CHAPTER 2 Acid Base and Salt
CHAPTER 2 Acid Base and Salt
CLASSIFICATION OF ACIDS
1. Based on their sources : Acids are classified into two types namely organic acids and
inorganic acids.
Organic acids:- Acids present in plants and animals (living beings) are organic
acids eg. HCOOH, CH3COOH (Weak acids).
Inorganic acids:- Acids from rocks and minerals are inorganic acids or mineral acids eg.
HCl, HNO3, H2SO4 (Strong acids).
3. Based on ionisation
Acids are classified into two types based on ionisation.
Strong acids:- These are acids which ionise completely in water eg.HCl
Weak acids:-These are acids which ionise partially in water eg. CH3COOH
Question 1: You have been provided with three test tubes. One of them contains distilled
water and the other two contain an acidic solution and a basic solution, respectively. If
you are given only red litmus paper, how will you identify the contents of each test tube?
Answer : If the colour of red litmus paper gets changed to blue, then it is a base and if there is
no colour change, then it is either acidic or neutral. Thus, basic solution can be easily
identified.
Let us mark the three test tubes as A, B, and C. A drop of the solution in A is put on the red
litmus paper. Same is repeated with solution B and C. If either of them changes colour to blue,
then it is basic. Therefore, out of three, one is eliminated. Out of the remaining two, any one
can be acidic or neutral. Now a drop of basic solution is mixed with a drop of each of the
remaining two solutions separately and then the nature of the drops of the mixtures is checked.
If the colour of red litmus turns blue, then the second solution is neutral and if there is no
change in colour, then the second solution is acidic. This is because acidic and basic solutions
neutralize each other. Hence, we can distinguish between the three types of solutions.
Example:
Hydrogen gas and zinc chloride are formed when hydrochloric acid reacts with zinc metal.
Zn + 2HCl → ZnCl2 + H2
Hydrogen gas and sodium chloride are formed when hydrochloric acid reacts with sodium
metal.
2Na + 2HCl → 2NaCl + H2
Hydrogen gas and iron chloride are formed when hydrochloric acid reacts with iron.
Fe + 2HCl → FeCl2 + H2
Hydrogen gas and zinc sulphate are formed when zinc metal reacts with sulphuric acid
Zn + H2SO4 → ZnSO4 + H2
Examples:
Sulphuric acid gives calcium sulphate, carbon dioxide gas, calcium sulphate and water
when it reacts with calcium carbonate.
CaCO3 + H2SO4 → CaSO4 + CO2 + H2O
Sulphuric acid gives sodium sulphate, carbon dioxide gas and water when it reacts with
sodium carbonate.
Na2CO3 + H2SO4 → Na2SO4 + CO2 + H2O
Hydrochloric acid gives carbon dioxide gas, calcium chloride and water when it reacts with
calcium carbonate.
CaCO3 + 2HCl → CaCl2 + CO2 + H2O
Hydrochloric acid gives carbon dioxide gas, sodium chloride along with water when reacts
with sodium carbonate.
Na2CO3 + 2HCl → 2NaCl + CO2 + H2O
Hydrochloric acid gives carbon dioxide, magnesium chloride and water when it reacts with
magnesium carbonate.
MgCO3 + 2HCl → MgCl2 + CO2 + H2O
Nitric acid gives sodium nitrate, water and carbon dioxide gas when it reacts with sodium
carbonate.
2HNO3 + Na2CO3 → NaNO3 + 2H2O + CO2
REACTION OF ACID WITH HYDROGEN CARBONATES (BICARBONATES):
Acids give carbon dioxide gas, respective salt and water when they react with metal hydrogen
carbonate.
Acid + Metal hydrogen carbonate → Salt + Carbon dioxide + Water
Examples:
Hydrochloric acid gives carbon dioxide, sodium chloride and water when it reacts with
sodium bicarbonate.
NaHCO3 + HCl → NaCl + CO2 + H2O
Sulphuric acid gives sodium sulphate, carbon dioxide gas and water when it reacts with
sodium bicarbonate.
2NaHCO3 + H2SO4 → Na2SO4 + 2CO2 + 2H2O
Sodium bicarbonate is also known as sodium hydrogen carbonate, baking soda, baking
powder, bread soda and bicarbonate of soda.
The gas evolved because of reaction of acid with metal carbonate or metal hydrogen
carbonate turns lime water milky. This shows that the gas is carbon dioxide gas. This
happens because of formation of white precipitate of calcium carbonate.
