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Halogen+Compound+ +PYQ+by+PC+Sir

1. The document provides 19 multiple choice questions related to halogen compounds and their reactions. The questions cover topics like nucleophilic substitution reactions, reactivity of halogen compounds, mechanism of reactions involving halogen compounds. 2. Common reaction types discussed include SN1, SN2, elimination, addition and substitution reactions. Properties of halogen compounds that determine their reactivity such as effect of alkyl groups, presence of other functional groups are also assessed. 3. The questions are from various medical entrance exams in India and test the understanding of fundamental concepts and ability to compare reactivity of different halogen compounds.

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Suraj Singh
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0% found this document useful (0 votes)
74 views4 pages

Halogen+Compound+ +PYQ+by+PC+Sir

1. The document provides 19 multiple choice questions related to halogen compounds and their reactions. The questions cover topics like nucleophilic substitution reactions, reactivity of halogen compounds, mechanism of reactions involving halogen compounds. 2. Common reaction types discussed include SN1, SN2, elimination, addition and substitution reactions. Properties of halogen compounds that determine their reactivity such as effect of alkyl groups, presence of other functional groups are also assessed. 3. The questions are from various medical entrance exams in India and test the understanding of fundamental concepts and ability to compare reactivity of different halogen compounds.

Uploaded by

Suraj Singh
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Halogen Compounds CHEMISTRY

EXERCISE-II [Previous Exam Questions]


1. An organic compound A(C4H9Cl) on 6. Among the following, the one which
reaction with Na/diethyl ether gives a reacts most readily with ethanol is
hydrocarbon which on monochlorination [AIIMS-2004]
gives only one chloro derivative than, A (1) p-nitro benzyl bromide
is [AIPMT-2001] (2) p-chloro benzyl bromide
(1) t-butyl choride (3) p-methoxy benzyl bromide
(2) Sec. butyl chloride (4) p-methyl benzyl bromide
(3) Iso butyl chloride 7. The major product obtained on treatment
(4) n-butyl chloride of CH3CH2CH(F)CH3 with CH3O–/CH3OH

RA
is – [AIIMS-2005]
2. Reactivity order of halides for dehydro- (1) CH3CH2CH(OCH3)CH3
halogenation is - [AIPMT-2002] (2) CH3CH=CHCH3
(1) R–F > R–Cl > R–Br > R–I (3) CH3CH2CH=CH2

TO
(2) R–I > R–Br > R–Cl > R–F (4) CH3CH2CH2CH2OCH3
(3) R–I > R–Cl > R–Br > R–F 8. Which of the following undergoes
(4) R–F > R–I > R–Br > R–Cl nucleophilic substitution exclusively by
SN1 mechanism? [AIPMT-2005]

3.
MgBr
(i)CO

2
P, In the above reaction
IT (1) Ethyl choride
(2) Isopropyl chloride
CH

(ii)H3O (3) Benzyl chloride
product 'P' is [AIPMT-2002] (4) Chloro benzene
CHO COOH
9. Which of the following is least reactive
(1) (2)
in a nucleophilic substitution reaction?
P

OH O [AIPMT-2007]
EE

(1) CH2=CHCl (2) CH3CH2Cl


(3) (4) C6H5–C–C6H5 (3) CH2=CHCH2Cl (4) (CH3)3C–Cl

10. In a SN2 substitution reaction of the type


4. When CH3CH2CHCl2 is treated with
D

R–Br + Cl DMF 


 R–Cl + Br , which
NaNH2, the product formed is :
one of the following has the highest
[AIPMT-2002]
A

relative rate? [AIPMT-2008]


(1) CH3–CH=CH2
CH3 CH3
(2) CH3–CCH
PR

NH2 (1) CH3–CH–CH2Br (2) CH3–C–CH2Br


(3) CH3CH2CH
NH2 CH3
Cl (3) CH3–CH2Br (4) CH3-CH2-CH2Br
(4) CH3CH2CH
NH2
11. Which one of the following is most
reactive towards electrophilic attack ?
5. Among the following the most reactive
[AIPMT-2008]
towards alcoholic KOH is [AIIMS-2004]
(1) CH2=CHBr NO2 OH
(1) (2)
(2) CH3COCH2CH2Br
Cl CH2OH
(3) CH3CH2Br (3) (4)
(4) CH3CH2CH2Br
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CHEMISTRY Halogen Compounds

