PREVIOUS B

IN
A S K E D

2017)
(2)
SUMMARY OF QUESTIONS

SOLID STATE
(March
2013,
2014,

farch 2013) (2)

(2)
1 solid.

(1) Distinguish between crystalline solid and amorpnou of 19.30

kg dm (Oct. 2 0 1 3 )
(3)
density face-centered
(2Gold occurs as face
centered cube and
has a
(2)
ntered ana m a s s of Au 19)
cube
has
-

which
(Oct. 2013)
ate atomic
.nC
radius of gold. (Molar ystal
gcmn
Calculato the
Calculate d e n s i t y 10
(3 number of atoms prese and
cubic (fcc)
crystal lattice having edge lengn
o100
of pm
100 pm an
(March 2014) (3)
What are Schottky defect and Frenkel delect density
of g. 8.966
cm
mol'
and

63.5g.
oace centercd cubic erystal lattice of copper has ofcopper
is nass

t h e volume of the unit cell. Given molar Find

the
Avogadro number N is 6.022 x 10°. 7.86
g.cm,
(Oct. 2014) (3)
Aunit cell of and density
iron
crystal has edge length pm
288 ice. (March 2015) (2)
b e r of atoms per unit cell and type of the crystal a
Number, NA
6.022 *
10
en: Molar mass ofiron =
56 g.mo'.Avogadro's
Explain
3
(March 2015) (3)
impurity defect in stainless steel with alag
density of
8.55 kg/an
S crystallises as body centered cube (BCC) and has
Niobium 93J. =

unit Cel
niobium
C late the atomic radius of niobium. (Given: Atomic s t r u c t uofr e . The edge length of
mass the

ver crystallises in a c e - c e n t e r e d cubic crystall

(Oct. 2015) (3)
TOund to be 408.7 pm. Calculate density of the unit celu
Given: Molar mass of (March 2016) (2)
silver
is 108 g. mol"|.
w h a t is ferromagnetism? Iron (Z = 26) is strongly ferromagne 3alculate the volume o
v e r crystallises in FCC structure. If density ofsilver is 10.51 gCm (IMarch 2016) (3)
|Atomic mass of silver (Ag) 108 (July 2016) (2)
g. mo"|
=

A face centered cube

(FCC) consists of many atoms? how Expla
the edge length
structure with
oDetermine the density of chloride which crystallizes in BCC type
Cesium Predict the co-ordination n u m b e r
of

of Cs and C1 are 133 and 35.5 respectively. (July 20116) (3)

CS ion E A asses
if rcs
1.69 and rc 1.81 A.=

Calculate the percentage efficiency of packing in case of simple cudic (March 2017) (2)
(15) Classify the following molecular
solids into different types
(a) Ammonium phosphate (b) Brass (c) Sg molecule (d) Diamond. (July 2017) (2)
4oAetalcrystallises into two cubic faces namely face centered (FCC) and body centered (BCC),
Wose unit cell edge lengths are 3.5 Å and 3.0 A respectively. Find the ratio of the densities of
FCC and BCC.
(July 2017) (3)
aculate the number of atoms in a unit cell of a metal crystallising in face centered cubic structure. (2)
(18) lonic solids are hard and brittle. Explain.
(March 2018) (2)
(19) The density of iron crystal is 8.54 gram cm3. If the edge
length of unit cell is 2.8 A and atomic mass is 56 gram
mol, find the number of atoms in the unit cell.
Given: Avogadro's number = 6.022 x 1023, 1 Å = 1x 108 cm]
(20) Classify the following molecular solids into different types:
(March 2018) (3)
(a) HC1 (b) CO (c) Solid ice
(d) SO (July 2018) (2)
(21) The density of silver having atomic mass 107.8 gram
mol is 10.8 gram cm. If the
cell is 4.05 x 10-5 cm, find the number of silver atoms in the unit cell. edge length of cubic unit
(N6.022 x 1023, 1À =10-8 cm)
(221 What is the ratio of octahedral holes to the number of anions in (July 2018) (3)
hexagonal closed packed structure
(23) Define Anisotropy. Distinguish between crystaline solids and amorphous solids. (March 2019) (1)
(24) Classify the following into different types: (March 2019) (3)
(a) Silver (b) (c) Diamond
P (d) NaCI
(25) Unit cell of a metal has edge length of 288 pm and density of 7.86 g cm-3 (March 2020) (2)
Determine the type of crystal
lattice. (Atomic mass of metal 56 g =
mol-
What is the coordination number of atoms in simple cubic crystal lattica (March 2020) (3)
(26)
127) A compound forms hexagonal close packea ncp) structure. What is the number
f (Sept. 2021) (1)
il Octahedral voids (ii) Tetraneara VOlds n ) 1Otal voids formed in 0.4 mol of it?
with
consequences
of Schottky defect reasons.
(Sept. 2021) (3)
the
(28) Write cubic cells. The edge length ofs
into f a c e - c e n t r e d
[Molar mass of gold1llis
(March 2022) (2)
(29) Gold crystallisesCalculate the density of gold. nol
4.08 cm.
x 10-8
metal deficiency
defect with example. (March 2022) (2)
(30) Explain (134) (March 2022) (2)
n n i a yD/
Board
f Board Questions

135
2 SOLUTIONS
State and ad explain van't Hoff-Boyle's law.
Colligative operties'.
Define 'Co
(March 2008) (2)
tion'.
Define Tsotonicsolutio
(Oct. 2008) (1)
Hoff-Avogadro's law.
State vant (March 2009, Oct. 2013) (1)
Detine:"
"Ebullioscopic stant' (March 2009) (1)
61 Defhne Solution
(Oct. 2009) (1)
71Define o s m o t i cp r e s s u Derive an
equation for (Oct. 2009; March 2011)
determination of molccular weight from osmotic (1)
pressure.
Define a ealution. Explain the terms solute and solvent.
solu (Oct. 2010) (2)
olationship
Derive t h e r e l a t i o between relative lowering of vapour pressure and molar (March 2011) (2)
mass of non-volatile
s o l u t e .

O Define osmosis. (March 2013, 2017) (2)

aw's law. How
law. How does solubility of a (March 2013) (1)
Henry's gas in water varies with the
t State
temperature?(Oct. 2013; July 2017) (2)
is boiling point?
A2What
the amount of CaCl, {van't Hoft factor, i
(IMarch 2013) (1)
1 3 ) C a l c u l a t e

pressure at i s 0.75 atmosphere.

=

2.47) dissolved in 2.5 L solution so that its osmotic

PnMolar mass of CaCl, isS 11l g. mo, R = 0.082 L. atm K' mot'
in Why do aquatic
animals prefer to stay at lower level of water (March 2014) (3)
14
Expla during summer? (March 2014)
(2)
ning 0.73 g of camphor (molar mass 152 g.mol-) in 36.8 g of acetone
solution containir

15 t 56.55°C. A solution of 0.564 g of unknown compound (boiling point 56.3°C)

in the same weight of acetone
Calculate the molar mass of the unknown compound. boils at 56.46'C.
(Oct. 2014) (3)
efne van't Hoff factor. How is it related to the degree of dissociation?
Defirn
(Oct. 2014) (2)
constant.
17 Define: Cryoscopic (Oct. 2014, July 2018) (1)
1S Derive van't Hoff general solution equation. (March 2015, 2019; July 2017) (2)
a 10x 10-3 kg of urea when dissolved in 0.0985 kg of a solvent, decreases freezing point of the solvent
by 0.211 K. 1.6 x 10 kg of another non-electrolyte solute when dissolved in 0.086 g of the same solvent
depresses the freezing point by 0.34 K. Calculate the molar mass of the another solute.
Given: Molar m a s s o f u r e a = 60]
(March 2015) (3)
20) Define ebullioscopic constant. Write its unit. (Oct 2015) (2)
21 What is the effect of temperature on solubility of gas in a liquid? (Oct 2015) (2)
22) Define boiling point. Write the formula to determine molar mass of a solute using
freezing point depression method. (March 2016) (2)
23) The vapour pressure of pure benzene is 640 mm of Hg. 2.175 x 10-3 kg of non-volatile
solute is added to 39 gram of benzene, the vapour pressure of solution is 600 mm of Hg.
Calculate molar mass of solute. [C = 12, H 1 . (March 2016) (3)
24) Why is molality of a solution independent of temperature ? (March 2016) (1)
L5) Define: (a) Osmosis (b) Freezing point. (July 2016) (2)
at 319.81 K. What is the molecular
40.795 g of sulphur is dissolved in 100 g of Cs,. This solution boils
1ormula of sulphur in solution? The boiling point of CS, is 319.45 K.
Given that K, for CS, = 2.42 K kg mol and atomic mass of S = 32.) (July 2016) (3)
(July 2016) (1)
27) State Henry's law. 28OK.
1.8 x 10-3 kg has the osmotic pressure of 0.52 atm at

o n of a substance having
mass

aiculate the molar mass of the substance used. (March 2017) (2)
Volume = 1 dm3, R = 8.314 JK- mo| dissolved in
non-volatile solute was
353.23 K. When 1.80 gram of
u n g point of benzene is to 354.11 K.
Calculate the molar
mass solute. of (2)
or benzene. The boiling point
is raised (March 2017)
td (uly 2017 (1)
for benzene 2.53 K mot']
Define: Osmotic pressure. water. Its
osmotic pressure at 12c (2)
is dissolved in 2000 cm3 of solute.
(ruly 2017)
An 169 gram mol-l) the m a s s of the
(2)
c Substance (M
=
calculate
'an 0.0821 L atm.
K-l mol,
was If R =
of solute. 2
2 nd to be 0.54 atm. of boiling point
and molar
mass

