KUIZ KIMIA KEBANGSAAN MALAYSIA (K3M) 2008 Peringkat Lanjutan Tingkatan 6 dan Matrikulasi Tarikh: 17 Julai, 2008 (Khamis) Masa: 10.00 pagi - 11.20 pagi Arahan: 1. Anda dilarang membuka kertas soalan ini sehingga diarahkan oleh guru pengawas anda. 2. Kertas soalan ini mengandungi 14 muka surat. 3. Kertas soalan ini mengandungi 40 soalan, soalan 1 hingga 40 adalah dalam Bahasa Inggeris. Anda dikehendaki menjawab semua soalan dalam jangka masa 1 jam 20 minit. 10 minit tambahan diberikan untuk mengisi dan menghitamkan nama peserta, nombor kad pengenalan peserta, kod sekolah, nama sekolah, alamat sekolah, tingkatan dan poskod. 4, Semua jawapan hendaklah ditanda dalam Borang Jawapan OMR yang dibekalkan dengan menggunakan pensel 2B. 5. Penggunaan kalkulator yang tidak boleh diprogramkan adalah dibenarkan © Institut Kimia Malaysia, IKM Tiada sebarang bahagian daripada kertas soalan ini boleh dicetak semula tanpa kebenaran daripada IKM.Kurz KiMIA KEBANGSAAN MALAYSIA (K3M) 2008 ahan mengisi Borang Jawapan OMR: Anda diminta mematuhi peraturan berikut semasa mengisi Borang Jawapan OMR. 1, Jangan lipat Borang Jawapan OMR. 2. Hitamkan sepenuhnya seperti (@®) dengan menggunakan pensel 2B 3. Jika ada kesilapan, padamkan kesilapan yang berkenaan sepenuhnya. 4, Tuliskan nama anda, nama sekolah dan alamat sekolah anda dalam ruang yang berkenaan dengan menggunakan huruf besar. 5. Tuliskan nama, nombor kad pengenalan, poskod dan kod sekolah anda serta hitamkan huruf atau angka yang berkenaan dalam ruang yang disediakan. 6. Hitamkan ruang ‘jantina’, ‘bangsa’ dan ‘tingkatan’ seperti (@. 7. Sekiranya kod sekolah tidak diisi dengan betul seperti dalam arahan, penyertaan tersebut akan dibatalkan.Kui Kini Regs Sblayso Ki 2008 PeringhotLanjvior 1 2. Based on the valence shell electron pair repulsion theory, what is the general shape of NF3? A. T-shape B, Tetrahedral [Link] pyramidal D. Planar with bond angle 120° Which of the following is NOT true of {Cu(NH3)s]SO.? A. Itis dark blue. B. There are 2 types of bonding in the compound. C. When | mole af the compound is dissolved in water, 2 mnoles of ions are formed. D. A blue precipitate is formed when aqueous sodium hydroxide solution is added. Which of the following Groups of elements react to form crystals of high solubility in water? A. Groups | and 17 B. Groups 2 and 16 C. Groups 13 and 16 D. Groups 14 and 17 Wireless router, which transmits microwave radiation, should not be placed near an aquarium as this would cause signal degradation. Why is this so? A. Aquarium glass blocks the microwave signal. B. Water in the aquarium absorbs microwave signal. C. Glass of the aquarium reflects the microwave signal. D, Temperature of the aquarium affects the microwave transmission.Kite Kimi Kebangsaan Molasso (R.A 2008 Perinat Lanier 5. An unknown organie compound, Z, analysed by mass spectrometry gave a molecular mass of 114 g mot”, An elemental analysis was also performed which showed that the compound contained 63% C, 9% H and 28% by mass. Which one of the following is compound 2? A CH, we NON AO BL ge a ea CG ee D. Heis Kini Ketan Malays (K 4 2008 Perumght Lajos What is the hybridization of carbon atoms 1, 2, and 3, respectively in the structure of the following compound? Hy an 4 N28 erat | usa A. sp’, sp, sp? BL [Link]’, Co spl, sp, sp? D. sp*.sp?, sp® Glycine (NH2CH2COOH) is the simplest member of a class of compounds. What is this class of compounds? A. Lipids B. Amino acids C. Carbohydrates D. Carboxylic acids If iodoethane is heated with ammonia in a sealed tube, which one of the following is not one of the products? A. CoHsNFb B. (CoHs)sN'T C. CHsNHCH; D. GHsNHGHs Treatment of 0.500 g of an impure sample of Fe;Q, led to the precipitation of the iron as iron(Iil) hydroxide. The precipitate was heated and 0.498 g of FexO3 was obtained, What is the percentage of FexOs in the original sample? A. 69.0 B. 