Halogen+Compound+ +PYQ+by+PC+Sir
Halogen+Compound+ +PYQ+by+PC+Sir
RA
is – [AIIMS-2005]
2. Reactivity order of halides for dehydro- (1) CH3CH2CH(OCH3)CH3
halogenation is - [AIPMT-2002] (2) CH3CH=CHCH3
(1) R–F > R–Cl > R–Br > R–I (3) CH3CH2CH=CH2
TO
(2) R–I > R–Br > R–Cl > R–F (4) CH3CH2CH2CH2OCH3
(3) R–I > R–Cl > R–Br > R–F 8. Which of the following undergoes
(4) R–F > R–I > R–Br > R–Cl nucleophilic substitution exclusively by
SN1 mechanism? [AIPMT-2005]
3.
MgBr
(i)CO
2
P, In the above reaction
IT (1) Ethyl choride
(2) Isopropyl chloride
CH
(ii)H3O (3) Benzyl chloride
product 'P' is [AIPMT-2002] (4) Chloro benzene
CHO COOH
9. Which of the following is least reactive
(1) (2)
in a nucleophilic substitution reaction?
P
OH O [AIPMT-2007]
EE
12. Which of the following reactions is an 16. Which of the following compounds
example of nucleophilic substitution undergoes nucleophilic substitution
reaction? [AIPMT-2009] reaction most easily?
(1) RX + Mg RMgX [AIPMT MAINS-2011]
(2) RX + KOH ROH + KX Cl
Cl
(3) 2RX + 2Na R – R + 2NaX (1) (2) NO 2
(4) RX + H2 RH + HX
Cl Cl
13. Trichloroacetaldehyde, CCl3CHO reacts
with chlorobenzene in presence of sulphuric (3) (4)
acid and produces - [AIPMT-2009]
RA
(1) Cl CH Cl CH3 OCH3
CCl3
Cl 17. Consider the reactions :
TO
(2) Cl C Cl [AIPMT MAINS-2011]
C2 H5OH
CH2Cl (i) (CH3)2CH–CH2Br
Cl (CH3)2CH–CH2OC2H5 + HBr
IT
C 2 H 5O
(ii) (CH3)2CH–CH2Br
(3) Cl C Cl (CH3)2CH–CH2OC2H5 + Br–
CH
H The mechanisms of reactions (i) and (ii)
OH
are respectively :
(4) Cl C Cl
(1) SN2 and SN1 (2) SN1 and SN2
Cl
14. In the following reaction (3) SN1 and SN1 (4) SN2 and SN2
P
1.Mg,Ether
C6H5CH2Br X,
2.H O
EE
3
18. Which of the following compounds will
Product 'X' is – [AIPMT Mains-2010]
(1) C6H5CH2OH give a yellow precipitate with iodine and
(2) C6H5CH3 alkali? [AIPMT Mains 2012]
D
ACHIEVER CAREER INSTITUTE, Reg. Office : 353, Rajeev Gandhi Nagar, Opp. City Mall Kota
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Halogen Compounds CHEMISTRY
RA
H OCH3
Cl
21. Correct order of reactivity towards
24. Product of following reaction is :
nucleophilic-substitution reaction of
TO
Br
following is : [AIIMS-2017] Zn dust
Br
[AIIMS-2017]
CH2–CH2–Cl CH2–Cl
(I) (II) (1) (2)
IT
Cl Cl (3) (4)
(III) (IV)
CH
25. Compound A, C8H10O, is found to react
OCH3 NO2 with NaOI (produced by reacting Y with
(1) II > I > IV > III (2) III > IV > I > II NaOH) and yields a yellow precipitate
(3) II > IV > I > II (4) IV > II > III > I with characteristic smell. A and Y are
P
respectively : [NEET-2018]
22. Which of the following react fastest with CH3
EE
(3) (4)
PR
Br
ACHIEVER CAREER INSTITUTE, Reg. Office : 353, Rajeev Gandhi Nagar, Opp. City Mall Kota
15
Mob.: 8955300365, 8955300394 ; Website: www.achieverkota.com ; E-mail: [email protected]
PR
A
D
EE
P
CH
IT
TO
RA