Chem Imp
Chem Imp
IN
A S K E D
2017)
(2)
SUMMARY OF QUESTIONS
SOLID STATE
(March
2013,
2014,
which
(Oct. 2013)
ate atomic
.nC
radius of gold. (Molar ystal
gcmn
Calculato the
Calculate d e n s i t y 10
(3 number of atoms prese and
cubic (fcc)
crystal lattice having edge lengn
o100
of pm
100 pm an
(March 2014) (3)
What are Schottky defect and Frenkel delect density
of g. 8.966
cm
mol'
and
63.5g.
oace centercd cubic erystal lattice of copper has ofcopper
is nass
unit Cel
niobium
C late the atomic radius of niobium. (Given: Atomic s t r u c t uofr e . The edge length of
mass the
Calculate the percentage efficiency of packing in case of simple cudic (March 2017) (2)
(15) Classify the following molecular
solids into different types
(a) Ammonium phosphate (b) Brass (c) Sg molecule (d) Diamond. (July 2017) (2)
4oAetalcrystallises into two cubic faces namely face centered (FCC) and body centered (BCC),
Wose unit cell edge lengths are 3.5 Å and 3.0 A respectively. Find the ratio of the densities of
FCC and BCC.
(July 2017) (3)
aculate the number of atoms in a unit cell of a metal crystallising in face centered cubic structure. (2)
(18) lonic solids are hard and brittle. Explain.
(March 2018) (2)
(19) The density of iron crystal is 8.54 gram cm3. If the edge
length of unit cell is 2.8 A and atomic mass is 56 gram
mol, find the number of atoms in the unit cell.
Given: Avogadro's number = 6.022 x 1023, 1 Å = 1x 108 cm]
(20) Classify the following molecular solids into different types:
(March 2018) (3)
(a) HC1 (b) CO (c) Solid ice
(d) SO (July 2018) (2)
(21) The density of silver having atomic mass 107.8 gram
mol is 10.8 gram cm. If the
cell is 4.05 x 10-5 cm, find the number of silver atoms in the unit cell. edge length of cubic unit
(N6.022 x 1023, 1À =10-8 cm)
(221 What is the ratio of octahedral holes to the number of anions in (July 2018) (3)
hexagonal closed packed structure
(23) Define Anisotropy. Distinguish between crystaline solids and amorphous solids. (March 2019) (1)
(24) Classify the following into different types: (March 2019) (3)
(a) Silver (b) (c) Diamond
P (d) NaCI
(25) Unit cell of a metal has edge length of 288 pm and density of 7.86 g cm-3 (March 2020) (2)
Determine the type of crystal
lattice. (Atomic mass of metal 56 g =
mol-
What is the coordination number of atoms in simple cubic crystal lattica (March 2020) (3)
(26)
127) A compound forms hexagonal close packea ncp) structure. What is the number
f (Sept. 2021) (1)
il Octahedral voids (ii) Tetraneara VOlds n ) 1Otal voids formed in 0.4 mol of it?
with
consequences
of Schottky defect reasons.
(Sept. 2021) (3)
the
(28) Write cubic cells. The edge length ofs
into f a c e - c e n t r e d
[Molar mass of gold1llis
(March 2022) (2)
(29) Gold crystallisesCalculate the density of gold. nol
4.08 cm.
x 10-8
metal deficiency
defect with example. (March 2022) (2)
(30) Explain (134) (March 2022) (2)
n n i a yD/
Board
f Board Questions
135
2 SOLUTIONS
State and ad explain van't Hoff-Boyle's law.
Colligative operties'.
Define 'Co
(March 2008) (2)
tion'.
Define Tsotonicsolutio
(Oct. 2008) (1)
Hoff-Avogadro's law.
State vant (March 2009, Oct. 2013) (1)
Detine:"
"Ebullioscopic stant' (March 2009) (1)
61 Defhne Solution
(Oct. 2009) (1)
71Define o s m o t i cp r e s s u Derive an
equation for (Oct. 2009; March 2011)
determination of molccular weight from osmotic (1)
pressure.
Define a ealution. Explain the terms solute and solvent.
solu (Oct. 2010) (2)
olationship
Derive t h e r e l a t i o between relative lowering of vapour pressure and molar (March 2011) (2)
mass of non-volatile
s o l u t e .
o n of a substance having
mass
aiculate the molar mass of the substance used. (March 2017) (2)
Volume = 1 dm3, R = 8.314 JK- mo| dissolved in
non-volatile solute was
353.23 K. When 1.80 gram of
u n g point of benzene is to 354.11 K.
Calculate the molar
mass solute. of (2)
or benzene. The boiling point
is raised (March 2017)
td (uly 2017 (1)
for benzene 2.53 K mot']
Define: Osmotic pressure. water. Its
osmotic pressure at 12c (2)
is dissolved in 2000 cm3 of solute.
(ruly 2017)
An 169 gram mol-l) the m a s s of the
(2)
c Substance (M
=
calculate
'an 0.0821 L atm.
