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IUPAC NOMENCLATURE by Bharat Panchal

This document provides guidelines for naming organic compounds using IUPAC nomenclature. It discusses naming conventions for parent chains, numbering, prefixes, suffixes, functional groups, substituents, cyclic and unsaturated hydrocarbons. Key aspects covered include: 1) Parent chains are named based on the number of carbons, with prefixes like di, tri, tetra indicating 2, 3, 4 carbons. 2) Numbering starts from the end nearest a functional group and proceeds in the direction that gives the lowest numbers to substituents. 3) Prefixes and suffixes indicate features like functional groups, number of substituents. 4) Substituents are named based on type and location following alphabetical

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vansh rana
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100% found this document useful (1 vote)
1K views34 pages

IUPAC NOMENCLATURE by Bharat Panchal

This document provides guidelines for naming organic compounds using IUPAC nomenclature. It discusses naming conventions for parent chains, numbering, prefixes, suffixes, functional groups, substituents, cyclic and unsaturated hydrocarbons. Key aspects covered include: 1) Parent chains are named based on the number of carbons, with prefixes like di, tri, tetra indicating 2, 3, 4 carbons. 2) Numbering starts from the end nearest a functional group and proceeds in the direction that gives the lowest numbers to substituents. 3) Prefixes and suffixes indicate features like functional groups, number of substituents. 4) Substituents are named based on type and location following alphabetical

Uploaded by

vansh rana
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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2 → di Comblexgb

3→ tri C. Which already contain


4- > tetra diitoi )
5s
benke
6s here 2- bis
3- tris
4- tetakis
5- →
bentakis
6 > hexakis
BASIC
OF ORGANIC
IUPAC NOMENCLATURE

Prefix + Word Root + suffix

2%
"
no .
of carbons i
" meth

Bond functional Group
substituent close /open .

G. → eth
1-
Type
R -

alkyl ↳ → boob
ane
-

✗ - Halo Cyclo ↳ → but


= ene
NO - Mito G- → bent
,
E. The
→ hex
No -
Nitroso
G- hebt
Alkoxy

OR -

(8 → Oct

↳ → Non
Cie → dec
Nomenclatural
p → Parent chain
N →
Numbering
Alphabetical order
A →

preference order

254 9 → Grouts
rant B → Bond ( = , =)
Success
5 → substituent
N
at → Normal
COMMON Prefix ⑨

CH] -
CH ]

du -
Eso #⑨
A-
Tertiary
CH]

CHS -

& -
Neo ⑨
CH
, A

secondary
Functional Group

Alcohol -

OH -
01
Amine -
NH
,
-
amine
Nitrile -
CN -
nitrile
Isonitrile ◦ -

NC -
isonilrile
11
Ketone e o one
-
-
-

d- H
Aldehyde -
-
al
carboxylic Acid - É -
ou -
Oic acid
Ester
Amide
-

¥°_ E- MHz -

-
alkylalranoate
amide
Acid Halide -
É -
✗ -041 halide
NOMENCLATURE OF
ˢA{ATa%Ha¥?%eAdRB°_ eachother
by single bond

C- C- C Propane
2→G > methyl
c- C- C- C- c. Pentane
3.→ Bro Bromo
I 2 3 45
C- C- C- C- C
2- Methyl pentane
& 1
a
I 4 5
21
C- C- C- C- C 3- Bromo -2 -
methyl
1 pentane
Br
5 4 3 29
if two dist . substituent are
C- C- C- C- C
I present at same position , preference
④ ③ will be given ace to alphabetical
-

Bromo
_ .

methyl
order

2- Bromo -
4- methyl pentane
2- Rrs method
• 2 1 45 6 I > as methyl

C- C- C- c- C- C 4 → as Methil


' '
c c

2,74 Trim ethyl hexane


-
CYCLIC HYDROCARBONS

F) Gedo butane
it
Fᵈ¥1 Probyicydobutane
-
1- Pentyl cyclopentane

I 2 3

e- c- c- C- C
4 5
[% 1- Bromo - 2- Chiro

1- Br cyclo butane
±
.

