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Safety Data Sheet: Corrosion Inhibitor A261

This safety data sheet provides information on Corrosion Inhibitor A261. It contains hazardous components like aromatic ketone compound, aliphatic alcohol polyglycol ether, methanol, aliphatic acid, propargyl alcohol, and formaldehyde. The product is harmful if swallowed, in contact with skin, or inhaled and can cause severe skin and eye damage. It may also cause cancer, organ damage, and is toxic to aquatic life. In case of accidental exposure, rinse affected areas thoroughly and seek immediate medical attention.

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Ambroise RICHARD
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0% found this document useful (0 votes)
280 views

Safety Data Sheet: Corrosion Inhibitor A261

This safety data sheet provides information on Corrosion Inhibitor A261. It contains hazardous components like aromatic ketone compound, aliphatic alcohol polyglycol ether, methanol, aliphatic acid, propargyl alcohol, and formaldehyde. The product is harmful if swallowed, in contact with skin, or inhaled and can cause severe skin and eye damage. It may also cause cancer, organ damage, and is toxic to aquatic life. In case of accidental exposure, rinse affected areas thoroughly and seek immediate medical attention.

Uploaded by

Ambroise RICHARD
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 14

SDS no.

A261
Version 9
Revision date 11/Mar/2018
Supersedes date 25/May/2017

Safety Data Sheet


Corrosion Inhibitor A261

1. Identification of the Substance/Preparation and of the Company/Undertaking


1.1 Product identifier

Product name Corrosion Inhibitor A261

Product code A261

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Used as a corrosion inhibitor in oilfield applications.

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
Schlumberger Technology Corporation
110 Schlumberger Drive
Sugar Land, Texas 77478, USA
Telephone: 1-281-285-7873

Schlumberger Canada, Ltd.


200, 125 - 9th Avenue SE
Calgary, Alberta T2G 0P6, Canada
Telephone: 1-613-992-4624

E-mail address [email protected]

Prepared by
Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Thai Hien Nguyen

1.4 Emergency Telephone Number

Emergency telephone (24 Hour) Asia Pacific +65 3158 1074, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0)
1235 239 671, USA +1 281 595 3518/+1 866 928 0789 , Canada +1 800 579 7421 , Argentina: +54 11 5984 3690, Brazil :
0800-720-8000 /0800-777-2323 (WGRA)

2. Hazards Identification
2.1 Classification of the substance or mixture

GHS - Classification

Health hazards
Acute toxicity - Oral Category 4
Acute toxicity - Dermal Category 4

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Acute toxicity - Inhalation (Vapors) Category 4


Skin corrosion/irritation Category 1 Subcategory 1B
Serious eye damage/eye irritation Category 1
Skin sensitization Category 1
Germ cell mutagenicity Category 2
Carcinogenicity Category 1B
Specific target organ toxicity - Single exposure Category 2

Environmental hazards
Acute aquatic toxicity Category 1
Chronic aquatic toxicity Category 1

Physical Hazards
Flammable Liquids Category 3

2.2 Label elements

Signal word
DANGER

Hazard Statements
H302 - Harmful if swallowed
H312 - Harmful in contact with skin
H332 - Harmful if inhaled
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H341 - Suspected of causing genetic defects
H350 - May cause cancer
H371 - May cause damage to organs
H410 - Very toxic to aquatic life with long lasting effects
H226 - Flammable liquid and vapor

Precautionary Statements
P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P240 - Ground/bond container and receiving equipment
P241 - Use explosion-proof electrical/ ventilating/ lighting/ equipment
P242 - Use only non-sparking tools
P243 - Take precautionary measures against static discharge
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

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P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P312 - Call a POISON CENTER or doctor/physician if you feel unwell
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention
P362 + P364 - Take off contaminated clothing and wash it before reuse
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

Hazards not otherwise classified


None known

Unknown acute toxicity 5% of the mixture consists of ingredient(s) of unknown toxicity.

