phe

equl gular
pmomentum postulate, thus It cannot explain the relative intensity of
postulote
explaining the second frequencies in the hydrogen spectrum.

OBJECTIVE Type Questions

[1mark ]
Multiple Choice Questions (a) 53 pm (b) 27 pm
(c) 18 pm (d) 13pm
4. In terms of the Bohr's radius ao, the radius of [NCERT Exemplar]
he second Bohr orbit of the hydrogen atom
is given by: 3. The radius of the innermost electron orbit of
(o) 4a0 (b) 8a0 a hydrogen atomn is 5.3 * 10- m. The radius
of the n=3orbit is:
(c) 2 ao (d) 2a0 (a) 1.01 x 10-10m (b) 1.59x 10-10m
(c) 2.12x 10-1°m (d) 4.77x 10-10m
Ans. (a) 4ao
Explanation: As r oc n' [CBSE SOP 2022]
For Bohr's second orbit, n = 2 Ans. (d) 4.77 x 1010 m
[CBSE Marking Scheme SOP 2022]
Therefore, radius of the second Bohr orbit of
the hydrogen atom is 4a0 Explanation:
Given that r= 5.3 x 10-1lm
A Caution Let ra be the radius at n=3.
Students are often confused in finding the correct So, r3 =nrË = 4.77 x 10-10 m
option. For it just find out the relation of the physical
quantity and calculate the answer. Related Theory
C The mean radius of an electron's orbit around the
2. Taking the Bohr radius as do = 53 pm, the nucleus of ahydrogen atomat its ground state, or
alus of L* ion in its ground state, on the lowest energy level, is defined as the Bohr's radius.
basis of Bohr's modeL. will be about:

Atoms 421
 Ans.
Ans. 4
5.
(d) (c) hydrogen
the atom. on
(a)ldentify Each reference, reference
thegiven around
Explanation:
centripetal (c) (d) (c) (b) (a) Thisarguments, B= wouldwhere (proton), If B= is anThe
correct.
momentum Explanation:
2Tt nh
Where momentum
(a) is willbe (a) (b) one
non-inertial inertial.
not the circular inertial.
the not isthe
Bohr-quantisation electron
electron is The escape atom.the an An 2do, The any Theelectron is TheBohr's the would
nlast binding
of
expressIon Me' decides
electron a frame motion frame expression8n'eh bethe
n angular
amountwhereradius stable
potential angular properties the
= statement
model a where is fixed
of acceleration. orbits, not moving
thelectron
e energy
3..2,
1, Bohr' s statements non-inertial. In in in proton
mass)
(M= to moving
electron T 3h orbit 3h frame of be
in of do, of isthe nucleus a which which binding work8n'sh?
momentumQuestion
[CBSE
Bank energy its isthe energy momentum of H even th e
model an of not integral. is me of
3h Bohr's is of
electron atom, not around isina
ifn orbiting second second
positive. that the proton applies the around a
atom. electronreference. true approximately. at H-atom,
statement
Therefore, (proton) electron correct energy frame (m=
= states = of correctly below IfSo,
electron Exemplar]
[NCERT electron rest,
radius.
-3.4 because would only
about of orbit electron the of is the it. electron a
angular
then 6 its of
that orbitingthe eV electron the orbits are at have because:
to By the fixed
considering
frameframe is would reference
nucleus will rest, revolving at not is
electron.
given orbitingsatisfies it proton
angular orbit based forms rest at similar mass). nuclei
I 2023] let in some be rest
the be
it to is in of of is in
is a

