Sarkar 2006
Sarkar 2006
DOI: 10.1007/s10661-005-9023-6
c Springer 2006
Abstract. Water quality indice are necessary for resolving lengthy, multi-parameter, water analysis
reports into single digit scores. This, in turn, is essential for comparing the water quality of different
sources and in monitoring the changes in the water quality of a given source as a function of time and
other influencing factors.
In this paper we present the computer-automated tool QUALIDEX (water QUALIty inDEX), which
has been developed by us to generate and operate water quality indice. Several popular indice – such
as the Oregon Water Quality Index developed in the 1970s by Oregon Department of Environmental
Quality and later updated in 1995, the Aquatic Toxicity Index developed by Wepener and coworkers
for protection of aquatic life at the Olifants river, Kruger National Park, South Africa, the water quality
index developed by Dinius in 1987, the Overall Index of Pollution (of surface waters) developed at
the National Environmental Engineering Research Institute (NEERI), and the water quality index of
the Central Pollution Control Board (CPCB) – have also been added to QUALIDEX in modular form.
There is also a New water quality index sub-module which enables the user to generate his or her
own index and compare its performance with these well-known indice. The package is also capable
of analyzing the variations in the water quality of different sites at different times. The software has
been coded in Visual C++ and has been integrated with MS Access database.
Keywords: water quality indice, drinking water, software, monitoring, virtual instrument
1. Introduction
Of all the natural resources, water is unarguably the most essential and precious. The
crucial role of water as the trigger and sustainer of civilizations has been witnessed
throughout the human history. But, up till as late as 1960s, the overriding interest in
the water has been vis a vis its quantity. Except in manifestly undesirable situations,
the available water was automatically deemed utilizable water. Only during the
last three decades of the twentieth century the concern for water quality has been
exceedingly felt so that, by now, water quality has acquired as much importance as
water quantity.
But expressing water quality, especially to a lay person, is enormously more dif-
ficult than expressing water quantity. The later can be expressed in precise terms as
volume contained in a lotic water body, for example in m3 or Km3 ; or flow in a lentic
202 C. SARKAR AND S. A. ABBASI
one, for example cusec (m3 sec−1 ). But water quality is a multi-parameter attribute;
a large number of physical, chemical and biological factors together determine the
water quality. Further, unlike the water quantity, water quality is a function of the
nature of water utilization. To wit, assessing and communicating water quality is
fraught with the following complications:
1. The water quality varies according to the type of use. A certain water quality
may be good enough for the purpose of irrigation but it mayn’t be good enough
for drinking. Furthermore, the criterion of an ‘acceptable water quality’ varies
from region to region and from time to time depending upon the prevailing
conditions.
2. Different agencies have developed different standards for various uses of water
which differ in terminologies for classification scheme, selection of indicator
parameters, classification scheme etc.
3. A given water sample may contain hundreds of constituents – element in neutral
or ionic form, anions, organics, suspended solids pathogens, radioactivity, color,
odor etc. The quality of water is defined in terms of these physical, chemical,
biological and bacteriological parameters each of which are expressed in dif-
ferent units of measurements. The extent of importance level of each of these
parameters in influencing the overall water quality for a given type of water use
is unknown and needs to be determined.
Rather than assigning numerical values to represent the water quality, these
classification systems categorized water bodies into one of several pollution classes
or levels. By contrast, indice that use a numerical scale to represent gradation in
water quality levels are a recent phenomenon, beginning with Horton’s index in
1965.
Horton (1965) set for himself the following criteria when developing the first
ever modern WQI:
(1) The number of variables to be handled by the index should be limited to avoid
making the index unwieldy.
(2) The variables should be of significance in most areas.
(3) Only such variables, of which reliable data is available, or obtainable, should
be included.