3. Composition/information on Ingredients

3.1 Substances

Not applicable

3.2 Mixtures

Chemical Name CAS No Weight-%


Aromatic Ketone compound Proprietary 30 - 60
Aliphatic alcohol polyglycol ether Proprietary 10 - 30
Methanol 67-56-1 7 - 13
Aliphatic acid Proprietary 3-7
Propargyl alcohol 107-19-7 3-7
Formaldehyde 50-00-0 3-7
Aromatic hydrocarbon Proprietary 1-5
Naphthalene (Impurity) 91-20-3 0.1 - 1

Comments
The product contains other ingredients which do not contribute to the overall classification. The specific chemical identity and/or
exact percentage (concentration) of composition has been withheld as a trade secret

HMIRA Registration Number: 11459 Filing Date: 19/May/2017

4. First Aid Measures


4.1 First aid measures

Inhalation Move the exposed person to fresh air at once. If breathing is difficult, (trained personnel
should) give oxygen. If not breathing, give artificial respiration. Get medical attention if any
discomfort continues.

Ingestion Do NOT induce vomiting. Get immediate medical attention. Rinse mouth. Risk of product
entering the lungs on vomiting after ingestion. Never give anything by mouth to an
unconscious person.

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Skin contact Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove
clothing if soaked through and wash as above. Burns: Flush with water immediately. While
flushing, remove clothes which do not adhere to affected area. Call an ambulance.
Continue flushing during transport to hospital. Chemical burns must be treated by a
physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids. Hold eye open and rinse
slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the
first five minutes, then continue rinsing eye. Get immediate medical attention.

4.2. Most important symptoms and effects, both acute and delayed

General advice Seek medical attention for all burns, regardless how minor they may seem. The severity of
the symptoms described will vary dependant of the concentration and the length of
exposure. If adverse symptoms develop, the casualty should be transferred to hospital as
soon as possible.

Symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically

5. Fire-Fighting Measures

5.1 Extinguishing media

Suitable extinguishing media


Dry chemical, CO 2, alcohol-resistant foam or water spray.

Extinguishing media which must not be used for safety reasons


None known.

5.2. Special hazards arising from the substance or mixture

Unusual fire and explosion hazards


Vapors are heavier than air and may spread along floors. Vapors may travel to source of ignition and flash back.

Hazardous combustion products


Thermal decomposition can lead to release of irritating and toxic gases and vapors.

5.3 Advice for firefighters

Special protective equipment for fire-fighters


As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures


Containers close to fire should be removed immediately or cooled with water.

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6. Accidental Release Measures


6.1. Personal precautions, protective equipment and emergency procedures

Remove all sources of ignition. Keep away from heat, sparks, and flame. Avoid contact with skin, eyes and inhalation of vapors.
Wash thoroughly after handling. Use personal protective equipment. See also section 8.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controls


Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and material for containment and cleaning up

Methods for containment


Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.

Methods for cleaning up


Take precautionary measures against static discharges. Use non-sparking tools and equipment. Contain and collect spillage with
non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local/national regulations (see Section 13). Ground and bond containers when transferring material. After cleaning,
flush away traces with water.

6.4 Reference to other sections

See section 13 for more information.

7. Handling and Storage


7.1 Precautions for safe handling

Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid spills and
splashing during use. Do not breathe vapors or spray mist. Keep away from open flames, hot surfaces and sources of ignition.

Hygiene measures
Use good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product. Wash
hands and face before breaks and immediately after handling the product.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Take
precautionary measures against static discharges. Use spark-proof tools and
explosion-proof equipment. Ensure all equipment is electrically grounded before beginning
transfer operations.

Storage precautions Keep container/package tightly closed and in a well-ventilated place. Keep away from open
flames, hot surfaces and sources of ignition. Keep away from direct sunlight. Follow safe
warehousing practices regarding palletizing, banding, shrink-wrapping and/or stacking.

