Unit 3A
Unit 3A
Management of MSW:
MSW management is a major issue & cities in India spend
approximately 20% of the city budget on solid waste services.
The primary steps involved in MSW management are generation,
collection, sorting and separation, transfer and disposal/
utilization.
1. Waste generation encompasses activities in which
materials are identified as no longer being of value and are
either thrown out or gathered together for disposal.
2. The functional element of Collection includes not only the
gathering of solid waste and recyclable materials, but also
the transport of these materials, after collection, to the
location where the collection vehicle is emptied. This
location may be a material processing facility, a transfer
station or a landfill disposal site.
3. Waste handling and segregation involves activities
associated with waste management until the waste is
placed in storage containers for collection. Handling also
encompasses the movement of loaded containers to the
point of collection.
4. Segregating different types of waste components is an
important step in the handling and storage of solid waste at
the source. The types of means and facilities that are now
used for the recovery of waste materials that have been
separated at the source include curbside collection, drop off
and buy back centers.
5. Transfer and transport involves two main steps. First, the
waste is transferred from a smaller collection vehicle to
larger transport equipment. The waste is then transported,
usually over long distances, to a processing or disposal site.
6. Today the disposal of wastes by land filling or land
spreading is the ultimate fate of all solid wastes, whether
they are residential wastes collected and transported
directly to a landfill site, residual materials from materials
recovery facilities (MRFs), residue from the combustion of
solid waste, compost or other substances from various solid
waste processing facilities.
HAZARDOUS WASTE
Hazardous wastes are those wastes which by reason of their
chemical activity or characteristics like ignitability, corrosivity,
reactivity and toxicity or other characteristics that are potentially
dangerous either immediately or over a period of time to human
beings and the environment.
As per Hazardous and Other Wastes (Management and
Transboundary Movement) Rules, 2016, hazardous waste means
“Any substance, whether in solid, liquid or gaseous form, which
has no foreseeable use and which by reasons of any physical,
chemical, reactive, toxic, flammable, explosive, corrosive,
radioactive or infectious characteristics causes danger or is
likely to cause danger to health or environment, whether alone
or when in connection with other wastes or environment, and
should be considered as such when generated, handled, stored,
transported, treated and disposed off’. These include
process based wastes like petrochemical industries wastes,
wastes out of production of plastic, etc. (Schedule I of the
above rule)
constituents with concentration limits like waste
containing Arsenic above 5 mg/l, Hg above 0.2 mg/l, etc.
(Schedule II of the above rule)
Characteristics based wastes like
- Toxicity: Waste toxicity is measured by using the Toxicity
Characteristic Leaching Procedure (TCLP). The TCLP
extract is analyzed for lead (or other constituents) to
determine. If it is above 5 ppm (milligrams/ liter) such
wastes are considered as hazardous. Examples: pesticides,
heavy metals.
- Corrosivity: Corrosive waste has a pH that is either less
than or equal to 2 (highly acidic) or greater than or equal to
12.5 (highly basic), or which can corrode steel at a certain
rate. Unneutralized caustic paint strippers and acidic paint
strippers (including the resulting sludge) may be corrosive.
Examples: acids and base.
- Ignitability: Ignitable waste generally includes liquids with
flash points below 140°F (60°C), flammable solids and
compressed gases, and oxidizers. Certain solvents from
paint strippers (e.g., xylene) and the resulting sludge or
slurry waste may be ignitable. Examples: Gasoline, paint
thinners and alcohol.
- Reactivity: Reactive waste includes substances that are
capable of easily generating explosive or toxic gases,
especially when mixed with water. These also include
waste that is unstable and undergoes violent change without
detonating. Examples: Gun powder, nitro glycerin.
Effects
Management of HW:
Scientific disposal of hazardous waste through collection,
storage, packaging, transportation and treatment, in an
environmentally sound manner minimizes the adverse impact on
human health and on the environment. The hazardous waste can
be disposed at authorized (by MoEF) captive treatment facility
installed by the individual waste generators or at Common
Hazardous Waste Treatment, Storage and Disposal Facilities
(TSDFs). There are 40 Common Hazardous Waste Treatment,
Storage and Disposal Facilities (TSDFs) available in 17
States/UTs.
Hazardous waste as lead acid battery scraps, used oil,
waste oil, spent catalyst etc. and other waste such as waste tyres,
paper waste, metal scrap, etc. are used as raw material by the
industries involved in recycling of such waste and as
supplementary resource for material and energy recovery.
Accordingly, it is always preferable to utilize such waste through
recycling, or for resource recovery to avoid disposal through
landfill or incineration. There are about 1080 registered
recyclers; 47 cement plants permitted for co-processing; and
about 108 industries permitted for utilization of hazardous waste.
BIOMEDICAL WASTE
Impact
Proper disposal of biomedical waste is of paramount importance
because of its infectious and hazardous characteristics. Improper
disposal can result in the following:
· Organic portion ferments and attracts fly breeding
· Injuries from sharps to all categories of health care personnel
and waste handlers
· Increase risk of infections to medical, nursing and other
hospital staff
· Injuries from sharps to health workers and waste handlers
· Poor infection control can lead to nosocomial infections in
patients particularly HIV, Hepatitis B & C
· Increase in risk associated with hazardous chemicals and drugs
being handled by persons handling wastes
· Poor waste management encourages unscrupulous persons to
recycle disposables and disposed drugs for repacking and
reselling
· Development of resistant strains of microorganisms
Incineration Technology
This is a high temperature thermal process employing
combustion of the waste under controlled condition for
converting them into inert material and gases.