K-l mol,
was If R =
of solute. 2
2 nd to be 0.54 atm. of boiling point
and molar
mass
gram is
is 100
b e n z e n e
weight
136 point
of pure molecular
(July 2018)
having
freezing
(85) What is freczing The solute
point of liquidr
quid? " ofa 5.12 kgmo
freezing point of the
a
2.0
when
gram
(March 2019) 13
added
(36) Define the
to 100 gram of benzene. IK, Jor Hypotonic
s o l u t i o n
of
one
atmosphere
(March 2020) 12
solution
(il) Hypertonic at
50°C
(37) What
(March 2020) (2
oxygen
is the ntration of dissolved
i atm')
partial pressure of oxygen at 50'C 1s mol
dm
and
x 10 solute
(March 2020) 14
(39) Derive the between and
mathematical point
Hoff-Avogadro's
ression
boiling
elevation of boiling point. State and explain
van't
between
clevation
of
(Sept. 2021) 13
(0)
Define 'Cryoscopic constant. Derive the relation
of it in
. 0.822 g
molar mass of
(41) What is the
solute prepared by
dissolving
(Sept. 2021) 13)
solution K?
0.3 dm'
molar mass Soluteifa aosmotic atm. at 298
by
osmotic
pressure
( Derive an
of water has an pressurc
of n o n
volatile
solute
(March 2022) 12
expression to calculate molar mass
solubility of
measurement. What is
(43) Henry's law constant 10r
for CH,Br is 0.159 mol dm-3
bar-! at 25°C.
Dal
(March 2022) 12
water 1s. CH,Brg pressure of 0.109 (March 2022) (2
B at in same temperature and partial
e n e the following terms: (i) Isotonic solution (ii) Osmo
IONIC EQUILIBRIA4
3
(Sept. 2021, March 2022) 121
Derive the
relationship between pH and pOH.
solubility an
eSolubility product'. Derive the relationship between (Sept. 2021) 13)
solubility product for Pbl,.
ana
Culate the pH of buffer solution composed of 0.01 M weak base BOH
0.02 M of its salt BA.
[K, =
1.8 x 10-5 for weak base (March 2022) 13)
4 CHEMICAL THERMODYNAMICS
G i v e one statement of first law ofthermodynamics and give its corollary. (March 2008) (2)
(2State and explain Hess's law ofconstant heat summation and give its four applications.
(IMarch 2008; Oct. 2008) 14)
(3) Derive the relationship between the heat of reaction at constant pressure and at constant volume.
isothermal and
reversible process. gas expands
(b)
until the volume of gas is increased
(c) into vacuum
by 3L. (R
sign conventions tions of AS in the 8.314 J
=
(15) Explain
with reason
483.2 kJ mol
.
(July
enthalpy change2017)
138 CH,COOH
4,H"(CH,COOH)
combustion of if the at 1a
enthalpy of kJ mol';
a m m o n i a ,
R
o
=
r m a
8.314
t i o n
JK'
mol")
Nm to 4
(March 2018)
10 Nm
constant oressure
mol
is -42.0 kJ
(Given:
Enthalpy
of
vaporization.
pressure
40
* 10°
the expansion.
at 300k
(b) from a during
(40) Define (a) Enthalpy of atomizatio (July 2018)
a b s o r b e d
reversibly
and heat
energyand
isothermally
(41) 5 moles of helium ex
Calculate
pand
(March 2019) 3
of
combustion
of 2g
g ofCO,?
(44) The standard enthalpy formation of 22
in the
How much heat will be evolv
(45) For the reaction: 175.8 JK- (March 2020) 2
AH° = +57.24 kJ, AS° =
NOA
At What
2NO21;
temperature the
reaction will be spontaneous
1 AH°(N-H)
=
389 kJ
sublimation.
property (i)
Enthalpy of from 20L to
(49) Define: (i) Intensive isothermally and
reversibly (Sept. 2021) (4
a r e expanded
2 moles of a n ideal gas mol")
the work done. (R
8.314 =
form 10 L to
JK
30L at 300 K. Calculate reversibly
One mole of a n ideal gas
is expanded
isothermally and (IMarch 2022) 12
(50) done in the process.
Calculate the work data:
15 L at 300 K. from the following
standard enthalpy of
of formation CH,OH
Calculate the
(51)
2H,O AHO= - 726 kJ mol-i
() CH,OH*z°i CO2 ;AH- 393 kJ mol
(ii) C+O19 CO21g) (March 2022) (3)
A H - 286 kJ mol-
(ii) Hazae H,O for
first law of thermodynamics (March 2022) (2)
mathematical equation for the
Write the
(52) (ii) Adiabatic process
(i) Isothermal process
5 ELECTROCHEMISTRY
(9)
electrode reaction and net cell
Write
rite electrode
139
Zn|Znaq)(0.I M) || Cu2 taqy (0.5 reaction for fucl ccll.