Ca(OH)2 + CO2 → CaCO3 + H2O
CaCO3 + CO2 + H2O → Ca(HCO3 )2
But when excess of carbon dioxide is passed through lime water, it makes milky colour of
lime water disappear. This happens because of formation of calcium hydrogen carbonate.
As calcium hydrogen carbonate is soluble in water, thus the milky colour of solution
mixture disappears.
USES OF ACIDS
Sulphuric acid (King of chemicals) is used in car battery and in the preparation of many
other compounds.
Nitric acid is used in the production of ammonium nitrate which is used as fertilizer in
agriculture.
Hydrochloric acid is used as cleansing agent in toilet.
Tartaric acid is a constituent of baking powder.
Salt of benzoic acid (sodium benzoate) is used in food preservation.
Carbonic acid is used in aerated drinks.
BASES
Base is a substance which releases hydroxide ions when dissolved in water. It is a substance
which is bitter in taste and soapy to touch (e.g. Washing soda, caustic soda and caustic potash).
They change red litmus to blue. They are pink with phenolphthalein and yellow with methyl
orange.
CLASSIFICATION OF BASES
1. Based on ionisation
Strong bases:- These are bases which ionise completely in aqueous solution
eg.NaOH, KOH.
Weak bases:- These are bases which ionise partially in aqueous solution eg. NH4OH,
Ca(OH)2.
Monoacidic base:- It is a base which ionises in water to give one hydroxide ion per
molecule eg.NaOH, KOH.
Diacidic base:- It is a base which ionises in water to give two hydroxide ions per
molecule eg. Ca(OH)2, Mg(OH)2.
Triacidic base:- It is a base which ionises in water to give three hydroxide ions per
molecule eg. Al(OH)3, Fe(OH)3.
Dilute alkali:- It is an alkali having a relatively low percentage of alkali in its aqueous
solution.
USES OF BASES
Sodium hydroxide is used in the manufacture of soap.
Calcium hydroxide is used in white washing the buildings.
Magnesium hydroxide is used as a medicine for stomach troubles.
Ammonium hydroxide is used to remove grease stains from clothes.
NEUTRALISATION REACTION:
An acid neutralizes a base when they react with each other and respective salt and water are
formed.
Acid + Base → Salt + Water
Since in the reaction between acid and base both neutralize each other, hence it is also known
as neutralization reaction.
Example:
Sodium sulphate and water are formed when sulphuric acid reacts with sodium hydroxide
(a base).
H2SO4 + 2NaOH → Na2SO4 + 2H2O
In similar way, when nitric acid reacts with sodium hydroxide, sodium nitrate and water are
formed.
HNO3 + NaOH → NaNO3 + H2O
Sodium chloride and water are formed when hydrochloric acid reacts with sodium
hydroxide (a strong base).
HCl + NaOH → NaCl + H2O
In similar way, calcium chloride is formed along with water when hydrochloric acid reacts
with calcium hydroxide (a base).
2HCl + Ca(OH)2 → CaCl2 + 2H2O
Example:
Calcium is a metal, thus calcium oxide is a metallic oxide which is basic in nature. When
an acid; such as hydrochloric acid; reacts with calcium oxide, neutralization reaction takes
place and calcium chloride; along with water; is formed.
2HCl + CaO → CaCl2 + H2O
Similarly, when sulphuric acid reacts with zinc oxide, zinc sulphate and water are formed.
H2SO4 + ZnO → ZnCl2 + H2O
When hydrochloric acid reacts with aluminium oxide, aluminium chloride and water are
formed.
Al2O3 + 6HCl → 2AlCl3 + 3H2O
Question 1: Why should curd and sour substances not be kept in brass and copper
vessels?
Answer : Curd and other sour substances contain acids. Therefore, when they are kept in brass
and copper vessels, the metal reacts with the acid to liberate hydrogen gas and harmful
products, thereby spoiling the food.
Question 2: Which gas is usually liberated when an acid reacts with a metal? Illustrate
with an example. How will you test for the presence of this gas?
Answer : Hydrogen gas is usually liberated when an acid reacts with a metal.
Take few pieces of zinc granules and add 5 ml of dilute H2SO4. Shake it and pass the gas
produced into a soap solution. The bubbles of the soap solution are formed. These soap bubbles
contain hydrogen gas.
We can test the evolved hydrogen gas by its burning with a pop sound when a candle is
brought near the soap bubbles.
