ALL INDIA TEST SERIES

OPEN TEST

JEE (Main)-2024
TEST DATE: 14-01-2024

ANSWERS, HINTS & SOLUTIONS

Physics PART – A

SECTION – A

1. C
Sol. Conservation of mechanical enrgy with respect to point P
1 1
(4)(2  1)2  (100)( )2
2 2
where  is maximum elongation in the spring
So,  = 6 cm
(100)(6) 2
So, maximum accelertion =  150 m/s
4

2. C
Sol. The block will start slipping when
8
0.3  20  t  t = 3 sec
4
From impulse momentum theorem
1
(8  6)  8  0.25  20  2
v 2  2.5 m/s
2

3. D
5  3 
Sol. U  (1)  R  T  (1)  R  T  4RT
2  2 
v r /m 2

v r /H 3
 v s/m 6

v s/He 5
v r /He 2 1
 
v r /H 4 2

4. C
Sol. At steady state charges on each surfaces are A B C
2Q(2d) 4Qd
So, VC  VA  
0 A 0 A
+2Q Q
+Q 0
0 2Q

5. B    
Sol. For equilibrium
 
E  Bv
   E
So, E  B  (B  v)  B
  2
 EB  B v 
v

B

6. A
2
 v 
Sol. vimage/lens    v object/lens
u
1 1 1
   v = + 60 cm
v 20 30
 ˆ  2iˆ  14iˆ m/s
v image/lens  (2)2 (4i)

î unit vector is towards right

7. D
Sol. There is no charge in wavelengh of characteristic spectrum due to change in energy of the
incident electrons. K wavelength is large as ampared to K wavelength.

8. B
 2  
Sol. a x , so   rad/s
64 8

A  4 2 (because the particle is having time period of 16 sec)
8
32 2
So, A  m

9. D
10  0.7
Sol. i  7.75 mA
1.2
10. B
Sol. Due to temperature increment all d1, d2 and r increases.
11. C
Sol. W AB = W CD = 0
WBC  nR(500  350)  150nR
WDA  nR(300  400)  100nR
3
Q AB  n R(350  300)  75nR
2
5
QBC  n R(150)  375nR
2
3
QCD  n R( 100)  150nR
2
5
QDA  n R(100)  250nR
2
Wnet 50nR 1
So,     
Qinput 450nR 9

12. D
 V ˆ V ˆ V ˆ
Sol. E i j k
x y z
 2k(xiˆ  yjˆ  zk)
ˆ

 qE
a
m
2k 3q
So, a 
m

13. B
(6.7)(4)
Sol. Q  6.7   6.825MeV
214

14. C
Sol. It activates due to electron hole pair formation after radiation is incident on depletion region.

15. B
1  2
Sol. I  I0 cos2 t
2
2(n1  n2 )t 1 I
 I0 cos2  I0 cos2 (4)  0
2 16 2

16. D
GMm  R2  1 2
Sol.   3    mv e  0
2R  4R2  2
GM  11  1 2
  ve  0
2R  4  2
11GM
ve 
4R
17. B
Sol. The circuit is in resonance
So rms potential difference across resistance is 220 V
220
So, I   2.2 A
100

18. C
Sol. Yellow  4
Violet  7
Brown  multiple 10
Gold  Tolerance 5%

19. D
R2 d
Sol. mgR  R (B0 t 2 ) at t = 2 sec
2R dt
2B0RQ
So,  
mg

20. C
Sol. FP  6r(3v 0  v0 ) towards the downward direction
So, P  (12rv 0 )(v 0 )  12rv 02

SECTION – B

21. 45
 1 2
Sol. I  (80)   (cos 30)2 (cos 30)2  22.50 W/m
2

22. 25
Sol. from work energy theorem
W E = K f  Ki
1 25m
qEa = m  42  32  
2   2
25m 25
a 
2qE 2  2  102  100
a = 6.25

23. 15
gx 2
Sol. y  x tan  
2u cos 2 
2

(10)x2
y  x tan30 
3
(2)(10)2
4
x 2 2
y  x
3 30
A 15
So,  5 3
B 3
24. 3113
Sol. Total surface area = 6(7.203)2  311.299  311.3 m2