8. Ans. 1:4:9Ans.(c) 6.
7.
groundthe level Let electron two theoryStudents of He-atom.
Caution and positive
Aapplicable around
and revolves lighter
Explanation:
someproposed
hydrogenwhich
atom Bohr (b) (a) (d) (c) (b) (a) The ground orbitRelated The
Theory Ratio 1:4:91:2:3
(c) (a) The
(d) (C) (b) (a) E2-E1 Explanation:
n=1,2, and 3.
state.
n=3 State. state.some
no excited it h En or Bohr's e molecular wil predicts
will form.spectrallines. He-atom. ismolecular
will form. will Bohr aroundBohr's ratios
all will more
also, valid of
of = atoms is is state
atoms atoms fallsion charge not not radii
t, H-atom,
me* -1 applicable theorå. are it the not notmodel radius
r?::r?
not n'h? 8eelectrons. between
of state often will to be be only be that the
and hydrogen charge atoms
which in continuous be of For
atoms be It Ze, applicable nucleus first
wil wil absorbed not applicable at applicable for the is the is first
and If fails confused also stationars
nucleus a applicable
be be only be where room the =1:4:9 three the
make tto
he all on lowest mean = three 1:3:52:4:6 (d) (b)
will radiation the in has of 12:22:
excited the to
applicable inthe is spectra a
Bohr
the as temperature. as orbits,
a somegbout the Z also to to energyhydrogenradius orbits
move at energy theof hydrogen case electron. is it [NCERT radii
transition
NCERT
xemplarl all H-atoms electron
single a for is
hydrogen well as
hydrogen
molecular atomic of
3
to of limitations. the
of
applicablemodelfor a of
to as it are:
the frequency atoms He-atom. a Exemplar] as a level. atom an
the llimitations
ike It is H-atom: electron's
are
it number
is discrete
n singe is in f or in at
wie lhis for form not
for the the
=2 first a of a its
 11.@
The Ans. 10. Caution A Ans.
9,
Paschen
series Lyman
series
(b) spectrum? alsoOroitsBohr'revolve of electron
circular
Explanation: ellipse
(c) an atom,
(a) According
() (c) b)nucleus state The w state.hence
) (a) to hydrogen s Students required Related
Ans. (b)
ne
(c) (0) region
Which of an a
Theory n=3 sufficient nthe model radiation
inciwher
He He He Panation: neBalmer possible. a a a excitation
to first correspondi
dentineExplon=2
nanatEg ion: state. 3(d) state.
visible shouldtheors. in electron circle circlecircleperfect any no the
no some
has atom orbits can indefinitely, an by some atmake
oms
issimpletransitions, series circular are atoms on
a
an series of one its excited
for ground Fatoms of
be It often of of electron to of
neutronsbecause:
inert reaionspectral
seriesThe revolve
in an electron energY
of transition=
is According an circle
constantly sample
of wil
model
Bohr chosen does orbit anwhich allowed Bohr's the make
WIlL a state. energy. toLet
gas. no comes allowed the
notconfused integral of excited state, E, will
and = only. around or
in 3, Brackett series
Balnmer
(d) series
(b) when
explain the any itsifcan to an
the is in to
radius model jump from atoms As AE arnd and a move
called 4. This angular decreasing
radius path according transition
5, multiple radius revolve states. atom this = n Ej
nucleus. is Bohr'as transition to
... visible elliptical why about is from all (E =be the
the nucleus is: of energy the 1
Balmer to
notcorresponding
why is = willrespectively.
nË only
limitation momentum around 1to - the to
first
of model, hydrogen the the E)
applicable = orbits [Diksha] radius to
moveH-atoms the excited
circular electron 2 h in groundenerau to n is energy
series. 2, Bohr =
lies are the the n
of an a 3,
not to hy =

Ans. Ans. de-Broglie's12.