Acids give hydrogen gas when they react with metal. This shows that all acids contain
hydrogen. For example: Hydrochloric acid (HCl), sulphuric acid (H 2SO4), nitric acid (HNO3),
etc.
When an acid is dissolved in water, it dissociates hydrogen. The dissociation of hydrogen ion
in aqueous solution is the common property in all acids. Because of dissociation of hydrogen
ion in aqueous solution, an acid shows acidic behavior.
Example:
Hydrochloric acid (HCl) gives hydrogen ion (H+) and chloride ion (Cl−) when it is
dissolved in water.
HCl (aq) → H+ + Cl−
Sulphuric acid (H2SO4) gives hydrogen ion (H+) and sulphate ion (SO4− −) in water.
H2SO4 (aq) → H+ + SO4− −
Nitric acid (HNO3) gives hydrogen ion (H+) and nitrate ion (NO3−) in water.
HNO3 (aq) → H+ + NO3−
Acetic acid (CH3COOH) gives acetate ion (CH3COO−) and hydrogen ion (H+).
CH3COOH (aq) → CH3COO− H+
Hydrogen ion which is produced by acid (when acid is combined with water molecule),
exists in the form of hydronium ion (H3O−) in aqueous solution. That’s why hydrogen ion
is always written with suffix (aq), such as H+ (aq).
HCl + H2O → H3O− + Cl−
H2SO4 + H2O → H3O− + SO4− −
Thus, because of dissociation of hydrogen ions; acid shows its acidic behavior.
Acids conduct electricity in their aqueous solution because of dissociation of hydrogen ion.
Hydrogen ion in aqueous solution conducts electricity.
A dry acid, such as dry hydrochloric acid does not change the colour of blue litmus paper to
red because a dry acid does not dissociate hydrogen ion. This is the cause that a moist litmus
paper is used to check the acidic or basic character of a gas.
NEUTRALISATION REACTION:
When an acid reacts with a base, the hydrogen ion of acid combines with the hydroxide ion of
base and forms water. As these ions combine together and form water; instead of remaining
free, thus both neutralize each other.
OH− + H+ → H2O
Example:
When sodium hydroxide (a base) reacts with hydrochloric acid, sodium hydroxide breaks
into sodium ion and hydroxide ion and hydrochloric acid breaks into hydrogen ion and
chloride ion. Hydrogen ion and hydroxide ion combine together and form water, while
sodium ion and chloride ion combine together and form sodium chloride.
NaOH + HCl → OH− + Na+ + H+ + Cl− → NaCl + H2O
The dilution of acid or base is exothermic. Thus, acid or base is always added to water and
water is never added to acid or base. If water is added to a concentrated acid or base a lot of
heat is generated, which may cause splashing out of acid or base and may cause severe damage
as concentrated acid and base are highly corrosive.
Question 1: Why do HCl, HNO3, etc., show acidic characters in aqueous solutions while
solutions of compounds like alcohol and glucose do not show acidic character?
Answer : The dissociation of HCl or HNO3 to form hydrogen ions always occurs in the
presence of water. Hydrogen ions (H+) combine with H2O to form hydronium ions (H3O+).
The reaction is as follows:
Although aqueous solutions of glucose and alcohol contain hydrogen, these cannot dissociate
in water to form hydrogen ions. Hence, they do not show acidic character.
Question 3: Why does dry HCl gas not change the colour of the dry litmus paper?
Answer : Colour of the litmus paper is changed by the hydrogen ions. Dry HCl gas does not
contain H+ ions. It is only in the aqueous solution that an acid dissociates to give ions. Since in
this case, neither HCl is in the aqueous form nor the litmus paper is wet, therefore, the colour
of the litmus paper does not change.
Question 4: While diluting an acid, why is it recommended that the acid should be added
to water and not water to the acid?
Answer : Since the process of dissolving an acid in water is exothermic, it is always
recommended that acid should be added to water. If it is done the other way, then it is possible
that because of the large amount of heat generated, the mixture splashes out and causes burns.
Question 5: How is the concentration of hydronium ions (H3O+) affected when a solution
of an acid is diluted?
Answer : When an acid is diluted, the concentration of hydronium ions (H3O+) per unit
volume decreases. This means that the strength of the acid decreases.
Question 6: How is the concentration of hydroxide ions (OH−) affected when excess base
is dissolved in a solution of sodium hydroxide?
Answer : The concentration of hydroxide ions (OH−) would increase when excess base is
dissolved in a solution of sodium hydroxide.