Tive the relation bet

etween
elevation

3 Defne: the number of moles (July 2017 (2

4 22.22 Semipermeable membrane.in 300
Calculate
water.
grams
of =
60 gram mol
gram of urea wa
was
dissolved
Molar mass of u r e a
of ure s o l u t i o n . (Given:
nolaity of the
urea
u
 UTTAM
C a l c u l a t e the
th SOuuOn
K.
2 7 8 . 4

gram is
is 100
b e n z e n e

weight

136 point
of pure molecular
(July 2018)
having
freezing
(85) What is freczing The solute

point of liquidr
quid? " ofa 5.12 kgmo
freezing point of the
a
2.0
when
gram

(March 2019) 13
added
(36) Define the
to 100 gram of benzene. IK, Jor Hypotonic
s o l u t i o n

of
one
atmosphere

following terms: (ii) p r e s s u r e

(March 2020) 12
solution

(2) Isotonic solution

under

(il) Hypertonic at
50°C

(37) What
(March 2020) (2
oxygen
is the ntration of dissolved
i atm')
partial pressure of oxygen at 50'C 1s mol
dm
and
x 10 solute

for oxugen 1.3

aw
(38) Define:
constant
(a) Molality (b) Osmotic pressure.
molar
m a s s
of a
non
-
law.
volatile

(March 2020) 14
(39) Derive the between and
mathematical point
Hoff-Avogadro's
ression
boiling
elevation of boiling point. State and explain
van't
between
clevation
of
(Sept. 2021) 13
(0)
Define 'Cryoscopic constant. Derive the relation
of it in
. 0.822 g
molar mass of
(41) What is the
solute prepared by
dissolving
(Sept. 2021) 13)
solution K?
0.3 dm'
molar mass Soluteifa aosmotic atm. at 298
by
osmotic
pressure

( Derive an
of water has an pressurc
of n o n
volatile
solute
(March 2022) 12
expression to calculate molar mass

solubility of
measurement. What is
(43) Henry's law constant 10r
for CH,Br is 0.159 mol dm-3
bar-! at 25°C.
Dal
(March 2022) 12
water 1s. CH,Brg pressure of 0.109 (March 2022) (2
B at in same temperature and partial
e n e the following terms: (i) Isotonic solution (ii) Osmo

IONIC EQUILIBRIA4
3
(Sept. 2021, March 2022) 121
Derive the
relationship between pH and pOH.
solubility an
eSolubility product'. Derive the relationship between (Sept. 2021) 13)
solubility product for Pbl,.
ana
Culate the pH of buffer solution composed of 0.01 M weak base BOH
0.02 M of its salt BA.
[K, =
1.8 x 10-5 for weak base (March 2022) 13)

4 CHEMICAL THERMODYNAMICS

G i v e one statement of first law ofthermodynamics and give its corollary. (March 2008) (2)
(2State and explain Hess's law ofconstant heat summation and give its four applications.
(IMarch 2008; Oct. 2008) 14)
(3) Derive the relationship between the heat of reaction at constant pressure and at constant volume.

(4) Prove that, AH = AE+ AnRT.

(Oct. 2008) (2)
(5) Write (March 2009) (4)
any two statements of first law of thermodynamics. Explain, "Internal energy is a state function".
(6) Write the applications of Hess's law. (March 2009) 4
(7) Derive the expression for the (Oct. 2009) (2)
ideal gas
Under what conditions work done by a gas is 'zero'?
work done by an in an
isothermal and irreversible
process.
(8) Distinguish between isothermal and adiabatic process. (Oct. 2009) (4)
Derive an expression for maximum aurng he expansion work dOnc (March 2010) (2)
reversible process. of an ideal gas in isothermal and
(101 Derive an expression for the effect of temperature on the heat of (March 2011) (4)
reaction at constant
(11) Define Enthalpy. Show that AH AE * PAV, at constant pressulre
=

pressure. (Oct. 2010) (2)

(12) Explain the concept of maximum work. Derive an expressian for (3)
expansion of one mole of an
ideal gas. maximum work done in (Oct. 2010)
(13) Prove that AH =
AU+ AnRT. What is the condition
under which
isothermal reversib
OCcupies 13L at 320 K.
AU (March 2011) =
(4)
(14) 300 mol of perfect gas Calculate the work AH?
a constant external
pressure af done in (March 2013) (2)
(a) isothermally against atm. joules when the
e

isothermal and
reversible process. gas expands
(b)
until the volume of gas is increased
(c) into vacuum
by 3L. (R
sign conventions tions of AS in the 8.314 J
=

(15) Explain
with reason

following reactions: mol- K-') (2)

(i) N2(e
+
3H2g 2NH(g) (March 2013)
CO2(s)
(i) CO@
(March 2013) (2)
Summaryof Board Questions
Iculate A H° for the
(16)
following reactions-
2H BOtaq
Given that:
B,O31+ 3H,0
(a) H,BO3aq) HBO,2(aq)
2B,03 +H,Our
137
(b) H,B,07 H,O AHO -0.02 kJ
HB,O7 H,O 4HB0 AH 17.3 kJ
What are th
conditions for
2taq AHO
spontaneous 11.58kJ
D e o r S D

free energy changePP1 e Define entropy. and non-

the rol
Derive the relation
18)
Derive
AH
AnRT. AU =
spontaneous reactions (Oct. 2013
Derive a relation betweer AH and in
terms of (3)
ne mole of a gas expands AU for a
ds by 3L chemical (Oct. 2013
against constant reaction.
2 0 )

a) L. atmosphere (b) Joules a (2)

(Oct. 2013)
Derive the relation between (c) Calories pressure of 3 2)
21)
aA bB
AG and
cC + dD equilibrium constant (K) for the atmosphere. Calculate the
(March 2014)
work
2)
done in
-
uhat is the value of
ASurr for the reaction- (March 2014) (3)
(22)
following reaction at 298K?
6CO216H,° CHi0 +602ie (March 2014) (2)
Given that, AG° =
2879 kJ mol1
AS -210 J
K mol,
Ceate and explain Hess's law
2
24) Derive the equation: W = -P
of constant
AV. heat summation.
(Oct. 2014; July (Oct. 2014 13
2) Define the following terms: 2018; March 2020)
(a) Enthalpy of fusion
(2
(b) Enthalpy of (March 2015) (3)
a Determine whether the reactions with theatomization
following AH and
whether exothermic or endothermic. AS values are spontaneous or (March 2015)
State the reactions are (2)
(a) AH= -110 kJ, AS= +40 JK' at 400 K non-spontaneous.
(b) AH + 40 kJ, AS= -120 JK'
at 250 K
onWrite one statement of first law of (March 2015)
thermodynamics
and its mathematical 3
expression. (March 2015)
281 Derive an
expression for maximum work in isothermal reversible (2)
expansion of two moles of an ideal gas.
n9 Write mathematical equations of first law of (Oct. 2015) (2)
(a) Adiabatic process
thermodynamics for the following processes:
(b) Isochoric process.
130) Define Enthalpy of sublimation. How is it related to (March 2016) (3)
enthalpy of fusion and enthalpy of vaporization?
(31) Calculate C CI bond
(March 2016) (2)
-

enthaply from following reaction:

CH,C+C1 CH,Cl2et HC
414, 243 and 431
AH°= -104 kJ if C-H, CI -Cl and H - Cl bond enthalpies
are
kJ-molF respectively. (March 2016) (3)
S4 Explain the relationship between Gibb's standard energy change of the reaction and equilibrium constant.
uly 2016) (2)
G3) Calculate the standard
enthalpy of the reaction,
2gTaphite* 3H2g CHoie AHO = ? from the following AHO values

(a) C 2 2co3H, AH=-1560k

(b)H 2a9 H,Ou' AHO=-285.8 kJ

uly 2016) (3)

AHO =-393.5 kJ
4 graphite)t 2() CO2g
Define the term 'enthalpy. (March 2017 (2)
system? the
35) Wll happen to the internal energy if work is done by the following data
Ca ula to form ethyl alcohol from
1or the reaction between ethene and
water
.0 7 =-1410 kJ (3
H,OH-1368
Does the cal kJ; AcH° C,Ha( of liquid ethano
(March 2017)
(2)
36) Derive
lculated AH0 represent the enthalpy of formation (IMarch 2017)

7) Writ an pression for maximum work. thermodynamics

for the following
processes
(2)
of the first law of July 2017)
la) ematical expression
Isothermal (b) Adiabatic
(c) Isochoric
(d) Isobaric
 UTTAM's XII Chemistry, Papers Soluti.
data: n
following
the
from = -

483.2 kJ mol
.

(July
enthalpy change2017)
138 CH,COOH
4,H"(CH,COOH)

combustion of if the at 1a
enthalpy of kJ mol';
a m m o n i a ,

(38) Calculate the standard

393.3 kJ mol;
A,H°(H,0) =-285.8
of one
mole
of
March 2018) (3
4,(CO)
(39) Calculate the energy a t
internal
2 9 8 K for
the
f

R
o

=
r m a

8.314
t i o n

JK'
mol")

Nm to 4
(March 2018)
10 Nm
constant oressure
mol
is -42.0 kJ
(Given:
Enthalpy
of
vaporization.

pressure
40
* 10°

the expansion.
at 300k
(b) from a during
(40) Define (a) Enthalpy of atomizatio (July 2018)
a b s o r b e d

reversibly
and heat
energyand
isothermally
(41) 5 moles of helium ex
Calculate
pand

the work done, change

in internal (March 2019)
system. work is done
(R 8.314JK' mol) by the whether

work done State

50°C.
Write the conditions for
maximum
at
(42) reaction

(43) Calculate the work do: in the following March 2019)

on the system or by the system.
571 kJ.
SO12O2ai SO31g formaldehyde.
0 =
-

(March 2019) 3
of
combustion
of 2g
g ofCO,?
(44) The standard enthalpy formation of 22
in the
How much heat will be evolv
(45) For the reaction: 175.8 JK- (March 2020) 2
AH° = +57.24 kJ, AS° =
NOA
At What
2NO21;
temperature the
reaction will be spontaneous

(46) Define: (a) Reversible process for the reaction

(b) Standard enthalpy change
N2i3He 2NH3i
are:
The bond enthalpies (March 2020
N-H (2)
N=N H-H
Bond 435 389
and 6 kJ
OI
works

AHO in kJ mol-l 946 (Sept. 2021)

heat is released by the
system (2
(4 reaction, 2 kJ of
a parucular Calculate AU.
done on the system. 2NHa1g) mol", (Sept. 2021)
218 159 kJ
Calculate the standard enthalpy N,Ha()t of AH°(N-N)
=

