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 Revision Date - 16/01/2021

Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:

Conclusion/Summary on mixture : No specific data.
STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects

Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Epoxy Resin EC50/48h >100 mg/l (Daphnia magna), LC50/96h >100 mg/l (Leuciscus idus), IC50 - Not available

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 Revision Date - 16/01/2021

Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available
Ethylbenzene EC50/48h 1.8-2.4 mg/l (Daphnia magna), LC50/96h 12.1 mg/l (Pimephales promelas), IC50/72h - Not available
Silicon dioxide EC50/48h - Not available, LC50/96h - Not available, IC50/72h - Not available
Iso-butanol EC50/48h 1439 mg/l (Daphnia magna), LC50/96h 1430 mg/l (Pimephales promelas), IC50/72h 1250 mg/l (Algae)
Methyl Isobutyl Ketone EC50/48h 170 mg/l (Daphnia magna), LC50/96h 505 mg/l (Pimephales promelas), IC50/16h >100 mg/l
(Scenedesmus subspicatus)

12.2 Mobility in soil

Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

13. DISPOSAL CONSIDERATIONS

Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III

Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

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SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE MANUFACTURER
Product Name : EPICON T-800 , HARDENER
Product No. : TH 6037T
Product Type : Epoxy paint coating, 2 components
Intended use : Coating : Solvent ( Refer to technical data sheet )
Manufacturer name : TOA-CHUGOKU PAINTS CO.,LTD
Address : 110 Moo 5 Wellgrow I.E. Bangna-Trad Rd. Km.36,
Bangsamak, Bangpakong Chachoengsao, 24130
Emergency contact / Dept : 66 038 570498 / Technical Lab
Telephone no. : 66 038 570498-9 Fax no. : 66 038 570500

2. HARZARDS IDENTIFICATION
GHS CLASSIFICATION Category Hazard statement
Flammable liquids 3 Flammable liquid and vapour
Acute Toxicity [skin , Dermal] 4 Harmful in contact with skin
Acute Toxicity [inhalation] 4 Harmful if inhaled
Acute Toxicity [ingestion , Oral] 4 Harmful if swallowed
Skin corrosion / irritation 2 Causes skin irritation
Serious eye damage / eye irritation 1 Causes serious eye damage
Skin sensitizer 1 May cause an allergic skin reaction
Specific target organ toxicity (single exposure) 3 May cause drowsiness or dizziness
Specific target organ toxicity (repeated exposure) 2 May cause damage to organs through prolong exposure
Aspiration toxicity 2 May be fatal if swallowed and enters airways
Acute hazards to the aquatic environment 3 Harmful to aquatic life
Long-term hazards to the aquatic 3 Harmful to aquatic life with long lasting effects

GHS LABEL ELEMENTS

Pictograms

Signal word : Danger

HAZARD STATEMENT
PHYSICAL
H226 : Flammable liquid and vapor.
HEALTH
H302 : Harmful if swallowed.
H305 : May be harmful if swallowed and enters airways
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H318 : Causes serious eye damage.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H373 : May cause damage to organs through prolong or repeated exposure cause the hazard.
ENVIRONMENT
H402 : Harmful to aquatic life.
H412 : Harmful to aquatic life with long lasting effects.

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PRECAUTIONARY STATEMENTS
PREVENTION
P210 : Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 : Keep container tightly closed.
P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P264 : Wash hand thoroughly after handling.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
RESPONSE/FIRST AID MEASURES
IF SWALLOWED
P301+P310 : Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 : Rinse mouth. Do NOT induce vomiting.
IF ON SKIN
P302+P352 : Wash with plenty of soap and water.
P303+P361+P353 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313 : If skin irritation or rash occurs: Get medical advice/attention.
P362 : Take off contaminated clothing and wash before reuse.
IF INHALED
P304+P340 : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES
P305+P351+P338 : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337+P313 : If eye irritation persists: Get medical advice/attention.
STORAGE
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
DISPOSAL
P501 : Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Specific of chemical material : Mixture
No. Substance name CAS No. W.t (%) CRITERIA
TLV LD50
1 Polyaminoamide 68410-23-1 70 - 80
2 Xylene 1330-20-7 1 - 10
3 Ethylbenzene 100-41-4 0.2 - 0.3
4 Iso-butanol 78-83-1 1 - 10

