TRIAL SET 5 / DK014 /
Section A A. 8.0 102 C. 1.3 10-1
[20 marks] moles moles
B. 8.0 101 D. 1.3 10-2
1. Which of these represent an element?
A. O3 moles moles
B. H2O
C. CO2 8. Select the compound in which
D. HNO3 sulphur has the highest oxidation
number
2. Which one of the following A. SO2 C. SCl2
substances as a homogeneous B. H2SO3 D. Na2SO4
mixture ?
A. Concrete 9. The oxidation number of vanadium
B. Water atom in (NH4)3VO4 is
C. Air A. +3 C. +5
D. Oxygen gas B. +4 D. +7
3. Choose the FALSE statement
describing the physical change. 10. Antimony can react with chlorine gas
A. Sugar dissolves in water. to give antimony trichloride.
B. Gasoline evaporating.
C. Digesting food. __Sb(s) + __ Cl2(g) → __SbCl3(l)
D. Drying clothes.
Which of the following is the most
4. How many neutrons are there in the correct set of stoichiometric
coefficients to balance this equation?
chloride ion, 3717 Cl- ?
A. 20 A. 1, 1, 1 C. 1,3, 2
B. 17 B. 4, 6, 4 D. 2,3, 2
C. 18
D. 37
11. Which of the following equations
5. The following species 24 12 Mg2+ , 27 does not represent a redox equation?
3+ 20
13 Al , 10 Ne,
19 -
9 F , all have the A. 2H2O → 2H2 + O2
same number of B. 2NaI + Br2 → 2NaBr + I2
A. Protons C. Cu(NO3)2 + Zn → Zn(NO3)2
B. Electrons + Cu
C. Neutrons D. 2NaCl + Pb(NO3)2 → PbCl2
+ 3NaNO3
D. Nucleons
12 State the orbitals for the quantum
6. Avogadro’s number of representative
numbers . n=3, l=0
particles is equal to one ____.
A kilogram C. kelvin
A. 3p B. 3s C. 3f D. 3d
B. gram D. mole
13 Which of the following orbitals are
7. How many moles of tungsten atoms
allowed?
are in 4.8 10 atoms of tungsten?
A. 2d B. 7s C. 3f D. 1p
TRIAL SET 5 / DK014 /
14 Sodium and silicon are example of two 18. Which is the correct statement for a
elements which belong to the same chemical equilibrium?
A. Group A. The rate of the forward reaction is
B. Period the same as that of the reverse
C. Block reaction.
D. Compound B. The total concentration of product
equals that of reactant
15 The electronic configurations of C. The rate constant of forward
element P and element Q are as reaction equals that of the reverse
follows: reaction.
P: 1s2 2s2 2p6 3s2 D. The product of equilibrium
concentration of products and
Q: 1s2 2s2 2p5 reactants equals to the Kc value.
When P and Q combine to form a
compound, determine the most 19 A mixture of gases is allowed to
possible formula of this compound and reach equilibrium at 7000C in a 12.0
the type of bonding between them. L flask. At equilibrium, the mixture
contains 0.208 M SO2 , 1.12×10-6 M
Formula Types of bonding O2 and 0.725 M SO3.
A. PQ2 covalent
B. P2Q covalent 2SO2 (g) + O2 (g) 2SO3 (g)
C. PQ2 electrovalent
D P2Q3 electrovalent What is the equilibrium constant, Kc?
16 Magnesium chloride formed when: A. 9.22 x 10-8 B. 3.11 x 106
C. 1.08 x 107 D. 4.56 x 108
A. Magnesium atom share two
electrons with oxygen atom
20 The rate of formation of water from
B. Each chorine atom donate one the reaction:
electron
C. Electrostatic force hold ion 2MnO4−(aq) + 6H+(aq) + 5H2O2(aq)
magnesium and ion chloride → 2Mn2+(aq) + 8H2O(l) + 5O2(g)
D. Magnesium has incomplete octet is 0.035 M s-1. What is the rate of
H2O2 being reacted?
