Safety Data Sheet

SikaBond® Construction Adhesive

Revision Date 06/23/2021 Print Date 06/23/2021

SECTION 1. IDENTIFICATION

Product name : SikaBond® Construction Adhesive

Other means of identification : No data available

Company name : 601, avenue Delmar

Canada
Pointe-Claire, QC H9R 4A9
Sika Canada Inc.
www.sika.ca

Telephone : (514) 697-2610 / 1 (800) 933-7452

Telefax : (514) 694-2792

E-mail address : [email protected]

Emergency telephone : CANUTEC (collect) (613) 996-6666 (24 hours)

Recommended use of the : For further information, refer to product data sheet.
chemical and restrictions on
use

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the Hazardous Products Regulations

Respiratory sensitization : Category 1

Skin sensitization : Sub-category 1A

Carcinogenicity (Inhalation) : Category 1A

Carcinogenicity : Category 2

Specific target organ toxicity : Category 2

- repeated exposure (Inhala-
tion)

GHS label elements

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H317 May cause an allergic skin reaction.

H334 May cause allergy or asthma symptoms or breathing diffi-
culties if inhaled.
H350 May cause cancer by inhalation.

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H351 Suspected of causing cancer.

H373 May cause damage to organs through prolonged or re-
peated exposure if inhaled.

Precautionary Statements :
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P260 Do not breathe mist or vapors.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
P284 In case of inadequate ventilation wear respiratory protec-
tion.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Additional Labeling
There are no ingredients with unknown acute toxicity used in a mixture at a concentration >= 1%.
Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Components
Chemical name CAS-No. Classification Concentra-
tion (% w/w)
xylene 1330-20-7 Flam. Liq. 3; H226 >= 1 - < 5
Acute Tox. 4; H332
Acute Tox. 4; H312
Skin Irrit. 2; H315
Eye Irrit. 2A; H319
STOT SE 3; H335
STOT RE 2; H373
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Asp. Tox. 1; H304

Quartz (SiO2) 14808-60-7 Carc. 1A; H350i >= 0.1 - < 1
STOT RE 1; H372
STOT SE 3; H335
4,4'-methylenediphenyl diisocyanate 101-68-8 Acute Tox. 4; H332 >= 0.1 - < 1
Skin Irrit. 2; H315
Eye Irrit. 2A; H319
Eye Irrit. 2B; H320
Resp. Sens. 1; H334
Skin Sens. 1; H317
Carc. 2; H351
STOT SE 3; H335
STOT RE 2; H373
Pentamethyl piperidylsebacate 41556-26-7 Skin Sens. 1A; H317 >= 0.1 - < 1
Actual concentration or concentration range is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : Remove contact lenses.

Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting without medical advice.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Obtain medical attention.

Most important symptoms : Asthmatic appearance

and effects, both acute and Allergic reactions
delayed sensitizing effects
May cause an allergic skin reaction.
May cause allergy or asthma symptoms or breathing difficul-
ties if inhaled.
May cause cancer by inhalation.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated
exposure if inhaled.

Notes to physician : Treat symptomatically.

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Safety Data Sheet

SikaBond® Construction Adhesive

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SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.

Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Deny access to unprotected persons.
gency procedures

Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Advice on safe handling : Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitization problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Follow standard hygiene measures when handling chemical
products.

Conditions for safe storage : Store in original container.

Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Store in accordance with local regulations.
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Safety Data Sheet

SikaBond® Construction Adhesive

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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
xylene 1330-20-7 TWA 100 ppm CA AB OEL
434 mg/m3
STEL 150 ppm CA AB OEL
651 mg/m3
TWAEV 100 ppm CA QC OEL
434 mg/m3
STEV 150 ppm CA QC OEL
651 mg/m3
TWA 100 ppm CA BC OEL
STEL 150 ppm CA BC OEL
TWA 100 ppm ACGIH
STEL 150 ppm ACGIH
Quartz (SiO2) 14808-60-7 TWA (Res- 0.025 mg/m3 CA AB OEL
pirable par-
ticulates)
TWA (Res- 0.1 mg/m3 CA ON OEL
pirable frac-
tion)
TWAEV 0.1 mg/m3 CA QC OEL
(respirable
dust)
TWA (Res- 0.025 mg/m3 CA BC OEL
pirable) (Silica)
TWA (Res- 0.025 mg/m3 CA BC OEL
pirable)
TWA (Res- 0.025 mg/m3 CA BC OEL
pirable) (Silica)
TWA (Res- 0.025 mg/m3 ACGIH
pirable par-
ticulate mat-
ter)
TWA (Res- 0.025 mg/m3 ACGIH
pirable par- (Silica)
ticulate mat-
ter)
TWA (Res- 0.025 mg/m3 ACGIH
pirable par-
ticulate mat-
ter)
TWA (Res- 0.025 mg/m3 ACGIH
pirable par- (Silica)
ticulate mat-
ter)
4,4'-methylenediphenyl diiso- 101-68-8 TWA 0.005 ppm CA BC OEL
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cyanate
C 0.01 ppm CA BC OEL
TWA 0.005 ppm CA ON OEL
C 0.02 ppm CA ON OEL
TWAEV 0.005 ppm CA QC OEL
0.051 mg/m3
TWA 0.005 ppm ACGIH
Engineering measures : Use of adequate ventilation should be sufficient to control
worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use pro-
cess enclosures, local exhaust ventilation or other engineer-
ing controls to keep worker exposure below any recommend-
ed or statutory limits.
Personal protective equipment
Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.

The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.

Hand protection : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.

Eye protection : Safety eyewear complying with an approved standard should

be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Hygiene measures : Avoid contact with skin, eyes and clothing.

Wash hands before breaks and immediately after handling
the product.
Remove contaminated clothing and protective equipment
before entering eating areas.
Wash thoroughly after handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : paste

Color : various

Odor : aromatic

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Odor Threshold : No data available

pH : Not applicable

Melting point/range / Freezing : No data available

point
Boiling point/boiling range : No data available

Flash point : Not applicable

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapor pressure : 0.01 hpa

Relative vapor density : No data available

Density : 1.457 g/cm3

Solubility(ies)
Water solubility : insoluble

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water
Autoignition temperature : No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : > 20.5 mm2/s ( 40 °C (104 °F))

Explosive properties : No data available

Oxidizing properties : No data available

Volatile organic compounds : 33 g/l

(VOC) content

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

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Possibility of hazardous reac- : Stable under recommended storage conditions.

tions

Conditions to avoid : No data available

Incompatible materials : No data available

Hazardous decomposition : No decomposition if stored and applied as directed.

products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Components:

xylene:
Acute oral toxicity : LD50 Oral (Rat): 3,523 mg/kg

Acute dermal toxicity : LD50 Dermal (Rabbit): 1,700 mg/kg

4,4'-methylenediphenyl diisocyanate:
Acute oral toxicity : LD50 Oral (Rat): > 4,700 mg/kg
Method: OECD Test Guideline 401

Acute inhalation toxicity : LC50: 1.5 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Method: Expert judgment

Skin corrosion/irritation
Not classified based on available information.
Serious eye damage/eye irritation
Not classified based on available information.
Respiratory or skin sensitization

Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
May cause cancer by inhalation.
Suspected of causing cancer.
IARC Group 1: Carcinogenic to humans
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SikaBond® Construction Adhesive

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Quartz (SiO2) 14808-60-7

(Silica dust, crystalline)
Group 2B: Possibly carcinogenic to humans
Titanium dioxide 13463-67-7
Group 2B: Possibly carcinogenic to humans
ethylbenzene 100-41-4
Group 2B: Possibly carcinogenic to humans
Carbon black, amorphous 1333-86-4