963 Cc. 99.6 D, 35.0nie Rint Kebangsoan Melaysie (86) 2008 Pevingn Cannan to. He 12. The acid dissociation constant for propanoic acid is 1.35 x 10 mol dav at 298 K, The pH of 0.100 mol din” of the acid is 2.93. atement is true of the acid if it is diluted to Which of the following s 0.010 mol dm’? A. The pH vahee is 3.93. B. The acid becomes weaker C. The degree of dissociation increases, D, The acid dissociation constant is decreased. Limonene is an oi] found in the peel of citrus fruits, CHy CH. NF 2 CH, When limonene is left to be oxidised by a strong oxidising agent, which of the following does not react with the product? A. Alkaline iodine B. Bromine water C. Sodium hydroxide solution D. 2,4-dinitrophenylhydrazine Nitrobenzene, CsHsNOz, is formed from nitration of benzene. Why aniline, CsHsNHz2, is not formed from the direct reaction between benzene and ammonia? A. Ammonia is a nucleophile. B. Ammonia is a Lewis acid. C. Ammonia has lone pair electrons, D. Benzene cannot undergo electrophilic addition reaction,Kus Kania Kehna Motes (RM) 2068 Pein toninan 13. 14, 15. 16. A sample of ethylbenzene, CoHsCH2CHs, is heated with an excess of alkaline potassium manganate(VI) solution, A white precipitate is obtained when a mineral acid is added to the mixture. ‘What is the maximum mass of the white precipitate formed from 5.00 g of ethylbenzene? AL 5.758 B. 641g C 783g D. 832g When solid silver chloride is shaken with aqueous potassium iodide, the colour of the solid gradually turns from white to yellow What causes this to happen? A. The CI ion diplaces the I’ ion, B. The Ky of Ag! is lower than the Ky of AgCL C. The Ky of AgCl is lower than the Key of Agt. D. Chlorine is a stronger oxidising agent than iodine. A liquid X is distilled together with steam at 95.6° C and 101 kPa, Given the relative molecular mass of X is 162 and the vapour pressure of water at that temperature is 8.5 x 10° Pa, what is the mass of X in 250 g of the distillate? A. 15728 B. 156.02 CG 166.0 D. 167.1 What is an ideal solution? A. Asolution which obeys Raoult’s law. B. A solution that releases heat when formed C. A solution whose vapour follows the ideal gas law. D. A solution whose vapour shows ideal behaviour,Koi Kimia Keanu Moles 84) 2008 Pertighat Lantutan 17. 18, 19. 20. Which of the following is always correet for a system in dynamic equilibrium? A+B === C+D AL [AJB] = [C]D] B. [C)[D]> [AJB] C. The rate of the forward reaction equals the rate of the reverse reaction. D, The activation energy for the forward reaction equals the activation energy for the reverse reaction. The equilibrium constant Ky for the following reaction is 319 Pa at 298 K and 1.8 x 10° Pa at $800 K, CaCOs(s) == Ca0(s) + COr(e) Which of the following statement is correct? ‘A. The forward reaction is endothermic. B. Increasing pressure will increase the yield of CO> The value of Kp depends on the amount of CaCO: used, The amount of CO> produced is not affected by temperature. ‘The E® values of two half cells are given below: 210° +2HO+2e¢ —* Ch.4 OW Cht2e— 21 +0.40V +1.36V If the cell reaction is: Ch +2 0H —* ClO’ + Cr + 4,0 ‘What is the emf of the cell formed? A. (0.68 ~ 0.40) V B. (136-040) V C. (0.68 40.40) V D. (136-040) =2V Given the standard electrode potential (E°) of a silver electrode, Ag’/Ag(1.0M) is +0.80 V, what is the electrode potential (E) ofa silver electrode, Ag’/Ag (0.5M)? A, +0.68V B, +0.76V Cc. +0.78V D. +0.82VKs Kina Kebargsann Malays (88D 2008 Perinat Leap dU, 2. Gold crystallises in face centered cubic lattice. How many unit cells are there in a gold sample whose mass is 1.560 g? (Relative atomic mass: Au, 196.97) A 115x108 B. 6.78x 10"? C1.19x 10 D. 2.00.x 10 At high temperature, nitrogen monoxide, NO, reaets with hydrogen as shown in the following equation 2NO(g) + 2 Halg) —* Noe) +2 H:0(g) Table 1 shows the experimental results obtained during a