25. 1
Sol. For anguarl impulse theorem
t  I  0
(2)(60)(2) 
  N-m
(40)  (60) 10
2
  = =1
10
26. 30
Sol. (1)(6) = (4 + 1 + 1)v, at the maximum height
So, v = 1 m/s
Where v is velcoity of the system along the horizotnal
For conservation of mechanical energy
1 1
(2)(3)2  (6)(1)2  (2)(g)(h)
2 2
93
h  0.3m = 30 cm
2g

27. 500
2
4R2S TS4  Rs 
Sol. S  TS4  
4d2  d 
2
8
 7  108 
2600  5.67  10 TS4  
11 
 1.1 10 
2600  1022  1.21
TS4  16 8
 0.113  1016
49  10  5.67  10
TS  5800 K
2.9  10 3
So, mp   500 nm
5800
28. 1125
Sol. In steady state 3 = 3V
So, P.D. across the capacitor = 15V
1
So, U0  (5)(15)2 J  562.50 J 3
2 3 5
2

1A 3A 2 = 24V

C = 5F

29. 1480
4

i 8e 4
Sol. Displaced current =   1.48 A = 1480 mA
2 2
30. 502
 1500  7.5  1500  5 
Sol.     500  501.67 Hz
 1500  5  1500  7.5 
Chemistry PART – B

SECTION – A

31. B
Sol. Cl  strong (– I), SO3  weak (– I)
+I : O   COO  CH3

32. A
Sol. No chiral centre is present. POS is absent and so the molecule is chiral.

33. D
Sol. NH3 is more basic than H2O. NH3 ionises as NH4 and NH2 .

34. C
Sol. CH2
NaNH2

Path 1


O
O O

Path  2 NaNH2 Br
Br

Br

O O

NaNH2

O
O
Br
II 
Br

Br
O

NaNH2

O
 I
35. D
Sol.

H3C N C S Bent

H3Si N C S Linear
36. B
Sol.

CH3 H

POS exist

H CH3

37. C
Sol. C – H bond is directly involved in dissociation to form enol for additon of Br 

38. A
Sol. Factual

39. D
Sol. H3C
C O I2
H3C  Vacant 
 
 filled e    orbital 

Charge transfer
I2 on dissociation converts to I

and then the colour starts fading out.

40. C
r r
 
na0 3a0
Sol. e e  n  3

r  r   2 2

 3d orbital.

41. C
Sol.

N N Sb
F F H H Cl Cl
F H Cl
102.3o 107o Close to 90o

42. B
Sol. Bond strength of D2 > H2.
43. B
Sol. Cl Cl
O O O O
KNH2

 NH3

NH NH
K

O
O KNH2
NH3
KCl
O
N O
H NH
O

NH3

Tautomerises
 OH
N
H

44. B
Sol. Compound 1 : concentration = C1; number of phosphate = C
Compound 2 : concentration = C2; number of phosphate = 2C.
Total phosphate = 36 m moles in 1 L
4C1  C2  36 m moles or 4C  2C  36 m moles
C = 6 m moles
 C1   compound 1  24 mM
C2   compound 2  6 mM

45. D
Sol. Bouveault-Blanc reduction is used to reduce esters to alcohols.

46. B
Sol. The technique is used to separate liquids that are miscible and differ slightly in boiling point.

47. C
Sol. CHO COOH

HO H HO H CHO

HO H HO H HO H
Br2 /H2 O 3
  Fe ,H2 O2

H OH H OH H OH

H OH H OH H OH

CH2OH CH2OH CH2OH

 CHO COOH

H OH H OH CHO

HO H HO H HO H
Br2 /H2 O 3
  Fe ,H2 O2

H OH H OH H OH

H OH H OH H OH

CH2OH CH2OH CH2OH

D-glucose

48. C
Sol. O O
O
OEt
H Br
NaOEt EtO

NaBr  

O
EtOH EtOH
C OEt O

C OEt

49. A
Sol. Salt bridge allows flow of ions.

50. B
Sol. Solid HF has zig-zag chains of HF molecules.
Intermolecular distance = 155 pm.

SECTION – B

51. 4
Sol.
PMe3 PMe3
H PMe3 Me3P H
Rh Rh
PMe3 Me3P C CR
RC C
C CR C CR

All cis
(1) (2)
 C CR H
Me3P H Me3P PMe3
Rh Rh
PMe3 Me3P C CR
Me3P
C CR C CR

(Inactive) (Inactive)
(3) (4)