OSHA Not applicable

NTP Known to be human carcinogen

Quartz (SiO2) 14808-60-7
(Silica, Crystalline (Respirable Size))

Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure if inhaled.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
Aspiration toxicity
Not classified based on available information.
Further information

Product:
Quartz (14808-60-7): This classification is relevant when ex-
posed to Quartz (silicon dioxide) in dust or powder form only,
including cured product that is subject to sanding, grinding,
cutting, or other surface preparation activities.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

xylene:
Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (green algae)): 2.2
plants mg/l
Method: OECD Test Guideline 201

Toxicity to fish (Chronic tox- : NOEC (Oncorhynchus mykiss (rainbow trout)): > 1.3 mg/l
icity) Exposure time: 56 d

Toxicity to daphnia and other : NOEC (Daphnia): 1.17 mg/l

aquatic invertebrates (Chron- Exposure time: 7 d
ic toxicity)
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Persistence and degradability

No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : Do not empty into drains; dispose of this material and its con-
mation tainer in a safe way.
Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.

Contaminated packaging : Empty containers should be taken to an approved waste han-

dling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulations

IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

TDG
Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

Canadian lists
No substances are subject to a Significant New Activity Notification.

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SikaBond® Construction Adhesive

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SECTION 16. OTHER INFORMATION

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
CA AB OEL : Canada. Alberta, Occupational Health and Safety Code (table
2: OEL)
CA BC OEL : Canada. British Columbia OEL
CA ON OEL : Ontario Table of Occupational Exposure Limits made under
the Occupational Health and Safety Act.
CA QC OEL : Québec. Regulation respecting occupational health and safe-
ty, Schedule 1, Part 1: Permissible exposure values for air-
borne contaminants
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
CA AB OEL / TWA : 8-hour Occupational exposure limit
CA AB OEL / STEL : 15-minute occupational exposure limit
CA BC OEL / TWA : 8-hour time weighted average
CA BC OEL / STEL : short-term exposure limit
CA BC OEL / C : ceiling limit
CA ON OEL / C : Ceiling Limit (C)
CA ON OEL / TWA : Time-Weighted Average Limit (TWA)
CA QC OEL / TWAEV : Time-weighted average exposure value
CA QC OEL / STEV : Short-term exposure value

ADR : Accord européen relatif au transport international des

marchandises Dangereuses par Route
CAS : Chemical Abstracts Service
DNEL : Derived no-effect level
EC50 : Half maximal effective concentration
GHS : Globally Harmonized System
IATA : International Air Transport Association
IMDG : International Maritime Code for Dangerous Goods
LD50 : Median lethal dosis (the amount of a material, given all at
once, which causes the death of 50% (one half) of a group of
test animals)
LC50 : Median lethal concentration (concentrations of the chemical in
air that kills 50% of the test animals during the observation
period)
MARPOL : International Convention for the Prevention of Pollution from
Ships, 1973 as modified by the Protocol of 1978
OEL : Occupational Exposure Limit
PBT : Persistent, bioaccumulative and toxic
PNEC : Predicted no effect concentration
REACH : Regulation (EC) No 1907/2006 of the European Parliament
and of the Council of 18 December 2006 concerning the Reg-
istration, Evaluation, Authorisation and Restriction of Chemi-
cals (REACH), establishing a European Chemicals Agency
SVHC : Substances of Very High Concern
vPvB : Very persistent and very bioaccumulative

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Notice to Reader:
The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada
product identified and described herein. This information is not intended to address, nor does it ad-
dress the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the
identified product that Sika believes to be reliable as of the date hereof. Prior to each use of any Sika
product, the user must always read and follow the warnings and instructions on the product's current
Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are
available at web site and/or telephone number listed.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING

FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL
THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE
FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY
OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sika.ca or 514-697-2610.

Revision Date : 06/23/2021

Date format : mm/dd/yyyy

Prepared by : R & D of Sika Canada Inc.

Material number : 106,403

CA / Z8

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