13.
principal
quantum
number. the masswhere For Constant.
Related
Theory are
allowed
anwhichExplanation: momentum
(c) Angular
Momentum (Potential
d) energy following
(b) According
(c) energy
Kinetic(a) nucleus. electrons.
electrons
the charged shows'
atom
physics Bohr's
the wavelength taken
it
hypothesis,
Explanation:
waveAccording (a) (d) (c) (b) (a) orbits in Wave for (d) (c)
contains an which forces.
permitted and any integral pernmitted Angular independent
analways an Bohr's electrons He
L, permitted the character.
to integral integral integral correspond particle
m by greatest
was be the has
speed angular quantities
discrete
take to travel nucleusBohr quantised
and mVrL== multiple the
momentum ie., an a the equal one
orbit to Of Bohr's the multiple
circumference hypothesis
duality. are
was stationary
integral
2r¯ electron multiple
of v orbit, circulate
classical all Hence, multiple of more
and the are momentum in contribution
atomic = to to
of the surrounded
the as wavelength not
2 nh postulates,separate nà. wavelength circular orbits
toms electron,
n the a is of According electron.
is 2T h possible
theory, first a multiple of of gave subject
central to
positive angular n=1,2,. only energy also
circularwavelength
where, model
small, to
de frequency wavelength of Exemplar]
by [NCERT
r to standing
of in orbits associated the bringing an
is those discover of
integer the an circular
the which by to state orbit to
momentum, h values? de orbit explanation
electron
is positively The this,
radius electrons
orbits orbiting modern [Diksha]
Plank's theofaround Broglie only can Broglie waves
is: in
called orbits that Bohr with the the
423 of be
is in if
 Ans. 14. (d) (c) (b) Select
Assertion
(a)from Two
15. e
Assertion-Reason
thQuestions
18. Reason(R): Assertion A
correct
explanation
A Both ofBoth
A.
not
explained
Explanation:
Assertion atom. (a)
Reason(R): is is statements
nThestions
follow:
that Read Both false true the
explainexplanation of
A. A A
codes (A)
y the explanation and correct
and but and
(A): and
following (A): the andR A R(a),
the R
hydrogen explainatomBohr's R is R are
(b), the
d toelectrons.
notare Al many the Simple
withdirectly stabilityBohr'sfrequencies.
different of not spectrum.
certain In is
false. are answer are
CASE fine are the also
single the energy closedsingle oftrue
true (c) other
passages
and atomic true could and
by spectrum the theory false. A.
electrons
subjected
being
just applied Bohr spectrum of
spectral and labelledgiven-one
labelled
to
an central an and slightly
lines
with but (d)
levels model lines
e model fine not Rthese
BASED atom, R R is as
force. of is but of
structure of is the given
answerthe in of to successfulls the completely Reason
cannot hydrogen but lines
hydrogen, hydrogen NOT questionsS
ancalculate
an a correct
s correct group below.
marks)
[4&5 atom atom could
are the (R).
be of
4
uestions
Both
Ans.(a) 17. Ans. 16. Ans.
t the electrons
is the nucleus Reason
(R):
Assertion plums
sphere are
Explanation: (c) (A):
Reason Assertion
subjected Explanation:
thalel Thisan beThe (a)
rticle electrical positively
Explanation:
impact A.
nucleus. explanationof assumed directly Both
atomexplanation of
A.
are isA
r, of true (R): electrons
because A arranged to A
unds forces arecharged
(A):positively with
(CBQs) and but one applied and
rameter kept This electrons
The to In
the into nucleus.
If the
Electron Thomson' atom
Thomson's
shape. in model.
Thomson's is many
implies,
that electrostatic
attractionond bes R trueare R
of reason
revolving it are
R stationary,
is known single
the is atom in to
in simple
model
Bohr
back attraction. protons the the uniformly false. the
primarily true chargeda is electrons.
because is
is pudding. supposed centtral calculate
would nucleus is as atoms
(0 and electrons model model and
= around revolve
around the they revolving model a
minimum the why
contained R matter
embedded plum force. are energy R
). the is
attracted is be due
would to theof the
goes Ffor the the
unstable. not
to like electrons
be ofpudding levels
n to were round round con correct
aa d
neary large the nucleus within Corect in the
atom being
the the ful the a of
 Ans. is
It Series.
Ans. Ans. Ans.
29. 25.Lyman 24. 23. Ans. 22.
21. 20.
kinetic
approach
closest
charged energy? on
the a-particle
Define remainWould whichName attractbecomesThe What orbits. momentum
non-radiating
multiple of aroundBohr Whatprotons than the This this? istheofThe and (C)
a mass is mass massWhat
VERY 2TT00
V
..Bohrgrounda Let
defined thin e electrostatic postulated are the circular
theSHORT the lie the the will and
due masses Numnber velocity
approach and
unchanged the sum is radius @o
particle gold in stationary
electrons stationary of to
of
isdistance spectral
uv neutrons
of ofthe state
as electron Bohr happen 2T h of an orbit
'.kinetic
foi. nucleus of athe of a ratio of of
What region. orbits stable electron? of
the an that the mass H-atom a SHORT
from for The formula field Such revolutions whoseelectron
series into proton of hydrogen
minimum energy of if in electron in orbits? masses in
an
will
distance a if electrons their nucleus defect.
closest charge proton tH-atom?
he of orbits in is mass radius
the a-particle ANSWER Delhi revolving which and less be
be of free of Exemplar]
[NCERT
nucleus 'K for nucleus the discrete,
certain' of per atom The V.
distance the hydrogen are is is It
electron. than is
approach. Gov. its is an
| of is where
-e, had the nucleus anthe state. always unit equal electr
2017] bombarded
[CBSEdistance the stationary
can constituent found revolves
of a QB itself. electron ta-particle
he ANSWER
at H-atom integral
angular revolve time to
closest charge 2022]atom Why sum
which ofdouble will less that the
the Anmarks|2 [1mark] = in
of
Type-l
Ans. Ans.
Ans. 27. 26.
28.
of
Totalbetween
on energy the This
energyWhat charges.
1PaschanWrite values ofthe Bohr forcharge a If answer. e Type
nucleus.
At initial
to distance negative
the proton = electric is
thispotential
the
Questions nucleus. charges the
gold The signifies formula 1.6
kinetic of is 1
a H-atom
distance, kinetic -45. series had *
offoil and
electron electron the relation QuestIons currentcharge
closest which 10-19c.
that
is Duesignificance involves a
energy energy electron is
isnegative. lines remains charge isflows
K.E greater
K= energydue doubled. and tothe in remain then given
= approach offor Give ins
electrostatic the time
4TEo P.E of hydrogen
[Delhi the only by
1 (SA-)) of nucleus,
than electronorbit? same the 3 44
Exemplar
(NCERT
the constant reasons l= T
Ze(2e) a-particle of wavelength the (VSA) and
change? How K.E. Gov. Bohrelectronand 2na
particle
charged
theto the because Q=e.The
is spectrum. product for Q
of the QB for e
does attractionbound negative formula
is incident electron. PE. 2022) given your
the
the to in of
equal is
 . 33, Ans. 32. 31, on
Here, electron dtom, quantum ctom Show Change experiment.
energy scattering book a
more Thus, mass of not of a In14K)
(Hydrogen Explain.
foil? th
scatteringin What
spectrum state
wavelength angular Calculate
Balmer thseries
e
According athin the Dividing doubled,IFK is
By result, hydrogen be
gold State The
V= m the varies that what if than the of sheet sheet to of
= is as of solid large
alpha-particle results short
given the incident foil, [CBSE momentum.
which series the ()
Velocits Mass angular number to the it an the mass is
experiment of does Bohr' s by
the as factor hydrogen (1.67
enough. then of of wavelength
hydrogen
of mvr = by. radius electron moves a-particlestarget solid a
hydrogen do it short
of ().
n of a- Question solid part the r= We
of the Bohr' s of [CBSE does x the you belong. the
quantisation
momentum Where
the fromn=1
of the
particle 102 Thishydrogen wavelength get
the
electron 2 nh is scattering at of
Calculate hydrogen 2 2
the in nucleus scattering expect
is Bracket 4r2K
e 2Ze? 1
electron theory atom. Question kinetic used scattering in the spectrum limit 1
n
orbit a would kg) is temperature Bank repeated
is hydrogen in (6.64 because placeelectromagnetic [CBSE 2Ze K
of to and (hydrogen). is is for
the less experiment, used Term-2 if
a of
[CBSE the inBank n not x angle a-particles [CBSE
2019] condition
series the spectrum. limittfhoer
SQP t
hydrogen = of ishe
revolving
hydrogen principal potential
3? a-particle bounce
particle 10"2 than the
in using shortest 913.4
2015] 2023] atom a 2022] Lyman
masswould place 2022]below gold
As kg). th e and .i)
is if a of .

