Vidyamandir Classes

READ THE FOLLOWING INSTRUCTIONS VERY CAREFULLY BEFORE YOU PROCEED

1. The question paper consists of 3 subjects : (Subject I : Chemistry, Subject II : Physics,
Subject III : Mathematics). Each Subject consists of one section only.
2. Section I contains 3 types of questions [Type 1, 2 & 3]
Type 1 contains 6 Single Correct Answer Type Questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE CHOICE is correct.
 Marking scheme [3 Marks for Correct answer & –1 NEGATIVE MARKING for wrong answer]
Type 2 contains 8 Multiple Correct Answer Type Questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE CHOICES may be correct.
 Marking scheme [4 Marks for All Correct answers, +1 for Partially correct answer and
–2 NEGATIVE MARKING for wrong answer]
Type 3 contains TWO paragraphs. Based on each paragraph, there are TWO questions. Each question
has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
 Marking scheme [3 Marks for Correct answer & NO NEGATIVE MARKING for wrong answer]
4. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your
Test Code, Roll No. and Group Properly in the space given in the ANSWER SHEET.
5. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
phone, any electronic device, etc., except the Admit Card inside the examination hall/room.
6. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in
the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
7. No one will be permitted to leave the test room before the end of the test, i.e. 05.00 PM.

VMC | JEE-2018 | Paper-2 1 XIITHPASS JEE ADV-1 |Code : ACEG

 Vidyamandir Classes

SUBJECT - I (CHEMISTRY) 62 MARKS

SECTION - I [TYPE-1]
SINGLE CORRECT ANSWERS TYPE
This section contains 6 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct:

1. 0.10 g of a sample containing CuCO3 and some inert impurity was dissolved in dilute sulphuric acid
and volume made up to 50 mL. This solution was added into 50 mL of 0.04 M KI solution where
copper precipitates as CuI and I  is oxidized into I3 as per the following balanced equation.
2Cu 2  5I  
 2CuI  I3

A 10 mL portion of this solution is taken for analysis, filtered and I3 ions are removed and then
treated with excess of acidic permanganate solution. Liberated iodine required 20 mL of
2.5  103 M sodium thiosulphate solution to reach the end point. Determine weight percentage of
CuCO3 in the original sample. (Given : Molar mass of CuCO3 is 123.5 g/mole)
(A) 7.41 (B) 74.1 (C) 45.75 (D) 21.25

2. P is the probability of finding the electron of hydrogen atom in a spherical shell of infinitesimal
thickness dr, at a distance r from the nucleus. The volume of this shell is 4 r 2 dr . The qualitative
sketch of the dependence of P on r for 6d xy will be :

(A) (B) (C) (D)

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3. What is the bond enthalpy of Xe – F bond?

XeF4  g  
 Xe   g   F  g   F2  g   F  g  ;  r H  292 kcal / mol
Given : Ionization energy of Xe = 279 kcal/mol
B.E. (F – F) = 38 kcal/mol, Electron Affinity of F = 85 kcal/mol
(A) 24 kcal/mol (B) 34 kcal/mol (C) 8.5 kcal/mol (D) None of these

4.

Which of the following is correct structural formula of organic compound 'X' ?

(A) (B)

(C) (D)

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5. In silica Si  O bond enthalpy is very high so it resist the attack by halogens and most of the acids and
metal but it reacts with NaOH to give :
(A) Si  OH 4 (B) Na 2SiO3 (C) Na 2SiO 2 (D) SiH 4

6. The product 'Z' in given sequence of reaction is :

(A) (B) (C) (D)

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SECTION - I [TYPE-2]
MULTIPLE CORRECT ANSWERS TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:
+
7. A sample of He ion is irradiated with photon of energy 51 eV, when the electron get excited to some
higher energy level. Which is true about this sample?
(A) The separation energy from this higher energy level is 3.4 eV
(B) The electron when de-excited from this higher energy level will emit photon of six different
wavelengths
(C) The ionization energy of He+ ion would be 54.4 eV
(D) The number of lines of Balmer series obtained in the spectrum of He+ ion is 3

8. Which of the following species has 2 different (central atom-surrounding atom) bond lengths?
(A) SF4 (B) I3 (C) SF6 (D) ClF3

9. 1 gram of a sample of CaCO3 was strongly heated and the CO2 liberated was absorbed in 100 mL of
0.5 M NaOH. Assuming 90% purity for the sample of CaCO3, how much volume of 0.5 M HCl would
be required to react with the solution to reach the phenolphthalein end point?
(A) 0.041L (B) 41 mL (C) 82 mL (D) 0.082L

