SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006
ULTRION™ 71223

Section: 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: ULTRION™ 71223

Substance type: CLP Mixture

1.2 Relevant identified uses of the substance or mixture and uses advised against:

Use of the Substance/Mixture : WATER CLARIFICATION AID

Identified uses : Water clarification Aid

Recommended restrictions on use : Reserved for industrial and professional use.

1.3 Details of the supplier of the safety data sheet:

Company : Nalco Ltd.

P.O. BOX 11, WINNINGTON AVENUE
NORTHWICH, CHESHIRE, U.K. CW8 4DX
+44 (0)1606 74488
For Product Safety information please contact:
[email protected]

1.4 Emergency telephone number:

Emergency telephone number : +44 1618841235

+32-(0)3-575-5555 Trans-European

Poison Information Centre : For medical professionals only: 0344 892 0111 Poison Control
telephone number Center

Date of Compilation/Revision: 07.12.2022

Version Number: 2.4

Section: 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Corrosive to metals, Category 1 H290

Serious eye damage, Category 1 H318

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H290 May be corrosive to metals.

H318 Causes serious eye damage.

Precautionary Statements : Prevention:

P234 Keep only in original packaging.

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P280e Wear eye protection/face protection.

Response:
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously
with water for several minutes. Remove
contact lenses, if present and easy to do.
Continue rinsing. Immediately call a
POISON CENTER or doctor/ physician.
P390 Absorb spillage to prevent material
damage.

Hazardous components which must be listed on the label:

Aluminum Chloride Hydroxide Sulphate

2.3 Other hazards

None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
Hazardous components
Chemical Name CAS-No. Classification Concentration:
EC-No. (REGULATION (EC) No 1272/2008) [%]
REACH No.
Aluminum Chloride 39290-78-3 Corrosive to metals Category 1; H290 20 - < 25
254-400-7 Serious eye damage Category 1; H318
Hydroxide Sulphate
01-2119531563-43

Dimethylamine - 25988-97-0 Chronic aquatic toxicity Category 3; H412 2.5 - < 5

607-843-9
Epichlorohydrin
Copolymer

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section: 4. FIRST AID MEASURES

4.1 Description of first aid measures

If inhaled : Remove to fresh air.
Treat symptomatically.
Get medical attention if symptoms occur.

In case of skin contact : Wash off with soap and plenty of water.
Get medical attention if symptoms occur.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Get medical attention immediately.

If swallowed : Rinse mouth.

Get medical attention if symptoms occur.

Protection of first-aiders : In event of emergency assess the danger before taking action.
Do not put yourself at risk of injury. If in doubt, contact
emergency responders.Use personal protective equipment as

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ULTRION™ 71223

required.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.

4.3 Indication of immediate medical attention and special treatment needed

Treatment : Treat symptomatically.

Section: 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : None known.

media

5.2 Special hazards arising from the substance or mixture

Specific hazards during : Not flammable or combustible.
firefighting

Hazardous combustion : Depending on combustion properties, decomposition products

products may include following materials:
Carbon oxides
nitrogen oxides (NOx)
Hydrogen chloride

5.3 Advice for firefighters

Special protective equipment : Use personal protective equipment.
for firefighters

Further information : Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations. In the
event of fire and/or explosion do not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency : Ensure adequate ventilation.
personnel Keep people away from and upwind of spill/leak.
Avoid inhalation, ingestion and contact with skin and eyes.
When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.
Ensure clean-up is conducted by trained personnel only.
Refer to protective measures listed in sections 7 and 8.

Advice for emergency : If specialised clothing is required to deal with the spillage, take
responders note of any information in Section 8 on suitable and unsuitable
materials.

6.2 Environmental precautions

Environmental precautions : Do not allow contact with soil, surface or ground water.

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6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Stop leak if safe to do so.
Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Flush away traces with water.
For large spills, dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway.

6.4 Reference to other sections

See Section 1 for emergency contact information.
For personal protection see section 8.
See Section 13 for additional waste treatment information.