study of the reaction at temperature 7K. Table 1 EEE Experimental Initial initial rate number concentration of | concentration of | ‘mol dm s i NO /mol dm* Hyfmoldm® | | i 0.0020 0.010 0.0028 2H 0.0060 | 0.010 0.0248 3 0.0020 0.020 0.0055 4 0.030 r What is the expected value of r? A. 0.0055 B. 0.0165 C. 0.0336 D. 0.0990 An aqueous solution containing Y”" ions forms a precipitate when an aqueous solution of potassium iodide is added to it. The solubility of the precipitate is 0.553 g dm” and its solubility product is 6.91 X 10°? mol* dm’? at 25°C. What is the relative atomic mass of ¥? AL 137 B. 207 Cc. 226 D. 461i Kiva Brannan Matas (R89) 2008 Perimstot Lompatan 24, Figure 1 is a map of a countryside. limestone is be ale : | w v | «BE ons | “ee £ 66%, XO 6 ages iow | Hee yo | 2: | oan | | \ Figure | At points V, W, X, ¥ and Z, water samples were taken and the concentrations of various analytes determined. The results are shown in the Table 2. Sample number i 4 | Dissolved oxygen (mg L) 8.0 2.5 pa 7 18.0 35 C (ng Le) {05 6x10 Ca™ (mg L") [Sx 1G? 5x10 [Coliform count (per 100 mL) [50 4000 Table 2 Which one of the choices correctly matches each sample to the location from which it was taken? ‘Sample No. 1 7 [4 7s] A Zz v__|y¥_ |x _|w B. Z wx fy lv C w|z_iy [x [v D. Zz v__ tx ly TwKia Kina Kebangsacan Malaya (R84) 2008 Perwghae Lampe 26. The standard reduction potentials of silver and nickel are E%(Ag"/ Ag) = + 0.80 V and E*(Ni?/Ni) = ~ 0.23 V. Which of the following statements is true? A. Ag! isan oxidising agent but Ni* is a reducing agent a better oxidising agent than Ni?” and Ag is @ better reducing agent than Ni a better oxidising agent than Ag’ and Ag is a better reducing agent than Ni, D. Ag" isa better oxidising agent than Ni” and Ni is a better reducing agent than Ag. 20 ml. of solution X was pipetted into a conical flask and titrated with solution ¥ from a burete. The pH was monitored with a pH meter throughout the experiment, and was plotted against the volume of solution ¥ added to give the graph below. oo so 500 180 20 250 m0 260 40g Volume of tant} Which of the following choices best identify the solutions Xand Y? x y A. KOH CH;COOH B. NaHCO; HBr C. CH;COOH NaHCO; D. HBr NaHCO;Kui Kine Ketargsran Moly (KM 2008 Perinat Lenten 21. 28. 29, What is the enthalpy change for the complete combustion of one mole of liquid isopropanol (molecular formula C;Hs0)? 3.C(s) #4 Ha (g) + 2 Og) — CH,O 4H =-318 ki mol! Cs) + O2(g) ——* COr(g) AH = -394 kJ mot! Ha (g) + 4 O2(g) —* H20() AH = -286 kJ mol! A, -362 KI B. -998kI C. -2008 ki D. -4016 kT A useful acid-base indicator is quinaldine red. In solution with pH below 1.5, it is colourless while it is red in solution with pH greater than 3.5 Which of the following solution will turn red if few drops of quinaldine were added? 1 0.1 MHCI Tl, 0.05 MNH3 Ill. 0.0005 M CH;COOH A. Land Il B. [and IU C. Mand til D. I, Mand Il In order to determine the sulphate composition of a fertiliser, a chemist dissolved 2.00 g of fertiliser in 100 mL of water, and added barium nitrate solution. The chemist noticed the formation of a white solid, and kept adding the barium nitrate solution until ne more solid is formed, The white solid was filtered and, after drying, weighed 1.90 g. What is the percentage by mass of sulphate in the fertiliser? (Relative atomic mass: Ba, 137; 8, 32; 0,16) A. 39.2 B. 41.0 Cc. 78.1 D. 95.5 10Ki Konia Rebun Malaysia (896 00h PermgbotLajutan 30. 