52. 8
Sol. N C C N N C S S C N
x=2 y=6

53. 168
  dEo  
Sol. Ho  nF E o  T  
  dT  
 2  96500 0.675  300   6.5  10 4  
 167.910 k J
54. 7
Sol. nCO2  6 nH2 O  4 nN2  1
Formula  C6H8N2
55. 6
Sol. pK a1  2.40 pK a2  9.60
1
pH 
2
pK a1  pK a2 
56. 28
Sol. UABC  UAB  UBC   UAC 
UAC  UAB  UBC
Now; UAB  qAB  w AB  600 J  O
UBC  qBC  w BC  200   PV 
 N 
 200   8  104 2 3  103 m3 
 m 
 
 200   240 J
 40 J
 UAC  600  40  560 J  x
x
  28
20
57. 50
Sol. O O O
 1. NaOEt
 
Ph H Ph CH3 2.  Ph Ph
MW  120 MW  208
MW  106
 10.6
nPhCHO   0.1
106
1 mole of PhCHO 1 mole product
Wexp ected
nProduct produced  0.1 
208
Wexp ected  20.8 g
 10.4 
%yield     100  50%
 20.8 

58. 25
Sol. CH3
H2 O
2CH3MgBr  H3C C OC2H5   H3C C CH3

O OH
10 mL  0.025  0.25 mmole  nCH3 COC2H5
nMeMgBr  0.5 mmole  M  V
0.5 mmole
V  2.5 mL
0.2 M
x  2.5mL
10x = 25

59. 4
dP k1k 2 Eo  S 
Sol.   k 2 Eo   0.02
dt k1  S 
k 2  Eo  k1k 2 Eo S 
 
2 k  1  k1  S 
 k 1  k1 S   2k1 S 
 k 1  k1  S
k1 1 1
   4000
k 1 S  
250  10 kg / dm3
6

60. 5
Sol. Let the concentration of FeSO4 and K2S be xM and the volume is V L
FeSO 4  K 2 S  FeS  K 2 SO 4
xV xV  
  xV xV
K sp  Fe 2  S 2 
2
xV 
6.3  10 18   
 2V 
x  5.02  109
 C  5.02
Mathematics PART – C

SECTION – A

61. B
2x 2  kx  5
Sol. lim 2
x  x 2  3x  4

so, there must be some k s.t.

2x 2  kx  5
 2  k  6
x 2  3x  4

62. A
Sol. Let  < , f(x) = cot1x
cot 1   cot 1  1  
Using L.M.V.T   = (c2 + 1)
  1 c2 cot 1   cot 1 
2
2 c 3 2<c <3
 3 < c2 + 1 < 4
4 <  (c2 + 1) < 3

63. C
Sol. As {a}   1
a
1
 1  {a3 }   3   1
a 
1
x
So,  1 x 1  x2 dx
0
Let x = sin, dx = cos.d
sin  1  sin2  
 /2  /2
sin   cos2  d
 1  sin    1 sin  d
0 0
 /2

 sin  1  sin   d  1  4
0

64. B
Sol. a(sinx + 2sinx.cosx) = 3sinx  4sin3x
2
= sinx(3  4sin x)
= sinx(3  4(1  cos2x))
a(sinx + 2sinx.cosx) = sinx(4cos2x  1)
As sinx  0, in (0, )
 a(1 + 2cosx) = 4cos2x  1
 4cos2x  2acosx  (1 + a) = 0
a  (a  2) 1 a 1
 cosx =  cos x   and
4 2 2
1
Since cosx = 
2
2
x=
3
a1 a 1
for cosx =  1  1 a  (3, 1)
2 2
 a1 1
if   a = 2
2 2
this will repeat one solution so a  (3, 1) {2}
65. B
Sol. z2  cz + 10 = 0
and z1, z2 are roots and c is real so z2 = z1
2
We have z1z2 = 10,  z1z1  10  z1  10
So, z1  10
and z1 + z2 = c
z1  z1  c
c c2 z1
2Re(z1) = c  Re(z1) =, Im  z1   10  1
2 4 z2
1 1 10 z
1 1 2 z z z
Now      2  1
z1 10 z1 10 z1 10 10
1 z
 1
z 2 10 1
1  1  z1
Now area of quadrational = Re  z1  2 Im z1 1 2  z 2  z1
2  10 
1 c2  1 
= c 10  1  
2 4  102 
1
1 2  2 
10  c 40  c   is maximum
2

