SAFETY DATA SHEET

According to Order No. 04/BIM/PER/1/2014

HYDRANSAFE HFDU 46
SDS # : 087820

Section 1. Identification
GHS product identifier : HYDRANSAFE HFDU 46

Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Fire-resistant hydraulic fluid

TOTAL
Supplier's details :
PT TotalEnergies Marketing Indonesia
South Quarter Tower B, 15th Floor
Jalan RA Kartini Kav. 8
Jakarta 12430, Indonesia
Tel: +62 21 7591 6999
Fax: +62 21 7591 6555
[email protected]

TotalEnergies Marketing Asia-Pacific Middle East Pte. Ltd.

182 Cecil Street
#27-01 Frasers Tower
Singapore 069547
Tel: +65 6879 2200
[email protected]

Emergency telephone :
number (with hours of
operation)
Indonesia: 007 803 011 0293 (toll-free in country)
Asia-Pacific: +65 3158 1074

Section 2. Hazards identification

Classification of the : Not classified.
substance or mixture

GHS label elements, including precautionary statements

Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
Prevention : Not applicable.
Response : Not applicable.
Storage : Not applicable.
Disposal : Not applicable.

Other hazards which do not : None known.

result in classification

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Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % (w/w) CAS number

reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-tert-butyl- ≤3 125643-61-0
4-hydroxyphenyl)propionate

Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene ≤0.3 68411-46-1

N-methyl-N-[C18-(unsaturated)alkanoyl]glycine ≤0.3 -
Additional information : The product is made from synthetic base oils

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention if symptoms occur.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Ingestion : Wash out mouth with water. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Do not induce vomiting
unless directed to do so by medical personnel. Get medical attention if symptoms
occur.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

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See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal : Carbon dioxide.
decomposition products carbon monoxide
nitrogen oxides (NO, NO₂ etc.)
Silicon Dioxide

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

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Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8).
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10
for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Benzenamine, N-phenyl-, reaction products with ACGIH TLV (United States).
2,4,4-trimethylpentene TWA: 3 mg/m³ Form: Respirable dust
TWA: 10 mg/m³ Form: Total dust
Advisory OEL : No known significant effects or critical hazards.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary.

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Hydrocarbon-proof gloves
Fluorinated rubber
nitrile rubber
Please observe the instructions regarding permeability and breakthrough time which
are provided by the supplier of the gloves. Also take into consideration the specific
local conditions under which the product is used, such as the danger of cuts,
abrasion, and the contact time.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : None under normal use conditions

Section 9. Physical and chemical properties

The conditions of measurement of all properties are at standard temperature (20°C / 68°F) and pressure (1013 hPa)
unless otherwise indicated
Appearance
Physical state : Liquid.
Color : Colorless.
Odor : Characteristic.
Odor threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Boiling point : Not available.
Flash point : Open cup: 280°C (536°F) [ASTM D 92]
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 0.92 to 0.94 [ASTM D 4052]
Density : 0.92 to 0.94 g/cm³ [15°C] [ASTM D 4052]
Solubility(ies) :
Media Result
cold water Not soluble
hot water Not soluble
Miscible with water : No.

Partition coefficient: n- : Not applicable.

octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): 43.7 to 51 mm2/s (43.7 to 51 cSt) [ASTM D 445]
Flow time (ISO 2431) : Not available.
Particle characteristics
Median particle size : Not applicable.
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Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : Stable under recommended storage and handling conditions (see Section 7).

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.

Incompatible materials : No specific data.

Hazardous decomposition : Carbon dioxide.

products carbon monoxide
nitrogen oxides (NO, NO₂ etc.)
Silicon Dioxide

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity Not available.
Product/substance Result Species Dose Exposure Test
reaction mass of isomers of: LD50 Dermal Rat >2000 mg/kg - OECD 402
C7-9-alkyl 3-(3,5-di-tert-
butyl-4-hydroxyphenyl)
propionate
LD50 Oral Rat >2000 mg/kg - OECD 401
Benzenamine, N-phenyl-, LD50 Oral Rat >5000 mg/kg - -
reaction products with
2,4,4-trimethylpentene
N-methyl-N-[C18- LC50 Inhalation Dusts Rat - Male 1.8 mg/l 4 hours -
(unsaturated)alkanoyl] and mists
glycine
LD50 Oral Rat >5000 mg/kg - -
Conclusion/Summary : Based on available data, the classification criteria are not met.
Irritation/Corrosion Not available. Not available. Not available.
Product/substance Result Species Score Exposure Test
reaction mass of isomers of: Eyes - Edema of the Rabbit 0 - OECD 405
C7-9-alkyl 3-(3,5-di-tert- conjunctivae
butyl-4-hydroxyphenyl)
propionate
Skin - Edema Rabbit 0 4 hours OECD 404
Skin : Based on available data, the classification criteria are not met.
Eyes : Based on available data, the classification criteria are not met.
Respiratory : Based on available data, the classification criteria are not met.
Sensitization Not available. Not available.

