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No. of Printed Pages : 10 (Set-III) DR-I
I Pre-Board Examination, 2023-24
Sub. : Chemistry
Time : 3 Hrs, | Class — XII [ M. M. : 70
Read the following instructions carefully :
(1) There are 33 questions in this question paper with internal choice.
(2) SECTION-A consists of 16 muitiple-choice questions carrying I mark
each. 1
(3) SECTION-B consists of 5 very short answer questions carrying 2 marks
each.
(4). SECTION-C consists of 7 short answer questions carrying 3 marks each.
(3) SECTION-D consists of 2 case- based questions carrying 4 marks each.
(6) SECTION-E consists of 3 long answer questions carrying 5 marks each.
(7) All questions are compulsory.
(8) Use of log tables and calculators is not allowed.
SECTION - (A)
1. An electrochemical cell behaves like an electrolytic cell when :
@ Eee =Eextemal (>) Eextemal ” Beet
(C) Ecey =9 @) — Eextemat
For areaction X+2Y 57 The Rate law expression is
order of the reaction ?
Rate =K¢x] [y]/2. What is the
@ 1 () 2
(©) 15 @ 3
5. Which of the following statement is correct in pseudo unimolecular reactions ?
(@) Both reactants are Present in low céncentrations.
(b) Both reactants are present in the same concentrations.
(c) One.reactant is present in excess.
(@)_ One reactant is non-reactive.
Chemistry/X1U/Set-I1/DR-I [2]
3. The number of unpaired electrons in gaseous species of Mn3*, Cr3* and V3" respectively
are:
(a) 4,3 and2 () 3,3and2
(c) 4,4 and2 (4) 3,3and3
4.
The potential Energy diagram for a reacjiou, R -» Pig shown below, Enthalpy change
of the reaction corresponds to ....
a = Transition
3
5 5 state
es
Reaction coordinate
@ a (b) a+b
() © @ b
For visually impaired students only
For a reaction X + 2Y -> Z The Rate law expression is Rate =41x] [yy/2. What is the
order of the reaction ?
(Ge (b) 2
Oe (@ 3
5. Which of the following statement is correct in pseudo unimolecular reactions ?
(a) Both reactants are present in low concentrations.
(b) Both reactants are present in the same concentrations.
(c) One reactant is present in excess.
(4) One reactant is non-reactive.
Chemistry/XIU/Set-HU/DR-I [3]
6. The table below shows the KH values for some gasses at 293 K and at the same
pressure :
KH(kbar) 144.97 69.16 76.48 34.86
Gases Helium Hydrogen Nitrogen Oxygen
In which of the following are the gases arranged in their decreasing order of solubility
(from left to right)?
(a) Helium > Nitrogen > Hydrogen > Oxygen
(b) Hydrogen > Helium > Nitrogen > Oxygen
(c) Nitrogen > Hydrogen > Oxygen > Helium
(d) Oxygen > Hydrogen > Nitrogen > Helium
7. The IUPAC name of [Pt (NH;),Cl (NO,)} is :
(a) Platinumdiaminechloronitrite
(>) Chloronitrito-N-ammine platinum(1)
(©) Diamminechloridonitrito-N-platinum(11)
(a) Diamminechloronitrito-N-platinum(11)
8. Which of the followin ig complexes are homoleptic ?
@ [CotNH) (b) [Co(NH,),Cl,}*
(© [Ni,0)C1,- (@)_— [Ni(NH,),CL]
9. Predict the product of the reaction :
CH,-CH,-CH,-O-CH,+HBr —>
(a) Propan-2-ol and Bromomethane
(b) Propan-1-ol and bromomethane
(c)’ 1-Bromopropane and Methanol
(4) 2-Bromopropane and Methanol
Chemistry/XT/Set-II/DR-I 10,
14]
Dehydration of alcohol is an example of
(a) addition reaction (b) elimination reaction
(c) substitution reaction (d)
redox reaction
Which of the following alcohols will not undergo oxidation?
(a) Butan-1-ol (b) — Butan-2-o1
(ec) 2-Methylbutan-2-0) (d) 3-Methylbutan-2-o1
Which of the following statements concerning methylamine is correct?
