Tschem PDF
Tschem PDF
t,
‘and for a given temperature (1), as V is more, pis
less, ie. as Vis more, p, will be smaller, Le.
Pi >Pa
Hence, option (b) is the correct answer.
7. A gas is present at a pressure of 2 atm. What
should be the increase in pressure, so that
the volume of the gas can be decreased to th
of the initial volume at constant
temperature? [10Sep. 2020, shift-tt]
(a)05atm (o)2atm (c)4aim —(d) Batm
Sol. (d)
Given, initial pressure = 2atm
Final volume = 4 th of initial volume (¥)
Let, initial volume = ¥
v
then, final volume = ~ (at constant temperature)
4
+s Final pressure = p; (to find)
Via =YaP228 Ss EAMCET Chapterwise Chemisty
s py MBL Yaa = tm Sol. (6) wv,
a ve “ mRT
Hence, increase in pressure ({.¢. final pressure)
= 8am
compressibility factor, p = pressure
jolume, = number of moles
{as constant, T = temperature,
8. Which among the following graphs, correctly
represents the Boyle’s Law? [11 Sep. 2020, Shift-l]
1 t Also, curves for (Z ¥5 P)
{t———— 1) If Z >1 the gas show positive deviation from
a ee dy cal behaviour and is lebe compressiie
(ii) 1f Z <1, gas show negative deviation
v— vo (iii) No, real gas give a straight line parallel to (ph
t ° t Hence, option (b) is the correct answer, icc, path
id (3) only.
ae @ep way (2) and (3) wee
10. The volume of a given amount of gas at 27°
at constant pressure is 420 cm’. If the
Tw v= temperature is reduced by 20°C at constant
ea, pressure, what will be the volume of the gas?
© [14Sep. 2020, shy
Iris a gas law, which states that the pressure (@) 350 cm? (b) 392 cm?
exerted by a gas of given mass of constant (©) 450. cm? (@) 480 om?
‘temperature is inversely proportional to the volume.
7 Sol. (6)
pay or pak According to Charles’ law,
{Pressure multiplied by volume equals constant k] Yon
‘We plot a graph between p and V constant Ve. Zhe
temperature is illustrated below, [Constant : Amount of gas and pressure]
> y= Bxy,
1 q
e be ¥ = 420em?, 7, = (2734 279 = 3008
Ty = [273+ (27 20)] = 2808)
v= = 280420 569 oy?
| 300 em
9. Which of the curve (Z vs p) will be followed 4 yy, 7 w
byatveal paar tsiSep.2020 sunt 7% THE compressibility factor z =P for
4 hydrogen gas a 273 K and 1 atm pressures
[14 Sep. 2020.
2 (@) ze10 a oe
A; 0 1 (©) greater than one —_(d) between zero anda”?
Sol. (c)
AUNTE condition (p
: = atm, T= 273K)
°8 For Umole (n=) of Hy(g), v= 23-4 Lol"
4 So pa PY x24
Pp mRT 1x 0082x273 1
(@) Pathway 3 only (0) Pathways 2 and 3 only te R=0.082 Latm mot ®!
(©) Pathways 1 and 2 only (d) Pathway 2 only = 1.000625
Z>1Gaseous and Liquid States
42, What is the ratio of kinetic energy of 7 grams
of nitrogen and 4 grams of oxygen at T(k)?
[14 Sep. 2020, shit-I]
(ts2 (B21 Ast art
Sol. (b)
The expression of average kinetic energy of a gas
molecule is,
3
KE = 5 x nkT
2
When, temperature (7 in K) is constant,
KE «en (mole)
OB, _ Py 7/2818 9
Wo, %, 4732 4-1
13, Equal amount of gases are kept in two
separate containers. If densities of the two
{gases are in 1 : 2 ratio and their temperatures
are in 2:1 ratio, calculate the ratio of their
respective pressures. [14Sep. 2020, Shift]
@it (by 1:2
2: (4st
Sol. (a) i
Fora gas, density (d) = 7
For equal amount of the same gas, d es
a Bohn,
Ahm 4 Ti
It should be mentioned in the question to match
with option (answer).
14, Given the ratio of amounts of nitrogen and
‘oxygen in a particular gaseous mixture is 4:1.
Calculate the ratio of number of their
molecules? [14 Sep. 2020, shift-tI]
(ay4:4 (b) 32:7
(4:15 (6) 13:8
Sol. (b)
Number of molecules (N) = Number of mole
(n) x Avogadro number (V4)
Mass of gas (W)_
‘Molar mass (M)*
> New®
M
so, Nita a Mita Moy. Mita y Mor
No, Mn, Wo, No, Mwy
432
=4 2 -32:7
1*287>
29
15. What is the approximate most probable
velocity of oxygen? If the kinetic energy of
one mole of oxygen is 3741.3 J.
[3 May 2019, Shift-]
(b) JA882% J kg"
(0) J3950 J kg”
(@) Va385% J kg!
(0) ¥155887 J kg!
Sol. (c)
“+ Kinetic energy (KE) =
where,
aT
= gas constant, T = temperature
2,
= (KE) i
me) (i)
“Most probable velocity (MP) = = i)
where, M = molecular mass of oxygen = 32
Given=> KE = 374135
‘Substituting the value of RT from Eq, (i), we
have,
= 55881000 = IS5BE7 J kg"
Hence, option (c) is the correct answer.