4. FIRST-AID MEASURES
4.1 Description of first-aid measures
General
: In all cases of doubt, or when symtoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconcious place in recovery position and seek medical advice.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with running clean fresh
water for at least 15 minutes, keeping the eyelids open and seek medical attention.
Skin contact
: Remove contaminated clothing and shoes. Wash skin throughly with soap and water or use
recognised skin cleanser. Do not use solvents or thinners.

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Inhalation
: Remove to fresh air. Keep patient warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occures, provide artificial respiration or oxygen by trained personnel.
Ingestion
: If accidentally swallow obtain immediate medical attention and show the container or label.
Keep patient warm and at rest. Do not induce vomitting.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute symptoms and effects
: Inhalation
Exposure to vapors may cause a health hazard.
Serious effects may be delayed following exposure.
: Skin contact
Irritating to skin. May cause sensitisation by skin contact.
: Eye contact
Irritating to eyes
: Ingestion
Harmful if swallowed
Potential delayed symptoms and effects
: Inhalation
No specific data
: Skin contact
Adverse symptoms may include the following: irritation, redness
: Eye contact
Adverse symptoms may include the following: irritation, watering, redness
: Ingestion
No specific data
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
: No specific treatment

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
: Recommended alcohol resistance foam, CO2, Powder fire extinuisher, water spray/mist
: Extinguishing media which must not be used for safety reasons.
Water jet zinc dust containing product should not be extinguished with water.
5.2 Special hazards arising from the substance or mixture
: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
: Appropriate breathing apparatus may be required.
5.3 Advice for firefighters
: Cool closed containers exposed to fire with water.
: Do not release runoff from fire to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
: Exclude sources of ignition and ventilate the area. Avoid breathing vapours.
: Refer to protective measures listed in sections 7 and 8.

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6.2 Environmental precautions

: Do not allow to enter drains or watercourses.
: If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
: Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
: Clean preferably with a detergent - avoid use of solvents.
6.4 Reference to other sections
: See Section 1 for emergency contact information.
: See Section 8 for information on appropriate personal protective equipment.
: See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling
: When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
: For personal protection see Section 8.
: Never use pressure to empty : container is not a pressure vessel.
: Always keep in containers of same material as the original one.
: Comply with the health and safety at work laws.
: Do not allow to enter drains or water courses.
: Operators should wear anti-static footwear and clothing and floors should be of the conducting type.
: Isolate from sources of heat, sparks and open flame.
: Avoid skin and eye contact.
: Avoid the inhalation of dust, particulates and spray mist arising from the application of this mixture.
: Avoid inhalation of dust from sanding.
: Smoking, eating and drinking should be prohibited in application area.
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits.
: In addition, the product should only be used in areas from which all naked lights and other sources of ignition
have been excluded.
: Electrical equipment should be protected to the appropriate standard. No sparking tools should be used.
: Mixture may charge electrostatically: always use earthing leads when transferring from one container to another
Information on fire and explosion protection
: Vapours are heavier than air and may spread along floors.
: Vapours may form explosive mixtures with air.
7.2 Conditions for safe storage, including any incompatibilities
: Store in accordance with local regulations.
: Notes on joint storage
Store away from oxidising agents, from strongly alkaline and strongly acid materials
Additional information on storage conditions
: Observe label precautions.
: Store between 0ºC and 40ºC in a dry, well ventilated place away from sources of heat and direct sunlight.
: Keep container tightly closed.
: Keep away from sources of ignition.
: No smoking.
: Prevent unauthorised access.
: Containers which are opened must be carefully resealed and kept upright to prevent leakage.

