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Atomic Structure Notes

Atomic structure consists of atoms, which are the smallest units that make up matter and can exist independently. Atoms are made up of even smaller particles like electrons, protons, and neutrons. An atom's identity is defined by its atomic number, which is the number of protons in its nucleus. Atoms of the same element have the same atomic number but can differ in mass number due to different numbers of neutrons. The photoelectric effect occurs when light of a sufficiently high frequency shines on a metal surface, causing electrons to be emitted. This phenomenon demonstrated that light behaves as particles called photons, with energy determined by its frequency.
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© © All Rights Reserved
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0% found this document useful (0 votes)
39 views

Atomic Structure Notes

Atomic structure consists of atoms, which are the smallest units that make up matter and can exist independently. Atoms are made up of even smaller particles like electrons, protons, and neutrons. An atom's identity is defined by its atomic number, which is the number of protons in its nucleus. Atoms of the same element have the same atomic number but can differ in mass number due to different numbers of neutrons. The photoelectric effect occurs when light of a sufficiently high frequency shines on a metal surface, causing electrons to be emitted. This phenomenon demonstrated that light behaves as particles called photons, with energy determined by its frequency.
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Atomic Sthructuu

Atom An atsm is th& mallt cemend that


ut o an
my ay maynat taue independent existence Jous takesa
pagt in a
chemal Eacton
Thu a mad mas
upo ill smallu panicles
Amauut chaTgl
Electsan 9 1o = xt6-%
Nataan (2 T Thomaen) e}
Preton (P) :6925x1o2kal.s x loisC_/y-0 x l6eu
eletostatic
NotatiarCH") by (Gnsldstein)
Neutren ( n ) 1 6 4 5 xl6 24 Neutral

Netatar -( ) b y - Chadwick )

E Repzesentatfion oan Atum Atomie No.)


A
CX Smbal atsm ) (Z:
X CA mas number Cntp)

Tsoto pe Atom nauing ama atamic o. but d enent


moLsno.
Prrat um CP 1 n=o,e =i)
H Deutium CP=, n= e-iD
Exampe
nitium Cp =i,n:2c=1)
Radfo cehe
6 3S
CC Cc N N

Sebau: AHoms couingame ma no.but diyenent


gtomicnu mbel
40 14
(97 C N
Ruthan Td ode
dinand heay
He-peuedht_afam
mb ouy
NLeus_at (enoe o aroM-
heu_delledn
-panticlea_ pa
Dast odha
3 ume iw delectr y keu angle
n 200o9 Ae dejlected almatt
enye
ac aron8 enp
He concluded mest a dhA
TNO tictes deptecteet cxSinT
2
Angle delectton

No-opasticlks olekeeteo 2 tan fsen

He3ad that e 1eirsiue 1urd dha nucleus


inacuein pih Mox uall ad hat
acclesat chasge patticle when Jetde hen 1t
Noy
enéngubyemithng adoJün ) and usill
ultimatel alintsnuleu, dnd atam w?l
relap.
IDidn pein n-Pechum H-atam.
oapettiS Crae
Chtgg guandiza J = ne

= 6 Xlo
Chage Ja a cala 9un ft.

9-xl0 v m

- Yeten tiak Eneng


Date 16/ o? 22 Page No 3

Electvomagnatic auo
Thay Jequine no medum Jo Pro pogate
Th
Electric Feld
Electi Naue
Magne tie Fetld

LhaliMIh.
PRag nathc Naue

0Dinectien o sacilatian oelectric and maqnetic


ed 1 to each
ethorand alss Lo dfectian
epiepogatfon g waue
is EMwave dent Jequire any medium gen
pTSpogatcn . n vacc um , E M Waue
raue usith
&peed o fghd C 3X 16msecl.
i hen Em waue enten om9ne mecfum de
anothen then its uelscfty Chang e but
Jemajn ame .
TequencY
A= m
Cest hm lo m
YWauelength ( -12