Calculate e.m.f.
ctandard reduction potential (SRP) M)ICu of the following cel a
Dsistance and of Zn and Cu are 0.76
(10 n d 1.46 10" conductivity
S.cm"
ot a cell
containing 0.001 M KCl
V and 0.334 V
respectively. (Oct. 2013) (2)
respectively. What is
the solution at 298K are 1500 2
(11) State the first and second law
of cell constant?
Write any four electrolysis. (March 2014)
(12) applications
With the elp of the
of
electrochemical series. (March 2014)
(3)
(13) equation, AG® (2)
property. nEcell explain that cell (Oct. 2014) (2)
14) How much electricity in terms of
potential is an intensive
tal 20 g of Ca from molten Faraday is required to (Oct. 2014) (2)
Gven: Molar mass of Calcum CaCl, (b) 40 g of Al from produce:
molten Al,O,
15) Draw neat and labelled Aluminium 40g.mol' and are
and
diagram of dry cell. 27g.molt' respectively.)
Arrange the following reducing agents in the order
(Oct. 2014) (2)
conditions. Justify the answer. of increasing strength (March 2015) (2)
under standard state
Element
Als) Cu Cl Ni
EO - 1.66 V
0.34 V 1.36 V 0.26 V
17 Calculate Eeell and AG for the
following (March 2015) (2)
at 28°C:
Mg+Sn" (0.04M)- Mg
18 (O.06M) +
SnEell 2.23 V. Is the reaction spontaneous?
Can copper sulphate solution be stored in
101 Resistance of conductivity cell filled with 0.1an iron vessel? Explain. (March 2015) (3)
M KCI solution is (Oct. 2015) (2)
molar conductivity of 0.02 M KCI 100 ohms, calculate the
solution. conductivity and
Given: Conductivity of 0. 1 MKCI solution is 1.29
(20) Define 'Molar conductivity'. Sm'.]
(Oct. 2015) (3)
(21) Define cell constant. Draw a neat and well (March 2016) (1)
labelled diagram of
(22) Conductivity of a solution is 6.23 105 primary reference
Qcm' and its resistance is 13710 0. electrode.
x (March 2016)
electrodees are 0.7 cm apart, calculate the If the
cross-sectional area of electrode.
(23) The conductivity of 0.02 M (March 2016) (3)
What is its molar
AgNO, at 25°C is 2.428x 10-3 Q-' cm.
conductivity?
(24) What are fuel cells? Write cathode and anode (uly 2016) (2)
reaction in a fuel cell1.
(25) 0.05 M NaOH solution offered a resistance of 31.6 W (March 2017) (2)
in a conductivity cell at 298 K. If the cell constant
of the cell is 0.367 cm.
Calculate the molar conductivity of NaOH solution.
(26) State Faraday's first law of (March 2017) (3)
electrolysis.
(27) Construct a labelled diagram for the (March 2017) (1)
cell: following
ZnZn29 (1 M) || H® (1 M)| H,(g.
atm)| Pt 1
(uly 2017
28 Write the cell
representation and calculate equilibrium constant for the following redox reaction: (2)
N+2Ags(ag) (1 M) Ni2tag(1 M)+2Ag at 25°C E°Ni -0.25 V and Ag =0.799 V
4) Draw a neat and labelled
(huly 2017) (3)
diagram of lead storage battery.
(March 2018) (2)
How
many faradays of electricity are required to produce 13 gram of aluminium from
solution? (Given: molar mass aluminium chloride
of Al 27.0 gram mot") =
32)
(A0.799 V, E° -2.37 V) (uly 2018) (2)
much quantity of electricity in coulomb is
required to deposit 1.346 x 10-s kg of Ag in 3.5 minutes
AgNO sohution? (Given: Molar mass of Ag is 108x 103 kg mot ) July 2018) (3)
0 Write features of
34) Define resistivity. reversible process. (July 2018) (1)
(uly 2018) (1)
l861 T any Faradays of electricity are required to produce 6g of Mg from MgCl,? (March 2019) (2)
olar solution at 25°C is 2230l cm mol,
What is its conductivity of 0.05 BaCl,
M
conductivity? (March 2019) (2)
electrochemical series. Write its applications. (March 2019) (3)
Standard e.m.f. of the following cell is 0.463 V
CuCuao 1Ag1ASs M)
(aq)
(1 M)
electrode?potential of Ag electrode is 0.800 V,
of Cu ndard
what is the standard potential
(March 2020) (1)
UTTAM's XII Chemistry Papers
140 Solution
electrochemical cel
t e cell reaction and calculate E° cell of the following
AlsAl"(ag Zn jaq"jaq
A
1 M)
-1.66 V, E
M)
= - 0.76 V.
(March 2020) (2
*ODetine terms: (a) Electrochemical serics (b) Corrosion. (March 2020) (3
write two
applications of electrochemical serie
Write the value of 2.303RT in Nernst cquation. (Sept. 2021) (
F
Calcilatonductivity of o.01 M acetic acid at 25°C Q- cm is 18 mol"
d e g r e e of dissociation in 0.01 M solution and dissociation consm o l .