STRENGTH OF ACID AND BASE
Acids in which complete dissociation of hydrogen ion takes place are called strong acid.
Similarly, bases in which complete dissociation of hydroxide ion takes place are called strong
base.
In mineral acids, such as hydrochloric acid, sulphuric acid, nitric acid, etc. hydrogen ion
dissociates completely and hence they are considered as strong acid. Since, in organic acids
hydrogen ions do not dissociate completely, so they are weak acid.
Alkalis are water soluble base, thus in alkali; complete dissociation of hydroxide ions takes
place and they are considered as strong base.
The complete dissociation of hydrogen ions or hydroxide ions is shown by a single arrow. The
incomplete dissociation of hydrogen ions or hydroxide ions is denoted by double arrow.
pH stands for the power of hydrogen ion concentration in a solution. pH values decide whether
a solution is acidic or basic or neutral. pH scale was introduced by S.P.L. Sorenson. It is
mathematically expressed as
pH = -log10[H+]
For neutral solution [H+] = 10–7M; pH = 7
For acidic solution [H+] > 10–7M; pH < 7
For basic solution [H+] < 10–7M; pH > 7
When OH– ions are taken into account the pH expression is replaced by pOH
pOH = -log10[OH–]
The strength of acid or base depends upon the hydrogen ion concentration. If the concentration
of hydrogen ion is greater than hydroxide ion, the solution is called acidic. If the concentration
of hydrogen ion is smaller than the hydroxide ion, the solution is called basic. If the
concentration of hydrogen ion is equal to the concentration of hydroxide ion, the solution is
called neutral solution.
pH is a scale which quantifies the concentration of hydrogen ion in a solution. The range of pH
scale is between 0 to 14.
The pH value decreases with increase in hydrogen ion concentration. If the value of pH is 0,
this shows maximum hydrogen ion concentration. pH value equal to 14 shows lowest hydrogen
ion concentration. pH value equal to 7 shows the hydrogen ion concentration is equal to
hydroxide ion concentration.
A neutral solution, such as distilled water has value of hydrogen ion concentration equal to 7
on pH scale. The acidic solution has value of hydrogen ion concentration less than 7 on pH
scale. The basic solution has value of hydrogen ion concentration greater than 7 on pH scale.
In pH scale ‘p’ stands for ‘potenz’. Potenz is a German word which means ‘power’ or
‘potential’. Here; ‘H’ stands for hydrogen ion. Thus, pH means the potential of hydrogen or
power of hydrogen.
1. pH in human body
Using pH factor the healthiness of our body is predicted. At pH level 6.9, the body
becomes prone to viral infections like colds, cough and flu. Cancer cells thrive inside
the body at a pH of 5.5.
The pH of a normal, healthy human skin is 4.5 to 6. Proper skin pH is essential for a
healthy complexion.
pH of stomach fluid is approximately 2.0. This fluid is essential for the digestion of
food.
Human blood pH range is 7.35 to 7.45. Any increase or decrease in this value, leads to
diseases. The ideal pH for blood is 7.4.
pH of normal saliva ranges between 6.5 to 7.5.
White enamel coating in our teeth is calcium phosphate, hardest substance in our body.
It does not dissolve in water. If pH of mouth falls below 5.5, the enamel gets corroded.
Toothpastes are generally basic, and is used for cleaning the teeth, can neutralize the
excess acid and prevent tooth decay.
2. pH in soil
In agriculture, the pH of soil is very important. Citrus fruits require slightly alkaline
soil, while rice requires acidic soil and sugar cane requires neutral soil.
3. pH in rain water
pH of rain water is approximately 7 showing high level of its purity and neutrality. If
rain water is polluted by SO2 and NO2, acid rain occurs, bringing the pH value less than
7.
INDICATOR:
Substances which show the acidic or basic behavior of other substance by change in colour are
known as indicator.
Type of Indicator: There are many types of indicators. Some common types of indicators are
Natural
Olfactory Indicator
Synthetic Indicator
Universal Indicator
NATURAL INDICATOR
Indicators obtained from natural sources are called natural indicators. Litmus, turmeric, red
cabbage, China rose, etc. are some common natural indicators used widely to show the acidic
or basic character of substances.
LITMUS
Litmus is obtained from lichens. The solution of litmus is purple in colour. Litmus paper comes
in two colour – blue and red.
An acid turns blue litmus paper red.
A base turns red litmus paper blue.