8. Exposure Controls/Personal Protection


8.1 Control parameters

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Chemical Name ACGIH TLV OSHA PEL Argentina - Brazil - Occupational Mexico -
Occupational Exposure Limits - Occupational
Exposure Limits - TWAs (LTs) Exposure Limits -
TWAs (CMPs) TWAs (LMPE-PPTs)
Aromatic Ketone compound Not determined Not determined Not determined Not determined Not determined
Aliphatic alcohol polyglycol Not determined Not determined Not determined Not determined Not determined
ether
Methanol 200 ppm 200 ppm TWA 200 ppm TWA 156 ppm TWA LT; 200 200 ppm TWA
260 mg/m3 TWA mg/m3 TWA LT VLE-PPT; 260 mg/m3
TWA VLE-PPT
Aliphatic acid 10 ppm 10 ppm TWA 10 ppm TWA 8 ppm TWA LT; 20 10 ppm TWA
25 mg/m3 TWA mg/m3 TWA LT VLE-PPT; 25 mg/m3
TWA VLE-PPT
Propargyl alcohol 1 ppm Not determined 1 ppm TWA Not determined Not determined
Formaldehyde 0.3 ppm C 0.75 ppm TWA Not determined Not determined Not determined
Aromatic hydrocarbon Not determined Not determined Not determined Not determined Not determined
Naphthalene (Impurity) 10 ppm 10 ppm TWA 10 ppm TWA Not determined 10 ppm TWA
50 mg/m3 TWA VLE-PPT; 50 mg/m3
TWA VLE-PPT

IDLH (Immediately Dangerous to Life or Health)


This product contains substance(s) classified as Immediately Dangerous to Life or Health (IDLH) by the US National Institute for
Occupational Safety and Health (NIOSH). The purpose of establishing an IDLH value is to ensure that the worker can escape from
a given contaminated environment in the event of failure of the most protective respiratory protection equipment. In the event of
failure of respiratory protection equipment every effort should be made to exit immediately.

Chemical Name IDLH (Immediately Dangerous to Life or Health)


Aromatic Ketone compound -

Aliphatic alcohol polyglycol ether -

Methanol 6000 ppm IDLH


67-56-1
Aliphatic acid 50 ppm IDLH

Propargyl alcohol -
107-19-7
Formaldehyde 20 ppm IDLH
50-00-0
Aromatic hydrocarbon -

Naphthalene (Impurity) 250 ppm IDLH


91-20-3

8.2 Exposure controls

A risk assessment is recommended to be performed by a qualified and trained personnel to analyze the worksite and recommends
the appropriate controls such as engineering controls, work practice controls, and administrative controls as primary means of
reducing employee exposure. When there is a remaining hazards after applying the primary controls, Personal Protective
Equipment (PPE) must be used.

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.

Engineering Controls

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Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Provide mechanical general and/or local exhaust
ventilation to prevent release of vapor or mist into work environment.

Personal protective equipment


Eye protection Tightly fitting safety goggles.
Hand protection Use protective gloves made of: Viton polyvinyl alcohol or nitrile-butyl rubber gloves Be
aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory Protection All respiratory protection equipment should be used within a comprehensive respiratory
protection program that meets the requirements of 29 CFR 1910.134 (U.S. OSHA
Respiratory Protection Standard) or local equivalent.If exposed to airborne mist/aerosol of
this product, use an organic vapor cartridge with a P-95 pre-filter attached. In work
environments containing oil mist/aerosol, use an organic vapor cartridge with a P-95
pre-filter attached.If exposed to vapors from this product, use a NIOSH/MSHA-approved
respirator with an organic vapor cartridge.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact, Eye wash and
emergency shower must be available at the work place.

Hygiene Measures Wash hands before breaks and immediately after handling the product, Remove and wash
contaminated clothing before re-use.

9. Physical and Chemical Properties


9.1 Information on basic physical and chemical properties
Physical state Liquid
Appearance Transparent
Color Orange
Odor Amine-like
Odor threshold No information available

Property Values Remarks


pH 5.7
pH @ dilution N/D
Melting / freezing point - 57 °C/ -71 °F
Boiling point/range 74 °C / 166 °F
Flash point 47 °C / 117 °F
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit 36.5 % (methanol)
Lower flammability limit 5.5 % (methanol)
Vapor pressure No information available
Vapor density > 1 (air = 1)
Specific gravity 1.028 - 1.039 @ 15.6 °C
Bulk density No information available
Water solubility 5 g/l @ 20°C
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature > 242 °C/ 468 °F
Kinematic viscosity No information available
Dynamic viscosity No information available
log Pow No information available

Explosive properties No information available


Oxidizing properties No information available

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9.2 Other information


Pour point No information available
Molecular weight No information available
VOC content(%) No information available
Density No information available

Comments
The data listed above are typical physical and chemical properties and should not be construed as product specification.