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 Revision Date - 16/01/2021

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures
: Provide adequate ventilation. Where resonably practicable, this should be achived by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates
and solvent vapours below the occupational exposure limits (OEL) suitable respirator must be worn.

Exposure Limits ACGIH TLV

Substance name STEL-15 min Long term-TWA-8hr
Polyaminoamide - -
Xylene 150 ppm 100 ppm
Ethylbenzene - 20 ppm
Iso-butanol 100 ppm 75 ppm

ACGIH (American Conference of Governmental Industrial Hygienist)

TLV=Threshold Limit Value - 8 hr/15 min. STEL=Short Time Exposure Limit (15m) - TWA=Time Weighted Average (8hr)
Personal protection equipment
Respiratory Protection
: Use a properly fitted, air-purifying or air-respirator complying with an approved standard if a risk-
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator.
When concentrations exceed the exposure limits shown above, worker must wear appropriate
respirators. Provision of other control such as exhaust ventilation should be considered if practical.
Eye Protection
: Wear safety eyeware, e.g. safety spectacles, goggle or visors to protect against the splash of liquid.
Eyeware should comply with an approved standard.
Wear a full face shield if mixing or pouring operations pose a risk of splashes.
An eyewash station is suggested as a good work place practice.
Hands Protection
: Gloves of an appropriate material should worn during mixing and application.
For prolonged or repeated handling, use the following type of gloves: gloves; nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be applied
once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Skin Protection
: Overalls which cover the body, arms and legs should worn. Skinshould not be exposed.
Barrier creams may help to protect areas which are difficult to cover such as face and neck.
They should howerve not be applied once ecposure has occurred. Petroleum jelly based types
Such as vaseline should not be used. All part of the body should be washed after contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : [ ] Solid [ x ] Liquid [ ] Paste [ ] Powder
Density : 0.95 - 0.99
Colour : Clear Yellow
Odour : Smell of solvent
Solubility : Insoluble in water

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 Revision Date - 16/01/2021

Explosion limits : LEL% 1.2 : UEL% 10.9

Vapour pressure : 2900 Pa at 20°C
Autoignition temperature : 432°C
Flash point : 34°C

10. STABILITY AND REACTIVITY

Reactivity : No information available.
Stability : Stable under recommended storage and handling conditions.
Possibility of Hazardous Reactions : When exposed to high temperatures may produce.
Hazardous polymerization : None under normal processing.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Keep away from oxidising agents, strongly alkaline and strong acid materials.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, oxide of nitrogen and smoke.

11. TOXICOLOGICAL INFORMATION

There are no data available on the product itself.
Exposure to solvent vapour concentration from the component solvents in excess of the state occupational exposure limits may
result in adverse health effects such as mucous and membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness,
downsiness andin extream cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness,
irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in
the eye may cause irritation and soreness with possible reversibledamage.
Substance name LD50 Oral LD50 Dermal LC50 Inhalation
Polyaminoamide >2000 mg/kg,Rat >2000 mg/kg,Rat Not available
Xylene >2000 mg/kg,Rat >2000 mg/kg,Rat 29 mg/l,Rat
Ethylbenzene >3000 mg/kg,Rat >5000 mg/kg,Rabbit 17.8 mg/l,Rat
Iso-butanol 2460 mg/kg,Rat 3400 mg/kg,Rabbit >24 mg/l,Rat

Skin corrosion/irritation:
Conclusion/Summary on mixture : Causes skin irritation.
: Method: Additivity approach, no testdata available.
Serious eye damage/irritation:
Conclusion/Summary on mixture : No specific data.

Respiratory or skin sensitization:

Conclusion/Summary on mixture : No specific data.
: No specific data on Respiratory sensitization.
: Method: Concentration Limit, no testdata available.
Germ cell mutagenicity:
Conclusion/Summary on mixture : No specific data.

Carcinogenicity:
Conclusion/Summary on mixture : No specific data.

Reproductive toxicity:
Conclusion/Summary on mixture : No specific data.