Section: 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling : Do not breathe spray, vapour. Do not get in eyes, on skin, or
on clothing. Wash hands thoroughly after handling. Use only
with adequate ventilation.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Remove and wash contaminated clothing before re-
use. Wash face, hands and any exposed skin thoroughly after
handling. Provide suitable facilities for quick drenching or
flushing of the eyes and body in case of contact or splash
hazard.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep away from strong bases. Absorb spillage to prevent
areas and containers material damage. Keep out of reach of children. Keep
container tightly closed. Store in suitable labelled containers.

Storage temperature : 0 °C to 30 °C

Suitable material : The following compatibility data is suggested based on similar

product data and/or industry experience: HDPE (high density
polyethylene), Polypropylene, PTFE, Glass, Rubber,
Fluoroelastomer, Perfluoroelastomer, Compatibility with Plastic
Materials can vary; we therefore recommend that compatibility is
tested prior to use.

Unsuitable material : The following compatibility data is suggested based on similar

product data and/or industry experience: Metals

7.3 Specific end uses

Specific use(s) : WATER CLARIFICATION AID

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Contains no substances with occupational exposure limit values.

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DNEL
Aluminum Chloride Hydroxide : End Use: Workers
Sulphate Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 40.1 mg/m3

PNEC
Aluminum Chloride Hydroxide : Fresh water
Sulphate Value: 0.0003 mg/l

Marine water
Value: 0.00003 mg/l

Sewage treatment plant

Value: 20 mg/l

8.2 Exposure controls

Appropriate engineering controls
Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Individual protection measures

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.Remove and wash contaminated clothing before re-
use.Wash face, hands and any exposed skin thoroughly after
handling.Provide suitable facilities for quick drenching or
flushing of the eyes and body in case of contact or splash
hazard.

Eye/face protection (EN : Safety goggles

166) Face-shield

Hand protection (EN 374) : Recommended preventive skin protection

Gloves
Nitrile rubber
butyl-rubber
Breakthrough time: 1 – 4 hours
Minimum thickness for butyl-rubber 0.3 mm for nitrile rubber
0.2 mm or equivalent (please refer to the gloves
manufacturer/distributor for advise).
Gloves should be discarded and replaced if there is any
indication of degradation or chemical breakthrough.

Skin and body protection : Wear suitable protective clothing.

(EN 14605)

Respiratory protection (EN : When respiratory risks cannot be avoided or sufficiently

143, 14387) limited by technical means of collective protection or by
measures, methods or procedures of work organization,
consider the use of certified respiratory protection equipment
meeting EU requirements (89/656/EEC, (EU) 2016/425), or
equivalent, with filter type: P

The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith
based on typical expected conditions of use. PPE selection should always be completed in conjunction with
a proper risk assessment and in accordance with a PPE management program.

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Environmental exposure controls

General advice : Consider the provision of containment around storage
vessels.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance : Liquid

Colour : colourless
Odour : odourless
Flash point :
does not flash
pH : 2, 100 %

Odour Threshold : no data available

Melting point/freezing point : -10 °C
Initial boiling point and boiling : 100 °C
range
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : 1.2 (20 °C)
Solubility(ies)
Water solubility : completely soluble
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water
Auto-ignition temperature : no data available
Thermal decomposition : no data available

Viscosity
Viscosity, dynamic : no data available
Viscosity, kinematic : < 80 mm2/s (20 °C)

Explosive properties : no data available

Oxidizing properties : no data available

9.2 Other information

no data available

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Section: 10. STABILITY AND REACTIVITY

10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

Conditions to avoid : Extremes of temperature

10.5 Incompatible materials

Materials to avoid : Mild steel
Aluminium
Strong bases

10.6 Hazardous decomposition products

Hazardous decomposition : Depending on combustion properties, decomposition products
products may include following materials:
Carbon oxides
nitrogen oxides (NOx)
Hydrogen chloride

Section: 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Toxicity

Product
Acute oral toxicity : There is no data available for this product.
Acute inhalation toxicity : There is no data available for this product.
Acute dermal toxicity : There is no data available for this product.
Skin corrosion/irritation : There is no data available for this product.

Serious eye damage/eye : There is no data available for this product.

irritation

Respiratory or skin : There is no data available for this product.

sensitization

Carcinogenicity : There is no data available for this product.

Reproductive effects : There is no data available for this product.

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Germ cell mutagenicity : Contains no ingredient listed as a mutagen

Teratogenicity : There is no data available for this product.

STOT - single exposure : There is no data available for this product.