2- Cydobrobylbentane
UNSATURATED HYDROCARBONS
c- care attached to each other
= ene
by atleast one multiple bond
E. yne

c- c- c
prob C- CIC -
C
-
g ene
-

But - 2- yne
3 2 1 , z z ,

Cl
5 4 3 2 a

C -
C -
C -
C :-C C. E. C- d- G- C- C- C
'
Br I 2 3 4 56 7
4- Bromo bent tyne
"

3- Chloro hebt -4 en -
I yne
-

(9%9947)
-

truth vowel rule


.
→ .

-
=
No two vowel
present with each other
C. =
C- c- CIC if two different bond [= , -= ) are

present at same position preference


I 2 3 45
,

will be give to double bond

pent -
1- end -
4- yne

word root ends with "


a
"

2
l 3 4 5

C- C G- C
-

C -

Penta -1,4 diene


-
CYCLIC

g Cydoboob -1 ene
4
-

3 21
C- C- C=c
1-

It
Cydobuta -13 -

diene
3- Aedobentge

but -1 ene
②a- metal
-

±④
chloro
Bromo

$ 2
3- Bromo - 5- chlo.ro -
4- methyl

cyclo bent Here


-
Alcohol -
OH -
01 5 19 ] 2 I

e- C- C- C- C
{ d- on Ethan -1-0-1
0h
'

PM 4- Chloro benteen -2-01

l{_{- Protean -2-01



I 2 3 4 5 5 1932 I

C
c- c- c- c- c
C- C- C-
-
C
,

tou tou on

Pentane -2,4 -
diol 4- Brom bent - -
ten -3-01
OH
C- C. Ethane -1,2 diol
2/45 -

¥_④
1 I
on on Glycol


3- Bromo -
4-
ethyl
cydobentan -1-01 Propane -1,2 ]
G-
C- C ,
-
biol

outoutoll Glycerol
Amines R MH ,
-
R MH
-
- R R - M R
-

K 3. amine
i amine 2° amine

I 2 I
c- C- C- C- MHz C- C- C Boban -
2- amie
4 3 21 1
Bulan 1- amine
-
NH
,

MHz MHz
C- C- C - C
I 21 3 4 Fi ,
4- Chloro

NIL ¥ cyclohexane/ -1 .

Cl amie
Butane -2,3 diamine -

-

4
C- C C
3
- -
MH C C
- - 21
meth
C- C- C- C
Y C
- -

I 2 I

c- °
d- Ethyl probate -
famine methyl

N -
Ethyl -
N -

methyl baton - 1- amice


B① ← Bromo

C. = C- in
2 I
probed

N Bromo
-
-
N -
brobyeeth -1 -
en - I -
amid
ketones R- § -

RI one

f&É Boban 2- one

t.EE?.~ji~Pentan-s-
-

one

s
5 Cydobentan -
tone

c- d- c=c
But -3 -
en -
2- one
2 3
i
4
Aldehyde -
§ -
h
-
al "

if Cq Cho included in Chai


is not
-

Carbaldehyde
"
if c
of Cho

included in chain
C- C- CHO

,§H°
3 2 I

Protean -
tab
µ cyclopentane -1
i. CHO -

carbaldehol

⑤ d-31c-⑨ 2
4 3 2 I

C- c- c- Cno
CHO

6t¥41
g.
3- Cyclo hex 2- enyl -

3- meths bulan -1 al
2- Ethyl
-

butane -1,4 dial-


?⃝
E- Eino is .