TURMERIC
Turmeric is another natural indicator. Turmeric is yellow in colour. Turmeric solution or paper
turns reddish brown with base. Turmeric does not change colour with acid.
RED CABBAGE
The juice of red cabbage is originally purple in colour. Juice of red cabbage turns reddish with
acid and turns greenish with base.
OLFACTORY INDICATORS
Substances which change their smell when mixed with acid or base are known as olfactory
indicators. For example onion, vanilla, clove, etc.
ONION
Paste or juice of onion loses its smell when added with base. It does not change its smell with
acid.
VANILLA
The smell of vanilla vanishes with base, but it’s smell does not vanishes with an acid.
Olfactory indicators are used to ensure the participation of visually impaired students in
laboratory.
SYNTHETIC INDICATOR
Indicators that are synthesized in laboratory are known as synthetic indicators. For example;
phenolphthalein, methyl orange, etc.
Phenolphthalein is a colourless liquid. It remains colourless with acid but turns into pink with a
base.
Methyl orange is originally orange in colour. It turns into red with acid and turns into yellow
with base.
Indicator Original colour Acid Base
Red litmus Red No change Blue
Blue litmus Blue Red No change
Turmeric Yellow No change Reddish brown
Red cabbage juice Purple Reddish Greenish yellow
Phenolphthalein Colourless Colourless Pink
Methyl orange Orange Red Yellow
Onion n/a No change Smell vanishes
Vanilla n/a No change Smell vanishes
UNIVERSAL INDICATOR:
Using a litmus paper, phelophthalein, methyl orange, etc. only the acidic or basic character of a
solution can be determined, but use of these indicators does not give the idea about the strength
of acid or base. So, to get the strength as well as acidic and basic nature of a given solution
universal indicator is used.
Universal indicator shows different colour over the range of pH value from 1 to 14 for a given
solution. Universal indicator is available both in the form of strips and solution. Universal
indicator is the combination of many indicators, such as water, propanol, phelophthalein,
sodium salt, sodium hydroxide, methyl red, bromothymol blue monosodium salt, and thymol
blue monosodium salt. The colour matching chart is supplied with universal indicator which
shows the different colours for different values of pH.
Question 2: What effect does the concentration of H +(aq) ions have on the nature of the
solution?
Answer : Concentration of H+(aq) can have a varied effect on the nature of the solution. With an
increase in H+ ion concentration, the solution becomes more acidic, while a decrease of H+ ion
causes an increase in the basicity of the solution.
Question 3: Do basic solutions also have H+(aq) ions? If yes, then why are these basic?
Answer :Yes, basic solution also has H+(aq) ions. However, their concentration is less as
compared to the concentration of OH− ions that makes the solution basic.
Question 4: Under what soil condition do you think a farmer would treat the soil of his
fields with quick lime (calcium oxide) or slaked lime (calcium hydroxide) or chalk
(calcium carbonate)?
Answer : If the soil is acidic and improper for cultivation, then to increase the basicity of soil,
the farmer would treat the soil with quick lime or slaked lime or chalk.
SALT
Salts are the ionic compounds which are produced after the neutralization reaction between
acid and base. Salts are electrically neutral. There are number of salts but sodium chloride is
the most common among them. Sodium chloride is also known as table salt or common salt.
Sodium chloride is used to enhance the taste of food.
CHARACTERISTICS OF SALT:
Most of the salts are crystalline solid
Salts may be transparent or opaque
Most of the salts are soluble in water
Solution of salts conducts electricity. Salts conduct electricity in their molten state also
The salt may be salty, sour, sweet, bitter and umami (savoury)
Neutral salts are odourless
Salts can be colourless or coloured
Classification of salts
1. Normal salts
A normal salt is obtained by complete neutralization of an acid by a base
NaOH + HCl → NaCl + H2O
2. Acid salts
Acid salts are derived by the partial replacement of hydrogen ions of an acid by a metal.
When a calculated amount of a base is added to a polybasic acid, acid salt is obtained, as
follows.
NaOH + H2SO4 → NaHSO4 + H2O
3. Basic salts
Basic salts are formed by the partial replacement of hydroxide ions of a diacidic or triacidic
base by an acid radical. A basic salt may further reacts with an acid to give a normal salt.
Pb(OH)2 + HCl → Pb(OH)Cl + H2O
Diacidic base Basic salt
4. Double salts
Double salts are formed by the combination of saturated solution of two simple salts in
equimolar ratio followed by crystallization. e.g. potash alum
FAMILY OF SALT:
Salts having common acidic or basic radicals are said to belong to same family.