STOT - single exposure:

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 Revision Date - 16/01/2021

Conclusion/Summary on mixture : No specific data.

STOT - repeated exposure:
Conclusion/Summary on mixture : No specific data.

Aspiration hazard:
Conclusion/Summary on mixture : No specific data.

Potential acute health effects

Inhalation : Exposure to vapours may cause a health hazard.
Serious effects may be delayed following exposure.
Ingestion : May be harmful if swallowed.
Skin contact : May cause skin irritation.
: May cause sensitisation by skin contact.
Eye contact : Irritating to eyes.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data
Ingestion : No specific data
Skin contact : Adverse symptoms may include the following: irritation, redness
Eye contact : Adverse symptoms may include the following: irritation, watering, redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Long term exposure
Potential immediate effects : No specific data
Potential delayed effects : No specific data
Potential chronic health effects : Not available
Conclusion/Summary
General : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels
Carcinogenicity : No known significant effects or critical hazards
Mutagenicity : No known significant effects or critical hazards
Teratogenicity : No known significant effects or critical hazards
Developmental effects : No known significant effects or critical hazards
Fertility effects : No known significant effects or critical hazards
Other information : Not available

12. ECOLOGICAL INFORMATION

There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
12.1 Aquatic toxicity
Substance name Results - Species - Exposure
Polyaminoamide EC50/48h - Not available, LC50/96h - Not available, IC50/72h - Not available
Xylene EC50/48h 1-10 mg/l (Daphnia magna), LC50/96h - 13.4 mg/l Fathead minnow, IC50/72h - Not available
Ethylbenzene EC50/48h 1.8-2.4 mg/l (Daphnia magna), LC50/96h 12.1 mg/l (Pimephales promelas), IC50/72h - Not available
Iso-butanol EC50/48h 1439 mg/l (Daphnia magna), LC50/96h 1430 mg/l (Pimephales promelas), IC50 1250 mg/l (Algae)

12.2 Mobility in soil

Soil/water partition coefficient (KOC) : Not available
Mobility : Not available

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 Revision Date - 16/01/2021

13. DISPOSAL CONSIDERATIONS

Paint ingredient, incinerated ash and used container should be disposed by recognized companies which are licensed
as industrial waste disposal by prefectural governor.
Do not dispose the sewage to the ground and drains after washed a container, instrument equipment, and like.
Incineration waste and waste water shoul be disposed in accordance with the regulation and legislations for Waste Disposal,
or entrust such business to the approved licensed parties.
Paint and waste should be disposed in small pieces by the open type of incinerator to have absorbed them with diatomite.
Containers which are not properly cleaned may contain (highly) flammable or explosive vapours.
Special precautions:
Use appropriate protective equipment for the removal and / or disposal of this product

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Make sure there are no damage, corrode and leak on the product container. Products should be also prevented from falling,
loosening or tumbling during transit. Packing , labelling and transport take place according to appropriate regulation.

International transport regulations ADR/RID IMDG IATA

UN Proper shipping name Paint Paint Paint
UN number 1263 1263 1263
Transport hazard class 3 3 3
Hazard Label

Packing group III III III

Environmental hazard No Yes No
Marine pollutant - Yes -

15. REGULATORY INFORMATION

Industrial use
The information contained in this safety data sheet does not constitute the user's own assessment of
workplace risks, as required by other health and safety legislation. The provision of the national health and
safety at work regulations apply to the use of this product at work.

16. OTHER INFORMATION

The information on this safety data sheet is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks, as
required by other health and safety legislation

Page 8 / 8
INSPECTION ACTIVITY OF PAINT SUPERVISOR

Paint supervisor will be inspected process of paint.