10. Which of the following compound/species is an aromatic species?

(A) (B) N–H

(C) (D)

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11. Which of the following represents a correct thermochemical equation for enthalpy of formation of
indicated molecule?
(A) CO2 (g) : C(graphite,s)  O2 (g)  CO2 (g)
1
(B) SO3 (g) : SO 2 (g)  O 2 (g)  SO3 (g)
2
1
(C) CH3SH(l ) : C(graphite,s)  S8 (rhombic,s)  2H 2 (l )  CH3SH(l )
8
(D) CH3CO2 H(l ) : 2C(graphite,s)  O2 (g)  2H2 (g)  CH3CO2 H(l )

12. Which of the following species are isostructural but not isoelectronic to N3 ?
(A) NCO (B) ClO (C) I3 (D) CNO

13. Which of the following statements is(are) correct?

(A) All real gases are less compressible than an ideal gas at high pressure
(B) Hydrogen and helium are more compressible than an ideal gas for all values of pressure
 PV 
(C) Except H2 and He, the compressibility factor Z     1 for all gases at low pressure
 nRT 
(D) The compressibility factor of real gases is independent of temperature
(P1V1T1)
14. Which of the following statement is false about process I and II ?
(A) I is isothermal expansion, II is adiabatic expansion I
P (P2V2T1)
II
(B) P2 is always more than P3 (P3V2T2)

(C) T1 is always less than T2 V

(D) Work done in isothermal process is always more than work done in adiabatic process
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SECTION - I [TYPE-3]
COMPREHENSION TYPE
This section contains 2 paragraphs, each describing theory, experiments, data etc. 4 questions related to
the two paragraphs with two questions on each paragraph. Each question has Only One option is correct
among the four given options (A), (B), (C) and (D).

Paragraph for Questions 15 - 16

If the boundary of system moves by an infinitesimal amount, the work involved is given by dw   Pext dV
For irreversible process w  Pext V (where V  Vf  Vi )
For reversible process Pext  P int  dP  Pint
V
So for reversible isothermal process w   nRT  n f
Vi
2 mole of an ideal gas undergoes isothermal compression along three different paths:
(i) reversible compression from Pi  2 bar and Vi  8 L to Pf  20 bar
(ii) a single stage compression against a constant external pressure of 20 bar, to same final volume as in
process (i).
(iii) a two stage compression consisting initially of compression against a constant external pressure of
10 bar until Pgas  Pext , followed by compression against a constant pressure of 20 bar until
Pgas  Pext

15. Work done in path (ii) and (iii) are respectively in L-bar :
(A) +144 and +80 (B) –144 and –80 (C) –36.84 and –80 (D) +36.84 and +80

16. Choose the correct option :

I. Entropy change of universe for path (i) is zero
II. Entropy change of universe for path (ii) is greater than zero but for path (iii) is equal to zero
III. Entropy change of universe for path (iii) is greater than zero
IV. Entropy change for path (ii) and (iii) is greater than zero
The correct choice is :
(A) I, II (B) II, III (C) Only I (D) I, IV
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Paragraph for Questions 17 - 18

Compound having same molecular formula but different structural formula are called as isomers. Structural
isomers has same molecular formula but different structural formula. While stereoisomers has same
connectivity of atoms but different spatial arrangement of atoms or group of atoms in space. Resonating
structure are different from isomeric structures. Consider the structures (W), (X), (Y) and (Z).

17. The incorrect statement is :

(A) (W) and (Y) are resonance structure (B) (W) and (Y) are positional isomers
(C) (X) and (Y) are tautomers (D) (Y) and (Z) are diastereomers

18. Which of the following is incorrect for (X) ?

(A) It shows stereoisomerism
(B) 3-Hexanone is its positional isomer
(C) 2, 2-dimethyl butanal is its functional isomer
(D) One of the conformers of (X) is

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SUBJECT - II (PHYSICS) 62 MARKS

SECTION - I [TYPE-1]
SINGLE CORRECT ANSWERS TYPE
This section contains 6 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct:

1. Figure shows a crude type of atomizer. When the bulb A is compressed,

air flows swiftly through the tube BC causing a reduced pressure in the
portion of vertical tube. Liquid rises in the tube, enters BC and is sprayed
out. If the gauge pressure in the bulb is P and Pa is the atmospheric
pressure, v is the speed of air in BC, find how large would v need to be to
cause liquid to rise to BC. Density of air  1.3 kg / m3 .
P   gh Ph g P h g P
(A) (B) (C) (D)
0.65 0.65 0.65 h g 0.65
2. A light uniform metal wire is used in a simple pendulum. If the room temperature rises by 10°C,
and the coefficient of linear expansion of the metal of the wire is 2  106 per °C, the period of the
pendulum will have percentage increase of :
(A) 2  103 (B) 1  103 (C) 2  103 (D) 1  103