2  4 
if c2 = 40  c2
c2 = 20  c = 2 5
66. C
2  sin2 x   2  2 1  tan2 x 
Sol. 
1  tan2 x 1  tan2 x
  cos x = sin x + 2  2
2 2 2

2 2
 sin2x = 2
 0  1  2  1
1  1  2
67. A
Sol. Let polynomial is P(x) and two integer roots are , 
 P(x) = (x  ) (x  ) (x2 + ax + b) for some integer a, b if p + iq is a root of P(x), then p  iq is
also a root (with q  0).
 x2 + ax + b = (x  (p + iq)) (x  (p  iq)) = x2  2px + p2 + q2
Product of the roots is p2 + q2 sum 2p
a = 2p, b = p2 + q2
1  i 11 1  i 11
from option , is only roots.
2 2
68. C
2 2
Sol. Given circle x + y  6x  4y + 11 = 0 (centre (3, 2) r = 2 tangent at (2, 3) will
2x + 3y  3(x + 2)  2(y + 3) + 11 = 0
x + y  1 = 0  x  y + 1 = 0
  1 1 
Coordinate of A  3  4 ,2  4    3  2 2, 2  2 2 
 2 2
Reflection of A with respect to line is C1
x  3  2 2  y   2  2 2  2 A
  2    2
1 1 2
x  2  3  2 2  1  2 2
(3, 2)
y  42 2 B
B 1  2 2,4  2 2  (2, 3)
Area of ABCD
1
= 2  2 2  4  2 2 2 = 6  4 2 
2 C D
3  2 2,0 
1  2 2,0 

69. D
Sol. The angle APB is obtuse if and only P lines
inside the circle with diameter AB (0, 4) E D (2 + 1, 4)
1
The area of AFB is =  2  4  4
2
Area of ABCDE = 4(2 + 1) 4 = 8
(0, 2) A
AB = 2 5 P
Radius of circle = 5
5
Area of circle inside ABCDE is
2 F B (4, 0) C (2 + 1, 0)
Probability is that APB is obtuse
5 5
= 
2  8 16

70. A
Sol.
B's . C's A's . C's A's . B's
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
k B's (5  k) C's (5  k) A's k C's k' A's (5  k) B's
If there are K B's in the 1st five letters, then there must be (5  k) is in the first five letter so there
must be K' C's and (5  K) A's in the next five letters and K A's and (5  K) B's in the last five
letter.
So the arrangement is
5
 5!  5! 5!
  k!(5  k)!   k!(5  k)!  k!(5  k)!
k 0  

71. C
n n
Sol.  n C j  jCi
i  0 j 1
n 1 1 n 2 2 2 n 3 3 3 3 n n n n
= C1( C0 + C1) + C2( C0 + C1 + C2) + C3( C0 + C1 + C2 + C3) …..+ Cn( C0 + C1 + …..+ Cn)
= 2nC1 + 22.nC2 + 23.nC3 + ….. + 2n.nCn
= (1 + 2)n  1 = 3n  1
72. C
Sol. Let P(x) = ax2 + bx + c reflect it over the x-axis we have ax2  bx  c
2 2
so f(x) = a(x + 5)  b(x  5)  c = ax + 10ax  bx  25a + 5b  c
f(x) + g(x) = 20ax + 10b since a  0

73. B
Sol. So locus of P is a circle with diameter AB = 2 P
1
Radius = 90°
2

A z1 B z2

74. B
9/10
 3 2 3
Sol. I=   2x  3x  x   dx
1/10
 2
9/10
  3 2 3
I=   2 1  x   3 1  x   1  x    dx
1/10
 2
9/10
4 2
 2I =  1dx  I=
1/10
5 5

75. A
Sol. Let 1  x3 = t
1 3 1 3 1
 1  t   1  t 
2 2
 3I1 = dt and 3I2 = dt
0 0
Applying integration by parts on 3I2
1 1
3 1 3
3I2 = 1  t 2   t 0   3  1  1  t 2    2t 2 1
 tdt
0
1 3
 3I2 =   3  1 2  1  t 2  1  t 2
 1 dt
0