STOT - repeated exposure : There is no data available for this product.

Aspiration toxicity : There is no data available for this product.

Components
Acute oral toxicity : Aluminum Chloride Hydroxide Sulphate
LD50 Oral Rat: 3,450 mg/kg

Potential Health Effects

Eyes : Causes serious eye damage.

Skin : Health injuries are not known or expected under normal

use.

Ingestion : Health injuries are not known or expected under normal

use.

Inhalation : Health injuries are not known or expected under normal

use.

Chronic Exposure : Health injuries are not known or expected under normal
use.

Experience with human exposure

Eye contact : Redness, Pain, Corrosion

Skin contact : No symptoms known or expected.

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Further information : no data available

Section: 12. ECOLOGICAL INFORMATION

12.1 Toxicity

Product
Environmental Effects : This product has no known ecotoxicological effects.

Toxicity to fish : no data available

Toxicity to daphnia and other : no data available

aquatic invertebrates

Toxicity to algae : no data available

Components

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Toxicity to algae : Aluminum Chloride Hydroxide Sulphate

72 h LC50: 14 mg/l

12.2 Persistence and degradability

Product
Biodegradability : Greater than 95% of this product consists of inorganic
substances for which a biodegradation value is not
applicable.
Result: Biodegradable

Components
Biodegradability : Aluminum Chloride Hydroxide Sulphate
Result: Not applicable - inorganic

Dimethylamine - Epichlorohydrin Copolymer

Result: Biodegradable

12.3 Bioaccumulative potential

Product
Bioaccumulation : This preparation or material is not expected to bioaccumulate.

12.4 Mobility in soil

Product
The portion in water is expected to be soluble or dispersible.

12.5 Results of PBT and vPvB assessment

Product
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

12.6 Other adverse effects

No adverse effects expected.

Section: 13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with the European Directives on waste and hazardous waste.Waste codes should
be assigned by the user, preferably in discussion with the waste disposal authorities.

13.1 Waste treatment methods

Product : Where possible recycling is preferred to disposal or
incineration.
If recycling is not practicable, dispose of contents/container in
accordance with local regulations
Dispose of wastes in an approved waste disposal facility.

Contaminated packaging : Dispose of as unused product.

Empty containers should be taken to an approved waste

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handling site for recycling or disposal.

Do not re-use empty containers.

Guidance for Waste Code : Inorganic wastes containing dangerous substances. If this
selection product is used in any further processes, the final user must
redefine and assign the most appropriate European Waste
Catalogue Code. It is the responsibility of the waste generator
to determine the toxicity and physical properties of the
material generated to determine the proper waste
identification and disposal methods in compliance with
applicable European (EU Directive 2008/98/EC) and local
regulations.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in
compliance with the selected mode of transport.

Land transport (ADR/ADN/RID)

14.1 UN number: UN 3264
14.2 UN proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
(Aluminum Chloride Hydroxide Sulphate)
14.3 Transport hazard class(es): 8
14.4 Packing group: III
14.5 Environmental hazards: No
14.6 Special precautions for user: Not applicable.

Air transport (IATA)

14.1 UN number: UN 3264
14.2 UN proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
(Aluminum Chloride Hydroxide Sulphate)
14.3 Transport hazard class(es): 8
14.4 Packing group: III
14.5 Environmental hazards: No
14.6 Special precautions for user: Not applicable.

Sea transport (IMDG/IMO)

14.1 UN number: UN 3264
14.2 UN proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
(Aluminum Chloride Hydroxide Sulphate)
14.3 Transport hazard class(es): 8
14.4 Packing group: III
14.5 Environmental hazards: No
14.6 Special precautions for user: Not applicable.
14.7 Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and the IBC
Code:

Section: 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

Seveso III: Directive : Not applicable.

2012/18/EU of the European
Parliament and of the Council

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on the control of major-

accident hazards involving
dangerous substances.

Candidate List of Substances : Not applicable.

of Very High Concern for
Authorisation

INTERNATIONAL CHEMICAL CONTROL LAWS

CANADA
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have
been reported in accordance with the New Substances Notification Regulations.

United States TSCA Inventory

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

NATIONAL REGULATIONS GERMANY

Water contaminating class : WGK 2
(Germany) Classification according to AwSV, Annex 1

15.2 Chemical Safety Assessment:

A Chemical Safety Assessment has been carried out for some of the substances in this mixture.