Ans. 35.
The
providesrevolving to FLet, revolves
F, Inahydrogenatom, inpossessed the derive of Using Putting From where,
=
move = a centripetal
necessary
force. moving If
the the Also, centripetal
circular the an
Electrostatic
electrostatic Centripetal significance ) nucleus force if
in around electron the
Rutherford 4n'm2 rn'h? mthis we the electron n h r
the electron in = =
circular orbit by value get, of atom Planck's
= Radius
necessary expression and charge force a Principal
the electrostatic circular
Fe=Fe force ofthe in r= in V=
my? K=
of
and force orbit of F= the required
F= of
force radius
nucleuselectron?
an hydrogen rcn (), on mass quantum
constant the
Atoms electron total model 4n'mkZe? 2Turmr electron orbit
centripetal nucleus. ofrequired of for 2KZe? we nh 2KZe? 1 KZe the my'
of radius r. n'h? (Ze)(e) 1 is orbit
attraction get, attraction
having negative the nucleus given ofand mnumber
attraction by having atom. of wil radius
r. total
force. the [CBSE
2014] the by, velocity
charge provide is r,
between electron charge-e of
energyWhatenergyatom, between Ze, then the
427 (Fe) +e then v
is the the
is
 Ans. 36.
Ans. 37.
(B) electron
(A) Here, .. Potential equation
From(). K.E.
radiation
Also
de-excites Derive (A)
e-excites
4 frequency
theFromrevolution Total of
Therefore,anyfowhere
r electronpermitted in byOn What in State
defining
the negative electron
radiation show SHORT which the energy
Bohr's an all is energy
h Paschen isBohr's bound r
from equals emitted
of expression is classical stationaryhe
torbits. P.E. = K.E, = K.E, = my2
thatfrom Plank's is the possible
to sign in
an L=nvr =
E.
=: E of
[Delhishortest to = of the
emitted
level theory, electron. ancirculate electron electron
for angular quantisation indicates
series the KE. (e)(-e) 1orbit, (e)(e)
[CBSE to levelwhen constant.
integral theory, e? m²
n large permitted
orbit, circular Gov. positive e' +
to the classical ANSWER
n for wavelength
of P.E. in
when 2T nh momentum onls SQP in
level Term-2 2022]
SQP values to athe -,n=1, the spectral that hydrogen
= hydrogen
frequency hydrogen multiple -e?
level inorbits
Term-2 conditionnucleus. 8re,r
4re,r e
n frequency frequency electrons
those the
is an
given of (n 2, allowed lines?
present revolving atom
electron of atom
n, atom .... 3, of
orbits 2022] e
| f - for
as, this 2 h an are
of of 1). ofmarks|3
Type-l|
(B)
Thus, For Gven WhereL
momentum,
permitted
mass principal
Thecalledelectron
Questions wavelengthWhere
R=For A= As
Therefore, radiusWhen Where wavelengthlengthquantum
Large2n So
n1 now shortest we
1.097 electron
r mabove
=n-1, R= know P l
n, equation then is is respectively.
f= xRydberg's Linear condition.
with
contined orbit m,
f= that 2l à equation mass
1- 1 10-
1wavelength P=% associated
A=
nT mk²:2e2r? À=8.21
P= revolves
= velocity quantum
number. and and
= =
1.097x10beconmes m-1 for 2r momentum
h mv
4r'mke 2n,n-2n²mk?zet =n, 1.097x10|: = 2Tr nh h and
Paschen to
When n r v
(SA-ll) constant 1 is
h
derivation Pr= or in21/n move is
x h P with V. isthe the are
1 Bonr'
1=n 10' putn circular a the ans positive speed
the
series, electron electron on radius
101 1 2 nh nh
(n-1)°n?(2n-1) of m 2 de-Brogie a angulor
andz= = orbit line famous intenev of of
it
o is:
1 and of of f h th
 Number of scattered particles detected
104 10 10 10 109 10 Ans.
38.
W.r.t.
particlesSpace a-particles. Hgure
O As l80. forlargedirections a-particles
beamtrajectory
parametersCollision' s Theangles. most 1%of From
positivestrong 90°a-particles Rutherford
scattering of
large the -hin orbit.in
the to the scattering hich
n is
100,000 these 20 determine Draw
head and the nucleus.
is 10 scattering.
Impact a-particles
of the
help the number foil [CBSE
angle
shows of repulsive about incident Scattering 40
60
80 nucleus a
rebound
empty, of charge
th e same
with impact
on a-particles, of Marking
of
plot
timnes nucleus
m With as passed plot
size parameter
collision particles impact
scatteringangle. ofgold
a-particle beam 1 and of f= as
only deflection Impact different force. particles in it inside the
concentrateddeflected angle orbital
back larger of parameter 8000 through is upper Describe a-particle toScheme 27r
anwas gets -=
small get This clear 100
120
140
parameter the scatteredshow
indicates atom a-particles parameter close distribution
isprobabilities. (in serves explains
scattered scatter
deflect degree) mk?efrequency
4n²
hence 10-14angle high, force the that limit atom,
% to
deflected backward
the
Term-2
which (b ) at a briefly scattering n'h
of m =for nucleus depends the will by by foil, on
powerful particles
that the most fo r most [CBSE Explain the variation
to rebound
undeviated is in of come more more only
2019] the picture,
SQP of
is 0?. mininmum center
by 180
160 existence how
number
incident 10,000 10-15 different a due of size
electron
of suffers impactgiven 2022]
the on
small from than than0.14%
the way how with by
m by as to of the with of
a