(48) 435 kJ mol',

mol-1, AH°(H-H)
=

1 AH°(N-H)
=
389 kJ
sublimation.
property (i)
Enthalpy of from 20L to
(49) Define: (i) Intensive isothermally and
reversibly (Sept. 2021) (4
a r e expanded
2 moles of a n ideal gas mol")
the work done. (R
8.314 =

form 10 L to
JK
30L at 300 K. Calculate reversibly
One mole of a n ideal gas
is expanded
isothermally and (IMarch 2022) 12
(50) done in the process.
Calculate the work data:
15 L at 300 K. from the following
standard enthalpy of
of formation CH,OH
Calculate the
(51)
2H,O AHO= - 726 kJ mol-i
() CH,OH*z°i CO2 ;AH- 393 kJ mol
(ii) C+O19 CO21g) (March 2022) (3)
A H - 286 kJ mol-
(ii) Hazae H,O for
first law of thermodynamics (March 2022) (2)
mathematical equation for the
Write the
(52) (ii) Adiabatic process
(i) Isothermal process

5 ELECTROCHEMISTRY

construction and working of standard hydrogen electrode. 14

Describe the
2008)
(1) (March 2008; Oct.
disadvantages. 4)
Give its two nuel cell. Write its advantages. (March 2009)
construction and working OI h2-0,
21 Describe the electrode potential and give the meaning
tor single
equation (3)
Write Nernst (March 2010)
(3) i n v o l v e d in it.
terms
the
of
e l e c t r o c h e m i c a l series?
Explain its applications in the deter 2010) (2)
What is oxidizing
and reducing agents. (March 2010; Oct.
(4) strength
of
of lead accum
(4)
of relative construction
and working (March 2011)
the atical e
(5) Explain Law and
write mathematical
expression of molar conductivity (2
Kohlrausch
dilution.
6)
State
solution
at
infinite
(March 2013) (2)
of the given in lead storage
battery
battery during discharge.
reactions (March 2013)
Write
the cell cnhution
solution 0.7 g of Ag is deposited after a certain
period of time.
(2
(7)
of AgNO,
In electrolysis quantity
In
electrolysis
of electricity required
ity of electrio in coloumb.
(Molar mass of Ag is 107.9 g mol') (March
2013)
(8) Calculate
the
 O Board Questi
SummarU

(9)
electrode reaction and net cell
Write
rite electrode
139
Zn|Znaq)(0.I M) || Cu2 taqy (0.5 reaction for fucl ccll.
Calculate e.m.f.
ctandard reduction potential (SRP) M)ICu of the following cel a
Dsistance and of Zn and Cu are 0.76
(10 n d 1.46 10" conductivity
S.cm"
ot a cell
containing 0.001 M KCl
V and 0.334 V
respectively. (Oct. 2013) (2)
respectively. What is
the solution at 298K are 1500 2
(11) State the first and second law
of cell constant?
Write any four electrolysis. (March 2014)
(12) applications
With the elp of the
of
electrochemical series. (March 2014)
(3)
(13) equation, AG® (2)
property. nEcell explain that cell (Oct. 2014) (2)
14) How much electricity in terms of
potential is an intensive
tal 20 g of Ca from molten Faraday is required to (Oct. 2014) (2)
Gven: Molar mass of Calcum CaCl, (b) 40 g of Al from produce:
molten Al,O,
15) Draw neat and labelled Aluminium 40g.mol' and are
and
diagram of dry cell. 27g.molt' respectively.)
Arrange the following reducing agents in the order
(Oct. 2014) (2)
conditions. Justify the answer. of increasing strength (March 2015) (2)
under standard state
Element
Als) Cu Cl Ni
EO - 1.66 V
0.34 V 1.36 V 0.26 V
17 Calculate Eeell and AG for the
following (March 2015) (2)
at 28°C:
Mg+Sn" (0.04M)- Mg
18 (O.06M) +
SnEell 2.23 V. Is the reaction spontaneous?
Can copper sulphate solution be stored in
101 Resistance of conductivity cell filled with 0.1an iron vessel? Explain. (March 2015) (3)
M KCI solution is (Oct. 2015) (2)
molar conductivity of 0.02 M KCI 100 ohms, calculate the
solution. conductivity and
Given: Conductivity of 0. 1 MKCI solution is 1.29
(20) Define 'Molar conductivity'. Sm'.]
(Oct. 2015) (3)
(21) Define cell constant. Draw a neat and well (March 2016) (1)
labelled diagram of
(22) Conductivity of a solution is 6.23 105 primary reference
Qcm' and its resistance is 13710 0. electrode.
x (March 2016)
electrodees are 0.7 cm apart, calculate the If the
cross-sectional area of electrode.
(23) The conductivity of 0.02 M (March 2016) (3)
What is its molar
AgNO, at 25°C is 2.428x 10-3 Q-' cm.
conductivity?
(24) What are fuel cells? Write cathode and anode (uly 2016) (2)
reaction in a fuel cell1.
(25) 0.05 M NaOH solution offered a resistance of 31.6 W (March 2017) (2)
in a conductivity cell at 298 K. If the cell constant
of the cell is 0.367 cm.
Calculate the molar conductivity of NaOH solution.
(26) State Faraday's first law of (March 2017) (3)
electrolysis.
(27) Construct a labelled diagram for the (March 2017) (1)
cell: following
ZnZn29 (1 M) || H® (1 M)| H,(g.
atm)| Pt 1
(uly 2017
28 Write the cell
representation and calculate equilibrium constant for the following redox reaction: (2)
N+2Ags(ag) (1 M) Ni2tag(1 M)+2Ag at 25°C E°Ni -0.25 V and Ag =0.799 V
4) Draw a neat and labelled
(huly 2017) (3)
diagram of lead storage battery.
(March 2018) (2)
How
many faradays of electricity are required to produce 13 gram of aluminium from
solution? (Given: molar mass aluminium chloride
of Al 27.0 gram mot") =

(March 2018) (3)

epresent a cell consisting of Mg?* | Mg half cell and Ag'| Ag half cell and write the cell reaction.

32)
(A0.799 V, E° -2.37 V) (uly 2018) (2)
much quantity of electricity in coulomb is
required to deposit 1.346 x 10-s kg of Ag in 3.5 minutes
AgNO sohution? (Given: Molar mass of Ag is 108x 103 kg mot ) July 2018) (3)
0 Write features of
34) Define resistivity. reversible process. (July 2018) (1)
(uly 2018) (1)
l861 T any Faradays of electricity are required to produce 6g of Mg from MgCl,? (March 2019) (2)
olar solution at 25°C is 2230l cm mol,
What is its conductivity of 0.05 BaCl,
M
conductivity? (March 2019) (2)
electrochemical series. Write its applications. (March 2019) (3)
Standard e.m.f. of the following cell is 0.463 V
CuCuao 1Ag1ASs M)
(aq)
(1 M)
electrode?potential of Ag electrode is 0.800 V,
of Cu ndard
what is the standard potential
(March 2020) (1)
 UTTAM's XII Chemistry Papers
140 Solution
electrochemical cel
t e cell reaction and calculate E° cell of the following

AlsAl"(ag Zn jaq"jaq
A
1 M)

-1.66 V, E
M)
= - 0.76 V.
(March 2020) (2
*ODetine terms: (a) Electrochemical serics (b) Corrosion. (March 2020) (3
write two
applications of electrochemical serie
Write the value of 2.303RT in Nernst cquation. (Sept. 2021) (
F
Calcilatonductivity of o.01 M acetic acid at 25°C Q- cm is 18 mol"
d e g r e e of dissociation in 0.01 M solution and dissociation consm o l .
400 concentration is 2 cm (Sept. 2021) (2
(3)State Koki uctivity of acetic acid at zero
two
of ions. Write and explain
applications
pplications of w ot independent migration (Sept. 2021) 14)
electrochemical series. Write unit of cell consta to Zn?
Ha moles of electrons are required for reduction of 2 moles of Zn

*
How
many faraday of electricity will be
Define reference required? (March 2022) (2)
electrode. Write the functions of salt
D w neat,
labelled diagram of standard briag (March 2022) (4)
hydrogen electrode (sH
6 CHEMICAL KINETICS
Distinguish between molecularity and order of the reacuon
(March 2008, 2009, 2011, 2020; Oct. 2008, 2009, 2010, 2013, 2014)
W h a t is 'rate law' ?
Show that half life of first order chemical reaction (2)
is initial
concentration of the reactant. inaepetldc O
Deine rate
of reaction. Derive integrated (March 2008) (3)
rate equation for first order reaction.
(4) State rate law. Write 'one' (Oct. 2008, 2010; March 2010, 2011) (3
example of it.
( What is half life
period of a reaction? Show that half-life (March 2009) (2)
for first order
reaction. period does not depend upon the initial concentration
(6) Define Rate law'. (Oct. 2009) 13)
(7) What is Pseudo first (IMarch 2010) (1)
order reaction?
(8) Define Molecularity' of Explain with suitable example.
chemical reaction. (March 2009, 2010) (2)
(9) Consider the reaction: (March 2010) (1)
3 S0ag
What are the values of the
13 (ag) +2S04*(ag) at particular time t, - dsodt =
2.2 x
10-2 M/s.
following at the same time?
(a) [ l

dt
(b)dS0,21 (c)d
dt
dt
( 101Define activation energy. Calculate (IMarch 2013) (3)
activation
four times when temperature changes irom 30°C energy 1or a reaction
of which rate
(11) Write molecularity of the following reaction:
to 50°C.
(Given R 8.314 JK-1 constant becomes =

mol-l1 (Oct. 2013) (3)

2NO O21 2NO2e)
(12) The decomposition of N,0i at 320k according to the
following equation follows (March 2014) (1)
first order reaction:
NO51g 2NO2122
The 1ncentration of N,O5te) l1s 1.24 *
10 mol.L and after 60
Calculate the rate constant of the reaction at 320K.
10-2 mol. L-1, minutes, 0.20 x

(13) Derive the relation between half-life period and rate constant
*

i d solution to for first order reaction.

give glucose and iructose
(March 2014) (3)
(14) Sucrose decomposes in
haurs.
Calculate fraction of sucrose (March 2014) (2)
to the first order rate according
which will remain law.
(15) Derive the relation between half life and rate constant for a first order reactin after 8 hours.
Oct. 2014; March 2015) (3)
Define: (a) Average rate of reaction (b) Instantaneous rate of reaction.
(16) react at high temperature as:
(March 2015, 2017) (2)
Ammonia and oxygen
(17) (Oct. 2015) (2)
4NH3e+ 502(8) 4NOR +6H,0e
experiment,
rate of
formation
of NOis 3.6 x 10-3.