Example
Sodium chloride (NaCl) and Calcium chloride (CaCl2) belong to chloride family.
Calcium chloride (CaCl2) and calcium sulphate (CaSO4) belong to calcium family.
Zinc chloride (ZnCl2) and Zinc sulphate (ZnSO4) belong to zinc family.
Potassium chloride (KCl): It is formed after the reaction between potassium hydroxide (a
strong base) and hydrochloric acid (a strong acid).
KOH + HCl → KCl + H2O
ACIDIC SALT
Salts which are formed after the reaction between a strong acid and weak base are called acidic
salt. The pH value of acidic salt is lower than 7. Example: ammonium sulphate, ammonium
chloride, etc.
Ammonium chloride is formed after reaction between hydrochloric acid (a strong acid) and
ammonium hydroxide (a weak base).
NH4OH + HCl → NH4Cl + H2O
Ammonium sulphate is formed after reaction between ammonium hydroxide (weak base) and
sulphuric acid (a strong acid).
2NH4OH + H2SO4 → (NH4 )2SO4 + 2H2O
BASIC SALT
Salts which are formed after the reaction between weak acid and strong base are called basic
salt. For example; sodium carbonate, sodium acetate, etc.
Sodium carbonate is formed after the reaction between sodium hydroxide (a strong base) and
carbonic acid (a weak base).
H2CO3 + 2NaOH → Na2CO3 + 2H2O
Sodium acetate is formed after the reaction between a strong base, sodium hydroxide and a
weak acid, acetic acid.
CH3COOH + NaOH → CH3COONa + H2O
Baking soda is obtained by the reaction of brine with carbon dioxide and ammonia. This is
known as Solvay process.
NaCl + CO2 + NH3 + H2O → NH4Cl + NaHCO3
In this process, calcium carbonate is used as the source of CO2 and the resultant calcium oxide
is used to recover ammonia from ammonium chloride.
BAKING POWDER:
Baking powder produces carbon dioxide on heating, so it is used in cooking to make the batter
spongy. Although baking soda also produces carbon dioxide on heating, but it is not used in
cooking because on heating; baking soda produces sodium carbonate along with carbon
dioxide. The sodium carbonate; thus produced; makes the taste bitter.
2NaHCO3 + heat → Na2CO3 + CO2 + H2O
Baking powder is the mixture of baking soda and a mild edible acid. Generally, tartaric acid is
mixed with baking soda to make baking powder.
NaHCO3 + C4H6O6 → CO2 + H2O + Na2C4H4O6
When baking powder (mixture of baking soda and an edible acid) is heated, the sodium
carbonate formed because of heating of baking soda neutralizes after reacting with tartaric acid
and sodium tartarate salt is formed. The smell of sodium tartarate is pleasant and taste is good.
This makes the cake or any other food tasty.
Examples:
COPPER SULPHATE PENTAHYDRATE (CuSO4.5H2O)
Blue colour of copper sulphate is due to presence of 5 molecules of water. When copper
sulphate is heated, it loses water molecules and turns into grey-white colour, which is known as
anhydrous copper sulphate. After adding water; anhydrous copper sulphate becomes blue
again.
CuSO4.5H2O + heat → CuSO4
PLASTER OF PARIS
Plaster of Paris is obtained by heating of gypsum, a hydrated salt of calcium.
1 3
CaSO4.2H2O + Heat → CaSO4. H2O + H2O
2 2
After addition of water Plaster of Paris is again converted into gypsum.
1 3
CaSO4. H2O + H2O → CaSO4.2H2O
2 2
Plaster of Paris is used in making of toys, designer false ceiling, etc. Doctors use Plaster of
Paris to set the fractured bone.
Question 2: Name the substance which on treatment with chlorine yields bleaching
powder?
Answer : Calcium hydroxide [Ca (OH)2], on treatment with chlorine, yields bleaching
powder.
Question 3: Name the sodium compound which is used for softening hard water.
Answer : Washing soda (Na2CO3.10H2O) is used for softening hard water.
Question 4: What will happen if a solution of sodium hydrocarbonate is heated? Give the
equation of the reaction involved.
Answer : When a solution of sodium hydrocarbonate (sodium hydrogencarbonate) is heated,
sodium carbonate and water are formed with the evolution of carbon dioxide gas.
Question 5: Write an equation to show the reaction between Plaster of Paris and water.
