oiat

diaoci at do
alet onpleei Whena
Ex:
0
ul caaninakis
),so4 so fe oaly ist ad Canaite Ex:
A
prsRanbie
nolan nsalt sinale
Sall: Deule
conpaund A
ete ccN)1 Lfe Exxi
change
lk the shich cOnpound
ini A
change.(NHz)1 [Ni Ex:
2+ 3+
aie conpsud
in A conple Catisnie I.
atem. atal cantal Uha
isnA lylecte opai
bond, coodinate yolaule Nabu
atan Atal
copeunda the Thes
INtoducbisn:
COMPOUNDS (oORDLNATLON
 Sene Impontt Tninlogy
Coaialion
sehen
centin Cantha igond
atom

Coondinaion titiu
1. (oodinakien ntitin A coanlinatia ntiby
contitute anta mtal ato
nolele
Ex [ Ni (co) 1 ke....
ceondirabion etiky
he atom to whie
dafinite guortia
0- slole paiolie table becaue they hav a uecat
( a ly
aeapk lone pai)
Ligond ue. donse abo Moleclea ain wie
donale
coondrate called
ligonda
chang
CN.B.
Nugabiy hangad
te....
) Nutall Ha NHa

ligarda Ganed dons atonu

a) Unidetate - I7 only do abon is
ceuinate
i ita noll which
Ehen it u alled unidaatake lig ond. (a)
is beud to tal utalL alon
Whe a ligend ator t the igand i
a singl dons
said to l idatate.
 NH
L) Didatat - igane
ia
called. disdanta
ligand.
Ca0,2 ©halat ion
NH CH CHa N# hal,2- dianin
Poy daabat Whe (u)
aker Ehe its ealled poydantat ligand.
Exi hescadetate.
edd EDTA(thylan dianin tataaenbate)
Coo

cHa
A) Ardantate Undatake ligand conkaiuy
tha caediaking site (or abom) in
calld alideatabe iqond
M-CN cynato bind witl 'c')
a M NC insyt (bind with 'n')
M- Ne itato - N

o ligand elon ator bo

uhieh rbal i
diskly
Cood
boadd.
ttdutate
Coa, .
didenbat

3+

Coodinakio sple
 squan collakiely called coordin
ation sphu.

(sunte isn Tua isisabl gnoup nitte outaide

callad cauntu
ceut is

TE. Csedination polyhedn

dietly atkachac eo tlhe cutral aton

dbline a coondinatien palykaden hia tahdal,i

Honalptie and Hetenolurbie complen- conplu

Gound to suly
Ex: called honoleptie orpla.
Lonple wthie

ak cantal utal aton - 16 is dabinel

i all the ligada

shans wih sontu

2+
ato
+ 2
N
42

2+
Ba = +

NH2

3
 NerRdatus:

I.Naring at Cationi spies

[Ceadinakio tity) couba ion
Hutal aton (oi.

|Palie 7oL ligandy

2 liganda bhen di t
2 - i

S panba 4- Gbalis

Nam hescanincoalt (m) hlanide

Tü)Pt c (NO) (NH)4 soy

Nae kabao chlonido nito latiun CT) sulehate

Nome dieloido chriun (m) tuate

Nan tsani dia coR (1) sulphate

NmL ti (ekbyler diari)ehsiwn (a) aloia)

NaL - diddordo islyladian) colalt C3) so

Nes
 (ouate io Ccoondination bity J
Naning
na + Metol bo ate (orci o
alekabatialy
Na L Co (NO)1
Name sodiu hacanikscoalbat (r)

potanai baionalato fnate (I

[ N CcN) ]
Ne pobansiu eatrayano nichalate (0)

No potasnian btr Briasnin erichlonido plabiate

Waibiag canpsund stuutune hon

N
sodliuhasunibito- - coalbat
Na [Co (NO,)]

+3

Na,lolNO)6]

pokasianpaatayanontrog!funate cm)
kal Fe(cN) NO1

potaahiun tuta chlonidoMate (T)

(m) itate
atka arria didlonidoplatinn (o) babolaidoalati
vi) (Co2 (en) (oNO)]
dalanidotietylendianianitnito -0-cobalt () in

MO compaund hauig
7onla lut dint stauebural borlal
4 his calle insinn

)stuusisin
aomtical isaro
Coondinabion isseriAn 6hkical insnsisn

Stucbul

6orliuation conpSUd containing abidetat

igond,.
Sere ondsilantate ligands -
M NC
Céxty iso ynako)
SCN
(isothio ynabo)
NO (Ntuto- N)
M ONO
(aitito -o)
 aRiotion issmuism

Ex

Loisnton

potubial ligard aud displae a ligond ashicl

1Soate
lydrate isorwis.
le is svila to ioninatia inonin
a soleat olel iu

selwut oleele
(violab)

StuSSU chanal boula

poitisn and anosgndk o ligand aul
mtal atom) The a 2 tyne

ot igad asu cantu aton.

he colinaion 4 ad 6 ahou this type of

( ttvahedalys yua planan)

 Squan plana corle boula

diarnidiclonido platiun)
NHs,
PL

o.
( octahedaal)

Adaatabe

t
don
otakudal
adjanb poikion ot
When bhe pontion th uici

P.T.0.
Ex

N02

Co
1

ipbiall isorniae
inag that anst Supeiod

canat be supinp
eallad dinal.
callad dootro (a) and laereo (e)
dapsnding us Ehe ditisu they notate the pslan
polanised light.
iNelig didatate ligeud.
Ex: ) Co (en),]
3+ 3+

Las

2+ 24

Laeo

spkically isatise.
Boading u Cosndinakis Conpaunds :
1. Weah Tueoy os Ceandinatiw conpund
Wasn prepac and chanetind
Ceondintio oneuda and 4tudiad. Ehi
hi plyniza
aud cherical y sirle enpunintal bhaiqus
Wu
ok mtal isn,
He stud at cMoide anl
wompounda.
asunE)
aiibakl
S

Jaraied,
soution

Cols GNH ( yllo) gau 2mob Ag e

1mol (vioat) q tua isor

The condukiniby ef the solukiona of

Ehat
shausing
Pontulatu

noally isnisall and

(.onidalio nunba)
I) The iws. goup
have dhaacbnatic seakial asagut coepordig bo
Alunt coorlinatie u.