In an

(a) Rate of
disappearance of ammonia (b) Rate of
Calculate:
formation of water.
(Oct. 2015) (3)
 Question
ru of
Boara
iUmnar
Zero order reaction' 141
efine
De.
hical
method to
EXpla der reaction x > y,determine (March 2016) (1)
1 8

a first o r d e r activation encrgy

+0% of the of
(20) I n a

given rcaction.
a
(March 2016) (2)
calculate r a t e c o n s of the reaction. np sample
ie of
compound remains unr
compound
n stant of a first unreacted in 45 minutes.
The
order reaction (March 2016) (2)
are
0.58 s'
(21
the energy of
What i sthe. activation for the at 313 K
and 0.045 s'
reaction? at 293 K.
the
henius
Arrhenius
equation for a first order July 2016) (3)
In
.Imoll respectively. reaction,
the values
temperature will its halfoflife'A' and
122) 98.6kJ At what
a n d
E,' are 4 10° sCc

IR 8.314 JK- motr period be 10 minutes?

rate law for the reaction
The (March 2017) (3)
23)
2H22NO N2(t 2H,0is given by rate
KJH,| |No
-

in the
"he action occurs
following two steps:
) Hzue2NOe N,OH,O
(p) N,OHate)
r ot
-NauH,O
is the rate of NO in the
mechanism? What is the
Wh
the following data for the molecularity of the elementary steps? (July 2017)
liquid phase reaction A > B,
(24)
Fro
determine the order of 4
rateconstant: reaction and calculate its
0 600
t/s
A]/Mol L1 0.624
1200 1800
0.4465 0.318 0.226
A certain reaction occurs in the following steps. (July 2017) (3)
(25)
(i) CtO3e ClO* O2tg)
iCiogO Clt O2g
la) What is the molecularity of each of the elementary steps?
b) Identify the reaction intermediate and write the chemical equation for overall reaction.
(March 2018) (2
D6 The reaction A + B> products is first order in each of the reactants.
(a] How does the rate of reaction change if the concentration of A is increased I factor 3?
(b) What is the change in the rate of reaction if the concentration of A is halved and concentration
of B is doubled?
(March 2018) (2)
(27) Define the order of chemical reaction.
Find the overall order of the following reactions:
CC4g t+ HCg Rate =k{CHC1| [Cl]
a) CHCl19* C
(b) 2NO O21 2NO21g Rate k[NO]20, (July 2018) (2)
R8) In a irst order reaction A -~ product,80 % of the given sample of compound decomposes in 40 min. What is the
half life period of the reaction? (uly 2018) (3)
Write Arrhenius equation. Derive an expression for temperature variations. (March 2019) (3
(29 is 0.3M.
The rate of a first order reaction, A > B is 5.4 x 10-6 Ms when [A]
S0 (March 2019) (1)
Calculate the rate constant of the reaction.
(March 2011) (1)
is 6.0 h. Calculate the rate constant.
04 The half life period of a first order reaction and its rate constant. (March 2020) (1)
half life of zero order reaction
Write the mathematical relation between first order reaction with
D e n n e instantaneous rate of reaction. Explain pseudo (March 2020) (3)
suitable example. (Sept. 2021) (4)
for first order reaction.
34)
Denne isomorphism. Derive integrated law expression (Sept. 2021) (2)
pseudo-first order reaction? Explain
with suitable example
nat is the expression for
half life and
order reaction. Obtain (March 2022) (3)
DEnne
half life of first
Tate constant of the first order reaction.
elementary reacion (March 2022) (1)
aentify the molecularity of following
NO 1 NO3 O
OF GROUPS 16, 17 AND 18
ELEMENTS (March 2013) (2)

Draw
7 of PCl, and PCI
2) What structure
and write geometry
ammonia? (March 2013) 13)
on
is the action of the following reagents (c) Na metal
(a) Excess of air (b) Excess
of chlorine
to group
16:
3) Explain the properties
with
reference

trends in the following (b) Density (March 2013) (4)

Atomic radii and ionic radii (d) Electronegativity

c) lonisation enthalpy
 UTTAM's XII Chemistry Papers
142 lution
(4) What is the action of chlorine (Cl) on the following: caustic soda.
concentrated
(a) Cold and dilute caustic soda. (b) Hot and

(c) Potassium bromide solution.

(Oct. 2013)
(5) Write electronic configuration and two uses of neon (Z 10). (Oct. 2013) 3)
(March 2014) (2)
(1
(6) Write resonating structures of ozone.
Describe anomalous behaviour of fluorine with the other elements
of group 17 with reterence to:
(7)

(8)
(a) Hydrogen bonding (b) Oxidation state (c) Polyhalide ions.
Describe anomalous behaviour of oxygen as compared with other elements of group l6 with reference
(Oct. 2014)
to-
(March 2014) (3
(a) Magnetic property (b) Oxidation state (c) Hydrides
(9) Draw the structure of: 13)
(a) Orthophosphoric acid (b) Pyrophosphoric acid (Oct. 2014)
(10) Explain the structure of sulphur dioxide.
(11) Write molecular formulae and structures of the following compounds:
(IMarch 2015) (2(2)
(a) Dithionic acid (b) Peroxy monosulphuric acid
(c) Pyrosulphuric acid
(12) Draw structures of: (a) Chlorine trifluoride
(d) Dithionous acid
(b) Chlorine pentafluoride.
(IMarch 2015) (4
(13) What is the action of dioxygen on (2)
(a) Calcium (b) Iron (c) Carbon disulphide?
(Oct. 2015)
(14) What happens when dilute sulphuric acid is treated with (a) Fe (b) CaF2 ? (3)
(15) What happens when thin copper leaves are thrown in jar containing chlorine? (July 2016) 2
(16)
(July 2016)
H,0 is liquid while H,S is gas at room temperature. Explain. 2)
(17) Write the electronic configuration of the following elements: (July 2016) 2)
(a) Sulphur (Z = 16) (b) Krypton (Z = 36)
(18) Write any 'two' uses of each of the
following: (a) H,SO, (b) Chlorine
(IMarch 2017) (2)
(19) What is the action of concentrated
sulphuric acid on the
(March 2017) (2)
following:
(a) Phosphorous
pentachloride (b) Copper (c) Potassium chlorate.
(20) Write balanced chemical equations for the following: (July 2017) (3)
(a) Action of ozone on hydrogen peroxide.
(21) Write the molecular and structural formulae of: (March 2018) (1)
(a) Thiosulphuric acid (b) Dithionous acid
(22) Draw the structure of IF, Write its geometry and the (March 2018) (2)
type of hybridization. (March 2018) (2)
(23) Explain the following with the help of balanced chemical
equation:
(a) Bleaching action of SO.
(b) Dehydration of formic acid by concentrated
HSO4,
(c) Burning of benzene in presence of excess of
dioxygen. (July 2018) 3
(24) Write structure and molecular formula for sulphurous acid.
(25) Write any four points of difference between fluorine and other (July 2018) (1)
(26) Write chemical reactions for different steps in the manufacturehalogens.
of sulphuric acid
(July 2018) (2)
lead chamber process. by
(27) Explain the (March 2019) (3)
following properties of group 16 elements:
(i) Electro negativity (ii) Melting and boiling points
(iii) Metallic character (iv) Allotropy
(28) What are oxides? Write different types (March 2019) (4
of oxides with
(29) Write the name and formula of one ore of zinc.
one
example each. (March 2019) 14)
(March 2020) ()
(30) Write two uses of each of the following : (a) Helium
(b) Neon. (March 2020) (2)
(31) Draw the structure of sulphurous acid. Explain
pentahalides.
why nitrogen does not form
(IMarch 2020) 3
(32) Explain interhalogen compounds.
How is oxygen prepared from the following compounds?
(a) KCIO (b) PbO2. (March 2020) 14)
(33 Write the name of interhalogen compound of chlorine which has
structure. square pyramidal
(34) Draw the structure of (Sept.2021)
sulphurous acid. Write two uses of helium. (Sept.2021)
(35) Write chemical equations involved during manufacture
contact process. Write two uses of of sulphuric acid
sulphur dioxide. by
(36) What is the action of concentrated (Sept.2021
H,SO4 on: (i)CaF, (ii) Cane sugar.
What is nucleotide? Write reaction for the
preparation of (Sept. 2021) 4
(37) What is the action of selenium on
magnesium metal? polyacrylonitrile (PAN). 2o22)
(38) Explain the trends in the
following atomic properties of group 16
(March

() Atomic radii (ii) lonisation enthalpy

(ii) elements:
Electronegativity (iv) Electron gain enthalpy.
(March 2 0 2

(Mar
 Write chemical composition
asition of
fgurations of first two ele
haemante. Write the
Cmatit

hemical equation forelements of group

contigu

al
Write

DWrite uses
of sulphur.
preparation of
17. names and
sulphur dioxide electronic 143
8 from
Give
the observed uter TRANSITION AND INNER
electronic
sulphur (March 2022) (3)
t)
Why
are compour

asition
of
copper
ured while configuration of
copper (ZTRANSITION
(March 2022) (3)
(2) xplain the of
d-Block elements
the d-block elements form in the
those of zinc -29 ELEMENTS
coloured periodic table.colourless?
Why
3/
4 Give reasons:
the

al Zinc
white
salts are compound? (March 2008) (3)
metal shows
(b) Tra sition catalytic (Oct. 2008)
(2)
ganese shows variable properties
oxidation
(March 2009) (2)
5) Writethe position of zinc
is the, seneral outer
30) in the states (Mn, Z =25)
6)
What
.he following electronic periodic table and write its
(7) Explai characteristicsconhguration
la) Tendency to form complexes
of
of electronic
transition series
transition elements: configuration. (Oct. 2009)
(3)
(b) Catalytic property. elements? (Oct. 2009)
(2)
sition elements show variable (March 2010) (1)
ransition elements?
hat are trar oxidation states.
ectronic configuration of Co Explain their Explain. position in (Oct. 2010)
(At. No.
nistinguish between Lanthanides and 27 Modern Periodic
Table and write (March 2011)
(2)
(2)
dolanthanides form coloured Actinides. the
nes the basicity of compounds? (March 2008, 2010; Oct. (March 2011) (2)
atomic number. hydroxides of lanthanide series 2015; July 2016)
elements decrease (2)
Write with increasei (March 2008) (2)
the outer observed electronic
(a) Gadolinium (64) configuration of:
(b) Ytterbium (70). (Oct. 2008) (2)
sA What are lanthanons Give names and
nlain why does lanthanum forms symbols of any 'two
rare (Oct. 2008)
(At. No. La= 57, Ce = 58)
La" ion, while cesium formsearths. (March 2009) (2)
2)
Ce ion.
n6 Write expected electronic configurations of (a) Nd
(Z 60) (b) Tm (Z
69)
=
(March 2009) (2)
17 Explain 63Eu and 7oYb show +2 oxidation state. =