Horton selected 10 most commonly measured water quality variables for his
index including dissolved oxygen (DO), pH, specific conductance, alkalinity, and
chloride. Specific conductance was intended to serve as an approximate measure
of total dissolved solids (TDS), and carbon chloroform extract (CCE) was included
to reflect the influence of organic matter. One of the variables, sewage treatment
(percentage of population served), was designed to reflect the effectiveness of abate-
ment activities on the premise that chemical and biological measures of quality are
of little significance until progress has been made in eliminating discharges of
raw sewage. The index weight ranged from 1 to 4. Notably Horton’s index didn’t
include any toxic chemicals. The index score is obtained with a linear sum aggre-
gation function. The function consists of weighted sum of sub-indice divided by
the sum of weights and multiplied by two coefficients M1 and M2 , which reflect
the temperature and obvious pollution, respectively:
n
wi Ii
WQI = i=1 M1 M2 (1)
i=1 wi
Horton’s index is easy to compute, even though the coefficients M1 and M2 require
some tailoring to fit the individual situations. The index structure, its weights, and
rating scale are highly subjective as they are based on the judgment of the author
and a few of his associates.
Horton’s pioneering effort has been followed up by those of several workers
who have striven to develop less and less subjective but more and more sensitive
and useful water quality indice.
204 C. SARKAR AND S. A. ABBASI
There are four main steps involved in the development of a water quality index
(Otto, 1978; Abbasi, 2002). However, depending upon the sophistication being
aimed at, additional steps may be taken.
sub-index score for one variable may severely limit the water use, but it may
be eclipsed or hidden by high sub-index scores for other variables. In order
to avoid this tendency of eclipsing valuable information, Smith advocated the
use of minimum operator approach that uses the lowest sub-index value as the
final index score. But then this approach has its own shortcomings: it fails to
provide a composite picture of water quality. Swamee and Tyagi (2000) have
conceived a mathematical formulation for developing an aggregate index which
has been demonstrated to be free from the problems of ambiguity and eclipsing.
On account of the different behavior of the water quality parameters, they have
divided the sub-indice in to three categories – uniformly decreasing, wherein
the sub-indice monotonically decrease with the increase in the level of the water
quality variable, non-uniformly decreasing, in which the sub-indice change at a
rate different from the rate of change in the levels of the water quality variables,
and unimodal, where the sub-indice show maxima at an optimum value of the
water quality variable, but decrease as the water quality variable departs from
optimum. They have proposed a full range of sub-index function equations for a
number of parameters which has been calibrated with the help of the sub-index
curves of NSF-WQI.
In some of the water quality indice, the technique of devising sub-indice and
their aggregation have been replaced by employing suitable statistical techniques to
determine the parameters of importance and the extent of their importance. These
approaches reduce the subjective assumptions associated with the traditional indice.
The statistical approaches mainly focus on deriving the correlations expressing the
associations among water quality parameters to determine the importance of each
as a determinant of water quality. Factor analysis (Joung, et al., 1978), principal
component analysis (Shin and Lam, 2001; Parinet et al., 2004), Kendall’s non-
parametric classification (Harkin, 1974), uniformity indexing method (Ball and
Church, 1980), non-linear regression (Cude, 2001) are some of the commonly
employed statistical tools in the formulation of water quality index.
Another approach that has evolved in the 1990s involves the classification of wa-
ter quality based on the fuzzy theory. Kung et al. (1992) employed fuzzy clustering
analysis for the classification of water quality while the fuzzy synthetic evaluation
technique has been used by Lu et al. (1999) and Bin Chang (2003) to analyze and
compare the levels of reservoir eutrophication in Taiwan.
Some of the water quality indice that have been frequently employed in public
domain for the purpose of water quality assessment are the NSF Water Quality
Index (NSFWQI), British Columbia Water Quality Index (BCWQI), Canadian Wa-
ter Quality Index (CWQI), Oregon Water Quality index (OWQI), and the Florida
Stream Water Quality Index (FWQI) (Said et al., 2004).
QUALIDEX 207
Of these the NSFWQI has been the forerunner of many indice and its method-
ology continues to be adapted to this day. To generate important scores for the
NSFWQI, a survey was conducted among 142 water quality scientists and 35 pa-
rameters were considered for possible inclusion. In the final form, NSFWQI relied
on nine parameters (Brown et al., 1970; Mitchell and Stapp, 1996).