 3I2 =   3  1 2  3I2   3  1 2  3I1

 I2 = 1   3  1 2   3  1 2 I1
I1 1   3  1 2 1
   1
I2  3  1 2  3  1 2
76. B
x
t10  1
Sol. Let f(x) =  t10  t 4  1 dt  6x  5
0
f(0) = 5 and f(1) is negative
x10  1 x4
f'(x) = 10  6   5 
x  x4  1 x10  x 4  1
 f'(x) is always negative  only 1 solution.
77. A
f x f y
Sol. f(x + y) =
f x   f y
1
 f(x + y) =
1 1


f x  f  y
1 1 1
  
f x  y f x  f y 
1
Let  g x 
f x

 g(x + y) = g(x) + g(y)  x, y  R
 g(x) = kx, where k is constant
1
  kx
f x

1
 f(x) = but f(1) = 32  k =
kx
32
 f(x) =
x
32
f(4) = 8
4

78. D
 5 
 sin x 
1  a4
Sol. This can be written as lim  5
x   5 
 4
x 
 1 a 
since a2 > 2
a4 > 4
a4 < 4
1  a4 < 3
|1  a4| > 3

79. D
x
Sol. g  x   2f    f  2  x 
2
x1
 g  x   2f     f   2  x   1
22
x
 g  x   f     f   2  x 
2
Given f"(x) < 0  x (0, 2)  f'(x) is decreasing in (0, 2)
x
Case I : If > 2  x and f'(x) is decreasing
2
x 4
f     f  2  x   x >
 2 3
4 
 g'(x) is decreasing in  ,2 
3 
 x
Case II : If < 2  x and f'(x) is decreasing
2
x  4
 f     f   2  x   x   0, 
2  3
 4
g(x) increases in  0,  .
 3

80. B
 /4 5 / 4 2
Sol. Area bounded =  1  cos x  dx   1  sin x  dx   1  cos x  dx = 2  2 2
0 / 4 5  /4

SECTION – B

81. 2
Sol. f(x) = x  ax  b  co-domain is [0, )
Domain also x  0
b
f(x) = 0, x = 0, 
a
 b b2 
  , 
 2a 4a 

O b/a O b/a
b
so  >0a<0
a
b b2 b b
    
a 4a a 4a
a  4a  a2 = 4a
a2 + 4a = 0
a = 0, 4

82. 2
2 2 3
Sol. So radical axis will be concurrent 1 1 4  0
2 k 2
k=2

83. 5
Sol. Possible values are {2, 1, 0, 1, 2}

84. 2
45
Sol. Since, sum of all numbers is 1 + 2 + 3 + …… + 9 = 45, each groups sum will be = = 15
3
groups are (9, 1, 5) (8, 3, 4) (7, 2, 6) and (9, 2, 4) (8, 1, 6) (7, 3, 5).
85. 8
Sol. Let the common diff. between consecutive ai be 'd'
then a15 = a1 + 14d
a15  a1 = 14d
Since 1  a1  10, 241  a15  250
231  a15  a1  249  231  14d  249
and d must be an integer  d = 17
Now, 1  a1  10, 13  a2  20, 241  a1 + 238  250
1  a1  10, 13  a1 + 17  20,  4  a1  3, 3  a1  12
 a1 = 3
So, a14 = 3 + 13  17 = 224.

86. 5
2 2 3 3 5
Sol. Let the first 2 term is x and y, then the terms would be x, y, xy, xy , x y and x y
3 5 3 5
 x y = 4000 = 5 .2
 x = 5, y = 2.

87. 36
Sol. 1 + 7 + 5 + 2 + 5 = 20
So, there are 3 possible cases :
(1) if mean is 5  x = 5  6  20 = 10
(2) if mean is 7  x = 7  6  20 = 22
20  x
(3) if mean is x  x = x=4
6
So, answer = 10 + 22 + 4 = 36

88. 800
Sol. y2 + 2xy + x2 = 400  40|x| + x2
(x + y)2 = (20  |x|)2 (20, 20)
(0, 20)
x + y = |x|  20
or x + y = 20  |x|

(0, 20) (20, 20)

89. 841
Sol. All possible location of P are integral points such that |x| + |y|  20
i.e. 1 + 3 + 5 + 7 + …… + 41 + 39 + 37 + …….. + 1
= 202 + 212 = 292 = 841

90. 61
Sol. The current range = 28  3 = 25
To double the range that is = 50
Since we do not want to change the median, we need to get a value less than or equal to 8 for
the smaller, making 53 fixed for the larger, since anything less than 3 is not beneficial to the
optimization. So taking our optimal values of 8 and 53, we have an answer 8 + 53 = 61.