(Oct. 2009)
18 Write the general outer electronic configuration of (2)
lanthanides and actinides.
(Oct. 2009) (2)
19 Write the expected electronic configurations of (a) (March 2010) (2)
20) What are 'Actinides? Write their Europium (Z =

63) (b) Erbium (Z =

68) (Oct. 2010)
position in the periodic table.
(21) Explain the of lanthanide contraction.
cause (Oct. 2010) (2)
(22) Write the different oxidation states of (March 2011, 2018) (2)
is more stable?
manganese. Why +2 oxidation state of
manganese
23 Write observed electronic (March 2013) (3)
configuration of elements from first transition series having
half filled d-orbitals.
(Oct. 2013) (2)
What is lanthanoid contraction? Explain the cause and effects of lanthanoid contraction.
(Oct. 2013) (3)
40What are lanthanoids? What is the position of actinoids in periodic table? (March 2014) (2)
nat are interstitial compounds? Why do these compounds have higher melting points
than (March 2015) (2)
corresponding pure metals?
Define lanthanoid contraction. Explain its effects. (March 2015) (3)
I e reactions involved in the zone of reduction in blast furnace during extraction of iron.
(March 2015) (2)
29) What is the osition of iron (Z 26) in riodic table?
(Oct 2015) (3)
EXplain why is Fe3 more stable than Fe"? (March 2016 (2)
21, Ti
=
22).
number Sc
=

31) What: colourless while Ti3 coloured? (Atomic actinoids.

(March 2016) (3)
lanthanoid and (March 2016) (1)
- b l o c k elements? Distinguish between
3alain the term - Interstitial compounds. (March 2017) (2)
33 of transition metal
ions.
d e t e

the factors which r e related to the

are
colour iS m o r e stable?
state of manganese (March 2017) (3)
Write the Crent
different Oxidation states of iron. Why oxidation
Given:
35) What Z of
Mn 25.) 57) forms
La" ion,
while
(July 2017) (3)
hat is why
lanthanum (Z =

lanthanoid
Cerium (Z Fo con Contraction? Explain, (July 2018) (2)
m (Z= 58) forms Ce* ion?
=

What
dare 'd' and
f block elements?
144 UTTAM's XII Chemistry Papers Sol
(37) What is the
action of the following
(a) Water on
lanthanola (c) Nitrogen, heat
(July 2018)
(38) (b) Sulphur, heat of sulphur
Explain the position of actinoids periodic table. What
is the action
solution if
Oactinoids in the per100
On lanthanoids? cCalculate
on lanthanoid
its atomic themagnctic mome
n e magnetic moment
of divalent
ion in aqucous

(39) Define (a)

number is 24. (March 2019)
Hydrometallury
Chemical (b) Electrometallurgy. (Oct 2015)
O W n t e the names formulac of any one ore of iron and Zinc cach.

of inium.
(March 2016)
(July 2017)
a m e s and chemical formulac of two' mincerals als from
metals irom their their ores. (Juln
mes
of various steps involved in the extraction
of pure (July 2017)
nat iis the
(43) What action of carbon on the following metal
Fe,O in blast furnace. oXI
(44) What is (March 2018)
(45) clectrometallurgy?
Wnite the name and chemical formula of one ore of
(March 2020)
(March 2020) 2
(46) Define flux. Write zinc
a note
leaching process.
on
L n e general electronic configuration of lanthanoids. Why are most or the
(March 2020)
compounds of transition metals coloured?
T exhibits +2 and +3 oxidation states. Write their electronic coniguration.
(March 2020) 1
Which will be more stable? Why? (Sept. 2021) 12
Why La(OH), is the strongest base, while Lu(OH), is
the weakest base
e wo applications of catalytic properties of transition metals and compounds.
(50) Write the chemical formula of (Sept. 2021) 13
Haematite.
(51) Define mineral. (Sept.2021)
S2 Calculate spin only magnetic moment of
divalent cation of transition metal with
(March 2022) (L
atomic number 25. Salts of
Ti4 are colourless. Give reason.
(March 2022) 14
(1 Write the formulae of the
9CoORDINATION cOMPOUNDS
following compounds-
(a) Sodium hexanitro-N-cobaltate
(I)
(b) Tetraaquodichlorochromium
(11) chloride
(c) Potassium
tetracyanoaurate (1II) ion.
(2) Write applications of co-ordination (March 2013) (3)
(3) What is effective atomic number compounds medicine and electroplating.
in
(EAN)? (Oct. 2013) (2)
Calculate EAN of
cobalt
(Z 27) in and[CO{NH,),|3
(4)
Classify the following ligands into monodentate and of (Z 30) in zinc [Zn{NH)4] SO. (March 2014) (3)
(a) Ammonia (b) Carbon monoxide
polydentate -

(c) Ethylene diamine (d) Ethylene diamine tetra

(5) On the basis of valence acetate ion.
bond theory (Oct. 2014)
Write the IUPAC name of explain the nature of in bonding [CoF,ion. 2)
(6) Explain cationic [Co{N0),(NH),.
(7) Illustrate with
complexes and
anionic complexes of (March 2015) (3)
example, the difference between a doubleco-ordinationation compounds. (Oct. 2015) (2)
(8) Explain the terms- salt and a
Ligand. co-ordination compound. (March 2016) 4
(9) Write the formula of
(10) Define ligand. Write four Tetraminodichloroplatinum
(IV) chloride. (March 2016) (1)
(11) What is 'effective atomic postulates Werner's theory.
of
(IMarch 2016) (1
Calculate the
number (EAN)?
effective atomic number of the (uly 2016) (3)
(a) KFelCNI, central metal
(b) Cr{CO) atom in the
Fe (Z 26) following compounds
(12) How ligands classified? Explain with
are
Cr(Z 24)
(131 Explain the geometry of suitalble examples. (March 2017) (3)
(14) Write the formula for |Co(NH,J,P" on the basis of
pentaammine hybridisation. (July 2017 13
geometry of |Cu[NH,J4° chlorocobalt
(151 Explain the (Z of Co
(ll) sulphate. =
27) (March 2018) (2)
(16) What is effective atomic on the
basis of
copper (Z number? Calculate effective hybridisation [At. No. Cu
29) in [Cu(NH,),12*
=

291.
(July 2018)
(17) Calculate the effective atomic number =
uly 2018)
atomic of
(181 EXplain ionisation number (E.A.N.) of
(19) What are bidentateisomerism in co-ordination copper in
(March 2019) 3)
Ligands? Give one
example,compounds with
(Cu(NH,12*. (Z of Cu (March 2020) (2)
suitable example. 29)
=
(20) Ilustrate with example, the a
Write two difference between a (March 2020) (2)
applications of coordinate
compounds. double salt and (Sept. 2021) (2
co-ordination cor
compounds.
(Sept. 2021) 3
 Summary of Board Questions
(21) Write lUPAC name of 145
(22) Write the |Fe(CO),] complex.
of
isomerism in the following
name (Sept. 2021) (1)
Cu{NHlPtCI,] and Pt|(NH,J,|CuCll complexes:
(23) Explain monodentate and ambidentate (March 2022) (1)
(24) Explain cationic, anionic and neutral ligands with example. (March 2022) (2)
sphere complexes with cxample.
(March 2022) (3)
| 10 HALOGEN DERIVATIVES
(1) Write a note on Wurtz reaction and
mention
any two uses of iodoform.
(2) Explain the mechanism of alkaline (March 2008) (3)
(3) Define optical activity. Explain hydrolysis of bromomethane.
(March 2008)
optical (4)
(4) State and activity of 2-chlorobutane.
explain Markownikoff's rule' with a suitable
(March 2008, Oct. 2008) (4)
(5) Define asymmetric carbon atom. example. (Oct. 2008, 2014) (2)
(6) What is the action of
following reagents on ethyl iodide? (Oct. 2008, March 2011) (1)
(a) Aq. KOH (b) Alcoholic KCN (c) Silver acetate
(7) Explain the mechanism of alkaline (March 2009) (3)
hydrolysis
(8) Give the structural formula and IUPAC name
of tert-butyl bromide.
(March 2009, 2010, 2017) (3)
of iso-butyl bromide.
(9) Complete the following reaction and identify A, B, C and D with correct formulae.
(March 2009) (1)
CH Br OSO BA
C Cold HI CH.OH D +
(Oct. 2010 (4)
10) Why does p-nitrochlorobenzene undergo displacement reactions readily with attackof
nucleophilic OH- ion?
(11) Write balanced chemical equations for the action of- (March 2013) (2)
(a) Phosphorus trichloride on propan-2-ol.
(b) Hydrogen bromide on styrene in the presence of a
peroxide.
(c) Methyl bromide on silver propanoate.
(12) Distinguish between SN' and SN mechanisms. (March 2013) (3)
(13) Write the structures of
(March 2014) (2)

(a) 3-chloro-3-ethylhex-1-ene (b) 1-lodo-2, 3-dimethylbutane (c) 1, 3, 5-tribromobenzene. (Oct.