(a) Methylamine is stronger base than NH;
(b) Methylamine is less basic than NH,
(c) Methylamine is slightly acidic
(@)_ Methylamine forms salts with alkali
In the following questions, two statements (Assertion) A and Reason (R) are
given. Select the most appropriate answer from the options given below:
(a) IfAand R both are correct and R is the correct explanation of A
(b) IfAand R both are correct but R is not the correct explanation of A
(c) Ais true but R is false
(@) Ais false but R is true
Assertion Hoffiann’s bromamide reaction is given by primary amines.
Reason : Primary amines are more basic than secondary amines.
|. Assertion : Alkyl halides are more reactive towards nucleophilic substitution -
reaction compared to aryl halides
Reason : In alkyl halides halogen is connected to sp” hybridised carbon.
. Assertion : Gabriel phthalimide reaction can be used to prepare aryl and alkyl
amines.
Reason : Aryl halides do not undergo nucleophilic substitution reaction easily
with phthalimide ion.
Chemistry/XIV/Set-IT/DR-I 22.
23.
[5]
. Assertion : On prolonged heating with HI, glucose forms n-hexane.
Reason +_In glucose, all the six carbon atoms are linked in a straight chain.
SECTION - (B)
What mass of NaCl (M = $8.5 g/mol) must be dissolved in 65 g of H,0 to lower its
freezing point by 7.5°C,
(Kf for water = 1.86 K kg mol“! and assume ‘i’ for NaCl is 1.87),
The rate of a reaction quadruples when the temperature changes from 293 K to 313 k.
Calculate the energy of activation of the reaction assuming that it does not change with
temperature. (log 4 =0.6020),
OR
For a first order reaction show that time Tequired for 99% completion is twice the time
required for completion of 90% of reaction.
. What do you understand by ambidentate ligand? Give-an example
. Which one of the following undergoes SN, faster :
(@) CH3-CH,~CH,~CH,Br and (CH,),CBr
(b) CH;CH,Br and CH,CH,I
- Write the chemical reactions to show that open structure of glucose contains: the
following:
(a) Straight chain with 6 C-atoms (b) Five -OH group
SECTION - (C) }
A solution of CuSO; is electrolysed for.10 minutes with a current of 1.5 amperes. What
is the mass of copper deposited ‘at the cathode? (Atomic mass of Cu = 63.5u)
The half-life for decay of radioactive C14 is 5730 years. Ms. Shanaya has an
archaeological artifact containing wood has only 80% of C!4 activity as found in living
trees. Calculate the age of the artifact. (log 10=1, log8 = 903)
Chemistry/XIV/Set-I1U/DR-I 24.
26.
27.
28.
29.
_ csc -
[6]
Write the stereochemistry and magnetic behavior of the following complexes (Atomic
mass of Ni=28u) :
(a). (N(CH, (b) K,[Ni(CN),]
(©) [Ni(CO),]
. How will you bring about the following conversions 7
(a) Chlorobenzene to biphenyl (6) 1-butene to 2-butene
(c) Chlorobenzene to 2-chloroacetophenone
Explain the mechanism of acid catalyzed dehydration of ethanol to form ethene.
‘An organic compound ‘A’ with molecular formula CHO, was hydrolysed with dil.
H,SO, to give a carboxylic acid ‘B’ and an alcohol “C’, ‘C° on dehydration gives
ethene and ‘C’ also on oxidation gives back ‘B’. Identify ‘A’, “B’ and ‘C’ and waite
reactions involved.
OR
Name the reagent used in the following reaction :
(@) CH,COCH, —> CH;CHOHCH,
(b) CH,CHO + CH;CHOHCH,
(0) CHsCH,CH; > CsHsCOO-K*
Complete the following reaction:
(@) CgHsNH, + CHCI, + ale. KOH >
(b) CgHgNoCl + CgHOH >
(c) CgHs NH, + Bra (aq.) >
SECTION - (D)
The following questions are case based questions, Read the passage carefully and
answer the question that follow :
Chemistry/X1/Set-H/DR-T bo]
Boiling point or freezing point of liquid solution would be affected by the dissolved
solids in the liquid phase. A soluble solid in solution has the effect of raising its boiling
point and depressing its freezing point. The addition of non-volatile substances to a
solvent decreases the vapor pressure and the added solute particles affect the formation
of pure solvent crystals. According to many researches the decrease in freezing point
directly correlated to the concentration of solutes dissolved in the solvent. This
phenomenon is expressed as freezing point depression and it is useful for several
applications such as freeze concentration of liquid food and to find the molar mass of
an unknown solute in the solution. Freeze concentration is a high quality liquid food
concentration method where water is removed by forming ice crystals. This is done by
cooling the liquid food below the freezing point of the solution. The freezing point
depression is referred as a colligative property and it is proportional to the molar
concentration of the solution (m), along with vapor pressure lowering, boiling point
elevation, and osmotic pressure. These are physical characteristics of solutions that
depend only on the identity of the solvent and the concentration of the solute. The
characters are not depending on the solute’s identity.