Ans.
40. 39.
restricted The
momentum Electron orbit
withoutstable Frommodel How (B) (A) size a most
in of
Thus, (i) (0) () below. the
figure in incident strongsmall
B of -particle
motion is a-particles of
corresponds orbitsBohr's the
revolves the explained the andWhat andWhat What distance
The The volume.
tool the
in r nucleus.
is of mv emission model-An stability 0 trajectories, on mass
E,
= Z En
= L=mVr = such in =can kinetic to goes
an an I =cannames
9° gold
= is which were of determineThus, of
-13.6 1 -13.6 integral electrona we we nucleus
byradians?radians? Target O
for circular to of closest foil the head
manner de-Brogie's
a of an say say are
H2 atomhydrogen is
Rutherford atom
Atoms eV z²eV nh certain
radiant observedtraced energy
on
atom 2multiple
orbit, electron about about given doubled.
approach
in upper
circular has is
collision.
that to
(b), (b),
of concentrated
energy a atom
energy.hypothesis? (b) by scattering
limit
2T h its can
number for How
as a-particle
[Diksha]
for and change?
different
angularorbits reside
in shown to Hence,
level Each Bohr = = ? does the
429 is of 0° 0° is
 430
41.
(B) (A)
when(i) when thirdtransitions Ancorrespond ldentify
electromagnetic
to an these glass Balmer
wavelength
certainelectromagnetic states.
atoms A And hypothesis
de-Broglie
From
Determine
()and photons. either photons
electron a glass from
wavelength
wavelength is is the excited state. electron higher
rt mv
by absorption strong container The with 2T nh h 2Trnh=
energy to one and Bohr
energy,
Total E A container
a jumplevel, container all mVr=L =
the absorbing
given across absorbs to. 27cr
or corresponding n 2Tr model
[CBSE in Explain. its
with of
photon photon final to it absorption Paschen
more Waves mv
ics Ground
state absorbed emitted the hydrogen its even does spectral are WavesS
atoms
Question the a contains
photon,
quantum Assume is
n=1 n=2 n=3 n=4 n=5 not
or orbithigher photon series found irradiated
with in
longest
with energy
emitting absorb
spectral exitingseries.
lines their
ass Bank atom undergoes to
levels.
and that to to containing hydrogen
shortest number
jumps wouldwhich Lyman, ground
2023] islevels more once lines. have
X the the The
in