2014) (3)
(14) Draw structure of DDT. Write its environmental effects.
(March 2015) (2)
(15) Identify A' and B' in the following reaction
CH-CH CH, HBr A'alc.KOH B (Oct. 2015) (2)
16) Discuss the mechanism of alkaline hydrolysis of bromomethane. (Oct. 2015) (4)
(17) How is chlorobezene prepared from aniline? How is chlorobenzene converted into diphenyl? (March 2016) (2)
18) Explain the terms- Optical activity. (March 2016) (1)
(19) How is propene converted into 1-bromopropane and 2-bromopropane? (March 2016) (2)
120) Write a note on Sandmeyer's reaction. (uly 2016, 201S) (2)
21) Identify 'A' and B' and rewrite the reactions.

CH3
a
NH3 NaNO,
K(A) Cu,Br (B) +N,I
HBr, 273 K

(6) H,C-CH, - CH - CH, Alcoholic KOH (A)+ (B) + 2KBr + 2H,0 (July 2016) (2)

Br (March 2017) (1)

42 Define racemic mixture. uly 2017 (4)
(23) Defi optical activity. Explain optical activity of
lactic acid.

Identify Aand B in the following reaction (March 2017) (2)

CH-Br+ Mgdry etherA + CO dry ether B+ Mg(Br)OH
(March 201S) (2)
H'/H,O
25) Exy for alkaline hydrolysis of
tert-butylbromide.
n y reaction mechanism
26) ldentify rewrite the complete reaction:
reaction and (March 2018) (2)
C
and
B'in the following
CH,-CH -Br +
AgCN A CHOH
B

27) C.H -Br*+Nal.dry acetoneC,H -I+ NaBr The reaction is (1)

Finkelstein reaction (July 2018)
la) Wurtz reaction Swarts reaction (d)
-Schiemann reaction (c)
on(b) Balz and rewrite complete reaction
Identify d B from the following reaction
(July 2018) (2)
AH B + MgCl{OH)
CH,CI +Mg dryether
 146 UTTAMs XII Chemistry
Papers Solution
(29) Complete and rewrite the
following chemical reaction:
1- chloro -2, 4-dinitrobenzene aq. alkali
368 K, H,
(July 2018)
(30) What is the action of the
following on ethyl bromide:
(i) alcoholic solution of
(ii) moist silver oxide
potassium hydroxide
(iii) silver acetate? (March 2019) (3
(31) Define Enantiomers. (March 2019) (
(32) What is Grignard reagent? (March 2019) (
Define optical activity. How many optical isomers are possible for glucose (March 2020) (2
(54) Write the chemical reactions of chlorobenzene with respect
to
(a) Sulphonation (b) Acetylation (c) Nitration. (March 2020) 1)
(35) What is the action
of the following on
(i) Methyl chloride in presence of anhydrous AlCl,
chlorobenzene
(ii) Fuming HSO (Sept. 2021) 12
(S6) Explain SN? reaction mechanism for alkaline hydrolysis of bromomethane. (Sept. 2021) 13
(37) Write the product formed when alkyl halide reacts with silver nitrite. (March 2022) (
(38) What is the action of the following on ethyl bromide?
(i) Na in dry ether ii) Mg in dry ether. (March 2022) 12
(39) Write chemical reactions for the following conversions:
(i) Ethyl bromide to ethyl methyl ether
ii) Ethyl bromide to ethene
(iii) Bromobenzene to toluene.
(iv) Chlorobenzene to biphenyl. (March 2022) (4

11 ALCOHOLS, PHENOLS AND ETHERS

(1) How is cumene converted into phenol? Give test to distinguish between phenol
and ethanol. (March 2008, 2010; Oct. 2010) 13)
(2) Draw the structure of 2-methyl-propan- 1 -ol. (TMarch 2008) (1)
(3) From methyl magnesium iodide how are the ethanol and propan-2-ol are prepared? (Oct. 2008) (2
(4) What is the action of the following on phenol?
(a) Bromine in CS
(b) Conc. H,SO, in presence of conc. HNO
(c) Conc. H,sO, at room temperature. (Oct. 200S) 3
(5) What is the action of following on 2-methyl propan-2-ol?
(a) 20% HsO, at 360 K
(b) NaBr and conc. H,SO (Oct. 200s) (2)
(6) Write the chemical test to distinguish between propan-1-ol, propan-2-ol and
2-methyl-propan-2-ol. (March 2009)
(3)
(71 What are phenols? How is carbolic acid prepared from aniline? Write
chemical
between alcohol and phenol.
a test to distinguish (4
(March 2009)
(8) What is the action of the following reagents on ethanol?
(a) Thionyl chloride (b) Mixture of red phosphorus and bromine
(c) Acidified potassium dichromate.
(Oct. 2009, March 2011) (2
(9) How is carbolic acid prepared from benzene sulphonic acid?
What is the action of conc. H,SO, on phenol at 373 K?
(Oct. 2009) (2
(10) How is phenol prepared from (a) Aniline (b) Chlorobenzene. (March 2010; Oct. 2010)
(2)
the action of sulphuric acid at dillerent
temperatures and different
the following compoundsP concentrations on

(a) Ethanol (b) Propan-2-ol (c) 2-Methyl-propan-2-ol (March 2010)

(3)
(12) How are ethyl alcohol, iso-propyl alcohol and tertiary butyl alcohol distinguished from
each other? (3
(Oct. 2010)
from cumene? Give two u s e s t (3)
(13) How is carbolic acid prepared (March 2011)
alcohols a r e much higher than those of the o (2)
(14) Boiling point of
ethyl-methyl
m e of methyl ether and
und explain action ding alkanes. Explain. (March 2011 (3
(15) Write of ethyl-
IUPAC n aarne action
of cold HI and hot Hl on it.
(16) How will you prepare dicthyl ether by continuous etherification processp (March (Oct.
4
2008)
(2)
ethers?
What are 2011)
(17) Williamson's synthesis. Mention ttwo (Oct. 2008, March (3)
Write a note o n (March 2009)
(18) when, ethyl methyl
e t h e r is
hydrolysed hu oxyethane. (1)
(19) What happens (Oct. 2009)
 Summary of Board Questions
147
(20) What is the action of dilute
sulphuric acid under pressure, on ethoxy ethane? (Oct. 2010) (1)
(21) How is ethyl methyl ether prepared from sodium
ethoxide? (March 2011) (1)
(22) How is ethanol prepared from methanal by
using Grignard reagent? (March 2013) (2)
(23) Explain the mechanism of action of hydroiodic acid on
(24) How is phenol converted into the following? 3-methylbutan-2-ol. (March 2013) (3)
(a) benzene (b) benzoquinone (c) picric acid
(25) Write the structural formula and lUPAC names of all (Oct. 2013) (3)
with molecular formula possible isomers of the compound
CaH,O. Write 'two' uses of phenol.
(March 2014)
(26) How is methoxyethane
prepared from methyl iodide. (4)
(27) What is the action (March 2014) (1)
of the following reagents on
phenol
(a) Bromine in CS, at low temperature
(b) Conc. H,SO, at room temperature. (Oct. 2014)
(28) How is carbolic acid prepared from the (2)
(i) Aniline (ii) Chlorobenzene and steamfollowing compounds:
at 698K?
(29) Mention two' physical properties of carbolic (DMarch 2015) (2)
acid.
(30) How the (March 2015) (1)
are
following compunds prepared?
(a) Benzyl alcohol from benzyl chloride. (b)
Propan -1-ol from
(31) How is carbolic acid prepared from chlorobenzene? What is the propanal (Oct. 2015) (2)
on carbolic acids?
action of bromine water
Write chemical test to
distinguish between carbolic acid and alcohol. (Oct. 2015) (3)
(32) Write the reactions involved in
dehydration of 10, 20 and 3° alchols.
(33) What is metamerism? Write the structure and IUPAC name of 'methyl-n-propyl ether.
(March 2016) (2)
What is the action of hot HI on it?
(34) How are the following conversions carried out?
(uly 2016) (3)
(i) 2-methylbutan-1-ol into 2-methylbutanoic acid.
(ii) Phenylethene into Benzoic acid
(iii) Benzoic acid into metanitrobenzoic acid.
(35) Define carbolic acid. How carbolic acid is prepared from benzene sulphonic acid?
(uly 2016)
(March 2017)
(36) How will you prepare ethanol, propan-2-ol and 2-methylpropan-2-ol from
Grignard's reagent? (ruly 2017) (3)
(37) How is phenol prepared from cumene?
(July 2017) (2)
(38) Prepare carbolic acid from benzene sulphonic acid. Write a chemical equation for the
action of neutral ferric chloride on phenol. (March 201 S) (3)
(39) Why ethanol has higher boiling point than ethane? (March 201S) (2)
(40) Write a preparation of phenol from cumene? What happens when phenol is heated
with zinc dust? (July 2018) (3)
41) Identify A and B respectively in the following reaction:
tert-butyl alcohol 20H,SO A+ H0 HBr B
363 K H,O2
(a) 2-methylpropene, 1-bromo-2-methylpropane
(b) 2-methylpropene, 2-bromo-2-methylpropane
(c) 2-methylpropane, 1-bromo-2-methylpropane
(d) 2-methylpropane, 2-bromo-2-methylpropane (uly 2018) (2)
What is the action of the following on isopropyl methyl ether? (a) cold H (b) hot HI huly 2018) (2)
2) (March 2019) (1)
43) What are ethers?
4) Write balanced chemical equations for the following:
(a) Action of sodium metal on ethanol
(March 2019) (2)
(b) Action of zinc dust on phenol.
W r i t e structural formula of the alcohol that results when acetaldehyde is
ether and the product is hydrolysed. (March 2020) (1)
reacted with CH,MgBr in the presence dry
of
ether. (March 2020) (2)
Explain the continuous etherification process for
the preparation of diethyl
How is ethanol prepared from the following compounds (March 2020) (3)
(a) Ethanal (b) Ethene (c)
Bromoethane.
(Sept. 2021) (2)
s Write a note on Kolbe reaction.
9) Convert the
following:
() Chlorobenzene to phenol
(ii) Ethanal to ethanol. (Sept. 2021) (3)
1) lodomethane to methoxy methane. (IMarch 2022) (2)
50) Write the preparation of phenol from aniline.
51) Write chem reactions of following reagents
on methoxyethane (March 2022) (3)
nemical
(i) Hot HI (ii) PCIs (iii) Dilute H2SO4-
 UTTAM's
XII hemistry apers
ACIDS
CARBOXYLIC
148 AND
KETONES