10. Stability and Reactivity


10.1 Reactivity

No specific reactivity hazards associated with this product.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerization
Hazardous polymerization does not occur.

10.4 Conditions to avoid

Avoid heat, flames and other sources of ignition.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition products

See Section 5.2.

11. Toxicological Information

11.1 Information on toxicological effects

Acute toxicity
Product information Methanol is more toxic to humans and primates than to most experimental animals, due to
differences in how it is metabolized. Non-primates do not appear to experience the acidosis
or vision effects observed in humans and primates.

Inhalation Harmful by inhalation. May cause irritation of respiratory tract. Vapors inhaled in high
concentration have a narcotic effect on the central nervous system. Symptoms of
overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of
breathing.

Eye contact Corrosive to the eyes and may cause severe damage including blindness.

Skin contact Harmful in contact with skin. Causes severe skin burns. May cause an allergic skin
reaction.

Ingestion Harmful if swallowed. Can burn mouth, throat, and stomach.

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Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation


Aromatic Ketone compound No data available No data available No data available
Aliphatic alcohol polyglycol ether No data available No data available No data available
Methanol 2528 mg/kg (Rat) 17100 mg/kg (Rabbit) 128.2 mg/L (Rat) 4h
ECHA Data ECHA Data
Aliphatic acid = 3310 mg/kg ( Rat ) = 1060 mg/kg ( Rabbit ) = 11.4 mg/L ( Rat ) 4 h
Propargyl alcohol = 20 mg/kg ( Rat ) = 55 mg/kg ( = 16 mg/kg ( Rabbit ) = 1200 ppm ( Rat ) 1 h = 1040
Rat ) = 110 mg/kg ( Rat ) ppm ( Rat ) 1 h
Formaldehyde = 100 mg/kg ( Rat ) = 270 mg/kg ( Rabbit ) = 0.578 mg/L ( Rat ) 4 h
Aromatic hydrocarbon > 5000 mg/kg ( Rat ) > 2 mL/kg ( Rabbit ) > 590 mg/m3 ( Rat ) 4 h
Naphthalene (Impurity) = 1110 mg/kg ( Rat ) = 490 > 20 g/kg ( Rabbit ) = 1120 > 340 mg/m3 ( Rat ) 1 h
mg/kg ( Rat ) mg/kg ( Rabbit )

Chemical Name IARC Group 1 or 2 ACGIH - Carcinogens OSHA listed carcinogens NTP
Aromatic Ketone compound No data available No data available No data available No data available
Aliphatic alcohol polyglycol ether No data available No data available No data available No data available
Methanol No data available No data available No data available No data available
Aliphatic acid No data available No data available No data available No data available
Propargyl alcohol No data available No data available No data available No data available
Formaldehyde Group 1; Monograph 100F A2 Suspected Human Present Known Human Carcinogen
[2012] Monograph 100F Carcinogen
[2012]; Monograph 88
[2006]; Monograph 62
[1995]; Supplement 7
[1987]
Group 1; Monograph 88
[2006]
Group 1; Monograph 62
[1995]
Group 1; Supplement 7
[1987]
Aromatic hydrocarbon No data available No data available No data available No data available
Naphthalene (Impurity) Group 2B; Monograph 82 A3 Confirmed Animal Present Reasonably Anticipated To
[2002] 2B Carcinogen with Unknown Be A Human Carcinogen
Relevance to Humans

Sensitization May cause allergic skin reaction.

Mutagenic effects Contains an known or suspected mutagen.

Carcinogenicity Contains a known or suspected carcinogen.

Reproductive toxicity Contains ingredients that are suspected reproductive hazards.

Developmental toxicity Component substance is listed on California Proposition 65 as a developmental hazard.

Routes of exposure Inhalation. Skin contact. Eye contact. Ingestion.

Routes of entry Inhalation. Skin contact. Eye contact. Ingestion.