Ans.
Ans. 42.(A)
(B) (A)
(A) (B)
For(ii) energy
lower Lyman
series.
level.Absorption Therefore,Minimum For
hydrogen In
h angular
Therefore, multiple
integral theory,
ofCirculatecircular
Quantisation energy Findorbits?
wavelengths definingState
Broglie An to
being electron n ground
Final
Esabsorption Final Emitted E2 =
the Amax = 2,
Bohr's - - =-13.6 Ej
eV
Planck momentum he level hypothesis
stationaryquantum E4 Es=
maximumquantum =-0.8
=-13.6 E1
E4 eV E4
eV E4= E1
energy E first atom
=1,2,
3,...L=mVr
n = for only torbits of = state,
relation = -energy
E1 emits excited
electrons diagram 0.31eV spectral -E
E, hc 10.2 13.6 will
any
constant. in 1 quantisation 13.6would = 1613.6
condition:
thoseallowed energy required
eV energy
permitted number number 12.75 will be
3 explain
orbits. =-3.4 state
2T nh 2T h
of between wavelength,
-0.5eV be lines
orbits shown and eVbe, 10.212375
an are when for
bu minimum. will of
Of A the How will wil
orbit, electron h3 condition excitation electron
permitted below. be be is
correspond 1213 ¢=
which
2016]
in the all[CBSE
the moves
classical
from stationary does 5. 1
possible energy
IS three in
the to
atne to defor
 Cne We
S74.3Sernes
Å (B)
consider
wavelength The momentum.which momentum,
angular or
JL of
When wavelengthlength momentum,
Thecalled
nermittedalectron Where,
ofa first radius quantmassum
and =pxr above
is electron
H-atom four LONG p=
l mprinciple L
Deuterium,951.4 Bohr's 'r momentum
Linearp= with is respectively,
is then,
condition. orbit m,
of spectral an mV
A,
Confined
equation
EBA = ECB = 2Tur nh associated mass
these ¢. revolves h velocity quantum and
If are quantisationintegral 2l= and
or n
instead A= hc hc
h
calculate
lines. lines xp 2Tr.
to
When n andr v
Exemplar]
[NCERT ANSWER
1218 r= in nh v, is is is are
multiple a with move number. the
in the Bohr' ans
positive speed
of nh
circular the
the A,the electron in radius
Hydrogen, of de-Broglieelectron
A
of a
shift 1028Lyman B angular linefamous integer angular
[4&5marks 2 of of
orbit
in A, is: the the
of of

