1 Module1
1 Module1
Delhi, 2015.
Ref. Books:
Module:2 PN Junction diodes: P-N junction Diode, Zener diode, Tunnel diode,
LED, OLED, Varactor diode and Photo Diode
3 0 2 0 4
J C
CAT1 15
FAT 40
Module:1
Semiconductor Fundamentals
Dr. B. Bindu,
Associate Professor,
SENSE
Outline
Energy bands, Fermi level
Direct and indirect band gap, electrons and holes
Doping, intrinsic and extrinsic semiconductors
Generation, recombination and injection of carriers
Drift and Diffusion of carriers
Basic governing equations in semiconductors
Transport Equations
Formation of Energy Bands
When two atoms are completely isolated from eachother, there
is no interation of electron wave functions between them and
they have identical electronic structures.
Band structure at 0K
Direct & Indirect Semiconductor
Direct Semiconductor Indirect Semiconductor
Needs
momentum
change
Ex: GaAs, GaN -> emits light Ex: Si, Ge -> emits heat
Intrinsic Semiconductors
Ideally 100% pure material
Elemental semiconductors
• Silicon (Si)
– Most common semiconductor used today
• Germanium (Ge)
– First semiconductor used in p-n diodes
Compound semiconductors
• Gallium Arsenide (GaAs)
Silicon (Si)
Atomic No. 14
A valence electron in a
nearby bond can move
to fill the broken bond,
making it appear as if the
‘hole’ shifted locations.
Energy Band Diagram
Ei = (EC+EV)/2
Intrinsic level, Ei
n=p=ni
10 −3
ni (Si,300 K )=1. 5 x10 cm
ni versus temperature
Extrinsic Semiconductors
Impurity atoms replace some of the atoms in
crystal
Phosphorous (P) (or Arsenic) replaces a Si atom and forms four covalent
bonds with other Si atoms.
The fifth outer shell electron of P is easily freed to become a conduction
band electron, adding to the number of electrons available to conduct
current.
Boron – Acceptor Impurity in Si
P-type semiconductor
Boron (B) replaces a Si atom and forms only three covalent bonds with
other Si atoms.
The missing covalent bond is a hole, which can begin to move through
the crystal when a valence electron from another Si atom is taken to form
the fourth B-Si bond.
Electron and Hole Concentrations
n = electron concentration 2
p = hole concentration ni =n⋅p
n-type: 2
n = ND, the donor concentration p=ni / N D
p-type:
2
p = NA, the acceptor concentration n=ni / N A
Fermi Level
Electrons in solids obey Fermi Dirac Statistics.
The function f(E) gives the probability that an available energy state E is
occupied by an electron at an absolute temperature T.
At 0K, all the states below EF are filled and above EF are empty. As T
Si Si Si Si Si Si Si Si Si
- +
Si Si Si Si P+ Si Si B- - Si
-
+
Si Si Si Si Si Si Si Si Si
Ec Ec Ec
Ef
E i = Ef Ei Ei
Ef
Ev Ev Ev
n p ni N D ni N A ni
Law of mass action
n N D p N A
ni2 ni2
np ni2 p n
ND NA
Electron and Hole Concentrations
−( E c−E )/kT
f
n=N c e
3/2
2 πmm n kT Nc is called the effective
N c ≡2
[ h2 ] density of states (of
the conduction band) .
−( E f −E )/ kT
v
p=N v e
Nv is called the effective
3 /2 density of states of the
2 πmm p kT
N v≡2
[ h2 ] valence band.
Modern Semiconductor Devices for Integrated Circuits (C. Hu) Slide 1-24
ELECTRON CONC. IN TERMS OF INTRINSIC CONC.
CARRIER TRANSPORT
Drift Currents