3. In the figure shown, the two projectiles are fired

simultaneously. The minimum distance between
them during their flight is :
(A) 2m (B) 10 3 m
(C) 10m (D) None of these
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4. Two cylinders A and B fitted with pistons contain equal amounts of an ideal diatomic gas at 300 K.
The piston of A is free to move, while that of B is held fixed. The same amount of heat is given to the
gas in each cylinder. If the rise in temperature of the gas in A is 30 K, then the rise in temperature of
the gas in B is :
(A) 30 K (B) 18 K (C) 50 K (D) 42 K

5. A kettle with 2 L of water at 27°C is heated by a coil heater of power 1 kW. The heat is lost to the
atmosphere at constant rate of 160J/sec, when its lid is open. In how much time will the water be
heated to 77°C with the lid open? (Specific heat of water is 4.2 kJ/kg)
(A) 8 min 20 sec (B) 6 min 2 sec (C) 14 min (D) 7 min

6. Water from a tap emerges vertically downwards with an initial velocity V0. Assume pressure is
constant throughout the stream of water and the flow is steady, find the distance from the tap at which
cross-sectional area of stream is half of the cross-sectional area of stream at the tap :
(A) V02 / 2 g (B) 3V02 / 2 g (C) 2V02 / g (D) 5V02 / 2 g

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SECTION - I [TYPE-2]
MULTIPLE CORRECT ANSWERS TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:

7. A car of mass M is moving on a horizontal circular path of radius R. At an instant its speed is V and is
increasing at constant rate  . At this instant :
(A) The net acceleration of car is towards centre of its path
MV 2
(B) The magnitude of the frictional force on car is greater than
R

(C) The friction coefficient between the ground and car is not less than
g
2
V
(D) The friction coefficient between the ground and car is   tan 1
Rg

8. A solid sphere A is rolling without slipping on a rough surface with angular speed ω as shown in
figure. It collides elastically with another identical sphere B at rest. Assume no friction acts between
the spheres during collision. Then : [Radius of sphere is R]
(A) After collision A and B move in opposite directions.
(B) After collision A and B move in same direction.
(C) After collision A stops permanently and only B moves.
5
(D) Velocity of centre of B after it starts pure rolling on the surface is ωR
7
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9. In the diagram shown, all three balls are identical. One of the three balls
falls vertically downwards with a velocity v as shown. It rebounds
v
vertically with a velocity .
2
Friction is absent and the other two balls move only in the horizontal direction after collision.
Given the collision takes place symmetrically, then :
3
(A) Net impulse that acts on the ball A during collision is mv
2
3
(B) Net impulse that acts on the ball B during collision is mv
4
3
(C) Net impulse that acts on ball B because of ball A during collision is mv
2
3
(D) Net impulse from the ground on ball B during collision is mv
4
10. An ideal gas has a molar heat capacity Cv at constant volume. The gas undergoes a process in which
T  To e V , where T and V are temperature and volume of the gas respectively and T0 and  are
constants. Then : (P is the pressure of gas and R is gas constant)
R PdV
(A) Molar heat capacity of the gas, C, can be written as C  Cv 
PdV  VdP
(B) PdV  VdP  nRT0  eV dV , for the ideal gas in this process
R R
(C) C  Cv  (D) C  Cv 
V 1 V

11. A plank is resting on a frictionless floor. A solid sphere is resting on the

plank. There is friction between the plank and the floor such that the sphere
always rolls without slipping on the plank. We start applying a constant
force F on the plank towards right.
(A) Acceleration of sphere is less than that of plank
(B) Both have same acceleration
(C) Work done by friction acting on the sphere is equal to its total kinetic energy
(D) Total kinetic energy of the system is equal to work done by F
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12. The coordinates of a particle moving in a plane are given by x(t) = a cos (pt) and y(t) = b sin (pt),
where a, b (< a), and p are positive constants of appropriate dimensions. Then :
(A) The path of the particle is an ellipse
(B) The velocity and acceleration of the particle are normal to each other at t   / 2 p
(C) The acceleration of the particle is always directed towards a focus
(D) The distance traveled by the particle in time interval t = 0 to t   / 2 p is a

