Safety Data Sheet: Corrosion Inhibitor A261
Safety Data Sheet: Corrosion Inhibitor A261
A261
Version 9
Revision date 11/Mar/2018
Supersedes date 25/May/2017
1.2 Relevant identified uses of the substance or mixture and uses advised against
Supplier
Schlumberger Technology Corporation
110 Schlumberger Drive
Sugar Land, Texas 77478, USA
Telephone: 1-281-285-7873
Prepared by
Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Thai Hien Nguyen
Emergency telephone (24 Hour) Asia Pacific +65 3158 1074, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0)
1235 239 671, USA +1 281 595 3518/+1 866 928 0789 , Canada +1 800 579 7421 , Argentina: +54 11 5984 3690, Brazil :
0800-720-8000 /0800-777-2323 (WGRA)
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS - Classification
Health hazards
Acute toxicity - Oral Category 4
Acute toxicity - Dermal Category 4
_____________________________________________________________________________________________
Page 1 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
Environmental hazards
Acute aquatic toxicity Category 1
Chronic aquatic toxicity Category 1
Physical Hazards
Flammable Liquids Category 3
Signal word
DANGER
Hazard Statements
H302 - Harmful if swallowed
H312 - Harmful in contact with skin
H332 - Harmful if inhaled
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H341 - Suspected of causing genetic defects
H350 - May cause cancer
H371 - May cause damage to organs
H410 - Very toxic to aquatic life with long lasting effects
H226 - Flammable liquid and vapor
Precautionary Statements
P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P240 - Ground/bond container and receiving equipment
P241 - Use explosion-proof electrical/ ventilating/ lighting/ equipment
P242 - Use only non-sparking tools
P243 - Take precautionary measures against static discharge
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
_____________________________________________________________________________________________
Page 2 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P312 - Call a POISON CENTER or doctor/physician if you feel unwell
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention
P362 + P364 - Take off contaminated clothing and wash it before reuse
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Comments
The product contains other ingredients which do not contribute to the overall classification. The specific chemical identity and/or
exact percentage (concentration) of composition has been withheld as a trade secret
Inhalation Move the exposed person to fresh air at once. If breathing is difficult, (trained personnel
should) give oxygen. If not breathing, give artificial respiration. Get medical attention if any
discomfort continues.
Ingestion Do NOT induce vomiting. Get immediate medical attention. Rinse mouth. Risk of product
entering the lungs on vomiting after ingestion. Never give anything by mouth to an
unconscious person.
_____________________________________________________________________________________________
Page 3 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
Skin contact Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove
clothing if soaked through and wash as above. Burns: Flush with water immediately. While
flushing, remove clothes which do not adhere to affected area. Call an ambulance.
Continue flushing during transport to hospital. Chemical burns must be treated by a
physician.
Eye Contact Rinse immediately with plenty of water, also under the eyelids. Hold eye open and rinse
slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the
first five minutes, then continue rinsing eye. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General advice Seek medical attention for all burns, regardless how minor they may seem. The severity of
the symptoms described will vary dependant of the concentration and the length of
exposure. If adverse symptoms develop, the casualty should be transferred to hospital as
soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
5. Fire-Fighting Measures
_____________________________________________________________________________________________
Page 4 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
Remove all sources of ignition. Keep away from heat, sparks, and flame. Avoid contact with skin, eyes and inhalation of vapors.
Wash thoroughly after handling. Use personal protective equipment. See also section 8.
The product should not be allowed to enter drains, water courses or the soil.
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid spills and
splashing during use. Do not breathe vapors or spray mist. Keep away from open flames, hot surfaces and sources of ignition.
Hygiene measures
Use good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product. Wash
hands and face before breaks and immediately after handling the product.
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Take
precautionary measures against static discharges. Use spark-proof tools and
explosion-proof equipment. Ensure all equipment is electrically grounded before beginning
transfer operations.
Storage precautions Keep container/package tightly closed and in a well-ventilated place. Keep away from open
flames, hot surfaces and sources of ignition. Keep away from direct sunlight. Follow safe
warehousing practices regarding palletizing, banding, shrink-wrapping and/or stacking.