12 ALDEHYDES,

acetalde h y dS
( c )
e?o d i u m b i s u l p h a t e
(March 2008)
on
reagents
() What is the action of following (b) Ammonia

(a) Na-Hg/H,O (March 2009)

(2) HoW will you obtain propan-2-one usin
acid?
(a) CH,CN (b) Ca salt of fatty p r o p a n - 2 - o n c r (March 2008)
What is the action of the following reagents
on
4
(a) Hydrogen cyanide (b) Hydrazine.
will you prepare ethanal from 1. 1-dichloroetnale
(
How (Oct. 2008)
What is the reaction of acetaldehyde with
(b) Fehlings s o l u t i o n ?
ldehyc
(Oct. 2008) 123)
(a) Ammonical silver nitrate Oct. 2008, 2010; March 20111
(a) Acetaldchyde
(b) Formaldenyuc
(what
is the action of ammonia on:
2)
(5) Write a note on Cannizarro's reaction. o.
write the preparation (March 2009)
(6Starting from Ca-salts of fatty acids,
(a) Acetaldehyde (b) Acetone (March 2009, 2010)142
(7) Write a note on aldol condensation.
(8) How is carbonyl group converted into (Oct. 2009, 2010) 2
OH
(a) CH,OH (b) CH OH (c)- CH,- (d) C
-
-

(9) Convert the following: (Oct. 2009; March 2010)

(a) Acetone into pinacol. (Oct. 2009)
(b) Formaldehyde into urotropine.
3)
(10) What is the action of following reagents on ethanal?
(a) Fehling solution (b) Tollen's reagent
(March 2010) (2
Clemensen's reduction.
(Oct. 2010) (2)
(11) Explain: (a) Cannizzaro's reaction (b)
(12) How will you obtain-

(aDiacetonamine from acetone? (b) Acetaldoxime from acetaldehyde? (IMarch 2011) (2

(13) What are aldehydes and ketones? Write a note on Cannizzaro's reaction. (March 2011) 14)
(14) How is ethyl ethanoate prepared from (a) Carboxylic acid (b) Acid chloride. (IMarch 2008) (2)
(15) How will you bring about following conversionsS?
(a) Acetic acid to acetyl chloride (b) Methyl cyanide to acetic acid
(c) Acetyl chloride to ethyl acetate (d) Ethyl iodide to ethyl acetate (Oct. 2008) (4)
(16) Convert the following:
(a) Dry ice into acetic acid (b) Ethyl acetate into acetone.
(March 2009) 14)
(17) How is ethyl acetate obtained from-
(a) Silver acetate (b) Acetic acid?
(18) How is acetic acid converted into (Oct. 2009) (2)
(a) Acetamide (b) Acetic anhydride?
(19) How is acetic acid prepared from (Oct. 2009) (2)
(a) Dry ice (b) Methyl cyanide?
(20) What is the action of ethyl
magnesium iodide on ethyl methanoate in
(March 2010)
(21) What happens when - equimolar quantities? (March 2010) 14
(a) Acetic acid is heated with P0,?
(b) Silver acetate is heated with
methyl iodide?
(c) Acetic acid is treated with sodium
(22) Define Ester'
bicarbonate?
(23) What is the action of excess (Oct. 2010) (3)
of methyl magnesium iodide
(24) How is on (Oct. 2010) (1)
4-methylpent-3-en-2-one obtained from ethyl ethanoate? (March 2011) (4)
(25) How are the following compounds prepared? propan-2-one?
(a) Benzaldehyde from benzene. (March 2013) (2)
(b)Acetophenone from benzene.
(c)Benzaldehyde from benzoyl chloride.
(26) Mention 'two' uses of
(27) propan-2-one.
Explain the mechanism of aldol (March 2013) (3)
(28) How is condensation.
benzophenone prepared from
benzonitrile ?
(March 2013) (1)
(29) Write note on aldol
a
(Oct. 2013; March 2015)
(301 Write
condensation.
a note on
self oxidation-reduction reaction ofof (Oct. 2013; July 2016; Marci 2018) (2)
aldehyde with suitahi
suitable (March 2014, 2017) (2
example. (March 2014) (2)
 Summary of Board Questions

(31) Identity A' and 'B' in

the
following reaction: 149
a21 Write the stueturc and CHMgBr +
CO,
Dry ether
H/H,O A
PC
B ' (Oct. 2014)
(33) 1lite balanced chemical luPAC names of all the metamers (2)
(a) formaldehyde equations for
(b) acetaldchyde action of ammonia represented by formula CqH
on io (Oct. 2014) (3)
341 Write a note On Friedel Craft's (c) acetonc
EAplain,
ite
why are
boiling pointsacylation. (Oct. 2014) (3)
(36) the structures and 1UPAC of carboxylic acids higher than (March 2015) (2)
(a) Adipic acid names of the
(b) a-methyl butyraldehyde.
following corresponding alcohols. (March 2015) (2)
(37) What is Stephen reaction? compounds:
28 Write the structure and l0PAC names
of
(March 2015) (2)
9) What are
tones? How isomeric aldehydes
are (Oct. 2015) (2)
(40) Explain the mechanisnm of ketones classificd? having molecular formula
C
411 Write 1UPAC esterification. H,0. (Oct. 2013)
T
names of the following (March 2016) (2)
compounds :
(March 201 6) (4)
(a) CH (b) CH- -c- cH,
1421 How is ethanoic acid
(43) Give IUPAC name of
prepared from dry ice? (July 2016) (2)
1441 What is the action of the CH,-CH,-CH-CHO (March 2017) (2)
(a) Phenyl hydrazine following reagents on
451 Write a note on self
(b) Zn-Hg/conc. HCi prepanone? (March 2017) (1)
(c) Sodium bisulphite
(46) Complete and rewrite the oxidation-reduction
reaction of (July 2017)
balanced chemical aldehyde with suitable example. (3)
(a) Chlorobenzene NaCN +CuCN equations: uly 2017) (2)
473 K, pressure
(b) Isobutyraldehyde 50%KOH
(c) Butanone +2,
(47) What is the action of the
4-dinitro-phenyl hydrazine H*
?
(a) LiAlH/ F^O* following reagents on ethanoic acid? (March 2018) (3)
(48)
(b) PCl, heat
Complete and rewrite the balanced (c) PO5 heat
chemical equation for the (March 2018) (3)
(a) Benzaldehyde 50% KOH
?
following reactions:
(b) Acetone phenylhydrazine-
+ H
49) Write balanced
equations for the following conversions: uly 2018) (2)
(a) Cyclopropane
carboxylic acid to
(6) Acetyl chloride to cyclopropylmethanol.
B0) A benzyl methyl ketone using dialkyl cadmium
compound used as pistachio flavour in
ice cream is ruly 2018) (2)
(a vanillin (b)
acetophenone (c) muscone
1 Write chemical (d) butyraldehyde
equation for the (March 2o19) (1)
following
(4) Gatterman-Koch formylation
(ii) Fischer esterification (ii) Rosenmund reduction
52) How will (March 2019) (3)
you convert
1 calcium acetate to acetaldehyde (i) acetone to acetone cyanohydrin
11) sodium
53) W acetate to methane (iv) benzoic acid to m-bromobenzoic acid?
Dalanced chemical reaction for (March 2019) (4)
541 preparation of acetic anhydride using acetic acid.
dentify 'A' and 'B' in the following reaction: (Mareh 2020) (1)

55) Expla CH,coci

Zn-Hg
A B H,O
HCI Conc, HCI, A (March 2020) (1)
56) Writ 1e mechanism of aldol addition reaction. Mention two uses of carboxylie acids.
(March 2020) (4)
name of reagent used during conversion of acetaldehyde to

S7 acetaldehyde
How is cyanohydrin. (Sept. 2021) (1)
58) Write benzophenone none prepared from benzonitrile?
pie (Sept. 2021) (2)
a note
on 'aldol' ndensation reaction of ethanal. Write chemical
) avolved when
cond
when benzaldehyde is treated with concentrated caustic potash. (Sept. 2021) (4)
Write thee name
1 is treated with 2,4-dinitrophenyl hydrazine,(March
of acetone
product formed, when 2022) (1)
 the
following
reaction (March 2022)
150 B
trom

(60)
ldentif
A

CH
and

B+ H,O (March 2022

AA action
of

(March 2022
the
2CH,- C - 0
acid
from:
What
is
acetic
preparation of
(ii) Acetyl chloride
with
example.

Wnite ketones

(61)
(i) Dry ice aliphatic
ication
of
classitica
Write the ? 13 AMINES

(62)
sodium
hypoidite
on
acetone

(b) Methyl c y a n i d e . (March 2008) a

using (a)
A c e t a l d o x I m e

Diethyl
amine.
(March 2008) (
and
and

by
N - E t h y l e t h a n a m i n e

prepared amine (b) e t h a n a m i n e ,

(Oct. 2008)
ethanamine

How
is
reaction of: (a) Ethyl chloride
on

Write
acetylation
is the
action ofacetyl 14
amines?
What
are
oWhat N-N-dimethylethanamine?
reactions.

(4) ldentify A, B,
C and D.
Write complete
CH C
CH D (March 2009) 14
Na +R-OH A CH B (b) O x i m e ?