Phnplityde
pm o
nplKole
Fssugh

Waw ength C): Dis tance betucen tuo ccaSe Cutie


Crest traugh.
9+ s meapuud m, cm,fcte,
Date 1ot 22 Page No.: O4

Amplitude Cad Height a cTest an depth


augh.
ntensity ca
Big htnes

Fsequoncy (v) No. wgue paabng thsugh a


paint Jnane econd. ( = me )
V= CsPeec al light?
Neu Cuength o Waue leng th)
Unit= HestCHz)a Sec

# Velocity Distance auelled by ue in isec

Unft Cm Sec m Isec


Waue Number ( ) Numbe s Waues_preut I
Gn unt o dength
tnt M m

Onden o Waue length o tM waues 4oe rcm Sen m


Radio
Radis WdU muco waue IntxLNed >
visîble>v
X- rays > Grama
iaya CosmicG Ray8

nds ieguncy Enengg


Goma Rau
X-aus> U Visible>
Snraned> Mso WeIN> Radie wae

Shoet-T-ick t Classicggadi X V un my Ran


Wat /8ec.

Electron valt (ev); UnSt oenengu


(iev=6 xlo J)
Tatal Enengy gain by electron hun_
to a_pgtental_dieience
acelenated sam aat
o volt Rndutn as LeV. jvet durbitsteation
stode
E+PrE Ck-Ep+PE

+
chengy 3un
objepdue to t
e
motio

-LE)galn-

Panticle Nadtune Em Waue


Enpeniment uwhfch weu eaplaineol enly ypaUntic le
nafune_au-

Black Bacly Racdiatian


Phstoeletic eject
Lihe-pectvum o -atam

Bhck Bady fadiatan (BBR)


all
Back Bedy Redy uhid amits and absambs
neuencyis called black body.
Radktn emitel b black bady called BRR.

2
eT
9ntet
BBR

X
Waue length (2)
Tempenatune
Date Page No

Aa uaue Jength decveasedndensfty ntseasey and


becema mximum a paticuday wauolength ad he
+hen
stants dessasig-
shen empertww ncsicases, ntety al nee
But maximum ntenalty n d
but c kusun uauelerqth

#
hun 9san Jec heated Jt_ tusns Jed and hen n

unthu heating beames blus wquelength


olecs eaes
Areanding do Ray efgh Jeu
CHe tosk Waue natuse o MW)

# These o r , BBR s not enpaned


8 Waue natuu Emw, lateian_
9nters Plan k quartum hecay erplair
BBR y_pontfcle natune
Waueleng th

PanR' qantum dheeny


ftams mskecules emits al abaamba enengy in
d'scete guantities called gquantun T photon
Eneng a phatons art dentfcal
Tata Enegg Js indegsad rau tiple og enengy a
_pNoiun._
T E nx to n No hotans
Taule E E hv =hC 6 6 xlo Js
LPlan a cana tant
ta= /240 EV Celectron valt)
Cn m x (o
Date Page No

Pheto eletruc Eeet

Phato aertrfc eleetrs


Photo electC

whan ht s tauble euencyjalls a n metul ounace


hen e an emiteet whih au called photo electons
Cund cuJnert_ ushsch klaus is Rhousr a phatpcunet
and oll_pheomenan is called phatpelectic ehfect
e
cUe giectel jntently thww s no lag
sbetuonstvieng a ght eam and jection electop

Wank Functian (O. a nWo) Minimum enungu


Siegusud, by e to escape sanm meta sudace
depends enly an atuu o mdal.

Wo hva

hovheld athoexhold wauelength


iequency,2
Fon Ptrodo elect sfc ekect o
Fan

9ntersityBofahtneas
sregvenc Calau
9tenaty h no phatens shiRing sh
metal plate pA7 untE ana pe Secand.
Date Page No.
7
#Mane intenalty , maru phatan

fheb ing mane hats electtr


(uunt 4 eneated and man
phato cwuert
Snteraf tu

2.
t I aequny hreae thon thon
Phap KE a e incseabes but no.c
Cwnert
e 1emajna (ssfat nd hence
phato cuULIent_S1emajns (cntant