400 concentration is 2 cm (Sept. 2021) (2
(3)State Koki uctivity of acetic acid at zero
two
of ions. Write and explain
applications
pplications of w ot independent migration (Sept. 2021) 14)
electrochemical series. Write unit of cell consta to Zn?
Ha moles of electrons are required for reduction of 2 moles of Zn
*
How
many faraday of electricity will be
Define reference required? (March 2022) (2)
electrode. Write the functions of salt
D w neat,
labelled diagram of standard briag (March 2022) (4)
hydrogen electrode (sH
6 CHEMICAL KINETICS
Distinguish between molecularity and order of the reacuon
(March 2008, 2009, 2011, 2020; Oct. 2008, 2009, 2010, 2013, 2014)
W h a t is 'rate law' ?
Show that half life of first order chemical reaction (2)
is initial
concentration of the reactant. inaepetldc O
Deine rate
of reaction. Derive integrated (March 2008) (3)
rate equation for first order reaction.
(4) State rate law. Write 'one' (Oct. 2008, 2010; March 2010, 2011) (3
example of it.
( What is half life
period of a reaction? Show that half-life (March 2009) (2)
for first order
reaction. period does not depend upon the initial concentration
(6) Define Rate law'. (Oct. 2009) 13)
(7) What is Pseudo first (IMarch 2010) (1)
order reaction?
(8) Define Molecularity' of Explain with suitable example.
chemical reaction. (March 2009, 2010) (2)
(9) Consider the reaction: (March 2010) (1)
3 S0ag
What are the values of the
13 (ag) +2S04*(ag) at particular time t, - dsodt =
2.2 x
10-2 M/s.
following at the same time?
(a) [ l
dt
(b)dS0,21 (c)d
dt
dt
( 101Define activation energy. Calculate (IMarch 2013) (3)
activation
four times when temperature changes irom 30°C energy 1or a reaction
of which rate
(11) Write molecularity of the following reaction:
to 50°C.
(Given R 8.314 JK-1 constant becomes =
(13) Derive the relation between half-life period and rate constant
*
In an
(a) Rate of
disappearance of ammonia (b) Rate of
Calculate:
formation of water.
(Oct. 2015) (3)
Question
ru of
Boara
iUmnar
Zero order reaction' 141
efine
De.
hical
method to
EXpla der reaction x > y,determine (March 2016) (1)
1 8
given rcaction.
a
(March 2016) (2)
calculate r a t e c o n s of the reaction. np sample
ie of
compound remains unr
compound
n stant of a first unreacted in 45 minutes.
The
order reaction (March 2016) (2)
are
0.58 s'
(21
the energy of
What i sthe. activation for the at 313 K
and 0.045 s'
reaction? at 293 K.
the
henius
Arrhenius
equation for a first order July 2016) (3)
In
.Imoll respectively. reaction,
the values
temperature will its halfoflife'A' and
122) 98.6kJ At what
a n d
E,' are 4 10° sCc
in the
"he action occurs
following two steps:
) Hzue2NOe N,OH,O
(p) N,OHate)
r ot
-NauH,O
is the rate of NO in the
mechanism? What is the
Wh
the following data for the molecularity of the elementary steps? (July 2017)
liquid phase reaction A > B,
(24)
Fro
determine the order of 4
rateconstant: reaction and calculate its
0 600
t/s
A]/Mol L1 0.624
1200 1800
0.4465 0.318 0.226
A certain reaction occurs in the following steps. (July 2017) (3)
(25)
(i) CtO3e ClO* O2tg)
iCiogO Clt O2g
la) What is the molecularity of each of the elementary steps?
b) Identify the reaction intermediate and write the chemical equation for overall reaction.
(March 2018) (2
D6 The reaction A + B> products is first order in each of the reactants.
(a] How does the rate of reaction change if the concentration of A is increased I factor 3?
(b) What is the change in the rate of reaction if the concentration of A is halved and concentration
of B is doubled?
(March 2018) (2)
(27) Define the order of chemical reaction.
Find the overall order of the following reactions:
CC4g t+ HCg Rate =k{CHC1| [Cl]
a) CHCl19* C
(b) 2NO O21 2NO21g Rate k[NO]20, (July 2018) (2)
R8) In a irst order reaction A -~ product,80 % of the given sample of compound decomposes in 40 min. What is the
half life period of the reaction? (uly 2018) (3)
Write Arrhenius equation. Derive an expression for temperature variations. (March 2019) (3
(29 is 0.3M.
The rate of a first order reaction, A > B is 5.4 x 10-6 Ms when [A]
S0 (March 2019) (1)
Calculate the rate constant of the reaction.
(March 2011) (1)
is 6.0 h. Calculate the rate constant.
04 The half life period of a first order reaction and its rate constant. (March 2020) (1)
half life of zero order reaction
Write the mathematical relation between first order reaction with
D e n n e instantaneous rate of reaction. Explain pseudo (March 2020) (3)
suitable example. (Sept. 2021) (4)
for first order reaction.