CH,CN Nitro-alkane IMarch 2010; Oct. 2009; July 2017)

prepared from (a) 4
H o w is ethylamine

of amines.
Explain basic nature
(6) What is the action of-
(a) Nitrous acid on ethyl
amine (Oct. 2010 (2)
acetonitrile?
(b) Mixture of sodium
and alcohol o n (Oct. 2010) 12)
salt'?
(7) What is a Quaternary ammonium
of ethyl methyl amine. (IMarch 2011) (2)
(8) What are amines? Give IUPAC name

(9) How will you convert?

into OH (March 2011) (2)
(a) - C BN into CH, - NH2 (b)-NH,
-

(10) What is the action of bromine in alkaline medium

on:

(a) CH,CH,NO (b) CH, - CH- NO, (IMarch 2013) (2)

CH3
(11) Write a short note on Hoffmann bromamide degradation. (March 2013) (3)
(12) How is nitromethane prepared from the following?
(a) alkyl halide (b) a-halogen carboxylic acid (c) a-nitroalkene (Oct. 2013) 13)
(13) Explain Hoffmann bromamide degradation reaction. (Oct. 2013; March 2017, 2018) 12)
(14) What is the action of the following reagents on aniline?
(a) Bromine water (b) Acetic anhydride (c) Hot and conc. sulphuric acid (March 2014) (3
(15) Identify the compound 'A' and B' in the
following equation:
CH, -CH, + HNO 423-600 K ASn/ conc.H B' +
H,O (March 2014) 12
(16) What will be the action of the mixture of sodium
nitrite and dillute
(a) Ethyl amine (b) Aniline (c) Triethyl amine? hydrochloric acid on:
(Oct. 2014)
(17) How are propan-1-amine
and
propan-2-amine prepared from oxime? (2)
(Oct. 2014
(18) How is ethyl amine prepared from methyl iodide? 2
(March 2015)
(19) Write a note on Gabriel phthalimide synthesis.
(March 2015)
3)
(20) What is the action of acetic anhydride on:
(a) Ethyl amine (b) Diethyl amine (2)
(21) What is the action of nitrous acid on- (Oct 2015)

(al Primary nitroalkane (b) >econaary

nitroalkane (c) 3
(22) How are: (a) 1-nitropropane and Tertiary nitroalkane. (Oct. 2015)

(b) 2-nitropropane prepared from suitable (2)

oxime? (March2016)
(23) How are 1-nitropropane, 2-nitropropane and
from each other using nitrous acid?
(24) What is the action of benzene diazonium chloride on
2-methyl-2-nitropropane are distinguished (March 2016)
(3

(a) Phenol in alkaline medium (b) Aniline (2)

(July 2016

(25) Identify 'A' and B' and rewrite the reactions:

Ag,O/H,O H (1
C,H,-N(CHJ A
A-
B+
(CH),N +
July 2016

H,O
Summary of Board Questions 151
(26) What is the action of mixture of
NaN0, and dil.HCl on
(a) Ethylamine (b) Aniline (c) Diethylamine (March 2017) (3)
(27) How is nitroenthane converted into:
(a) Ethyl amine (b) N-ethylhydroxyl amine
What is the action of (c) acetic acid ? (huly 2017) (3)
(28)
(29)
p-toluinesulphonylchloride
What is the action of lithium
on
cthylamine and diethylamine? (March 2018) (2)
aluminium hydride in the
following compounds? presence of ether on the

(a) nitroethane (b) 2-methyl-1-nitropropane.

(30) Write resonance structures of (July 2018) (2)
aniline. What is the action of benzene
on ethanol? diaozonium chloride
(31) Write the structure of (July 2018) (2)
Phenylmethanamine. (March 2019) (1)
(32) Write short note on Hoffmann
a
elimination.
(33) What are amines? (March 2019) (3)
(34) Define : Quaternary ammonium salt. (March 2019) (1)
(35) Write the chemical reaction involved in the formation of (March 2020) (1)
(36) Write reactions to prepare ethanamine from
ethyl amine using acetaldoxime. (March 2020) (3)
(i) Acetonitrile (ii) Nitroethane
(iii) Propionamide. (Sept. 2021) (2)
(37) How will you convert
(i) Methyl iodide to methyl isocyanide.
(ii) Methyl cyanide to ethanoic acid ?
(38) Write chemical reactions (Sept. 2021) (2)
to prepare ethanamine from:
(i) Acetonitrile (1i) Nitroethane.
(March 2022) (2)

(1)
14
Give chemical reactions of glucose with
BIOMOLEcULES
(a) Hydroxyl amine (b) Bromine water.
(2) How will you convert glucose into: (a) Gluconic acid
(March 2008) (2)
(b) Saccharic acid (Oct. 2008) (2)
(3) How is the glucose prepared from sucrose?
(March 2009, 201 7) (2)
(4) Define the term Simple protein'.
(Oct. 2009) (1)
(5) Explain the term proteins.
(March 2008) (1)
(6) Classify the following carbohydrates
(a) Cellulose (b) Maltose (c) Fructose.
(Oct. 2009) (2)
(7) What are conjugated proteins? How is peptide linkage formed in proteins? (March 2010) (3)
(8) What is the action of the following on glucose?
(a) Acetic anhydride (b) Hydroxyl amine.
(Oct. 2010) (2)
(9) What happens when glucose is treated with-
(a) Bromine water (b) Dilute nitric acid (c) Hydrogen cyanite (HCN) (March 2014) (3)
(10) Describe laboratory method for preparation of glucose. Write the reaction that indicates
the presence of CHO group in
-

glucose. (Oct. 2014) (3)

(11) Draw the simple Fischer projection formulae of D-(4-glucose and D - ructose. (Oct. 2014) (2)
(12) How are proteins classified on the basis of molecular shapes? (March 2015) (2)
(13) Define carbohydrates. What are reducing and non-reducing sugars? (March 201 5) (3)
l 4 What are monosaccharides? Draw ring structure of a - D - (+)- glucopyranose ? (Oct. 2015) (2)
(15) What is peptide linkage? How is tripeptide formed? (Oct. 2015) (3)
(16) What are
carbohydrates? (March 2016) (1)
(17) What is the action of following reagents glucose?
on

(a) bromine water (b) dilute HNO (c) Hydroxyl amine uly 2016) (3)
(18) Define enzymes. How is peptide linkage formed? (uly 2017) (3)
(19) What happens when glucose is treated with
(a) hydroxylamine (b) hydrogen cyanide. (July 2017) (2)
(20) How glucose is prepared from cane
suger?
Write the formula of the (March 2018) (3)
complex copper (1I) hexacyano ferrate (1).
What areamino acids? Write the correct reaction for formation
amino acids. of peptide bond Derweet (March 2018) (2)
(22) How is glucose (July 2018) (2)
prepared from starch?
 UTTAM's All Cemistry Papers
(July 2018) Solution
(July 2018)
152
Draw the
structure
of Thymine. triacylglycerol 1s
(d) amine
(23) in
n e
functional group
present
( ) ester (July 2018)
(b) ether
(March 2019)
glucose?

(a) alcohol reagents

on
(trans). 2
of following
G l u c o p y r a n o s e

(25) What is the action

(a) Bromine water
(b) Hydroxylamine

in a
-

D -(t)
-

linkage
formed?
(March 2019)
number of
hydroxyl
groups
present
method? Define
How is peptide hormones.
(March 2020)
(26) Write the
prepared by
commercial

a-D-(+)-glucopyranose.
(March 2020) 2
glucose
1 Haworth
Write
rojection
f o r m u l a of
d e n a t u r a t i o n of
proteins. (Sept. 2021) 3
(28) ? Explain
are
m o n o s a c c h a r i d e s

RNA. with
examples. (Sept. 2021)
What
(30) Write the name of sugar present in
of
molecular
shapes
(IMarch 2022) (2)
the basis
(March 2022) 2
oroteins on
Write classification of with exampic
an acid.
(31) in protein of adipic
peptide linkage
structure

Explain formation of
Write
2 p r e p a r a t i o n of
glucose.
(33) Write commercial method of
CHEMISTRY
POLYMER
INTRODUCTION
TO
15 (March 2008, 2010; Oct. 2009t
involved in preparation of
Nylon-b6. 2
W r i t e chemical reactions
prepared?
(October 2008) 13
What synthetic fibres? How is terylene (March 2009, 2011; Oct. 2009, 2010)
(2 are

(3) Define Fibre'. the preparation of

substances used in
names and chemical formulae of the chemical (Oct., 2010)
wnte (2
nylon-66. (March 2011)
(5 Give chemical reactions involved in preparation of Terylene. 2
(6) Write the chemical reaction to prepare novolac polymer. (March 2013) 2
How are polymers classified on the basis of polymerisation process? (Oct. 2013) (2)
(8) Write the structure of melamine. (Oct. 2013) (1
(9) Write names and chemical formulae of monomers used in preparing Buna-s. (IMarch 2014) 12
(10) How is Nylon 6, 6 prepared? Write any two' uses of terylene. (Oct. 2014)
(11) Explain with examples, branched and linear polymers. (IMarch 2015) 12)
(12) What are biodegradable polymers and non-biodegradable polymers? Write tone example' of each.
(IMarch 2015) (2
(13) Write the reactions involved in the preparation of -
(a) Teflon (b) Orlon (c) PVC.
(14) Write the reaction for the preparation of Nylon-6.
(Oct. 2015) (3
(15) Write the formulae of the raw materials used for (March 2016) 1
preparation of Buna-S. (July 2016)
(16) How are the following polymers prepared?
(a) Orlon (b) Teflon
(17) Explain the term: Homopolymers (July 2016) (2
(18) How is nylon 6,6 prepared? (March 2017) (2
(19) How is Terylene prepared? (IMarch 2017) (1
(20) Explain the preparation and uses of nylon-2-nylon-6. (uly 2017) (2)
(21) A polymer which contains ester linkage is: (March 2018)
(a) Teflon (b) Buna-N (c) Neoprene
(22) Write chemical reactions to prepare the (July 2018)
following polymers:
(i) Teflon (i) Nylon-6
(23) Define non-biodegradable polymer. Write the preparation (March 2019)
1241 Write names and structure ot monomers used in e. 2)
the (March 2020)
(25) Write classification of polymers on the basis of preparation.
ture. 2
ner. (Sept. 2021
(26) Write the name of biodegradable polyamide copolymer.
(March 2022)

16 GREEN CHEMISTRY AND

(March 2022)

(1) Write the name of nanostructural material used in

three principles of green chemistry.
tyres to NANOCHEMISTRY
increase their life.e.
(2) Explain (Sept. 2021)
(2
(3) Write the name
of the alloy used in Fischer Tropsch.
process in (Sept. 2021
chemistry. Write two disadvantages af- the
14) Define green synthesis of gasoline.
e. (March 2022)
hnology. (March 2022)