Eieguen

S ndpendent ol fndensity

Stensty
# hstein phete electTo equatan
E

KE EhVhv
mx +C

-ho
- Practic
ally K.t Cat
renuen ey ntensity-? be negatfe So, 1h
p tfen cbsn ann n
eTelctfcal
Patential
#Stoppihg etenial (u a
upplynegatiuepotental
o n colecfon phie
u a electvans a e Jepe lled-
dhen plha.to cuuient decreace 2eno whe
and d oni stage, culerd becomA
VA Auicfentdo epeL dtho electvons tasng
axinun RE.
Ns
RE)na
Put r Einstein equ atian
eVs
Vs hV-hs h
e

Atamic Madal
Bshr syatemike
Applicable nly singe CTS,

H, HeT, * , 8e1,B

Pauhulates i
anCund nucleus Jn ciruwan palh
ilectrens mass
cled onita s

auing Jadiiy and enengy

tationamy state.
in anbit dau nat change usTHAU
nangy
tim ut ushen unps am kUn to higken
e

ad
enmgsb s6it Jt abzanbs enngy emts
Jsuwn ft
sh jumps ram g h n to
enag b clik. inA
Eneagy abanmba s emited ja oqua!
enengg 6 o tuo Gibks.

A6 EE- Erelksud
Ekectro mau enl n haae nbi ë a n ushfoh
angula mamentum as eleetadn Sneqn tpl« ek_
x e d oits a alauRd
heene only
no
h (n= nawnai
C l ,- -
Hngusen

hplaun Rs canstan

mun n

Ve oct a e n nb ne

2 8 A1o x2m/sec
2 18 lo
V=Vo

Date

Sn SL3X A
A1-m

H-atsm

Sxlo n

TaT
2 A Jlon
VO 1XK 2

Dale -

## a u e n -
4 acdatian a Enengy e
T61 Takal énengy_ KE Kme tic ahena
fatenda nang

Re k (e) (ze)- FZe -

2e

2
Centoipttaacer

Z e 2 Fo7ce

KE

Date-- PMg o.

T.E

T.E KE

Lat T.E iepn e>ented bu

KZe

F2em

MTR
13-62 eVJatam
E= =2.18 102
x
atam-
n

1312 /rh-

#E_-13.6 x 2 EVatam-
n
yn E
2 21T E1
Date/_I Page No.

and n2 al onbta
n

136*2 E 13-6 x
Eh

AE En En
AE -13.6 x 2 13 6 x 22

AE 13 62

DE 13 6 2
n
h E 13-6 h
/13./3.6

Red bwE Contant

RH2n Rydbng-fanmula
dbng
n
RH - m
Cm
to36tcm
Page No.

Oale-=
dagram 51NQran
Jesel

S -2C4E-s
,Jey

quaund su (n=l
ncited Stade CE-S9: GthuLthan

nn CLE nmun enET9y eqwTed


onoton
9raund Aate (ns to n
t0emOuR

T E= 136 2 V
-ushan ho LEs in Jaule
ganfzatfan Patenhia

hengy 1,uded 0 emouu e


Ë|Excitotfon Igy

-62 AA-
n

Dato--- Page No.

Birlng Eneny on Sepenatån Enanay 9


eued to e mOU Kom an sfate D-
Jnnite (),_SE
Page a

Spectrum Cattenn g radatians )

Ba sed an @ni
Baxed, an utuue
Emiasian p e c h r u m R b s a n p r
|ntinuous D s c e t e
Peettm SpEctt ghe DT fe lou
highM

ne speciUm Band

E9obtaln -nsm
maecS

etomb

(Gntinudu èpectnum

LPhatogaphe
Pidte

Date - Page No

FNo s Spectrek n e

No Max en diedt graund leuet.


ines 2 n (nD

No .oma xiros= 4nCAnt

An Di- n
Page No

Date__ H-atam
#Spetrel LPnes og

HumPhUN
See S
P-fund
BaeRett
Sli n 3
Paschen = 2
Senie
Ba lme
Sale
Cvisfble t9naTed Rary
yman Tegen
Seie