The British Columbia Ministry of Environment, Lands and Parks in Canada
have developed the British Columbia Water Quality Index (BCWQI). The index
has been developed at great effort, over a long time span (Zandbergen and Hall,
1998). However, BCWQI has been found to be extremely sensitive to sampling
design and has been applied to variety of uses – drinking, recreation, irrigation,
livestock watering, wild life and aquatic life. In 1997, the Water Quality Guide-
lines Task Group of the Canadian Council of Ministers of Environment (CCME)
decided to study the different existing approaches to index formulation and their
efforts led to the development of a standardized system – an unified water quality
index that has been employed throughout Canada for the purpose of water quality
assessment (CCME, 2001). The Canadian Water Quality Index (CWQI) was based
on the concept of British Columbia Water Quality Index (BCWQI). Instead of the
conventional Delphi approach, the CWQI employed three factors, each of which
has been scaled between 0 and 100 namely scope, frequency and amplitude. They
are the measures of variance from selected objectives of water quality which are
combined together to create a vector in an imaginary ‘objective exceedance’ space.
‘Objectives’ may refer to Canada-wide water quality guidelines or site specific wa-
ter quality objectives. The length of the vector is then scaled to range between 0
and 100, and subtracted from 100 to produce an index which is 0 or close to 0 for
very poor water quality, and close to 100 for excellent water quality (CCME, 2001;
Khan et al., 2003). The index was subsequently revised to overcome the problems
that arose due to the formulations for estimating the frequency and amplitude. The
revised index have been employed by Khan et al. (2003) to analyze the water qual-
ity trends in three selected watersheds of Atlantic region: Mersey River, the Point
Wolfe River, and the Dunk River sites.
The Oregon Water Quality Index, developed by the Oregon Department of En-
vironmental Quality (ODEQ) in the late 1970s and updated several times since then
is another frequently used WQI in public domain (Cude, 2001).
The Florida Stream Water Quality Index (FWQI), developed in 1995 under the
Strategic Assessment of Florida’s Environment program is an arithmetic average of
twelve water quality parameters namely, water clarity (turbidity and total suspended
solids), dissolved oxygen, oxygen demanding substances (biochemical oxygen de-
mand, chemical oxygen demand, total organic carbon), nutrients (phosphorus and
nitrogen), bacteria (total and fecal coliform), and biological diversity (natural or
artificial substrate micro-vertebrate diversity and Beck’s biotic index). Index values
ranging from 0 to less than 45 represents good quality, 45 to less than 60 represents
fair quality, and 60 to 90 represents poor quality (SAFE, 1995).
208 C. SARKAR AND S. A. ABBASI
QUALIDEX comprises of four modules, namely – the database module, the index
generation module, the water quality comparison module and the report generation
module. The basic architecture of QUALIDEX is depicted in Figure 1.
The water analysis data covering the parameters needed for each of the five indice
available in the QUALIDEX are stored in the database module. The module com-
prises of five MS Access files, one for each of the component indice. A typical
dataset as keyed into this module is depicted in Figure 2. For each of the index,
the corresponding parameter values of a specific site at a particular date and time
are stored in the respective MS Access spreadsheet. The MS Access files have
been connected to the software through the Open Database Connectivity (ODBC)
data source administrator of windows. A user friendly interface has been developed
within the software itself to enable the users to enter, save and edit raw water quality
data as shown in Figure 4.
The software enables the user to generate the following well-known water quality
indice for any water source of the water quality use:
In addition the software contains the New Water Quality Index Sub-module with
which new index may be generated on the basis of the parameters chosen by the
QUALIDEX
Figure 2. Typical data set keyed into the MS Access database module of the Overall Index of Pollution (OIP).