34)
Denne isomorphism. Derive integrated law expression (Sept. 2021) (2)
pseudo-first order reaction? Explain
with suitable example
nat is the expression for
half life and
order reaction. Obtain (March 2022) (3)
DEnne
half life of first
Tate constant of the first order reaction.
elementary reacion (March 2022) (1)
aentify the molecularity of following
NO 1 NO3 O
OF GROUPS 16, 17 AND 18
ELEMENTS (March 2013) (2)
Draw
7 of PCl, and PCI
2) What structure
and write geometry
ammonia? (March 2013) 13)
on
is the action of the following reagents (c) Na metal
(a) Excess of air (b) Excess
of chlorine
to group
16:
3) Explain the properties
with
reference
c) lonisation enthalpy
UTTAM's XII Chemistry Papers
142 lution
(4) What is the action of chlorine (Cl) on the following: caustic soda.
concentrated
(a) Cold and dilute caustic soda. (b) Hot and
(8)
(a) Hydrogen bonding (b) Oxidation state (c) Polyhalide ions.
Describe anomalous behaviour of oxygen as compared with other elements of group l6 with reference
(Oct. 2014)
to-
(March 2014) (3
(a) Magnetic property (b) Oxidation state (c) Hydrides
(9) Draw the structure of: 13)
(a) Orthophosphoric acid (b) Pyrophosphoric acid (Oct. 2014)
(10) Explain the structure of sulphur dioxide.
(11) Write molecular formulae and structures of the following compounds:
(IMarch 2015) (2(2)
(a) Dithionic acid (b) Peroxy monosulphuric acid
(c) Pyrosulphuric acid
(12) Draw structures of: (a) Chlorine trifluoride
(d) Dithionous acid
(b) Chlorine pentafluoride.
(IMarch 2015) (4
(13) What is the action of dioxygen on (2)
(a) Calcium (b) Iron (c) Carbon disulphide?
(Oct. 2015)
(14) What happens when dilute sulphuric acid is treated with (a) Fe (b) CaF2 ? (3)
(15) What happens when thin copper leaves are thrown in jar containing chlorine? (July 2016) 2
(16)
(July 2016)
H,0 is liquid while H,S is gas at room temperature. Explain. 2)
(17) Write the electronic configuration of the following elements: (July 2016) 2)
(a) Sulphur (Z = 16) (b) Krypton (Z = 36)
(18) Write any 'two' uses of each of the
following: (a) H,SO, (b) Chlorine
(IMarch 2017) (2)
(19) What is the action of concentrated
sulphuric acid on the
(March 2017) (2)
following:
(a) Phosphorous
pentachloride (b) Copper (c) Potassium chlorate.
(20) Write balanced chemical equations for the following: (July 2017) (3)
(a) Action of ozone on hydrogen peroxide.
(21) Write the molecular and structural formulae of: (March 2018) (1)
(a) Thiosulphuric acid (b) Dithionous acid
(22) Draw the structure of IF, Write its geometry and the (March 2018) (2)
type of hybridization. (March 2018) (2)
(23) Explain the following with the help of balanced chemical
equation:
(a) Bleaching action of SO.
(b) Dehydration of formic acid by concentrated
HSO4,
(c) Burning of benzene in presence of excess of
dioxygen. (July 2018) 3
(24) Write structure and molecular formula for sulphurous acid.
(25) Write any four points of difference between fluorine and other (July 2018) (1)
(26) Write chemical reactions for different steps in the manufacturehalogens.
of sulphuric acid
(July 2018) (2)
lead chamber process. by
(27) Explain the (March 2019) (3)
following properties of group 16 elements:
(i) Electro negativity (ii) Melting and boiling points
(iii) Metallic character (iv) Allotropy
(28) What are oxides? Write different types (March 2019) (4
of oxides with
(29) Write the name and formula of one ore of zinc.
one
example each. (March 2019) 14)
(March 2020) ()
(30) Write two uses of each of the following : (a) Helium
(b) Neon. (March 2020) (2)
(31) Draw the structure of sulphurous acid. Explain
pentahalides.
why nitrogen does not form
(IMarch 2020) 3
(32) Explain interhalogen compounds.
How is oxygen prepared from the following compounds?
(a) KCIO (b) PbO2. (March 2020) 14)
(33 Write the name of interhalogen compound of chlorine which has
structure. square pyramidal
(34) Draw the structure of (Sept.2021)
sulphurous acid. Write two uses of helium. (Sept.2021)
(35) Write chemical equations involved during manufacture
contact process. Write two uses of of sulphuric acid
sulphur dioxide. by
(36) What is the action of concentrated (Sept.2021
H,SO4 on: (i)CaF, (ii) Cane sugar.
