Series RCH Code No. RSPL/3. Roll No. Candidates must write the exde on the title page of the answer-book. © Please check that this question paper contains 12 printed pages. © Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. © Please check that this question paper contains 35 questions ¢ Please write down the Serial Number of the question before attempting it. e 15 minutes time has been allotted to read this question paper. CHEMISTRY (Theory) Time allowed : 3 hours Maximum Marks : 70 General Instructions : Read the following instructions carefully. @ @) © ‘ @ @ p @ | (h) RSPL/3 There are 35 questions in this question paper with internal choice. ‘Section A consists of 18 multiple-choice questions carrying 1 mark each. Section B consists of 7 very short answer questions carrying 2 marks each. ‘Section C consists of 5 short answer questions carrying 3 marks each. Section D consists of 2 case-based questions carrying 4 marks each. Section E consists of 3 long answer questions carrying 5 marks each. AIL questions are compulsory. Use of log tables and calculators is not allowed. 1 : PIO.SECTION ~A The following questions are multiple-choice questions with one correct answer. Each question carries I mark, There in no internal choice in thin section. () COJNaOH, A (cH 1 Seo Ac eeo sO & aor os > X and ‘Y respectively are: HH HH OCOcH, 4~—-COOH (a) Ccoon C-c00en, ) ox COOH oO ou COCH, ai OCOCH, - cron. Coon ww OL goon, cy coon 2. Klin acetone undergoes Sy2 reaction with each P, Q, R and 8, The rates of the reaction vary as ° i ¢-CH,—Cl H,C-Cl CH,—CH—CH, CH,=CHI—CH,C1 C J 1 R = @ (a) P>Q>R>S (b) S>P>Q>R () P>R>Q>S @ R>P>S>Q 8, How many moles of Jodine are liberated when 1 mole of K,Cr,O, reacts with KI in acidic medium? (@) 1 (b) 2 © 3 (d) 4 RSPL/3 2dy "Tho ntandavd 1" for hall coll renetions are An 4 Bo Yn We OV Ho" 4 20 Ko MW OAAV The standard om of coll hnvelving the ranean Wa! 4 Yn ——» Yavet 4 Wer i () -096V hy) nhaTy () H1Q0V () 082V 5. In tho ronetion 2NO 4 Oly» 2NOGI, han hoon found that doubling the concentration of both the renetanta ineramon the rate by n factor of & but doubling the concontration of Cl, alono, only doubles the rate, Whieh of the following: wtatoment is correct? (a) Tho renetion in nocond ordor wart, Cly (b) The reaction in frat ordor wart, NO (©) ‘The ovorall order of renetion in 2 (@)_ The overall order of reaction in 6. ‘The reaction X—y Product follows firvt order kinoticn in 40 minutes, the concen} n of *X’ changes from 0.1. M to 0,026 M then rate of reaction when concentration of *X’ is 0.01 M iv [log 4 = 0.6021) (a) 1,73 x 104 MAnin (hb) 8.47 % 10" Minin (©) 8.47 x 10 M/min (@) 1,78 « 10°" Ménin 7, An organic compound (CyHyN) whon treated with nitrous acid gives an alcohol and N, gas was evolved. [A] on warming with CHCl, and caustic potash gave [B] which on reduction gave isopropyl methyl amine, ‘A’ is (a) CHy—CH—NH, (b) CH,CH,NHCH, SH, (©) CHy—N—CH, (a) CH,CH,CH,NH, ‘Hy RSPL/3. a8, Amongst Ni(CO),, [Ni(CN),)* and (NiC1,}” (a) Ni(CO), and [NiCL J are diamagnetic and [Ni(CN),]” is paramagnetic, (b) [NCI and [Ni(CN),|* are diamagnetic and [Ni(CO),] is paramagnetic. (©) Ni(CO), and [Ni(CN),} are diamagnetic and {NiCl,]?" is paramagnetic. (@) Ni(CO), and [Ni(CN),}? are tetrahedral (sp®) and [NiC1,}”" is square planar. CHy HBr cys: 9. The product of the reaction Oa FE, Wis CH, @ ‘OH ©) Chr Br OH CH, @ Ch 10. The compound which on reaction with aqueous nitrous acid at low temperature produces an oily nitrosamine is (a) CH.NH, () CH,CH,NH, (©) (CH,).NH (@) (C,H),N 11. Acetone is treated with excess of ethanol in presence of HCI. The product obtained is 0 i (a) CH,—CH,—CH,—C—CH, 9 I (>) CH,CH,CH,—C—CH,—CH,—CH, RSPL/3ou © CH,—9—00,H, CH, C,H, @ CHy—G—on, C,H, 12. Slope of straight line obtained by plotting Ink Vs z is -5000, the activation energy for forward reaction is [R = 8.314 JK“ mol] (a) 415.7 kJ/mol (b) 41.57 kJ/mol (c) 4157 J/mol (d) 420 kJ/mol 13. Cyclohexene on ozonolysis followed