¥ c- C- Cleo
'
a
3- Aedobentylbroban tal
-

I 2 3

C- C- C bicarbaldehyde
Propane-1,2 ,
]
-

duo duo { no

identical treatment
Acid COOH Oic acid
Carboxylic
-
-

3 2 t
COOH
C- C- COOH

Protean -
toicacid a
# -
Cydobutane
-
1- carbolic
G- c- C- C- Coon acid
I 2 3

5 43 2 I
C- C- C
' 1
Pent -
4- en -
1- oicacid I
(004
Coon cooy

Propane -1,33 toicarboxslicacid


-
Est① R -
COO -
R
'

Ers
alkyl alkanet

C- C- COO
-
-

£ €-00 -

GI

Methyepropanoate Ethylbutanoate
Aromatic HYDROCARBONS

Cotto

¥1 Benzene }
Nabhthalene
{ Anthracene


""

Toluene
Chlorobenzene
Benzyl
- Cn - n

,
ICH }
Methyl benzene or Toluene
Benzae
ÉÉ
Benzo

¥Y 1- Bromo -

2- chlorobenzene
3ÑHUd
°

m
6
{ʰ °

3 M
1,2

1,3 or
or 1,6

1,5
-

-
O

m -
- ortho

meta

1,4 - b - para
4

P
I
ee Br

ÉÉ
"

FEI.rs .
ÉÉ 3

I
1,2 Diction benzene
-

1,1 -
Dibromo 1,4 Diiodo benzene
-

-
-

benzene or
or
0 - Di chlorobenzene m - pibnomo benzene b- Diiodobenzehe
40011 ICH Br
,
-

Phenol
f Benzoic acid
F Benzyl
bromide

pole "

¥" Aniline
¥4 Benloudenloride Acetobheone

3 Methoxy benney ion cool


◦✗ benzoic acid
Amesol 2- Hydroxy
or salicylic acid
CHO
• PU
€-1 Benzaldehyde "◦

2. Hydroxy benzaldehyde
Nill cooysalicyldetydl
F Benzene diazonium
chloride € ,
Tere bhthalic
acid
NOMENCLATURE OF POLY FUNCTIONAL GROUP

Carb Acid -
COOH
-

carboxy
}
.

Acid
sulphuric Acid sulbho
Sogn
-
-

ester E- or alkoxy Carbonyl


}
-
_

Acid Halide acid


_
-4
-

Halotormyl
Acid Amide _ -
nite Derivative -

carbonyl
,
Nitrile EN
-

cyano
} _= Bond
-

Isonitrile -
N :c _

isocyano
Aldehyde É formyl / 0×0
-1,7 } Bond
-
-

=
Ketone ,
-0×0 / keto

Alcohol OH hydroxy
}
-
-

Thiol SH Bond mercabto


- -
-

Amine amino
-

Nita -
in
'

-
Coote

:@ Hydroxy toicacid
3
3- -

2- nibobutan -

Nitro
hydroxy

⑦ M ←amiu
0×0
.

Ctg -
§ -
du -
du -
COOH
2- Amino -
3- hydroxy -4-0×0
4 I 2 1
5 benteen -
1- oicaa 'd

⑦ °

d
'

CH - -
CH -

COOH
, ,

4 ] 2
I

Cha CHO
GH CH
4- Chloro -3 methoxy
• - - -
-

,
⑥ batan tal
-

↓ methane .

Chloro
?⃝
?⃝
4 I 2
f

C- C- C- C- OH
7.9 2- Ameenobutan -1-01

OH

city &nˢ_ §
'
CH, 3-
ttydnoxybutan
• _

2-
-

one
,
0

OH
'
°
4 3- Ethyl 5-
hydroxy

cyclohexane -1
-
-
one

%¥°
COMMON NOMENCLATURE

c- C- C- c- C
n -
pentane

C- E- c- c isotsentane µ
c

c- d- c neo - pentane *
'
c
MA n -
Heptane

*E Iso -

Heptane

*.
neo -
Heblane
i
C- c- on on

&
tert-Butyl alcohol
i
C- 8 -
N
Hz
a
{
c- C ¥8 on
tert-Butyl amine
- -

Sec -

Butyl -
alcohol

i
C-C- MHz
ALOU Iso bentgl alcohol

µ¥Nᵗʰ neeopentglamlne

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