QUALIDEX 211
user, and the concerned weightage, applicability range, sub-index, and aggregation
function defined by the user.
where WQI is the water quality index result, n is the number of sub-indice and Si
is the sub-index i. The OWQI helps to evaluate the effectiveness of water quality
management activities. It may also be employed to develop environmental indi-
cators, such as percentage of river monitoring sites with significantly improving
water quality, or the percentage of sites with excellent water quality.
3.2.1.2. Aquatic Toxicity Index (ATI). It was developed by Wepener et al. (1992)
to assess the health of aquatic ecosystems. Since extensive toxicity database are
212 C. SARKAR AND S. A. ABBASI
available for fishes, the toxic effects of different water quality to fishes have been
employed as health indicators of the aquatic ecosystem. The physical water quality
parameters employed were pH, dissolved oxygen and turbidity while the chemi-
cal determinant included ammonium, total dissolved salts, fluoride, potassium and
orthophosphates and the potentially hazardous metals chosen were total zinc, man-
ganese, chromium, copper, lead and nickel concentrations. An ATI scale, similar
to the WQI scale proposed by Smith (1990) for salmonid spawning was used. The
Solway modified unweighted additive aggregation function (House and Ellis, 1980)
was initially employed to aggregate the values obtained from the rating curves
2
1 1 n
I = · qi (3)
100 n i=1
where I is the final index score, qi is the quality of the ith parameter (a value between
0–100) and n is the number of determinants in the indexing system. Wepener
et al. didn’t employ the weighted sum system, as too little information is available
about the importance of one determinant compared to another under different local
conditions and the inherent chemistry of the system as a whole. Moreover, it is
impossible to compare the factors which have a direct and interactive effect upon
one another. In order to avoid concealing the identity of the determinant which limits
the water’s suitability for use, the minimum operator function was also employed. A
computer software package (WATER), written in Pascal with “Turbo Pascal Version
6” was developed to compute both the additive and minimum operator final index
values. Wepener et al. (1999) assessed the spatial and temporal trends of water
quality of Olifants river and Selati river in Kruger national park during the course
of metal mining project over a two year period (February 1990–April 1992) based
on their index.
where IWQ is the Dinius water quality index whose value ranges from 0–100, Ii
is the sub-index function of the pollutant parameter, Wi is the unit weight of the
QUALIDEX 213
pollutant parameter whose value ranges from, 0–1 and n is the number of pollutant
parameters.
These numbers are termed as class index and they indicate the level of pollution
in numeric terms. The parameter concentration is then assigned to the respective
mathematical expression to obtain a numerical value called an index (Pi ) which
indicates the level of pollution for that parameter. The Overall Index of Pollution
(OIP) is then evaluated as a mean of all the individual pollution indice (Pi ) as
follows
Pi
OIP = i (5)
n
3.2.1.5. Water quality index of Central Pollution Control Board (CPCB), India.
It was developed by Ved Prakash et al. (1990) and is primarily based on the WQI
Figure 4. User-friendly interface for entering, editing and saving raw water quality data into the
database module.
QUALIDEX 215
where Ii = subindex for the ith water quality parameter; wi = weight associated
with the ith water quality parameter; P = number of water quality parameters
The developed index was employed to evaluate the water quality profile of river
Ganga in its entire stretch and to identify areas requiring urgent pollution control
measures.
The indice described above have been coded within this module. Table I lists the
complete details of each of these indice. To evaluate any particular water quality
Figure 5. Common interface to analyze the individual parameters of the Overall Index of Pollution
(OIP).