What is nucleotide? Write reaction for the
preparation of (Sept. 2021) 4
(37) What is the action of selenium on
magnesium metal? polyacrylonitrile (PAN). 2o22)
(38) Explain the trends in the
following atomic properties of group 16
(March
(Mar
Write chemical composition
asition of
fgurations of first two ele
haemante. Write the
Cmatit
al
Write
DWrite uses
of sulphur.
preparation of
17. names and
sulphur dioxide electronic 143
8 from
Give
the observed uter TRANSITION AND INNER
electronic
sulphur (March 2022) (3)
t)
Why
are compour
asition
of
copper
ured while configuration of
copper (ZTRANSITION
(March 2022) (3)
(2) xplain the of
d-Block elements
the d-block elements form in the
those of zinc -29 ELEMENTS
coloured periodic table.colourless?
Why
3/
4 Give reasons:
the
al Zinc
white
salts are compound? (March 2008) (3)
metal shows
(b) Tra sition catalytic (Oct. 2008)
(2)
ganese shows variable properties
oxidation
(March 2009) (2)
5) Writethe position of zinc
is the, seneral outer
30) in the states (Mn, Z =25)
6)
What
.he following electronic periodic table and write its
(7) Explai characteristicsconhguration
la) Tendency to form complexes
of
of electronic
transition series
transition elements: configuration. (Oct. 2009)
(3)
(b) Catalytic property. elements? (Oct. 2009)
(2)
sition elements show variable (March 2010) (1)
ransition elements?
hat are trar oxidation states.
ectronic configuration of Co Explain their Explain. position in (Oct. 2010)
(At. No.
nistinguish between Lanthanides and 27 Modern Periodic
Table and write (March 2011)
(2)
(2)
dolanthanides form coloured Actinides. the
nes the basicity of compounds? (March 2008, 2010; Oct. (March 2011) (2)
atomic number. hydroxides of lanthanide series 2015; July 2016)
elements decrease (2)
Write with increasei (March 2008) (2)
the outer observed electronic
(a) Gadolinium (64) configuration of:
(b) Ytterbium (70). (Oct. 2008) (2)
sA What are lanthanons Give names and
nlain why does lanthanum forms symbols of any 'two
rare (Oct. 2008)
(At. No. La= 57, Ce = 58)
La" ion, while cesium formsearths. (March 2009) (2)
2)
Ce ion.
n6 Write expected electronic configurations of (a) Nd
(Z 60) (b) Tm (Z
69)
=
(March 2009) (2)
17 Explain 63Eu and 7oYb show +2 oxidation state. =
(Oct. 2009)
18 Write the general outer electronic configuration of (2)
lanthanides and actinides.
(Oct. 2009) (2)
19 Write the expected electronic configurations of (a) (March 2010) (2)
20) What are 'Actinides? Write their Europium (Z =
lanthanoid
Cerium (Z Fo con Contraction? Explain, (July 2018) (2)
m (Z= 58) forms Ce* ion?
=
What
dare 'd' and
f block elements?
144 UTTAM's XII Chemistry Papers Sol
(37) What is the
action of the following
(a) Water on
lanthanola (c) Nitrogen, heat
(July 2018)
(38) (b) Sulphur, heat of sulphur
Explain the position of actinoids periodic table. What
is the action
solution if
Oactinoids in the per100
On lanthanoids? cCalculate
on lanthanoid
its atomic themagnctic mome
n e magnetic moment
of divalent
ion in aqucous
of inium.
(March 2016)
(July 2017)
a m e s and chemical formulac of two' mincerals als from
metals irom their their ores. (Juln
mes
of various steps involved in the extraction
of pure (July 2017)
nat iis the
(43) What action of carbon on the following metal
Fe,O in blast furnace. oXI
(44) What is (March 2018)
(45) clectrometallurgy?
Wnite the name and chemical formula of one ore of
(March 2020)
(March 2020) 2
(46) Define flux. Write zinc
a note
leaching process.
on
L n e general electronic configuration of lanthanoids. Why are most or the
(March 2020)
compounds of transition metals coloured?
T exhibits +2 and +3 oxidation states. Write their electronic coniguration.
(March 2020) 1
Which will be more stable? Why? (Sept. 2021) 12
Why La(OH), is the strongest base, while Lu(OH), is
the weakest base
e wo applications of catalytic properties of transition metals and compounds.
(50) Write the chemical formula of (Sept. 2021) 13
Haematite.
(51) Define mineral. (Sept.2021)
S2 Calculate spin only magnetic moment of
divalent cation of transition metal with
(March 2022) (L
atomic number 25. Salts of
Ti4 are colourless. Give reason.
(March 2022) 14
(1 Write the formulae of the
9CoORDINATION cOMPOUNDS
following compounds-
(a) Sodium hexanitro-N-cobaltate
(I)
(b) Tetraaquodichlorochromium
(11) chloride
(c) Potassium
tetracyanoaurate (1II) ion.
(2) Write applications of co-ordination (March 2013) (3)
(3) What is effective atomic number compounds medicine and electroplating.
in
(EAN)? (Oct. 2013) (2)
Calculate EAN of
cobalt
(Z 27) in and[CO{NH,),|3
(4)
Classify the following ligands into monodentate and of (Z 30) in zinc [Zn{NH)4] SO. (March 2014) (3)
(a) Ammonia (b) Carbon monoxide
polydentate -
291.