CUv-Rays
2,3,4
Lyman Series 2 ,t
BalmerSenies n t,S, ---

3
aschen Sesues
4 n2S,6,
BTacRett Senies
6,+
P- fud enies ns 5 n t , 8 ---

Humphe Seues
RN n n
Lyman eries 2
2
f i t ne (aint 2
CP-Line
Secsnd fne
est
Last in alba called deue mit an manginalL
JnaJast ln ha m aximuun 'enungy
and
minimuno. auelengthi.
3t s the Ahantat Lhe
fet inn hao the maxîmun uwaue (ength ard
munimum eneg
Dale--
# d e 5 g l i e Hype ahesisr CDucu, nattu. o elecTsen
E E mc

m Repleice CbY V

P enu

Nalid. al eC ept phSMn.

a cange piantfel a o g cha19 da

- am
#fo7 iesron
A

age

#|Heisenb en_'s Uncestaintrindiple


Ëxact_pasitfon and nomentom_ogst iDg
panticle (an'tbe detesmioc. Occua te ly ato paqticoh
fïne Slqnilicant only_han_microscopl< object)
4 AA An Ap =_ 4*

4
lan dfsplace met
a n g u l momnertuno

X d|

AP

AE-t
ecentung 1picethaCOnCt Lntte
itb rct Pbab iNty

Page No

Dalo
*Lituona cBehys Macdel
Paplaun Jhe_specIo e_ctsms rea Fin
i
(euldn"t
He
man Than h{
oueln 't aplan jho splitt og salno u
He Ceoagnrkficld_Lzeemn elkcct2 arel

elecdsice ld fande-bzcqlie
)couldy't_explah
efe typaha73 cnd
Hesenbng 2reneuntypLnCupie -
Page No

Date

Atsmic bital tals2


Atsm shell>subshell

Cn S,P,d,b CPPP)
3Efono Apae nsncd
Cnki tal I t s thu Lincing
Ducles ehwu pratotilfty
Mgxfroun. (5%)
is 2
sata
Maximam no o e in sne
#Lyees e «nkftas
1 S- s t f t a l . -

Spheuiajnshape
land
V-Nodal P u n a n z No dal f
2. P-7tal
Node Noda PTaNe

-> Node
P
Node
mding isO.
Nsd fan at shfch_prebasirty 7 9 , NZ Nelkfane

3. d - n t ° t a s -

Natt

Nodedy2 dnz
Y2, YX Nod
edal flane Plane
Page

wO hade (rU

Nedal Phng Ran ad which._pnobabili*


Sineng e _ s zeno
Nsdalpkin

Cne-
Suatum Nunbend:
Set sk 4 nunberzs hieh ssmplefely dene
n an atam
ainipal uantun numben (nD
t Rents shekln9
Pmksible valuo to ,(ng N).
NNo
o shull
e subsne inqiuGn he
can accemcidaje ms than 32c

hgulan memendum d she

She I Sukahe Gnbita

S
2.. L S,P
S,id 4 3 S -9

SPd,f 3 S 9=
16 | 37
Ahell =
n_
No smb tals n gfuen

Eqt:
den enuy2ti-L tzt
l
-L
Ea=E2La

bu gdp a e c o s d

hngulan manentun
nhal Ciandum N o ( : = 7 Gasital
HLtum aurnbe/ Saban
epieber auphal numa.

idiuo J 0 Jo Cn-1)
ble Name
Sph&7icaa
Sho
ninopa Dunble
Tundomehtau

MbAhe

2S
3S,SP1
23

vLCtL)
b/tal Hgufan f60 ehfum

Ehgnedi &uan twm Nurnbs 2la


t describes iendeen eg_a2g tals-
M
P,P
2 2,-2,0,1, _dng dg 2 , da *
Each Value decnibe SN SH fal_

a and dn can nten char

intonchange da 3 d2 can intenc hange

e n uantum Numben CS sn Ms)


ushethen cock.wss an a
Denibe &pih e
ceckuse

Elodeuls LAat-clocR-ise
Ldosn sptn
atfcockwae
Any alu cannepnesent clsc Ruwse

Tatalspîn (s) E2Na-unainad eetran


2

%*
No. unpaed e
S
pin Angulon 'omentuun s&t)
Date
21s1 41
Peimun Spih pleity
(M.M)
CL) mpatkart
Spin Magnuic mament B M
Bahn ugnitan
no. unpairud e