16. ‘The variation of compressibility factor (Z)
with pressure (p in bar) for some gases are
shown in the figure below. Identify the gases
(A), (B) and (C) respectively [3May 2019, Shift-I!]
18)
c)
Oy
N
(b) ideal gas, Hp,CO,
{@) real gas, No, CO,
{(¢) real gas, Hy, CO,
(0) ideal gas, CO,, Hy
Sol. (6)
‘The extent of deviation shawn by real gases from
ideal behaviour is measured in terms of
compressibility factor (Z) which is defined as the
ratio of pV and nT.
Mathematically,30
For ideal gases, Z =1
Easily liquefiable gases such as CO, exhibit
larger deviation as compared to gases such as
H,,0,,Nj etc, that liquefy with difficulty.
(On,
(reo,
Zz “A (Wdeal gas)
P
17. Diffusion of CH,(g) and O(g) occurs under
similar conditions, then the ratio of their
rates of diffusion is [3May 2019, shift}
(2) 1.414 ()0.707 (ce) 2.912 (A) 1.732
Sol. (a)
From Graham's law of diffusion:
eg Mai
fon V Men,
here, rey, =rate of diffusion of CH, gas
ate of diffusion of O, gas
‘molecular mass of CH, =16
molecular mass of O, gas = 32
Bz
7? = fam4i4
7g 72014
18. The nitrogen gas pressure inside a container
of volume 2.6 cm? is 2.3 atm at 27°C. The
approximate number of moles of nitrogen
present in the container is
[8 =00821L atm mol”! K™] (4 may 2019, Shitt-I]
(a) 4x10% (b) 17 x10
()4«104 (2 x10%
Sol. (d)
Given,
Pressure of Ny gas = 23atm
Volume = 26 cm’ = 2.6 107 L
Temperature = 27% + 273=300K
Gas constant (R) = 0.0821 L atm mol”! K~
From, ideal gas equation
TS EAMCET Chapterise Cheri,
pe 23at #26 10
* 00821 L atm mol 7K 300K
n= 2x10 mol
19, Which of the following statements is not
correct regarding kinetic theory of gases?
(4May 2019, she
(2) Gases are considered as point masses
(b) Kinetic energy ¢' gas molecules increases ym
temperature
(6) Total energy of molecules belore and ater te
collisions is diferent
(6) The distribution of molecular speed of a gis
remains constant at a particular temperature
Sol. (c)
The explanation of given statements areas
follows:
(a) Gas particles are considered as point masses
or rigid particles
(b) Kinetic energy of gas molecules are directly
proportional to absolute temperature.
ss KE.aT
‘Therefore, K.E. increase with increasing
temperature,
(©) Rigid elastic gas particles show collisions and
follow energy conservation rule. Therefore,
energy of molecules before and after the
collisions are equal.
(d) The distribution of molecular speed of gas
remain constant at particular temperature.
Hence, option (c) is incorrect.
20. The van der Waals’ equation for 0.5 mol of
gas is
most)
)
(p+ 35 )ev- maar
)
)
[4 May 2029, hit
Sol. (b)
Where, a = correction in pressure
m= number of molesGaseous and Liquid States
n=a5mol
07-080) as
Pp
Thus, option (b) is correct
(re ge)ar- err
21. Which one of the following represents Boyle's
temperature of a gas? [May 2019, Shift]
(@ The temperature at which an ideal gas obeys
Boyle's law,
(b) The temperature at which the compressibilty
factor is less than 1 for a real gas.
{c) The temperature at which a gas obeys ideal gas
law over an appreciable range of pressure.
(©) The temperature at which the compressibility
factor deviates from 1 for an ideal gas.
Sol. (c)
The Boyle’s temperature is defined as the
temperature at which a real gas obeys ideal gas
laws over an appreciable range of pressure.
22, Which one of the following given highest
volume of 0, at STP on complete
decomposition? [4May 2019, shit-]
(2) 2mLof 100VH,0, (b) 500mLof 30VH,0,
()1Loft0VH,O, ~ (d) 100ml of 20VH,0,
Sol. (b)
2Hp,
= p+ O49
2val ot 685) Vt
122400" mi at
By definition of volume strength
(2) 100 vol H,0, means
1 mL of 10, = 100 mLofo,atSTP
-2mL of HO; = 2*100= 200ml of 0;
(b) 30 vol of H,0; means
I mL of #9, = 30ml. of 0, at STP.
+500 mL of HO, = 30 «500 =15,000 mL. of
E
(€) 10 vol of ,0, means
1 mL of HD, = 10 mL of O, at STP.
+1000 mL (1L) of H,0, =10x10000f 0,
=10,000mt of 0,
(4) 20,v0l of H,0, means
I mL of #0, = 20mL of, at STP.
£100 mL of 0, = 20100 = 2000 mL of 0}.
Hence, 500 mL. of 3010, gives highest
volume of O, at STP on complete
decomposition.
31
23. Which of the following is/are correct for
Boyle's law? [6 May 2019, Shift-1]
Tht Ty