by reaction with Zn dust and water gives a compound ‘E’. Compound ‘£’ on further treatment with aq. KOH and heating yields ‘F’. Compound F° is CHO CHO @ CY wo CF COOH COOH ag (d) ) Crom 14. Which of the following about [Cr(NH,),]Cl, is wrong? (a) It has d°sp* hybridisation, octahedral in shape (b) The complex is paramagnetic (©) It is outer orbital complex (d)_ It gives 3 moles of AgCl with AgNO,(aq) 7.0. RSPL/3 5 PEIn the following questions (Q. No. 15 = 18), 0 statement of assertion followed by statement of n reason is given, Choose the correct answer out of the following choi (a) Both A and R are true and R is the correct explanation of A. () Both A and R are true but R is not the correct explanation of A. (©) Ais true but R is false. (@) A is false but R is true. 15. Assertion: Diethyl ether has dipole moment. Reason: It is bent molecule, dipoles do not get cancelled. 16. Assertion: Fibrous proteins have -pleated secondary structure. Reason: Fibrous proteins are insoluble in water. 17. Assertion: Magnetic moment of Mn” (25) is 5.92 BM. Reason: Mn” has 7 unpaired electrons, 18. Assertion: Aniline and ethyl amine can be distinguished by carbylamine test. Reason: Benzene diazonium chloride forms azo dye with aniline at 0-5° SECTION - B energy of activation, (Given: log 2 log 6 = 0.7782, 010, log 3 = 0.4771, log 4 = 0.6021, 20. Give reasons:21. Give the plausible explanation for the following: 22. 24, 25. RSPL/3 (a) Glucose does not give 2,4-DNP test, (b) Starch and cellulose both contain glucose units as monomer yet they are structurally different. OR (a) What is difference between D or L and d(+) and U(-)? (b) The two strands of DNA are not identical but are complementary, why? Give the formulae of the following complex compounds: (a) Potassium tetra hydroxido zincate(II) (b) Hexaammine platinum(IV) chloride . Define rate constant and give the mathematical relationship between typ and rate constant of first order reaction. What happens when: (a) Acetophenone is treated with methyl magnesium bromide and product is hydrolysed. (b) Benzene reacts with CH,COCI in presence of AICly. Write the chemical reaction involved. Convert: (a) But-1-ene to 1-Iodo butane. (b) Chloroethane to 1-Propanamine. OR (a) Alkyl halides, although polar but insoluble in water, why? (b) Why is Grignard reagent prepared in anhydrous conditions?SECTION - C ‘This section contains 5 questions with internal choice in two questions. ‘The following questions are short answer type and carry 3 marks each. 26. 27, 28. The freezing point of a solution containing benzoic acid (M = 122 g/mol) in 35 g of benzene is depressed by 2.94 K. What is percentage association of benzoic acid if it forms dimer in solution? (K; for benzene = 4.9 K kg mol”) (a) What happens when hydroboration of propene followed by H,0, in alkaline medium is carried out? Write chemical reaction involved. (b) How will you convert the following: (® Phenol to o-hydroxy benzaldehyde (ii) Methanal to Ethanol What happens when: (a) Bromobenzene is treated with Mg in presence of dry ether. (©) Chlorobenzene is treated with CHCl in presence of anhydrous AlCly. (c) Methyl chloride is treated with AgCN. Write the chemical reactions involved. oR Complete the following: (a) 20H,—CH—CH,—CH, + 2Na—P2-, cl ©) CH,—CH—CH, + KOH(ale) —, «ay _HBr I Peroside B © Hc SOX, «yy HOM", RSPL/329. Account for the following: (any 3) (a) Ethyl amine is soluble in water whoro as aniline is not. () Aniline, on nitration gives 47% m-nitro anilino, (©) pK, of aniline is more than that of benzyl amino. (@) Tertiary amines do not react with Hinsberg reagent, 30. Give reasons: (a) [Co(NH,),CIICI, is purple in colour, [Atomic number of Co = 27] (b) [PtCl,]** square planar. [Atomic number of Pt = 78] © (Ni(NH,).]”* forms paramagnetic, outer orbital complex. [Atomic number of Ni = 28] SECTION - D The following questions are case-based questions. Each question has an internal choice and carries 4 (14142) marks each. Read the passage carefully and answer the questions that follow. 