2 6 2-02
ts 3-8-

= J3s- 5,32-

Uto CLnpained e P na n
SPed CCalouned)
eak afsnacd turnoo mgra ie d :
u - o C No un palned e ) Dia monaePe e l u n iea>)

Da aeepea a tourandA magratie


eld.
Peaeniaeand nan degenenate n t a l s i
S a m e eneHE_
orbtala Jaelanging o m Mubotellar
d nate.
C3 ald dege nenaey
(Sold degane a -

hekr
paanee aeedni and maqnaBic }reld
degenu1 getA dearaye

_
4 Eleefronic ooiqungfor
ling e n ah atom.
-No
KeAesentatian_
k e
shulf- Substul-

Dald

faulTs. ncuson incple


No duo _e h an-
atem can haue all am uartu 4
Only 2 e can beaccanedotedin

tunds Rle e Diaxmum luhprety


) = 1 s l + 1 .

kapce n ha gnta na 4
Paining
AubehalL mHil each enbttal Ja eccupd
-
e n_panalle spin
Dut

amba0 Table
TEENCYE_erg
n

A1 e 1aTad encha.ngeJo

Rug kLL ndple

iSngle
3p 3d< Us-p =4d -
nden aS 25-
Enngy

D3Nn0EL22

3d Up2 phun ' Kidn ury 4


s
2

25 <2 3p2ts43dH eSs<deS

e7g Tht onbitals ia th ma bshell


decyoca e aith h c v c a n fha arMÍL nOO

Umany .

S.
J-P2

hzodngen blaue mecanice hodel


n dhfa mdel dual natuag ne nd T
hia msde canaidenasaSncng

ncuanimpltve awe

Speiatarr nc *n

tapdCran aPe

SX*m

Hamitshian
= H.
Dale
ntegTal en o ctod Tn4
aanhun 0. au

Dphinira jdilatcs= ,e,9

(Radfuy) q5ADeio Due

USin 8SPn Ccia atitude - ans C2enth ang.

ta a g a m a angle2
Sin Sth

/n
m
Soding en eq gr S quantum nd. (n,,
#SoluHGn a V f(9,9, 0)
Sph guanhum . nct guan NS
frretdntra h

( n -1)
Rad'al Node /Sphunleol Mode
C3
3 CS4-D
-
Nooa a l elanc Pe)
ngula
lota de ENt AV_(n -
Da --'=

derni catiao obau_faniin


Thdm Tsent a ier

-2 **-

ssme pakpnsn i a n r s
Sshn r a d t u s
ds prEm Tmucte
FmTuctews
aa ta e
n PNndpat uardu- be

and )
F(O,O * ( Seme tenms in
Wan Rnq. toal
h t o ge *h
u foget Seca (Encept pelsnemiL)

CUtoqet 'h ean nela+ien btur Cantesian a


plufcal_coancdrate.

iu)toget h o. sadal pao See deqee polyon¥


al
naphs
Radfal Waw nction (R)
f o 1 smdial nocda
s 2S
R

Cdstancekrom nuc teus)


fan uDpadial Aode
3

# OfhU_ Cur tals


RoV RN-
R 2p/3dYP 3p14d 1sf

p ,Sd,6f
# 6naph fa amian anp,d gf
Gnly dhune s thain dtance
Tam ucd eusS
Dal"-
2. Racl prebabxlty denalnby

in
of peak dereasa h hcrease dist1e
Haight
-2P 13di9t

RN2
Sdl6f_

| bnoba bYlhy denaYy jar s-onital na kTrmun at Mt feus


tanp,d.tProbakrIty dedty ocIs Zenot
nucleu do nd maxima put R ) =
4RacikProbabfltyfunction (v'n
RNEO (RN
2s 13plud Tst

an

Date -

PN3

A
Heght feak nereae
tokfnd Maxîmau d (Yn kJ)=o

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