13. A body totally immersed in water is raised slowly in the water by a height h. The density of the body
is d, the density of water is d0 (where d  d0 ) and the volume of the body is V. Then :
(A) The net work done in raising the body is Vdgh
(B) The work done by external agent in raising the body is Vgh  d  d 0 
(C) The gravitational potential energy of water is not changed by raising the body
(D) The work done on the body by the gravitational force is equal and opposite to the work done
by the hydrostatic force so that net work done is zero

14. A spring balance reads w1 with a block suspended from it. If the block is
submerged in a liquid whose density is less than density of block, the
spring balance reads w2. The experiment is repeated twice, once on
surface of earth and another time on surface of moon. If acceleration due
to gravity on surface of moon is one-sixth of that on surface of earth,
then:
(A) w1 is same on earth and moon (B) w2 is same on earth and moon
w1
(C) (w1 – w2) is same on earth and moon (D) is same on earth and moon
w2

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SECTION - I [TYPE-3]
COMPREHENSION TYPE
This section contains 2 paragraphs, each describing theory, experiments, data etc. 4 questions related to
the two paragraphs with two questions on each paragraph. Each question has Only One option is correct
among the four given options (A), (B), (C) and (D).

Paragraph for Questions 15 - 16

A smooth uniform disc of mass m and radius R is connected with a very
heavy cart C  by an inextensible string. Initially the string is loose and
the cart is moving with a velocity v0.
15. The linear impulse exerted on the disc when string becomes taut will be:
mv0 2mv0 mv0
(A) mv0 (B) (C) (D)
3 3 2
16. Velocity of the centre of disc after impulse will be :
2v0 v0 v0
(A) v0 (B) (C) (D)
3 2 3
Paragraph for Questions 17 - 18
Two uniform solid spherical balls of radius r and 2r and of same density
 are welded together and released in a very long viscous liquid column
of lesser density  and viscosity  .

17. What is the initial acceleration of the spheres?

      
(A) g (B)  1  g (C) 1   g (D)   1 g
      
18. What is the terminal velocity acquired by the spheres?
2 (   ) gr 2 2 (   ) gr 2 4 (   ) gr 2 4 (   ) gr 2
(A) (B) (C) (D)
3  9  3  9 
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SUBJECT - III (MATHEMATICS) 62 MARKS

SECTION - I [TYPE-1]
SINGLE CORRECT ANSWERS TYPE
This section contains 6 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct:

1. S1 : A student is allowed to select at most n books from a collection of (2n + 1) books. If the total
number of ways in which he can select at least one book is 63, the value of ‘n’ is 4
S2 : Number of ways to arrange letters of the word ‘CINEMA’ so that order of vowels do not
change is 120
S3 : The number of ways one can put three balls numbered 1, 2, 3 in three boxes labeled a, b, c
such that at the most one box is empty is equal to 24
S4 : A box contains 5 different red balls and 6 different white balls. The number of ways in which
4 balls can be selected taking at least 1 ball of each color is 310
(A) TTFF (B) FTTT (C) FTFT (D) TTTT

2. The perpendicular distance from (7, 0) to common tangent(s) to parabola y 2  4 x and circle
9
x2  y2  is :
4
(A) 6 (B) 5 (C) 4 (D) 3
 n n
3. If f  2m  , 2m    mn, then f  x, y   f  y, x   0 (m, n, x, y  R ) :
 8 8
(A) Only when x = y (B) Only when x  y
(C) Only when x   y (D) For all x and y

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4. Let ABC be a triangle, let A be the point (1, 2), y = x is the perpendicular bisector of AB and
x  2 y  1  0 is the angle bisector of C. If equation of BC is given by ax  by  5  0 then the value
of a + b is :
(A) 1 (B) 2 (C) 3 (D) 4

1
5. If az 2  bz  1  0 ; where a, b, z  C; a  ; and have a root  such that   1 , then ab  b 
2
1 1 5 3
(A) (B) (C) (D)
4 2 4 4

6. The number of possible straight lines, passing through (2, 3) and forming with co-ordinate axes a
triangle whose area is 12 sq. unit, is :
(A) 1 (B) 2 (C) 3 (D) 4
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SECTION - I [TYPE-2]
MULTIPLE CORRECT ANSWERS TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:
7. Consider the circle x 2  y 2  8 x  18 y  93  0 with centre C and point P(2, 5) outside it. From the
point P, tangents PQ and PR are drawn to the circle with S as the mid-point of QR. The line joining P
to C intersects the given circle at A and B. Which of the following hold(s) good ?
(A) CP is the arithmetic mean of AP and BP
(B) PR is geometric mean of PS and PC
(C) PS is the harmonic mean of PA and PB
4
(D) The angle between the two tangents from P is tan 1  
3
8. Consider two circles S1  x 2  y 2  8 x  0 and S 2  x 2  y 2  2 x  0 . Let PQR be formed by the
common tangents to circles S1 and S2. Then which of the following hold(s) good ?
(A) Incentre of PQR is (1, 0)
(B) The equation of radical axis of circles S1 and S2 is y = 0
16
(C) Product of slope of direct common tangents is
9
(D) If transverse common tangent intersects direct common tangents at points A and B, then AB
equals 4