17. Lewis structure of SOCl2 is given as A. 8.75×10−4 M s−1
follows B. 2.19×10−3 M s−1
C. 8.75×10−3 M s−1
D. 2.19×10−2 M s−1
O
Cl S Cl
The formal charges on sulphur,
chlorine and oxygen are
S Cl O
A. 0 0 0
B. -1 +2 -1
C. +2 -1 -1
D. +2 -2 0
TRIAL SET 5 / DK014 /
Section B
C1 Matter = 5 marks
C3 Mole Concept = 10 marks
C4 Chemical Equation and Stoichimetry = 14 marks
C5 Electronic Configuration = 10 marks
C8 Chemical Equilibrium = 10 marks
C9 Reaction Kinetic = 11 marks
Section B
[60 marks]
1. (a) Classify each of the following as an element, compound or mixture.
i. Water
ii. Chocolate Chip Cookie
(2 marks)
(b) Label each process as a physical or chemical change:
i. A piece of metal is bent in half.
ii. Methanol is burned and leaves a residue
iii. An aspirin is crushed into fine powder
(3 marks)
2. (a) Calculate:
i. the number of Al atoms in 0.25 mol of Al2(SO4)3
ii. the mole of 0.020 cm3 O2 gas at STP. (4 marks)
(b) A 25.00 g sample of an orange compound contains 6.64 g of potassium, 8.84 g of
Chromium, and 9.52 g of oxygen. Find the empirical formula.
(4 marks)
(c) How many grams of potassium nitrate, KNO3 are needed to prepare 250.0 mL
of a 3.00× 10-2 M KNO3 solution.
(4 marks)
3. (a) Hydrofluoric acid (HF) can be prepared according to the following
equation:
CaF2 + H2SO4 🡪 HF + CaSO4.
i. Balance the above equation
ii. Determine the limiting and excess reactant when 75.0 g of H2SO4 and 63.0
g of CaF2 were reacted
iii. How many grams of HF can be produced?
iv. If the actual yield of HF is 26.2 g, what is the percent yield?
TRIAL SET 5 / DK014 /
(10 marks)
(b) Lithium nitride, Li3N reacts with water to produce ammonia, NH3 and lithium
hydroxide according to below equation.
Li3N + H2O 🡪 NH3 + LiOH
i. Balance this equation
ii. Determine the mass of ammonia and lithium hydroxide produced when
30 moles of lithium nitride completely react with excess water.
(5 marks)
(c) Balance the equations below:
Cl2(g) + S2O32-(aq) → Cl-(aq) + SO42-(aq) in acid solution (3 marks)
4. (a) Answer the questions below:
i. State Pauli exclusion principle (1 mark)
ii. Sketch 2px and 3px orbitals (2 marks)
iii. Give a set of quantum numbers for an electron in 3p orbital. (1 mark)
iv. States the quantum numbers n, l and m of the 3dxy orbital (3 marks)
(b) Arrange the following orbital in the order of increasing energy:
6p , 4s , 4f , 5s, 4dxy, 3dyz, 3py, 4pz, 2s, 3dxy, 3pz, 2px (1 mark)
(c) The following quantum numbers represent three valence electrons
for an atom.
(n=3, l=0, m=0, s= +1/2)
(n=3, l=0, m=0, s= - 1/2)
(n=3, l=1, m=0, s= +1/2)
Write the electronic configuration and orbital diagram for the atom (2 marks)
(d) Write the electronic configuration of Ti (Z=22) and Ti2+ (2 marks)
5. (a) According to the following unbalanced reaction, if the rate of appearance of
oxygen gas is 4.00 x 10-2 M s-1, what is the rate of disappearance of
KClO3 (g)?
KClO3 (g) 🡪 KCl (g) + O2(g)
(2 marks)
(b) When two compounds A and B, are mixed together, they form compound C, by a
reaction that’s not well understood. Fortunately, the following rate information
was experimentally determined, as shown below:
Experiment [A] (mol L-1) [B] (mol L-1) Rate (mol L-1 s-1)
1 0.05 0.05 4.0 x 10 -3
TRIAL SET 5 / DK014 /
2 0.10 0.05 8.0 x 10-3
3 0.05 0.10 1.6 x 10-2
i. Determine the rate law for this reaction.
ii. What is the overall order of the reaction?
(4 marks)