_____________________________________________________________________________________________
Page 5 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
Chemical Name ACGIH TLV OSHA PEL Argentina - Brazil - Occupational Mexico -
Occupational Exposure Limits - Occupational
Exposure Limits - TWAs (LTs) Exposure Limits -
TWAs (CMPs) TWAs (LMPE-PPTs)
Aromatic Ketone compound Not determined Not determined Not determined Not determined Not determined
Aliphatic alcohol polyglycol Not determined Not determined Not determined Not determined Not determined
ether
Methanol 200 ppm 200 ppm TWA 200 ppm TWA 156 ppm TWA LT; 200 200 ppm TWA
260 mg/m3 TWA mg/m3 TWA LT VLE-PPT; 260 mg/m3
TWA VLE-PPT
Aliphatic acid 10 ppm 10 ppm TWA 10 ppm TWA 8 ppm TWA LT; 20 10 ppm TWA
25 mg/m3 TWA mg/m3 TWA LT VLE-PPT; 25 mg/m3
TWA VLE-PPT
Propargyl alcohol 1 ppm Not determined 1 ppm TWA Not determined Not determined
Formaldehyde 0.3 ppm C 0.75 ppm TWA Not determined Not determined Not determined
Aromatic hydrocarbon Not determined Not determined Not determined Not determined Not determined
Naphthalene (Impurity) 10 ppm 10 ppm TWA 10 ppm TWA Not determined 10 ppm TWA
50 mg/m3 TWA VLE-PPT; 50 mg/m3
TWA VLE-PPT
Propargyl alcohol -
107-19-7
Formaldehyde 20 ppm IDLH
50-00-0
Aromatic hydrocarbon -
A risk assessment is recommended to be performed by a qualified and trained personnel to analyze the worksite and recommends
the appropriate controls such as engineering controls, work practice controls, and administrative controls as primary means of
reducing employee exposure. When there is a remaining hazards after applying the primary controls, Personal Protective
Equipment (PPE) must be used.
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.
Engineering Controls
_____________________________________________________________________________________________
Page 6 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Provide mechanical general and/or local exhaust
ventilation to prevent release of vapor or mist into work environment.
Hygiene Measures Wash hands before breaks and immediately after handling the product, Remove and wash
contaminated clothing before re-use.
_____________________________________________________________________________________________
Page 7 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
Comments
The data listed above are typical physical and chemical properties and should not be construed as product specification.
Hazardous polymerization
Hazardous polymerization does not occur.
Acute toxicity
Product information Methanol is more toxic to humans and primates than to most experimental animals, due to
differences in how it is metabolized. Non-primates do not appear to experience the acidosis
or vision effects observed in humans and primates.
Inhalation Harmful by inhalation. May cause irritation of respiratory tract. Vapors inhaled in high
concentration have a narcotic effect on the central nervous system. Symptoms of
overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of
breathing.
Eye contact Corrosive to the eyes and may cause severe damage including blindness.
Skin contact Harmful in contact with skin. Causes severe skin burns. May cause an allergic skin
reaction.
_____________________________________________________________________________________________
Page 8 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
Chemical Name IARC Group 1 or 2 ACGIH - Carcinogens OSHA listed carcinogens NTP
Aromatic Ketone compound No data available No data available No data available No data available
Aliphatic alcohol polyglycol ether No data available No data available No data available No data available
Methanol No data available No data available No data available No data available
Aliphatic acid No data available No data available No data available No data available
Propargyl alcohol No data available No data available No data available No data available
Formaldehyde Group 1; Monograph 100F A2 Suspected Human Present Known Human Carcinogen
[2012] Monograph 100F Carcinogen
[2012]; Monograph 88
[2006]; Monograph 62
[1995]; Supplement 7
[1987]
Group 1; Monograph 88
[2006]
Group 1; Monograph 62
[1995]
Group 1; Supplement 7
[1987]
Aromatic hydrocarbon No data available No data available No data available No data available
Naphthalene (Impurity) Group 2B; Monograph 82 A3 Confirmed Animal Present Reasonably Anticipated To
[2002] 2B Carcinogen with Unknown Be A Human Carcinogen
Relevance to Humans
_____________________________________________________________________________________________
Page 9 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
Toxicity to algae
See component information below.
Toxicity to fish
See component information below.
Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates
Aromatic Ketone compound No information available No information available No information available
Aliphatic alcohol polyglycol ether No information available No information available No information available
Methanol 15400 mg/L LC50 22000 mg/l EC50/LC50 18260 mg/L EC50
Freshwater Fish Freshwater Algae Daphnia Magna
ECHA Data ECHA Data OECD 202 ECHA Data
Aliphatic acid = 79 mg/L LC50 Pimephales 300.82 mg/l EC50 (Algae) = 72h = 47 mg/L EC50 Daphnia magna 24
promelas 96 h = 75 mg/L LC50 73,400 µg/l EC50 (Algae - Navicula h = 65 mg/L EC50 Daphnia magna
Lepomis macrochirus 96 h seminulum) = 96h 48 h
Propargyl alcohol 1.49 - 1.56 mg/L LC50 Pimephales No information available = 32 mg/L EC50 Daphnia magna 24
promelas 96 h h
Formaldehyde 22.6 - 25.7 mg/L LC50 Pimephales No information available = 2 mg/L (EC50; Daphnia magna)
promelas 96 h = 1510 µg/L LC50 = 20 mg/L (EC50; water flea)
Lepomis macrochirus 96 h = 41
mg/L LC50 Brachydanio rerio 96 h
0.032 - 0.226 mL/L LC50
Oncorhynchus mykiss 96 h 100 -
136 mg/L LC50 Oncorhynchus
mykiss 96 h 23.2 - 29.7 mg/L LC50
Pimephales promelas 96 h
Aromatic hydrocarbon = 45 mg/L LC50 Pimephales = 2.5 mg/L EC50 Skeletonema = 0.95 mg/L EC50 Daphnia magna
promelas 96 h = 1740 mg/L LC50 costatum 72 h 48 h
Lepomis macrochirus 96 h = 41
mg/L LC50 Pimephales promelas
96 h = 2.34 mg/L LC50
Oncorhynchus mykiss 96 h = 19
mg/L LC50 Pimephales promelas
96 h
Naphthalene (Impurity) = 31.0265 mg/L LC50 Lepomis = 0.4 mg/L EC50 Skeletonema = 2.16 mg/L LC50 Daphnia magna
macrochirus 96 h 0.91 - 2.82 mg/L costatum 72 h 48 h = 1.96 mg/L EC50 Daphnia
LC50 Oncorhynchus mykiss 96 h = magna 48 h 1.09 - 3.4 mg/L EC50
1.6 mg/L LC50 Oncorhynchus Daphnia magna 48 h
mykiss 96 h 5.74 - 6.44 mg/L LC50
Pimephales promelas 96 h = 1.99
mg/L LC50 Pimephales promelas
96 h
_____________________________________________________________________________________________
Page 10 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
12.4 Mobility
No information available.
This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT)
This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB)
None known.
Disposal Method Disposal should be made in accordance with federal, state and local regulations.
Contaminated packaging Do not burn, or use a cutting torch on, the empty drum. Empty containers may contain
flammable or explosive vapors. Empty containers should be taken for local recycling,
recovery or waste disposal. Dispose of contents/container to an approved waste disposal
plant.
14.1. UN number
UN No. (DOT) UN2924
UN No. (MT/ANTT) UN2924
UN No. (TDG) UN2924
UN/ID No. (ADR/RID/ADN/ADG) UN2924
UN No. (IMDG/ANTAQ) UN2924
UN No. (ICAO/ANAC) UN2924
UN No. (DPC) UN2924
_____________________________________________________________________________________________
Page 11 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC Code
Please contact [email protected] for info regarding transport in Bulk.
Europe - REACH
All products supplied from the European Economic Area (EEA) are compliant with the REACH Regulation EC 1907/2006.For
products supplied from the EEA, Schlumberger and/or its suppliers have pre-registered and is registering all of the substances that
it and/or its suppliers manufactures in or imports into the EEA that are subject to Title II of the REACH Regulation. All products
supplied from outside the EEA are subject to REACH only if imported into the EEA. The importer of the products must comply with
REACH for each imported substance. Contact [email protected] for REACH information.
IMPORTS, Canada
No import volume restrictions.
_____________________________________________________________________________________________
Page 12 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
California Proposition 65
WARNING
This product can expose you to chemicals including those listed below, which is [are] known to the State of California to cause
cancer, birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov
This Safety Data Sheet has been prepared in compliance with the Hazardous Products Regulations.
Version 9
This SDS has been revised in the 2, 3, 8, 9, 14, 15, 16. Prepared in accordance with WHMIS 2015 Prepared in accordance
_____________________________________________________________________________________________
Page 13 / 14
Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018
_____________________________________________________________________________________________
HMIS classification
Health 3*
Flammability 2
Physical hazard 0
PPE X
Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
measur ement s,t estsordat ader ivedf rom supplier’
sownst udyorf urni shedby ot her s.Inpr ovidingt hi
sSDS
information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness
of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the
maxi mum ext entper mi ttedbyl aw,suppl ier
’swarrant yobli
gati
onsandbuyer ’ssoler emedi esar easst atedinsepar at
e
agreement between the parties.
This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
Page 14 / 14