Answer : The chemical equation for the reaction of Plaster of Paris and water can be
represented as
Question 4: Which one of the following types of medicines is used for treating
indigestion?
(a) Antibiotic (b) Analgesic (c) Antacid (d) Antiseptic
Answer : (c) Antacid is used for treating indigestion.
Question 5: Write word equations and then balanced equations for the reaction taking
place when −
(a) dilute sulphuric acid reacts with zinc granules.
(b) dilute hydrochloric acid reacts with magnesium ribbon.
(c) dilute sulphuric acid reacts with aluminium powder.
(d) dilute hydrochloric acid reacts with iron filings.
Answer : (a) Sulphuric acid + Zinc → Zinc sulphate + Hydrogen
Question 6: Compounds such as alcohols and glucose also contain hydrogen but are not
categorized as acids. Describe an activity to prove it.
Answer : Two nails are fitted on a cork and are kept it in a 100 mL beaker. The nails are then
connected to the two terminals of a 6-volt battery through a bulb and a switch. Some dilute
HCl is poured in the beaker and the current is switched on. The same experiment is then
performed with glucose solution and alcohol solution.
Observations:
Result:
HCl dissociates into H+ and Cl− ions. These ions conduct electricity in the solution resulting in
the glowing of the bulb. On the other hand, the glucose solution does not dissociate into ions.
Therefore, it does not conduct electricity.
Conclusion:
From this activity, it can be concluded that all acids contain hydrogen but not all compounds
containing hydrogen are acids.
That is why, though alcohols and glucose contain hydrogen, they are not categorised as acids.
Question 7: Why does distilled water not conduct electricity, whereas rain water does?
Answer : Distilled water is a pure form of water and is devoid of any ionic species. Therefore,
it does not conduct electricity. Rain water, being an impure form of water, contains many ionic
species such as acids and therefore it conducts electricity.
Question 8: Why do acids not show acidic behaviour in the absence of water?
Answer : Acids do not show acidic behaviour in the absence of water because the dissociation
of hydrogen ions from an acid occurs in the presence of water only. It is the hydrogen ions that
are responsible for the acidic behaviour.
Question 9: Five solutions A, B, C, D and E when tested with universal indicator showed
pH as 4, 1, 11, 7 and 9, respectively. Which solution is
(a) neutral?
(b) strongly alkaline?
(c) strongly acidic?
(d) weakly acidic?
(e) weakly alkaline?
Arrange the pH in increasing order of hydrogen-ion concentration.
Answer :
(a) Neutral → Solution D with pH 7
(b) Strongly alkaline → Solution C with pH 11
(c) Strongly acidic → Solution B with pH 1
(d) Weakly acidic → Solution A with pH 4
(e) Weakly alkaline → Solution E with pH 9
The pH can be arranged in the increasing order of the concentration of hydrogen ions as: 11 <
9<7<4<1
Question 10: Equal lengths of magnesium ribbons are taken in test tubes A and B.
Hydrochloric acid (HCl) is added to test tube A, while acetic acid (CH3COOH) is added
to test tube B. In which test tube will the fizzing occur more vigorously and why?
Answer : The fizzing will occur strongly in test tube A, in which hydrochloric acid (HCl) is
added. This is because HCl is a stronger acid than CH3COOH and therefore produces
hydrogen gas at a faster speed due to which fizzing occurs.
Question 11: Fresh milk has a pH of 6. How do you think the pH will change as it turns
into curd? Explain your answer.
Answer : The pH of milk is 6. As it changes to curd, the pH will reduce because curd is acidic
in nature. The acids present in it decrease the pH.
Question 12: A milkman adds a very small amount of baking soda to fresh milk.
(a) Why does he shift the pH of the fresh milk from 6 to slightly alkaline?
(b) Why does this milk take a long time to set as curd?
Answer : (a) The milkman shifts the pH of the fresh milk from 6 to slightly alkaline because in
alkaline condition, milk does not set as curd easily.
(b) Since this milk is slightly basic than usual milk, acids produced to set the curd are
neutralized by the base. Therefore, it takes a longer time for the curd to set.
(ii) During indigestion (caused due to the production of excess of hydrochloric acid in the
stomach), we administer an antacid (generally milk of magnesia, Mg(OH) 2 which is basic in
nature). The antacid neutralizes the excess of acids and thus gives relief from indigestion.
Question 15: Give two important uses of washing soda and baking soda.