(July 2018)
(17) Calculate the effective atomic number =
uly 2018)
atomic of
(181 EXplain ionisation number (E.A.N.) of
(19) What are bidentateisomerism in co-ordination copper in
(March 2019) 3)
Ligands? Give one
example,compounds with
(Cu(NH,12*. (Z of Cu (March 2020) (2)
suitable example. 29)
=
(20) Ilustrate with example, the a
Write two difference between a (March 2020) (2)
applications of coordinate
compounds. double salt and (Sept. 2021) (2
co-ordination cor
compounds.
(Sept. 2021) 3
Summary of Board Questions
(21) Write lUPAC name of 145
(22) Write the |Fe(CO),] complex.
of
isomerism in the following
name (Sept. 2021) (1)
Cu{NHlPtCI,] and Pt|(NH,J,|CuCll complexes:
(23) Explain monodentate and ambidentate (March 2022) (1)
(24) Explain cationic, anionic and neutral ligands with example. (March 2022) (2)
sphere complexes with cxample.
(March 2022) (3)
| 10 HALOGEN DERIVATIVES
(1) Write a note on Wurtz reaction and
mention
any two uses of iodoform.
(2) Explain the mechanism of alkaline (March 2008) (3)
(3) Define optical activity. Explain hydrolysis of bromomethane.
(March 2008)
optical (4)
(4) State and activity of 2-chlorobutane.
explain Markownikoff's rule' with a suitable
(March 2008, Oct. 2008) (4)
(5) Define asymmetric carbon atom. example. (Oct. 2008, 2014) (2)
(6) What is the action of
following reagents on ethyl iodide? (Oct. 2008, March 2011) (1)
(a) Aq. KOH (b) Alcoholic KCN (c) Silver acetate
(7) Explain the mechanism of alkaline (March 2009) (3)
hydrolysis
(8) Give the structural formula and IUPAC name
of tert-butyl bromide.
(March 2009, 2010, 2017) (3)
of iso-butyl bromide.
(9) Complete the following reaction and identify A, B, C and D with correct formulae.
(March 2009) (1)
CH Br OSO BA
C Cold HI CH.OH D +
(Oct. 2010 (4)
10) Why does p-nitrochlorobenzene undergo displacement reactions readily with attackof
nucleophilic OH- ion?
(11) Write balanced chemical equations for the action of- (March 2013) (2)
(a) Phosphorus trichloride on propan-2-ol.
(b) Hydrogen bromide on styrene in the presence of a
peroxide.
(c) Methyl bromide on silver propanoate.
(12) Distinguish between SN' and SN mechanisms. (March 2013) (3)
(13) Write the structures of
(March 2014) (2)
CH3
a
NH3 NaNO,
K(A) Cu,Br (B) +N,I
HBr, 273 K
(6) H,C-CH, - CH - CH, Alcoholic KOH (A)+ (B) + 2KBr + 2H,0 (July 2016) (2)
12 ALDEHYDES,
acetalde h y dS
( c )
e?o d i u m b i s u l p h a t e
(March 2008)
on
reagents
() What is the action of following (b) Ammonia
S7 acetaldehyde
How is cyanohydrin. (Sept. 2021) (1)
58) Write benzophenone none prepared from benzonitrile?
pie (Sept. 2021) (2)
a note
on 'aldol' ndensation reaction of ethanal. Write chemical
) avolved when
cond
when benzaldehyde is treated with concentrated caustic potash. (Sept. 2021) (4)
Write thee name
1 is treated with 2,4-dinitrophenyl hydrazine,(March
of acetone
product formed, when 2022) (1)
the
following
reaction (March 2022)
150 B
trom
(60)
ldentif
A
CH
and
(March 2022
the
2CH,- C - 0
acid
from:
What
is
acetic
preparation of
(ii) Acetyl chloride
with
example.
Wnite ketones
(61)
(i) Dry ice aliphatic
ication
of
classitica
Write the ? 13 AMINES
(62)
sodium
hypoidite
on
acetone
Diethyl
amine.
(March 2008) (
and
and
by
N - E t h y l e t h a n a m i n e
(Oct. 2008)
ethanamine
How
is
reaction of: (a) Ethyl chloride
on
Write
acetylation
is the
action ofacetyl 14
amines?
What
are
oWhat N-N-dimethylethanamine?
reactions.
(4) ldentify A, B,
C and D.
Write complete
CH C
CH D (March 2009) 14
Na +R-OH A CH B (b) O x i m e ?
of amines.
Explain basic nature
(6) What is the action of-
(a) Nitrous acid on ethyl
amine (Oct. 2010 (2)
acetonitrile?
(b) Mixture of sodium
and alcohol o n (Oct. 2010) 12)
salt'?
(7) What is a Quaternary ammonium
of ethyl methyl amine. (IMarch 2011) (2)
(8) What are amines? Give IUPAC name
CH3
(11) Write a short note on Hoffmann bromamide degradation. (March 2013) (3)
(12) How is nitromethane prepared from the following?