216
TABLE I
Sub-index functions and the weightages of the component indice of QUALIDEX
Parameter Weightage Range applicable (x) Sub-index function (y) Aggregation function Water quality classification
DO (mg/l) – 0 ≤ DO ≤ 5 y = 10x
5 < DO ≤ 6 y = 20x − 50
6 < DO ≤ 9 y = 10x + 10
DO > 9 y = 100
pH – – y = 98 exp[−(x − 8.16)2 · (0.4)]
+17 exp[−(x − 5.2)2 · (0.5)]
+15 exp[−(x − 11)2 · (0.72)]+2
Parameter Weightage Range applicable (x) Sub-index function (y) Aggregation function Water quality classification
(micro-mhos/cm)
pH 0.077 <6.9 100.6803+0.1856( p H )
6.9–7.1 1
>7.1 103.57−0.2216 (pH)
Nitrate (mg/l) 0.090 – 125(N)−0.2718
Temperature (◦ C) 0.077 – 102.004−−0.0−−382(T a−T s)
Color (Color units – Pt std) 0.063 – 127(C)−0.2394
(Continued on next page)
219
TABLE I 220
(Continued)
Parameter Weightage Range applicable (y) Sub-index Function (Pi ) Aggregation function Water quality classification
Turbidity – ≤5 Pi =1
5–10 Pi = (y/5)
10–500 Pi = (y + 43.9)/34.5
pH – 7 Pi =1
7 Pi =1
>7 Pi = exp((y − 7)/1.082
<7 Pi = exp((7 − y)/1.082
Color – 10–150 Pi = (y + 130)/140
150–1200 Pi = y/75
% DO – <50 Pi = exp(−(y − 98.33)/36.067)
50–100 Pi = (707.58 − y)/14.667
≥100 Pi = (y − 79.543)/19.054
<2 Pi =1
C. SARKAR AND S. A. ABBASI
Parameter Weightage Range applicable (y) Sub-index Function (Pi ) Aggregation function Water quality classification
Cl – ≤150 Pi =1
150–250 Pi = exp((y/50) − 3)/1.4427)
>250 Pi = exp((y/50) + 10.167)/10.82
NO3 – ≤20 Pi =1
20–50 Pi = exp((145 − y)/76.28)
50–200 Pi = y/65
SO4 – ≤150 Pi =1
150–2000 Pi = ((y/50 + 0.375)/2.5121
QUALIDEX
TABLE I
(Continued)
Parameter Weightage Range applicable (x) Sub-index Function (Ii ) Aggregation function Water quality classification
index, the user needs to first specify the site as well as the date and time at which he
wants to analyze the water quality and subsequently extract the respective values of
the component water quality parameters for the site. Individual dialog boxes have
been created for the detailed assessment of the status of each of the water quality
parameters included in an index. This can be accessed through a common interac-
tive interface from where the user has to navigate through the parameter-specific
dialog boxes in a sequential manner. For each water quality parameter included
in an index, the user has to first extract the raw parameter value of the site from
the database. The software subsequently evaluates the sub-index value of the pa-
rameter. Option has been developed to view the sub-index curve for the parameter
which indicates the variation of the pollution levels with the parameter value. In
case of the Overall Index of Pollution (OIP), there is the option for the classifica-
tion of the water quality with respect to each of the individual parameters. Finally,
the individual sub-index values are aggregated to produce the overall water quality
index score. The comparisons of the state of individual water quality parameters
are automated graphically and the overall status of the water quality at a partic-
ular site and time is indicated by the index score in the water quality meter and
the water quality is classified in accordance with the classification scheme of the
index.
Figure 6. Sample dialog-box for the evaluation of sub-index function of a component parameter of
the Overall Index of Pollution (OIP).
224 C. SARKAR AND S. A. ABBASI
3.2.1.6. The New Water Quality Index (NWQI) Sub-module. This sub-module
enables the users to generate their own water quality index and compare the results
with the other well known indice presently included in QUALIDEX. It provides
flexibility to the users to choose the component water quality parameters which they
feel, have a significant influence upon a specific water quality, associate appropriate
sub-index functions with them and thereby assess the overall status of the water
quality on the basis of their perception of the water pollution problem in their local
areas. The minimum operator aggregation function has been employed so as to
identify the parameter with the lowest sub-index score that plays most significant
role in depleting the water quality. Consequently, after identifying the parameter
that contributes maximum to the pollution, appropriate counter measures may be
taken to manage the pollution. A sample screen shot of this module has been shown
in Figure 9, while a typical work flow for operating the New Water Quality Index
has been depicted in Figure 10.