Tueany'
i hy cooreliaon conpounda hase diue

Why only cattain alerta pou bhe aakall

proputy of Bonni condiaation coneaunda,
harateinbie
nagntie and optieal propanbien.
To enlain this
Fld hesy ertgkad te

Valene Bond Thsy -

Poakulate Maia beakuus
Ae. bo this tasy the ubal atom

etahdal Squane lar

Caoinabion
Sp2
Gatonuby
Tetahedaal
Squan plana
Taigonal bayranid
sp atakdl
ottakdal
 DLaragtbie Magnebis
-
Gbakadal Gainty-
Hylaidisetisn-
dsp
11
CNA,),1 IloForabin
is Q'ap}
3&
paiig ligand Espinanally
e will NH. 3 o du
11 1
3d 34
[Az]
Soidation
Co 2
skubusetahidal Coondination i)
Gonding
eti weai paaagkia bewil wil 16
eained.
byidiakion. iv)
ustathe upon dapending end cenplees spin)
obibl aute ) Clo bit bonding
bon pain laton donate
 Si (3d)
Note
Hue conplex i calee'n ital
'spin paiaud conpl.

CAI 3d'4s onidabin +3

27

[A] 3 d
3d 4s

Epuiholly 4d
3d

sp d hy bridisakto

1,7 1 11

hybaidisakion spd2
octahal
Magti Pananagnbi

Note Sunee high spin

'spia bae' conle

üCoodination no.

E:

P.T.0.
26
NL saidation
Na2
3d
1 1L 1L1

Lalke lace 3d
110|11 4
Sp hybidistian
3d

Hybaidinabion
Gamaty - kalahedal
Mogatin- Paranagki

paticinasing hybidis atbia}

Ni LAn] 3 Sxidalion NG. +2

d spr hynidiabin
Fenatio ot IN(ew
Hybnidisadin -

d sp
Greomuty Squa ploran
Magakin dianaguki
is

Linitatisu Valanee
Valanee Bond Thesy
VeT nlains the fonation, stuucku and
rognatie belhaiour af csendinalim cerpowd
The colo enhilited y coordinotion canpaund
$qpontikakin iabrpkation

Magnkie data

ligoa.
Jugondiag
kou oodintu conplun

Cytal
Ae. to thin Eheoy, bh banelin bots clal
atall aton and ligod a puy ionice (eetokti
Ugonda conidud

O daguate aital

is dantby and is alik nto

 spitbing
n cetaked coedination utib
hyiont, he d an
dz onlitala, hic point ouranel Bha

hih a
disubd

upulaio

danatd
3ls bo abo

p.T. O.
 M

ENERGY

3tebo

Mtal d- itals
d
sphniea

o-lta i
do dapeada upor th

Ligonda
anlitting

ligonda peoduee seak biald.

Wiale
3d
 Srutodhusica soies

sputrohnicall suis.
J < Br
NH a

stog
Hi coinatisn atibia,

e tnie diskilwtion dpad

alatie ogaikud ot

elital

kon high eai coplen.

2) k Ao> P

Notw: Callati ahs Bhas

atitia

splilkiny as
to

fe
diatane. Ab

So Lour sei
coniguatkien

Spittig donbd

Magabie Prory dakami

npaied
spin olbeule
whe Magnabie MoenE
unpaiud e

[anl3d 4 hiatio o, =

(pani wil ot take alau)

J s ( s 2)
S. 42 BM

skould

Coaneliakion conRsund
complun thui wide coloun
So

S at
Long uohite.
The coou cenel is
conplinantag
stich in alanbee. The complinkay colou
colo in

colou is alod comple

ud.

Cood. Comoud Colo albe

2 +
Violub
Bu

Lte CHeo). 1 B

whs
d-onbital

aso an eneite

the complesc

Uain daton in d- oulitl

Du to
yisht cou
cystal ilel splitbiag doe wol o u . Hee bu
sulrtane 3+

coloula.

qaieie Uganl aabually lound ab khe lor end

(As Ehe ganela ae couhidesl point chages tha aioic

Liqonde should eneetb gabuu splilting llk )
1t doea wot talee into account bhe covalert charetn

Banding Metal caalny

canlsoy compsunda containing
metols

canlbayl conpleeA
t
Ni

TeraheAal

Bonding
Mc Goud fonel by dontia lone RaiL
Eh canbol cabon ¿to vacank bital mebal
M-c
 ati- bending T* onlital nebad
iN) M- bonding aeatu
bond Glw Co ond Metal.

Stalalty ef coandiaatio copsuda:

inaled in bhe statu at auiliin. spis

M+ hL

We unite atalility at cowtont as holaus

M+ L

ke

[MLILL]

|ML1
[MLa][L]

talilit
Alkenakiely Gwall aalility constot
hus
MLu

LMILLJ
The stuwise anl aall skalli
Jelatel

Iastaliilit oanaki coniko

Fovatio Couub.