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Product/substance Route of Species Result

exposure
reaction mass of isomers of: skin Guinea pig Not sensitizing
C7-9-alkyl 3-(3,5-di-tert-
butyl-4-hydroxyphenyl)
propionate
Skin : Based on available data, the classification criteria are not met.
Respiratory : Based on available data, the classification criteria are not met.
Mutagenicity Not available.
Product/substance Test Experiment Result
reaction mass of isomers of: OECD 471 Experiment: In vitro Negative
C7-9-alkyl 3-(3,5-di-tert- Subject: Bacteria
butyl-4-hydroxyphenyl)
propionate
OECD 473 Experiment: In vitro Negative
Subject: Mammalian-Animal
Cell: Somatic
OECD 474 Experiment: In vivo Negative
Subject: Mammalian-Animal
Cell: Somatic
:
Conclusion/Summary : Based on available data, the classification criteria are not met.
Carcinogenicity Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Reproductive toxicity Not available.
Product/substance Maternal Fertility Development Species Dose Exposure
toxicity toxin
reaction mass of isomers of: - Negative Negative Mouse - Male, Oral -
C7-9-alkyl 3-(3,5-di-tert- Female
butyl-4-hydroxyphenyl)
propionate
- - - Rabbit Oral -
Conclusion/Summary : Based on available data, the classification criteria are not met.
Teratogenicity Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Specific target organ toxicity (single exposure)
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Specific target organ toxicity (repeated exposure)
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Aspiration hazard
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.

Information on the likely : Not available.

routes of exposure

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Potential acute health effects

Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Product/substance Result Species Dose Exposure
reaction mass of isomers of: Sub-acute NOAEL Oral Rat - Male, 5 mg/kg NOAEL -
C7-9-alkyl 3-(3,5-di-tert- Female
butyl-4-hydroxyphenyl)
propionate
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Product/substance Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts
(ppm) (mg/l) and mists)
(mg/l)
N-methyl-N-[C18-(unsaturated)alkanoyl]glycine N/A N/A N/A N/A 1.8

Other information Not available.

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Section 12. Ecological information

Toxicity
Product/substance Result Species Exposure Test
reaction mass of isomers of: Acute EC50 3.1 mg/l Algae - Scenedesmus 72 hours OECD 201
C7-9-alkyl 3-(3,5-di-tert-butyl-
4-hydroxyphenyl)propionate
Acute EC50 >100 mg/l Daphnia - Daphnia magna 24 hours OECD 202
Acute LC50 74.1 mg/l Fish 96 hours -
Chronic NOEC <0.01 mg/l Daphnia - Daphnia magna 21 days OECD 211
N-methyl-N-[C18- Acute LC50 9.3 mg/l Fish - Leuciscus idus 96 hours -
(unsaturated)alkanoyl]glycine
Acute NOEC 0.91 mg/l Algae - Desmodesmus 72 hours 201
subspicatus

Persistence/degradability
Product/substance Aquatic half-life Photolysis Biodegradability
reaction mass of isomers of: - - Not readily
C7-9-alkyl 3-(3,5-di-tert-butyl-
4-hydroxyphenyl)propionate
Benzenamine, N-phenyl-, - - Not readily
reaction products with
2,4,4-trimethylpentene
N-methyl-N-[C18- - - Readily
(unsaturated)alkanoyl]glycine

Bioaccumulative potential
Product/substance LogKow BCF Potential
reaction mass of isomers of: 9.2 260 low
C7-9-alkyl 3-(3,5-di-tert-butyl-
4-hydroxyphenyl)propionate
Benzenamine, N-phenyl-, 5.1 1730 high
reaction products with
2,4,4-trimethylpentene

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Mobility in soil : Given its physical and chemical characteristics, the product generally shows low soil
mobility The product is insoluble and floats on water Loss by evaporation is limited

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction. Waste packaging should be recycled. Incineration or landfill

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should only be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Empty containers or liners may retain
some product residues. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.

Section 14. Transport information

ADR IMDG ICAO/IATA
UN/ID No Not regulated. Not regulated. Not regulated.

UN proper - - -
shipping name
Transport hazard - - -
class(es)

Packing group - - -
Environmental No. No. No.
hazards

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

Section 15. Regulatory information

Law No. 74/2001 - Banned
None of the components are listed.
Law No. 74/2001 - Restricted
None of the components are listed.
Law No. 74/2001 - : Not determined
Chemicals that may be used
Ministry of Health - Law No. 472/Menkes/Per/V/1996
Carcinogen
None of the components are listed.
Corrosive
None of the components are listed.
Irritation
None of the components are listed.
Mutagen
None of the components are listed.
Oxidizer
None of the components are listed.

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Poison
None of the components are listed.
Teratogen
None of the components are listed.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.

Rotterdam Convention on Prior Informed Consent (PIC)

Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia inventory (AIIC) : All components are listed or exempted.
Canada inventory (DSL/NDSL) : All components are listed or exempted.
China inventory (IECSC) : All components are listed or exempted.
Europe inventory (EC) : All components are listed or exempted.
Japan inventory : Japan inventory (CSCL): All components are listed or
exempted.
Japan inventory (ISHL): All components are listed or
exempted.
New Zealand Inventory of Chemicals (NZIoC) : All components are listed or exempted.
Philippines inventory (PICCS) : All components are listed or exempted.
Korea inventory (KECI) : All components are listed or exempted.
Taiwan Chemical Substances Inventory (TCSI) : All components are listed or exempted.
Thailand inventory : Not determined.
Turkey inventory : Not determined.
United States inventory (TSCA 8b) : All components are listed or exempted.
Vietnam inventory : Not determined.
The information stated in this section relates solely to the conformity of the chemical product with the
countries Inventories. The information used to confirm the inventory status of this product may be based on
additional data to the chemical composition shown in Section 3. Other regulations may apply for importation
or marketing authorizations.

Section 16. Other information

History
Date of revision : 2023/05/29
previous revision date : 2022/05/10
Version : 1.01

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Key to abbreviations : ATE = Acute Toxicity Estimate

BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Procedure used to derive the classification
Classification Justification
Not classified.
References : Not available.
Indicates information that has changed from previously issued version.
Disclaimer
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

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