Ans.
Type Ans.
45. 43.
For H-atom Bohr was If the
Hence, = n=Quantum
number Where,
h= r=
According MassOrbital Radius
momentum earth's
a 25.61 3 of the In
Questions2nx6x10x3x10x1.5x1011 Earth' Planck's 1.5 xaccordance
quantum
10*radius EcB EBA Ecwhere,
B Now,
proton
uniformly
point a theory, of
the x of = = =
when x thespeed revolution
revolution 101 the m/s. 1.5 EnergyEnergyEnergy
nucleus had quanta 103 constant to
isEarth,
6.62x1o-34 orbit
(A) the =2.6 quantized of m (Mass number
x with
mvrg=h distributed, a n= mvr = the [Delhi =3 1 hcgap gap gap ECA EcA =
groundstate Bohr's m of 101 around
in R= radius numberis x = Earth,
= the of =
toms H-0.1A, 2.6 1074 6.62 6.0 Gov.earth mthat the between
hc, hc between
between EcB ho
atom (LA) mvr2 2T nhand Earth
x x v= with the Bohr's +
Exemplar] R 10. that × 1 EBA
[NCERT and givenmodel, 1024
SQPcharacterises
calculate and 10r 3around = level level level
ground 6.0 sun
x Term-2 orbital
(B)
energy the characterizes kg 10 model,
Js as: x in A A B
R= m/s the 10 an and and and
state charge angular
10using
of
2022]
Sun,
speed orbit
C, B, C,
431 kg) the find
¢. a
 = 13.6eV (1 + 22A
(neglecting small term 8) Total energy.
0 = 8+ 2ra SA + ra (8)=e?
8[1 +2ra] = ra2 IEa 2mr²A-(1+2^r,)
-27.2 + 13.6 (1 + 22ra)] eV
8=
= -27.2+ 13.6 + 27.22ra eV
(1+2r,2) Total E =-13.6 + 27.2rA
= NA (1+ 2rA)1
Change in energy = -13.6 + 27.20rA -(-13.6)
S=-ra1- 2ra^] =-rA+ 2rA? = 27.2\r eV

NUMERICAL Type Questions

48. Find out the angular momentum of an 49. Assume that there is no repulsive force
electron in the third orbit of its atom? (2m) between the electrons in an atom but the
Ans, Here, n=3,h = 6.6 x 103 Js force between positive and negative charges
Angular momentum, L nh is given by Coulomb's law as usuaL Under
2Tt
such circumstances, calculate the ground
3×6.6x10-34 x7
L = state energy of a He-atom.
2x22
[NCERT Exemplar](2m)
L =3.15 x 10-34 Js