(a) alkyl halide (b) a-halogen carboxylic acid (c) a-nitroalkene (Oct. 2013) 13)
(13) Explain Hoffmann bromamide degradation reaction. (Oct. 2013; March 2017, 2018) 12)
(14) What is the action of the following reagents on aniline?
(a) Bromine water (b) Acetic anhydride (c) Hot and conc. sulphuric acid (March 2014) (3
(15) Identify the compound 'A' and B' in the
following equation:
CH, -CH, + HNO 423-600 K ASn/ conc.H B' +
H,O (March 2014) 12
(16) What will be the action of the mixture of sodium
nitrite and dillute
(a) Ethyl amine (b) Aniline (c) Triethyl amine? hydrochloric acid on:
(Oct. 2014)
(17) How are propan-1-amine
and
propan-2-amine prepared from oxime? (2)
(Oct. 2014
(18) How is ethyl amine prepared from methyl iodide? 2
(March 2015)
(19) Write a note on Gabriel phthalimide synthesis.
(March 2015)
3)
(20) What is the action of acetic anhydride on:
(a) Ethyl amine (b) Diethyl amine (2)
(21) What is the action of nitrous acid on- (Oct 2015)
H,O
Summary of Board Questions 151
(26) What is the action of mixture of
NaN0, and dil.HCl on
(a) Ethylamine (b) Aniline (c) Diethylamine (March 2017) (3)
(27) How is nitroenthane converted into:
(a) Ethyl amine (b) N-ethylhydroxyl amine
What is the action of (c) acetic acid ? (huly 2017) (3)
(28)
(29)
p-toluinesulphonylchloride
What is the action of lithium
on
cthylamine and diethylamine? (March 2018) (2)
aluminium hydride in the
following compounds? presence of ether on the
(1)
14
Give chemical reactions of glucose with
BIOMOLEcULES
(a) Hydroxyl amine (b) Bromine water.
(2) How will you convert glucose into: (a) Gluconic acid
(March 2008) (2)
(b) Saccharic acid (Oct. 2008) (2)
(3) How is the glucose prepared from sucrose?
(March 2009, 201 7) (2)
(4) Define the term Simple protein'.
(Oct. 2009) (1)
(5) Explain the term proteins.
(March 2008) (1)
(6) Classify the following carbohydrates
(a) Cellulose (b) Maltose (c) Fructose.
(Oct. 2009) (2)
(7) What are conjugated proteins? How is peptide linkage formed in proteins? (March 2010) (3)
(8) What is the action of the following on glucose?
(a) Acetic anhydride (b) Hydroxyl amine.
(Oct. 2010) (2)
(9) What happens when glucose is treated with-
(a) Bromine water (b) Dilute nitric acid (c) Hydrogen cyanite (HCN) (March 2014) (3)
(10) Describe laboratory method for preparation of glucose. Write the reaction that indicates
the presence of CHO group in
-
(a) bromine water (b) dilute HNO (c) Hydroxyl amine uly 2016) (3)
(18) Define enzymes. How is peptide linkage formed? (uly 2017) (3)
(19) What happens when glucose is treated with
(a) hydroxylamine (b) hydrogen cyanide. (July 2017) (2)
(20) How glucose is prepared from cane
suger?
Write the formula of the (March 2018) (3)
complex copper (1I) hexacyano ferrate (1).
What areamino acids? Write the correct reaction for formation
amino acids. of peptide bond Derweet (March 2018) (2)
(22) How is glucose (July 2018) (2)
prepared from starch?
UTTAM's All Cemistry Papers
(July 2018) Solution
(July 2018)
152
Draw the
structure
of Thymine. triacylglycerol 1s
(d) amine
(23) in
n e
functional group
present
( ) ester (July 2018)
(b) ether
(March 2019)
glucose?
in a
-
D -(t)
-
linkage
formed?
(March 2019)
number of
hydroxyl
groups
present
method? Define
How is peptide hormones.
(March 2020)
(26) Write the
prepared by
commercial
a-D-(+)-glucopyranose.
(March 2020) 2
glucose
1 Haworth
Write
rojection
f o r m u l a of
d e n a t u r a t i o n of
proteins. (Sept. 2021) 3
(28) ? Explain
are
m o n o s a c c h a r i d e s
RNA. with
examples. (Sept. 2021)
What
(30) Write the name of sugar present in
of
molecular
shapes
(IMarch 2022) (2)
the basis
(March 2022) 2
oroteins on
Write classification of with exampic
an acid.
(31) in protein of adipic
peptide linkage
structure
Explain formation of
Write
2 p r e p a r a t i o n of
glucose.
(33) Write commercial method of
CHEMISTRY
POLYMER
INTRODUCTION
TO
15 (March 2008, 2010; Oct. 2009t
involved in preparation of
Nylon-b6. 2
W r i t e chemical reactions
prepared?
(October 2008) 13
What synthetic fibres? How is terylene (March 2009, 2011; Oct. 2009, 2010)
(2 are