3h. 32. The following equation represents the oxidation of an organic pollutant by potassium dichromate(V1) in the determination of the extent of pollution + 4 3 [organic pollutant] + [Link],0;7 + 16 HY + 3CO; + 8H,0 If the volume of dichromate(VI) reacted with 1.5 mL of the organic pollutant is 10.30 mL and its molarity is 0.0933 M, what is the concentration of the organic pollutant in millimole per litre? A. 427 B. 641 Cc. 961 D. 1441 In the characterization of water or wastewater sample, total solids (TS) determination is performed (0 assess the total amount of soluble and insoluble solids present by evaporating the water to dryness; whereas total volatile solids (TVS) is the organic portion in TS and it is obtained by heating TS at 550°C, Weight of empty crucible = 48.6212 2 Weight of crucible + dry solids after evaporation of water = 48.6432 g Weight of crucible + unburned solids after heating at 550°C = 48.6300 g Volume of water sample 15 mL What are the values of TS and TVS in mg/L? 4S (mg/L) TVS (mg/L) A. 1470 880 B. 220 587 Cc. 22.0 13,2 D. 1.47 0.88, An element exists in two solid forms M and M’, The standard enthalpies of combustions to the oxides MO: and M’Q at 298 K are ~ 400 kJ mol" and = 405 kJ mol! respectively. What is the enthalpy change for the transition from M to M’ under standard conditions at 298 K? A. -5kJ mol! B. - 805 kJ mol” Cc. +5kImol™ D. +10k) mol? nKis Rimi Kebamgzaan Maley KB) 2008 PorigtasLanjtc 36. A current of 5.0 A is passed for 5 minutes through five aqueous solutions connected in series. The anode in each solution is the metal of the cation in the same solution while the cathode is carbon Which of the following cell anode will have the largest change in mass? A. AgiAg’. 1.0 mol L! . AVAL, 1.0 mol L™ C. CwCu™, 2.0 mol L" D. Zn/Zn**, 2.5 mol L'! ‘The amount of oxygen required to oxidise an organic substance to carbon dioxide and water can be calculated by stoichiometry if the chemical composition of the substance is known. This amount of oxygen is known as the theoretical oxygen demand (ThOD), What is the ThOD of 108.8 mg/L of glucose? (Relative atomic mass: C,12; Hl; 0,16) A, 19.3 mg/L B. 116 mg/l. C. 180 mg/L D. 192 mg/L ‘The vapour pressure of benzene is 9.90 x 10° Pa at 300 K. What is the vapour pressure of a solution containing 12.8 g of naphthalene, CyoHls, in 100 g of benzene at the same temperature? A, 9.18x 10° Pa B. 9.25 10° Pa C. 9.90 x10' Pa D. 20.0 x10" Pa Consider the following reaction: H,(g) + h(g) === 2HI(g) 4H = - 9.6K What is the effect of increasing pressure? A. Increases the rate of the forward reaction only. B. Increases the rate of the reverse reaction only C. _ Increases the rate of bota forward and reverse reactions by the same factor. D. Increases the rate of forward reaction more than the rate of the reverse reactionie Sti Keberseen Malays 84) 2008 Perigh Lenten 37. 38, 39. The activation energy of the following reaction is 99 kl. 2N Kg) ——* 2NO(e) + Ch (z) Which of the following statements is correct? A. The enthalpy of reaction is + 99 kJ/mol B. The activation energy for the reverse reaction is -99 kl The enthalpy of formation of NOCI(g) is - 49.5 ki/mol. D. In the presence of a suitable catalyst, the activation energy will be lower than 99 kl. ‘The electronegativities of five elements are given in the table below: Be P Electronegativity | _0.7 Which of the following bonds has the least ionic character? AW R-T B. P-S Cc Q-T D. P-Q Given the following reaction, Pals) + 5 Or(g) ——» 2 P20s(s) If the initial rate of reaction consumes 1 mole per second of phosphorus, Ps, what is the initial rate of consumption of oxygen? A. 0.2 moles per second B. | mole per second C. 2 moles per second D. 5 moles per secondic Ka Kebangsan Malay eK 2008 Povingtt Lajas 40. Consider the Maxwell-Boltzmann distribution curves below Nef noleeles What is the fraction of molecules having energy greater than £1 at temperature 72? R+O P+O AL +O P R P+O R+O P+Q-RKUIZ KIMIA KEBANGSAAN MALAYSIA (K;M) 2008 JAWAPAN UNTUK SOALAN ARAS LANJUTAN Arjuran ee ale oe ao 22ulic kon amen a 230i Aaa 24 |p INSTITUT KIMIA MALAYSIA Epa) 25 |p cian 26 |B 220 Bm eamalc A Seale 20) Las aed toc 30 |c fee el aa oma a2 |e 13 [a somalia 4 |B 34 |B 1s [A asm 1s |A 36 [c KEMENTERIAN TAG alo PELAJARAN MALAYSIA as [A 38 [A 19 |B Soman 0) 20 |e 40 [A