Atoms 433
 Ans. Ans. 50.
53. 52. 12.551. A
then emitted.
When series series emitted.
Calculate temperature.
2 andthe excite Therefore,
light. =
v first
the in
: For Calculate
When
calculate from isThe Balmer Orbital
period = Velocity
- The hydrogen
13.6
ground
n energy
energy
= an of
2,
short a
energy
the eV. the
corresponding gaseous of excited the
the electron,
If
state wavelength electroneV V= V= atomz
is
iswavelength an hydrogen
of orbital
- Determine
2= 1 1 1 -3.4 1.51 level
electron theshort 127 C state
A energy 1.517 = Distance
Velocity 2heo 2hsn ze?
=
=6.545 1.1x10' x= hydrogen
hydrogen 2x3.14>x5.29x 10x137 =
6545 5x1.1
eV, eV
- Wnere, 1 period
36 1l-10 - wavelength
spectrum x and of
then 1.51 limit series
Å ofmakes of the beam used is 10 hydrogen
2019](2m) n
[CBSE
2017|(2m)
[CBSE 2017|(2m) [CBSE 3x103 c of
10-/
x x10 m [CBSE the hydrogen
n atom =
C 2r
eV spectrum.
36 = forwavelengths
of sec. is 1 the
5 spectral to a
3. isthe
2017|(2m) transition the x velocity electron
m - limit913.4 Å. at 137
3.4 Lyman atom.
atom ines roomn
line eV, for to of

Ans. Ans. Ans. 54,

56. 55.
atom, series. the bombard A angular If eV
Energy =1 momentum n= My is If
that be
What de-Broglie
relation,
2 toFor For Radius Find
in
state Paschen
Energywavelength hydrogen
temperature. the
Energy For Here, momentum
angular is must th e x 1t
12.9 =Ls-L=
=3.18 = 5line conserved, given 3.14 an the
hydrogen 1034 xchange
tO it
(n) Z angular can is electron excited of first
-13.6
13.6 is n in x wavelength
required of eV momentum required first Balmer
the 2.12 n"
to the series atoms =2. to excited
final the hydrogen be emit orbit,
gaseousbeam in So, of a state
atom,atomic Up 5h
angular put xrevolving
electron = suchwhat minimumH
momentum 10-10=
state to and - series
the 2TrnÀ, =
=-13.6 E E would to m²/s kg 2h E1-Es an
atom F= nrn= state
= of of of in
12.9 = excite number Z first electron
state Hy Hy 6.67 Å. 2.12 = = of
= which corresponds
Exemplar](3m) [NCERT would = =
(n). th e electronic momentum=3h photon
photon? line 3.14 2 0.53 2, ron
inthe
1 -13.67? in be in in
n? member =3
= n energy =hydrogen
an the excited? groundin x n x 2017|(2m)
[CBSE electron
conserved,
then be
first energy 13.6 = in 0.53
atom
from
initial of 2014](3m)
[CBSE x 5. of 2.12 orbit, 4
the n 1.06 Balmer Å
-ground the the n'Å
stateanof member of 0.54 to that
atom. of roomat is x according
orbiting
atom,
Calculate level used x
electron transition angular
System state 10-1m
Balmer 10 series. must
13.06 = state
or the to so
n
This energy must be equal to or less than the 57.The energy levels of a hypothetical atom
energy of the incident electron beam.
are shown below. Which of the shown
13.6 transitions will result in the emission of a
13.6 - 12.9 =
n [:n'=1] photon of wavelength 275 nm? Which of
these transitions correspond to emission of
13.60 radiation of.
= 19.43.
0.7 (A) maximum and
ng 4 (B) minimum wavelength?
A B 0 eV
Hence, the hydrogen atom would be excited up
to 4 energy level. D -2 eV

Rydberg's formula for the spectrum of the -4.5 eV

hydrogen atom is given b:
1 1 1 -10 eV
= RI
n n) [CBSE 2011](3m)
Here, 2. is the wavelength. Ans. If aphoton of wavelength à = 275 nm is to be
Rydberg's constant, R= 1.097 x 10 m-1 emitted, then energy of photon is given by
For the first member of the Paschen series hc
E=
nË =3, n, = 4
1
=1.097 x 10 6.63x1034 x3x108 -eV = 4.5 eV
E =
275x10 x1.6x10-19
A= 10752.4 Å
Hence transition B would result in the emission
For the first member of Balmer series,
of a photon of wavelength 275 nm.
nË = 2, ng =3
(A) Transition A corresponds to maximum
1 = 1.097 x 10 wavelength.
(B) Transition D corresponds to minimum
=6563.3 Å. wavelength.

Detailed solutions for D

OSelf-Practice questions
accessible here