31. DNA — A Double Helix E. Chargaff found that base composition in DNA varied from one species to other species but in all cases the amount of Adenine was equal to thymine (A="T) bonded with two H-bonds, where as amounts of cytosine and guanine were found to be equal, bonded with three hydrogen bonds. The total amount of purines (A + G = G +) is equal to total amount of pyrimidines, AT/GC ratio varies considerably between species e.g. this ratio is 1.52 in man while in E. Coli it is 0.98. X-ray diffraction of DNA, Watson and Crick proposed a double helical structure of DNA. DNA duplicate in living cell (replication). The polynucleotides chains are linked with phosphodiester linkages. GC pairs give more stability to DNA as compared to AT pairs in DNA. P.1O. RSPL/3Answer the following questions: (a) Which component of DNA makes it chiral? (b) What are monomers of nucleic acids? (©) The two samples of DNA, ‘A’ and ‘B’ have melting temperatures 340 K and 350 K respectively, Can you draw any conclusion from this data regarding their base content? OR In E, Coli DNA the AT/GC ratio is 0.93. If number of moles of adenine in its DNA sample are 465,000. Calculate the number of moles of guanine present. 82. The following table gives Molal Boiling point elevation and Freezing point Depression Constants for some solvents. Solvent bp/K | K/Kkg mol} fp/K | K,/K kg mol Water 373.15 052 273.0 1.86 Ethanol 351.5 1.20 155.7 1.99 Cyclohexane 353.74 2.79 279.55 20.00 Benzene 353.3 2.53 278.6 5.12 Chloroform 334.4 3.63, 209.6 4.79 Carbon tetrachloride | 350.0 5.03 250.5 318 Carbon disulphide 319.4 2.34 164.2 3.83 Diethyl ether 307.8 2.02 156.9 1.79 Acetic acid 391.1 2.98 290.0 3.90 Observe the table carefully and answer the questions that follow: (a) Which solvent has highest K, and why? (b) Which solvent has lowest K, and why? (© G Why does cyclohexane have high K}? (ii) Cyelohexane is used in which type of solute and why? RSPL/3 10OR (Why is K; of water higher than K,, of water? (ii) Why does CCI, have highest K? SECTION - E The following questions are long answer type and carry 6 marks each. Two questions have an internal choice. 33. (a) Write the products formed when benzaldehyde reacts with the following reagents, (2) CH,CHO in presence of NaOH followed by heating. Gi) see{) (i) cone. (b) Distinguish between the following by suitable chemical test ( CH,—CH=CH—COCH, and CH,CH,CO—CH=CH, (ii) Benzaldehyde and Benzoic acid OR (a) A compound %X’ with molecular formula C,H,,0 reduces Tollen’s reagent and undergoes Cannizzaro’s reaction. On vigorous oxidation it gives Benzene 1,2-dicarboxylic acid. Identify X and write the chemical reactions involved. Arrange the following in increasing order of their reactivity towards nucleophilic addition reaction: CH,COCH,, HCHO, CH,CHO, (coon, (c) Draw the structure of 2,4-DNP derivative of acetaldehyde. (b) Is i P.O.34. (n) Why in alternating current used inatead of direct current in measuring resistance of electrolytic solution in conductivity oN (b) What are products of electrolynin of CuCl fa) in presence of platinura electrodes? Nx containing, (c) A current of 1.5 A was pasued through electrolytic AgNO, and CuSO, solution with inert electrodes, The ve ig) deposited was 1.5 %. How long, did the current low and what Will ve weight of copper deposited? [Atomic mans of Ag = 108, Ci 5,1 ¥ = 96500 CJ or (a) Caleulate emf of folloving cell at 298 Ks Alls) [AI* (0,1 M) || Cu*(0.01 M) | Cuts) (Given: Ej, = 2.00 V Jog 10 = 1)) (b) Why does mercury cell give constant voltage over longer period of time? (©) Which electrolyte is used in lead storage batter/? 25. (a) Give reasons for the Solloving: () Transition metals form alloys. Gi) Cr han higher melting point than zinc. (ii) Min shown +4 oxidation sate in Mn¥, but +7 in Mn,0,. (b) Why in Cu (aq) is more stable than Cut (ag/? (oc) Why docs ‘Ce show +4 oxidation state? REPLIZ 12