12. Which of the following reactions is an 16. Which of the following compounds
example of nucleophilic substitution undergoes nucleophilic substitution
reaction? [AIPMT-2009] reaction most easily?
(1) RX + Mg  RMgX [AIPMT MAINS-2011]
(2) RX + KOH  ROH + KX Cl
Cl
(3) 2RX + 2Na  R – R + 2NaX (1) (2) NO 2
(4) RX + H2  RH + HX
Cl Cl
13. Trichloroacetaldehyde, CCl3CHO reacts
with chlorobenzene in presence of sulphuric (3) (4)
acid and produces - [AIPMT-2009]

RA
(1) Cl CH Cl CH3 OCH3
CCl3
Cl 17. Consider the reactions :

TO
(2) Cl C Cl [AIPMT MAINS-2011]
C2 H5OH
CH2Cl (i) (CH3)2CH–CH2Br  
Cl (CH3)2CH–CH2OC2H5 + HBr

IT

C 2 H 5O
(ii) (CH3)2CH–CH2Br  
(3) Cl C Cl (CH3)2CH–CH2OC2H5 + Br–
CH
H The mechanisms of reactions (i) and (ii)
OH
are respectively :
(4) Cl C Cl
(1) SN2 and SN1 (2) SN1 and SN2
Cl
14. In the following reaction (3) SN1 and SN1 (4) SN2 and SN2
P

1.Mg,Ether
C6H5CH2Br  X,
2.H O
EE

3
18. Which of the following compounds will
Product 'X' is – [AIPMT Mains-2010]
(1) C6H5CH2OH give a yellow precipitate with iodine and
(2) C6H5CH3 alkali? [AIPMT Mains 2012]
D

(3) C6H5CH2CH2CH2C6H5 (1) Acetamide


(4) C6H5CH2OCH2C6H5 (2) 2-Hydroxypropane
A

15. Which one is a nucleophilic substitution (3) Acetophenone


(4) Methyl acetate
PR

reaction among the following?


[AIPMT-2011]
(1) CH3CHO + HCN  CH3CH(OH)CN 19. Arrange the following compounds in order
H2 O
(2) CH3–CH=CH2   CH3–CH–CH3 of their boiling point. [AIIMS-2016]
H
CH3
OH
(I) CH3–C–Br
(3) RCHO + RMgX  R–CH–R
CH3
OH (II) H3C–CH–CH 2–CH3
CH3 Br
NH3
(4) CH3–CH2–CH–CH 2Br  (III) CH3–CH2–CH2–CH2–Br
CH3 (1) I > II > III (2) III > II > I
CH3–CH2–CH–CH 2NH2 (3) II > I > III (4) III > I > II

ACHIEVER CAREER INSTITUTE, Reg. Office : 353, Rajeev Gandhi Nagar, Opp. City Mall Kota
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Halogen Compounds CHEMISTRY

CH3 Cl CH3ONa 23. Cl2 / h


 Product of reaction is
20. C   Product (Major)?
H C6 H 5
[AIIMS-2017]
[AIIMS-2017]
CH3 OCH3 C6H5 OCH3 Cl
CH2–CH3
(1) C (2) C (1) (2)
H C6 H 5 H CH3 Cl
CH3 C6H5
(3) C (4) C6H5–CH=CH2 (3) CH2–Cl
(4)

RA
H OCH3
Cl
21. Correct order of reactivity towards
24. Product of following reaction is :
nucleophilic-substitution reaction of

TO
Br
following is : [AIIMS-2017] Zn dust
Br  
[AIIMS-2017]
CH2–CH2–Cl CH2–Cl
(I) (II) (1) (2)

IT
Cl Cl (3) (4)
(III) (IV)
CH
25. Compound A, C8H10O, is found to react
OCH3 NO2 with NaOI (produced by reacting Y with
(1) II > I > IV > III (2) III > IV > I > II NaOH) and yields a yellow precipitate
(3) II > IV > I > II (4) IV > II > III > I with characteristic smell. A and Y are
P

respectively : [NEET-2018]
22. Which of the following react fastest with CH3
EE

(1) CH3 OH and I2


aqueous acetone? [AIIMS-2017]
(2) CH–CH3 and I2
(1) (2) OH
D

Br Br (3) CH2–CH3–OH and I2


Br (4) H3C CH2–OH and I2
A

(3) (4)
PR

Br

ACHIEVER CAREER INSTITUTE, Reg. Office : 353, Rajeev Gandhi Nagar, Opp. City Mall Kota
15
Mob.: 8955300365, 8955300394 ; Website: www.achieverkota.com ; E-mail: [email protected]
PR
A
D
EE
P
CH
IT
TO
RA

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