Specific target organ toxicity - Category 2


Single exposure
Specific target organ toxicity - Not classified.
Repeated exposure

Target organ effects Optic nerve (nervus opticus).

Aspiration hazard Not classified.

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12. Ecological Information


12.1 Toxicity

Toxicity to algae
See component information below.

Toxicity to fish
See component information below.

Toxicity to daphnia and other aquatic invertebrates


See component information below.

Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates
Aromatic Ketone compound No information available No information available No information available
Aliphatic alcohol polyglycol ether No information available No information available No information available
Methanol 15400 mg/L LC50 22000 mg/l EC50/LC50 18260 mg/L EC50
Freshwater Fish Freshwater Algae Daphnia Magna
ECHA Data ECHA Data OECD 202 ECHA Data
Aliphatic acid = 79 mg/L LC50 Pimephales 300.82 mg/l EC50 (Algae) = 72h = 47 mg/L EC50 Daphnia magna 24
promelas 96 h = 75 mg/L LC50 73,400 µg/l EC50 (Algae - Navicula h = 65 mg/L EC50 Daphnia magna
Lepomis macrochirus 96 h seminulum) = 96h 48 h
Propargyl alcohol 1.49 - 1.56 mg/L LC50 Pimephales No information available = 32 mg/L EC50 Daphnia magna 24
promelas 96 h h
Formaldehyde 22.6 - 25.7 mg/L LC50 Pimephales No information available = 2 mg/L (EC50; Daphnia magna)
promelas 96 h = 1510 µg/L LC50 = 20 mg/L (EC50; water flea)
Lepomis macrochirus 96 h = 41
mg/L LC50 Brachydanio rerio 96 h
0.032 - 0.226 mL/L LC50
Oncorhynchus mykiss 96 h 100 -
136 mg/L LC50 Oncorhynchus
mykiss 96 h 23.2 - 29.7 mg/L LC50
Pimephales promelas 96 h
Aromatic hydrocarbon = 45 mg/L LC50 Pimephales = 2.5 mg/L EC50 Skeletonema = 0.95 mg/L EC50 Daphnia magna
promelas 96 h = 1740 mg/L LC50 costatum 72 h 48 h
Lepomis macrochirus 96 h = 41
mg/L LC50 Pimephales promelas
96 h = 2.34 mg/L LC50
Oncorhynchus mykiss 96 h = 19
mg/L LC50 Pimephales promelas
96 h
Naphthalene (Impurity) = 31.0265 mg/L LC50 Lepomis = 0.4 mg/L EC50 Skeletonema = 2.16 mg/L LC50 Daphnia magna
macrochirus 96 h 0.91 - 2.82 mg/L costatum 72 h 48 h = 1.96 mg/L EC50 Daphnia
LC50 Oncorhynchus mykiss 96 h = magna 48 h 1.09 - 3.4 mg/L EC50
1.6 mg/L LC50 Oncorhynchus Daphnia magna 48 h
mykiss 96 h 5.74 - 6.44 mg/L LC50
Pimephales promelas 96 h = 1.99
mg/L LC50 Pimephales promelas
96 h

12.2 Persistence and degradability

No product level data available.

12.3 Bioaccumulative potential

No product level data available.

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12.4 Mobility

No information available.

12.5 Results of PBT and vPvB assessment

This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT)
This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB)

12.6 Other adverse effects.

None known.

13. Disposal Considerations


13.1 Waste treatment methods

Disposal Method Disposal should be made in accordance with federal, state and local regulations.

Contaminated packaging Do not burn, or use a cutting torch on, the empty drum. Empty containers may contain
flammable or explosive vapors. Empty containers should be taken for local recycling,
recovery or waste disposal. Dispose of contents/container to an approved waste disposal
plant.