- Prior to paint
- During of paint
- After paint

PRIOR TO PAINT is : -
A. SURFACE PREPARATION
Surface preparation of substrate, surface preparation will be checked are as follows :-

No. Item Method Extent Criteria

1 Surface cleanliness VISUAL All Surfaces SSPC Specification
(removal of rust &
harmful material)
2 Surface Profile VISUAL Spot Comparison with
standard specimen
surface roughness of
kean tator
Check by Random Comparison with label
Tesste press indication of press “ O ”
“ O ” film test or film
Check by - Take a number or
Dept. Micrometer reading of instrument
B. WEATHER CONDITION

Weather condition for painting shall be applied in accordance with paint manufacturer’s
instruction and data sheet, general weather condition for paint application are :-

2.2.1 Ambient temperature / 10°C AMB. T C 40°C.

2.2.2 Surface temperature should not be over 50°C.
2.2.3 Dew point / + 3°C and over of surface temperature.
2.2.4 Relative humidity / below 85% R.H. and below 95% R.H. for inorganic zinc
rich primer

C. ADHESION TEST

No. Item Method Extent Criteria

1 Adhesion test “ ASTM ” Test ASTM Specification

Designation D 3359 panel

D. CURING CHECK

No. Item Method Extent Criteria

1 Chlorinated Rubber Random ASTM Specification

2 Epoxy paint Place the saturated Random Paint manufacturer’s

cloth with solvent on Specification
paint film and leave
at minimum 24 hrs.
URING PAINT APPLICATION including of :-

1. Mixing ratio of paint and thinner check.

Mixing ratio of paint and thinner shall be in accordance with paint manufacturer.

2. Wet film thickness shall be checked by wet film thickness gauge.

3. Defect of wet paint film such as paint sagging, bubbling, and etc., should be
prevented and have to before repair paint film become dry.

AFTER PAINTING

After painting, supervisor will check as following item :-

1. When paint film become dry, the thickness of paint film will be measured with the
dry film thickness gauge and dry film thickness should be accordance with paint
specification and recorded in inspection report.

2. Appearance check and defect of dry paint film such as holiday, bubble, paint
sagging and etc., shall be repaired in accordance with paint manufacturer
comment.
 COATING INSPECTION REPORT

CLIENT TRC CONSTRUCTION PUBLIC COMPANY LIMITED REPORT NO. :

PROJECT : CLEAN FUEL PROJECT- 15New Tank Construction Work DATE :

PROJECT NO. : PREP'D :

JOB CODE : CHK'D :

SPEC. NO. : APP'D :

REF. DWG. NO. :

SURFACE PREPARATION : WE CERTIFY THAT THE STATEMENT

SURFACE PROFILE : IN THIS REPORT ARE CORRECT

ABRASIVE USED : SPECIFIED

PAINT Dry Film THK.(Min.)

MAT. MANUFACTURER (PAINT)

: TOA-CHUGOKU PAINTS CO.,LTD.

MEMBER NO. OF DRY FILM THICKNESS

ENVIRONMENTAL COND. AVE. DFT.
NAME COAT 1 2 3 4 5 6 7 8

1 st AMB.Temp. Surface Temp. % R.H. A

DATE B

/ / Dew Point WEATHER COND. C

2 nd AMB.Temp. Surface Temp. % R.H. A

DATE B

/ / Dew Point WEATHER COND. C

3 rd AMB.Temp. Surface Temp. % R.H. A

DATE B

/ / Dew Point WEATHER COND. C

4 th AMB.Temp. Surface Temp. % R.H. A

DATE B

/ / Dew Point WEATHER COND. C

D
PAINTING MATERIAL CONTROL

* QUALITY CONTROL OF PRODUCTION *

(A) Raw Material Control

• Specific Gravity
• Oil Absorption
• Moisture
• Colour
• Sieve Residue
• Viscosity
• Water Content

(B) Finish Product Control

• Fineness
• Specific Gravity
• Drying Time
• Viscosity
• Sagging Resistance
• Colour Matching
PRODUCTION PROCESS CONTROL

RAW MATERIAL RAW MATERIAL

MIXING

GRINDING RAW MATERIAL

ADJUSTING

RAW MATERIAL

FILTERING

PACKING RAW MATERIAL