Non-Incineration Technology
Non-incineration treatment includes four basic processes:
thermal, chemical, irradiative, and rarely biological which are
used for noninfectious biomedical wastes. The majority of non-
incineration technologies employ the thermal and chemical
processes. The main purpose of the treatment technology is to
decontaminate waste by destroying pathogens. Facilities should
make certain that the technology could meet state criteria for
disinfection.
Autoclaving
The autoclave operates on the principle of the standard
pressure cooker.
The process involves using steam at high temperatures.
(121 deg. C. and steam pressure of15 psi. for 60-90
minutes)
The steam generated at high temperature penetrates waste
material and kills all the micro organism.
Microwave Irradiation
The microwave is based on the principle of generation of
high frequency waves.
These waves cause the particles within the waste material to
vibrate, generating heatthis heat generated from within kills
all pathogens.
Chemical Methods:
1 % hypochlorite solution can be used for chemical disinfection
Plasma Pyrolysis
Plasma pyrolysis is a state-of-the-art technology for safe
disposal of medical waste. It is an environment-friendly
technology, which converts organic waste into commercially
useful byproducts. The intense heat generated by the plasma
enables it to dispose all types of waste including municipal solid
waste, biomedical waste and hazardous waste in a safe and
reliable manner. Medical waste is pyrolysed into CO, H2, and
hydrocarbons when it comes in contact with the plasma-arc.
These gases are burned and produce a high temperature (around
1200oC)
AGRICULTURAL WASTE
Agricultural waste is waste produced as a result of various
agricultural operations. It includes manure and other wastes from
farms, poultry houses and slaughterhouses; harvest waste;
fertilizer run- off from fields; pesticides that enter into water, air
or soils; and salt and silt drained from fields.
Curbside Collection
The home owner is responsible for placing the containers to be
emptied at the curb on the collection day and for returning the
empty containers to their storage location until the next
collection.
Biomethanation/ Biogasification
Production of biogas under controlled condition is often termed
as Biogasification / biomethanation, also known as Anaerobic
Digestion (AD). In the absence of oxygen, anaerobic bacteria
decompose wet waste organic matter (90% moisture is desirable)
to produce biogas as follows:
Organic matter + anaerobic bacteria CH4 + CO2 + H2S + NH3
+ other end products + energy
Deenbandhubiodigester:
Action for Food Production (AFPRO), a voluntary organization
based in New Delhi developed this model in 1984.
Pyrolysis:
Pyrolysis involves an irreversible chemical change brought about
by the action of heat in an atmosphere devoid of oxygen.
Synonymous terms are thermal decomposition, destructive
distillation and carbonisation. Pyrolysis, unlike incineration is an
endothermic reaction and heat must be applied to the waste to
distil volatile components. Process of converting plastic to fuels
through pyrolysis is possible, but yet to be proven to be a
commercially viable venture.
Gasification
Gasification is a partial combustion of organic or fossil based
carbonaceous materials, plastics etc. into carbon monoxide,
hydrogen, carbon dioxide and methane. This is achieved at high
emperatures (650°C and above), with a controlled amount of
air/oxygen and/ or steam. The process is largely exothermic but
some heat may be required to initialize and sustain the
gasification process. The main product is syngas, which contains
carbon monoxide, hydrogen and methane (producer gas).
Typically, the gas generated from gasification will have a net
calorific value of 4 - 10 MJ/Nm3.The other main product
produced by gasification is a solid residue of non-combustible
materials (ash) which contains a relatively low level of carbon.
Disposal –
This is the least preferred option for the management of
solid wastes and employed only when there is no option but to
dispose of wastes. The waste which cannot be subjected to any of
the processing may be disposed through following engineered &
non engineered methods depending on the type of waste to be
disposed & other relevant needs (like filling low lying areas,
space availability, etc.)methods.
Ocean Dumping
The disposal of refuse by dumping into sea is possible only in
case of coastal cities, where available land is less. While
dumping the refuse, care is taken to take the refuse in barges,
sufficient distance away, 2 to 3 km from the beach and dumped
there. The refuse may be washed ashore under tidal conditions.
This method is very costly and is not used in India.
Leachate pond
Advantages of Landfilling:
In addition to provide an option for waste management, it
also serves to improve/ reclaim poor quality land.
It raises the ground elevation/surface grade of the site.
Completed landfills have been converted to municipal
parks, playgrounds, golf courses, community land use
projects.
It is the most economical alternative for SW disposal
which accounts for its frequent application.
Other disposal methods are not entirely safe and efficient
throughout the year.
Thus landfilling is the most convenient option -
Incineration is a costly process, residue requires ultimate
disposal on land. Composting is a seasonal option. It is
not possible to reclaim and recycle all SW material.
Disadvantages of Landfilling:
Difficult to find suitable site within economically feasible
distance.
It is not possible to build a completely safe and secure
SW landfill.
Some of the pollutants may escape in the environment in
the form of leachate.
Potential harm to public health due to air, soil, water and
noise pollution
Damage to local ecosystem due to the construction,
dumping, etc..
Public oppose due to fear of mishandling, pollution,
odours issues, etc.
Control Measures:
It is important to minimize contamination from landfill to
the surrounding environment. Hydrology (GW flow) and
geology (Rock type, soil permeability) of the site has a
direct influence on the possibility of water pollution (GW
pollution).
Landfill should not be located in low lying wetland areas
i.e. near marshes, swamps, as the waste should not come
in contact with surface/ GW.
It should not be located in flood plains of streams/ rivers.
There should be minimum distance of 60m from any
lake/pond.
Vertical separation of 1.5 m between base of landfill and
seasonally high GW table elevation.
It should not be located in unstable areas or if it is present
it must be designed to resist forces caused by seismic
activity.