14. Transport information

14.1. UN number
UN No. (DOT) UN2924
UN No. (MT/ANTT) UN2924
UN No. (TDG) UN2924
UN/ID No. (ADR/RID/ADN/ADG) UN2924
UN No. (IMDG/ANTAQ) UN2924
UN No. (ICAO/ANAC) UN2924
UN No. (DPC) UN2924

14.2. UN proper shipping name


FLAMMABLE LIQUID, CORROSIVE, N.O.S. (contains methanol, aromatic ketones),

Product (RQ): 390 gallons (formaldehyde)

14.3 Hazard class(es)


DOT Hazard class 3 (8)
ANTT Hazard class 3 (8)
TDG Hazard class 3 (8)
ADR/RID/ADN/ADG Hazard class 3 (8)
IMDG/ANTAQ Hazard class 3 (8)
ICAO/ANAC Hazard class/division 3 (8)
DPC Hazard class 3 (8)

14.4 Packing group


DOT/ANTT Packing group III
ANTT Packing group III
TDG Packing group III
ADR/RID/ADN/ADG Packing group III
IMDG/ANTAQ Packing group III
ICAO/ANAC Packing group III

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DPC Packing group III

14.5 Environmental hazard


Marine pollutant Yes, Aromatic ketone

14.6 Special precautions


Not applicable

14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC Code
Please contact [email protected] for info regarding transport in Bulk.

15. Regulatory Information


International inventories

USA (TSCA) Complies


Canada (DSL) Complies
Philippines (PICCS) Does not comply
Japan (ENCS) Does not comply
China (IECSC) Does not comply
Australia (AICS) Does not comply
Korean (KECL) Does not comply
New Zealand (NZIoC) Does not comply

Europe - REACH
All products supplied from the European Economic Area (EEA) are compliant with the REACH Regulation EC 1907/2006.For
products supplied from the EEA, Schlumberger and/or its suppliers have pre-registered and is registering all of the substances that
it and/or its suppliers manufactures in or imports into the EEA that are subject to Title II of the REACH Regulation. All products
supplied from outside the EEA are subject to REACH only if imported into the EEA. The importer of the products must comply with
REACH for each imported substance. Contact [email protected] for REACH information.

IMPORTS, Canada
No import volume restrictions.

U.S. Federal and State Regulations

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SARA 311/312 Hazard Categories


Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate
classifications. Under the amended regulations at 40 CFR 370, EPCRA 311/312 Tier II reporting for the 2017 calendar year will
need to be consistent with updated hazard classifications.

Chemical Name SARA 302 / TPQs SARA 313 CERCLA RQ


Aromatic Ketone compound N/A N/A N/A
Aliphatic alcohol polyglycol ether N/A N/A N/A
Methanol N/A 1.0 % 5000 lb final RQ
2270 kg final RQ
Aliphatic acid N/A N/A 5000 lb final RQ
2270 kg final RQ
Propargyl alcohol N/A 1.0 % 1000 lb final RQ
454 kg final RQ
Formaldehyde 500 lb TPQ 0.1 % 100 lb final RQ
45.4 kg final RQ
Aromatic hydrocarbon N/A N/A N/A
Naphthalene (Impurity) N/A 0.1 % 100 lb final RQ
45.4 kg final RQ

California Proposition 65

WARNING

This product can expose you to chemicals including those listed below, which is [are] known to the State of California to cause
cancer, birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov

Chemical Name California Proposition 65


Methanol developmental toxicity
67-56-1
Formaldehyde carcinogen
50-00-0
Naphthalene (Impurity) carcinogen
91-20-3
Ethylene oxide developmental toxicity
75-21-8 male reproductive toxicity
female reproductive toxicity
carcinogen
Canadian Classification

This Safety Data Sheet has been prepared in compliance with the Hazardous Products Regulations.

16. Other Information


Supersedes date 25/May/2017

Revision date 11/Mar/2018

Version 9

This SDS has been revised in the 2, 3, 8, 9, 14, 15, 16. Prepared in accordance with WHMIS 2015 Prepared in accordance

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Corrosion Inhibitor A261 SDS no. A261
Revision date 11/Mar/2018

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following section(s) with OSHA HAZCOM 2012.

HMIS classification

Health 3*
Flammability 2
Physical hazard 0
PPE X

N/A - Not Applicable, N/D - Not Determined.

Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
measur ement s,t estsordat ader ivedf rom supplier’
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sSDS
information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness
of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the
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’swarrant yobli
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agreement between the parties.
This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.

_____________________________________________________________________________________________

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