Monitoring the variations in the quality of water of a region helps in gaining invalu-
able insights into the underlying causative factors. A comprehensive assessment
Figure 7. Sample dialog-box for the overall water quality assessment for the Overall Index of Pollution
(OIP).
QUALIDEX 225
1. assess the spatial variations in water quality (i.e. the variations at different sites)
2. assess the temporal variations in the water quality of a site (i.e. the variations at
different time intervals)
There is provision for the comparison of water quality with respect to each of the
five water quality indice included in the software. Through this module, the user has
the option to compare the water quality of up to seven samples. In order to assess the
spatial variations in the water quality of the samples collected from different sites,
the user has to choose the respective sites, date and time of collection of the samples
from the drop down menu. The software subsequently extracts the parameter values
of the sites from the database module and evaluates the overall index value for the
selected sites. Incase, the user wants to assess the temporal variations in the water
quality of a given site, he needs to select the particular site as well as the dates and
times for which he wants the comparisons. The software will extract the parameter
Figure 8. Sample dialog-box for the water quality comparison using Overall Index of Pollution (OIP).
226 C. SARKAR AND S. A. ABBASI
values and evaluates the overall index values for the site at different time intervals.
The final results are automated in the form of user friendly bar graphs and the water
quality index scores are indicated in the water quality meter.
The results of the calculations performed in the water quality index generation
module and the water quality comparison module may be viewed in the form of
compact summary tables through this module. For each run, the corresponding
summary tables are stored in html files within the software which can be accessed
from the report generation menu on the GUI of QUALIDEX. General format of the
report generated for the Water Quality Comparison Module has been depicted in
Table II. The comparison matrix consists of a number of cells. Each of the cells of the
matrix has been divided into two sectors which contain the water quality parameter
value of the site and the corresponding evaluated sub-index function value. At the
bottom of the matrix, the overall index score is evaluated by aggregating all the
sub-index function values of component parameters for a particular site. The water
quality classification is also depicted depending on the aggregate index value.
Figure 9. Sample dialog box which enables the user to select the sub-index function for a parameter
in the New water Quality Index.
QUALIDEX 227
TABLE II
General format of the report generated for the water quality comparison module for the overall index
of pollution (OIP)
Sample screen shots of QUALIDEX have been shown in Figures 3–8 for the
Overall Index of Pollution (OIP). Figure 3 shows the main menu forming the
graphic user interface of QUALIDEX from where the corresponding modules of
QUALIDEX may be accessed. Figure 4 shows the interface developed for entering
228 C. SARKAR AND S. A. ABBASI
Figure 10. Sequence of steps for the generation of the new water quality index sub-module.
QUALIDEX 229
raw water quality data, editing data, as well as saving them into the database module.
Figure 5 represents the standard interface developed for analyzing the component
water quality parameters of an index (Overall Index of Pollution in this case). Fig-
ure 6 represents a sample dialog box of the Overall Index of Pollution developed
for analyzing an individual parameter by generating the sub-index function curve
and evaluating the sub-index function of the parameter. Figure 7 depicts the stan-
dard format of overall water quality assessment performed in the Water Quality
Index Generation Module. This includes evaluation of the WQI value, a graphical
comparison of the water quality status of the components parameters of the module
and classification of the water quality. The figure also shows the virtual instrument
‘water quality meter’ with which changes in the water quality occurring with, say,
inflow of a pollutant or sea water can be visually seen as well as recorded.
The sub-index values and the corresponding index scores have been compared
for the Overall Index of Pollution (OIP) with the help of water quality of seven dif-
ferent sites. The corresponding output generated by the Water Quality Comparison
module has been depicted in Figure 8. The figure also displays the readings on the
‘water quality meter’.
Acknowledgments
The authors thank the Ministry of Water Resources, Government of India, New
Delhi, for financial support vide Grant titled, R&D . . . Reuse.
230 C. SARKAR AND S. A. ABBASI
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