(a) Why is glycol and water mixture used in car radiator in cold countries?
(b) Identify which liquid have the higher vapour pressure at 90°C if the boiling points
of two liquids A and B are 140°C and 180°C respectively.
(©) Give reason :
(Cooking is faster in pressure cooker than in cooking pans.
(i) RBC shrink when placed in saline water but swell in distilled water.
OR
(c) Draw the graph between vapour pressure and temperature and explain the elevation
in boiling point of a solvent in a solution.
Chemistry/X11/Set-I1I/DR-I 12]
30, The following questions are case based questions. Read the passage carefully and
answer the question that follow : ‘
Carbohydrates are optically active polyhydroxy aldehyde and ketone. They are also
called sacchatides. All those carbohydrates which reduces Fehlings solution and Tollens
reagent are called reducing sugars. Glucose is the most important source of energy for
mammals, is obtained by hydrolysis of starch, Vitamins are necessary food factors in
the diet. Protein are polymers of alpha amino acids and perform various structural and
dynamic functions in the organisms.
(a) The penta-acetate of glucose does not react with hydroxylamine. What does it
indicate?
(6) Why cannot vitamin C be stored in our body?
(c) Define following : :
(Peptide linkage (i) Denaturation
OR
(c) Define following :
() Anomers Gi) Glycosidie linkage
SECTION - (E)
31. (a) Write the reactions taking place at anode and cathade of H,-O, fuel cell.
©
Calculate emf and AG? for following cell, at 298K :
Mg (s)/Mg?* (0.001 M) // Cu?* (0.0001 M) / Cu (s)
(Given Standard reduction potential of Mg Electrode = -2.36 V & SRP of Cu
Electrode = +0.34 V)
OR
(a) (@ Write the product of electrolysis of NaCl (aq),
(ii) How much charge is required for reduction of 1 mol of MnO; to Mn2*
Chemistry/XIV/Set-IM/DR-I 19)
(b) State Kohlrausch Jaw of independent migration of ions. Calculate A°m for acetic
acid.
(Given 1°HCI = 426 § cm? mol!, 4°NaCl = 126 S cm? mol-!, 4°AcONa = 91 S
cm? mol!)
32. (a) Complete the following reactions :
‘ @ ChOF +r 4Ht ...
-.
: (i) K,Cr,0, + KCI + H,SO, ...
(b) Account for the following :
@ . Cr?*is reducing in nature while with same d orbital configuration (44), Mn3*
is an oxidising agent
Gi) Transition metals and their compounds are generally found to be a good
catalyst
(iil) Zn, Cd & Hg are not considered as transition elements.
OR
Complete the following reactions :
@ MnO; +1 +H*
(i) MnO, + KOH+0,
(b) What is lanthanide contraction? Write its cause and consequence...
@
33. (a) Account for the followings :
() Formaldehyde does not undergo aldol condensation.
(i) Electrophilic substitution reaction in benzoic acid takes place at m-position.
Give a brief account of the following:
Q)
() Reimer-Tiemann reaction
(i) Hell-Volhard-Zelinsky reaction
(ii) Clemmensen reduction
Chemistry/XIV/Set-IL/DR-I [10]
OR
(a) Arrange the following set in the increasing order of the property mentioned against
them:
() Ethanal, propanal, propanone, butanone (reactivity towards nucleophilic
addition reaction)
(i) Benzoic acid, 3, 4-dinitrobenzoic acid, 4-methoxybenzoié acid (acidic
strength)
(b) How will you distinguish between the following pairs of compounds ?
() Propanal and propanone (i) © Ethanal and propanal
ii) Phenol and benzoic acid
Chemistry/XI/Set-IL/DR-I