Section: 16. OTHER INFORMATION

Procedure used to derive the classification according to REGULATION (EC) No 1272/2008

Classification Justification
Corrosive to metals 1, H290 Calculation method
Serious eye damage 1, H318 Calculation method
Full text of H-Statements
H290 May be corrosive to metals.
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.

Full text of other abbreviations

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods by
Road; AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No
1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute
for Standardisation; DSL - Domestic Substances List (Canada); ECHA - European Chemicals Agency; EC-
Number - European Community number; ECx - Concentration associated with x% response; ELx - Loading
rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical
Substances (Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally
Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on
Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration;
ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in
China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL -
Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI -
Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 -

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Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the
Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-
operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,
Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical
Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of
Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data
Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical Substance Inventory; TECI -
Thailand Existing Chemicals Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very
Bioaccumulative

Further information
Sources of key data used to : IARC Monographs on the Evaluation of the Carcinogenic Risk
compile the Safety Data of Chemicals to Man, Geneva: World Health Organization,
Sheet International Agency for Research on Cancer.

The possible key literature references and data sources which

may have been used in conjunction with the consideration of
expert judgment to compile this Safety Data Sheet: European
regulations/directives (including (EC) No. 1907/2006, (EC) No.
1272/2008), supplier data, inter-net, ESIS, IUCLID, ERIcards,
Non European official regulatory data and other data sources.

Prepared By : Regulatory Affairs

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is
indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text.

Annex: Exposure Scenarios

Exposure Scenario: Water clarification Aid

Life Cycle Stage : Industrial uses: Uses of substances as such or in preparations at industrial
sites

Sector of use : SU2a Mining, (without offshore industries)

SU2b Offshore industries

SU4 Manufacture of food products

SU5 Manufacture of textiles, leather, fur

SU6a Manufacture of wood and wood products

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SU6b Manufacture of pulp, paper and paper products

SU8 Manufacture of bulk, large scale chemicals (including

petroleum products)

SU9 Manufacture of fine chemicals

SU11 Manufacture of rubber products

SU12 Manufacture of plastics products, including compounding and

conversion

SU13 Manufacture of other non-metallic mineral products, e.g.

plasters, cement

SU14 Manufacture of basic metals, including alloys

SU16 Manufacture of computer, electronic and optical products,

electrical equipment

SU17 General manufacturing, e.g. machinery, equipment, vehicles,

other transport equipment

SU23 Electricity, steam, gas water supply and sewage treatment

Contributing scenario controlling environmental exposure for:

Environmental release category : ERC6b Industrial use of reactive processing aids

Daily amount per site : 10000 kg

Type of Sewage Treatment : Standard STP

Plant

Contributing scenario controlling worker exposure for:

Process category : PROC8a Transfer of substance or preparation (charging/ discharging)

from/ to vessels/ large containers at non-dedicated facilities

Exposure duration : 15 min

Operational conditions and risk : Indoor

management measures

Local Exhaust Ventilation is not required

General ventilation Ventilation rate per hour: 1

Skin Protection : see section 8

Respiratory Protection : see section 8

Contributing scenario controlling worker exposure for:

Process category : PROC4 Use in batch and other process (synthesis) where opportunity
for exposure arises

Exposure duration : 60 min

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Operational conditions and risk : Indoor

management measures

Local Exhaust Ventilation is not required

General ventilation Ventilation rate per hour: 1

Skin Protection : see section 8

Respiratory Protection : see section 8

Contributing scenario controlling worker exposure for:

Process category : PROC15 Use as laboratory reagent

Exposure duration : 60 min

Operational conditions and risk : Indoor

management measures

Local Exhaust Ventilation is not required

General ventilation Ventilation rate per hour: 1

Skin Protection : see section 8

Respiratory Protection : see section 8

Contributing scenario controlling worker exposure for:

Process category : PROC28 Manual maintenance (cleaning and repair) of machinery

Exposure duration : 240 min

Operational conditions and risk : Indoor

management measures

Local Exhaust Ventilation is not required

General ventilation Ventilation rate per hour: 1

Skin Protection : see section 8

Respiratory Protection : see section 8

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