9. Given a, b, c (taken in order) are in A.P ; b, c, d (taken in order) are in G.P and c, d, k (are taken in
order) are in H.P. If a = 2 and k = 18, then the possible values of c can be :
(A) 6 (B) 6 (C) 9 (D) 9

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10. Let 1 be the length of the latus rectum of the parabola 9 x 2  6 x  36 y  19  0 . Let  2 be the
length of the latus rectum of the hyperbola 9 x 2  16 y 2  18 x  32 y  151  0 . Let n be the unit digit

in the product of 1 and  2 . The number of terms in the binomial expansion of 1  x  is :

n

(A) multiple of 3 (B) an odd number (C) multiple of 5 (D) an even number

 ac  ab  bc  ab  bc  ac 
11. If a, b and c are in H.P., then the value of is :
 abc 2
 a  c  3a  c  2 1
(A) 2 2
(B) 
4a c bc b 2
2 1  a  c  3a  c 
(C)  (D)
bc a2 4a 2 c 2
12. Let A, B, C be three sets of complex numbers as defined below :

A  z :| z |  2 3 ;    
B  z :  lm  z    4 Re  z  and C  z : | arg z |  tan 1 2
2

Then set A  B  C contains the complex number(s) :
(A) 2i 2 (B) 2 i2 2 (C) 2 i2 2 (D) 0  i0

13. If | x 2  3x  2 |  | x 2  5 x  6 |  | 2 x  4 |, then x may take all the values of the set :

(A) [1, 3] (B) [3, 5] (C) [5, 10] (D) 3, 6  2
14.  
The number of solutions of the equation 2|kx|  log e | x |  1 is two. Then value of k may be :
(A) 2 (B) 3 (C) 4 (D) 5
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SECTION - I [TYPE-3]
COMPREHENSION TYPE
This section contains 2 paragraphs, each describing theory, experiments, data etc. 4 questions related to
the two paragraphs with two questions on each paragraph. Each question has Only One option is correct
among the four given options (A), (B), (C) and (D).

Paragraph for Questions 15 - 16

In the diagram as shown, a circle is drawn with centre C(1, 1) and
radius 1 and a line L. The line L is tangent to the circle at Q. Further
L meets the y-axis at R and the x-axis at P in such a way that the

angle OPQ equals  where 0    .
2
15. Equation of the line PR is :
(A) x cos   y sin  sin  cos   1 (B) x sin  y cos   cos   sin  1
 
(C) x sin  y cos   cos   sin  1 (D) xtan  y  1  cot  
2

16. Area of triangle OPR when   is :
4
(A) 3  2 2  
(B) 3  2 2 
(C) 6  4 2  (D) None of these

SPACE FOR ROUGH WORK

VMC | JEE-2018 | Paper-2 19 XIITHPASS JEE ADV-1 |Code : ACEG

 Vidyamandir Classes

Paragraph for Questions 17 - 18

1/ 3
Let f be a real valued function with domain R satisfying f  x  3  1  1  3 f  x   3  f  x    f  x  
2 3
 
for all x  R. Then :
17. The period of f (x) is :
(A) 6 (B) 3 (C) 2 (D) 9

18. The value of f  3  f  9   f 15   f  21  f  27   f  33  f  39   f  45   f  51  f  57  equals:

(A) 0 (B) f  3 (C) 5 f  3 (D) 3 f  3

SPACE FOR ROUGH WORK

VMC | JEE-2018 | Paper-2 20 XIITHPASS JEE ADV-1 |Code : ACEG

 Vidyamandir Classes

SPACE FOR ROUGH WORK

VMC | JEE-2018 | Paper-2 21 XIITHPASS JEE ADV-1 |Code : ACEG

 Vidyamandir Classes

SPACE FOR ROUGH WORK

   End of JEE Advanced-1 | PAPER-2 | JEE-2018   

VMC | JEE-2018 | Paper-2 22 XIITHPASS JEE ADV-1 |Code : ACEG