Answer : Two important uses of washing soda and baking soda are as follows:
(1) Washing soda:
(a) It is used in glass, soap, and paper industries.
(b) It is used to remove permanent hardness of water.
(2) Baking soda:
(a) It is used as baking powder. Baking powder is a mixture of baking soda and a mild acid
known as tartaric acid. When it is heated or mixed in water, it releases CO2 that makes bread
or cake fluffy.
(b) It is used in soda-acid fire extinguishers.
ASSIGNMENT QUESTIONS SET – 1
CHAPTER – 2
ACIDS, BASES AND SALTS
1. What is baking soda? How is it obtained from sodium chjloride? Mention any two uses of
baking soda.
2. What is the commercial name of bleaching powder? How is bleaching powder prepared?
What are its different uses?
3. What do you mean by the strength of an acid? What are strong and weal acids?
4. What do you mean by the strength of a base? What are strong and weak base?
5. Three test tubes A, B and C contain distilled water, a basic solution and an acid solution
separately. How would you identify the contents of the test tubes with the help of a red
litmus paper only?
6. What are the different uses of sodium carbonate (Washing soda)?
7. State the important properties of washing soda.
8. What happens when carbon dioxide gas is passed through limewater? Give equations for
the reactions that take place.
9. With the help of universal indicator the pH values of solutions A, B, C, D and E were
found to be 5, 2, 12, 7 and 10 respectively. Say which solution is
(i) neutral
(ii) strongly base
(iii) strongly acidic
(iv) weakly acid
(v) weakly basic
Arrange the pH in the increasing order of H+ ions configuration.
10. Discuss briefly the reactions occurring when a concentrated solution of sodium chloride
(brine) is electrolyzed?
11. Explain how is washing soda produced using sodium chloride as one of the raw materials?
12. (a) What is a salt? Give the names and formula of any two salts. Also name the acids and
bases from which these salts may be obtained.
(b) What is meant by hydrated and anhydrous salts? Explain with example.
13. (a) What is plaster of paris? Write its chemical formula.
(b) How is plaster of paris prepared? Write the chemical equation of the reaction involved.
(c) Explain why plaster of paris should be stored in a moisture proof container.
(d) State two important uses of plaster of paris.
14. (a) What is bleaching powder? Write its chemical formula.
(b) How is bleaching powder prepared? Write the chemical equation of the reaction
involved.
(c) State two important uses of bleaching powder.
15. (a) What happens when zinc granules are heated with sodium hydroxide solution? Write
chemical equation of the reaction which takes place.
(b) What happens when basses react with nonmetals oxides? Explain with the help of an
example. What does this reaction tell us about the nature of non-metal oxides?
ASSIGNMENT QUESTIONS SET – 2
CHAPTER – 2
ACIDS, BASES AND SALTS
6. A teacher gave two test tubes – one containing water and the other containing sodium
hydroxide solution to two students. Then he asked them to identify the test tube containing
sodium hydroxide solution. Which one of the following can be used for correctly
identifying the test tube containing the solution of sodium hydroxide?
(a) Blue litmus (b) Red litmus (c) Sodium carbonate solution (d) Dilute HCl
8. When a drop of unknown solution X is placed on a strip of pH paper, a deep red colour is
produced. This sample is which one of these?
(a) NaOH (b) HCl (c) Water (d) CH3COOH
9. A student tests a sample drinking water and reports its pH value as 6 at room temperature.
Which one of the following might have been added in water?
(a) Calcium chloride (b) Sodium chloride (c) Sodium bicarbonate (d) Bleaching powder
10. Solid sodium bicarbonate was placed on a strip of pH paper. The color of the strip
(a) turned red (b) did not change (c) turned green and slightly yellow (d) turned pink
11. Four drops of red litmus solution were added to each of the following samples. Which one
turns red litmus blue?
(a) Alcohol (b) Distilled water (c) Sodium hydroxide sol (d) HCl
12. The pH of which of the following samples can not be found directly using pH paper?
(a) Lemon juice (b) Dilute HCl (c) Solid sodium bicarbonate (d) Solution of a detergent.
16. What are the products obtained when potassium sulphate reacts with barium iodide in an
aqueous medium?
(a) KI and BaSO4 (b) KI, Ba and SO2 (c) K, I2 and BaSO4 (d) K, Ba, I2 and SO2
19. You are given four unknown solutions I, II, III, and IV. The pH values of these solutions
are found to be 3, 7, 8, and 10 respectively. Among the given solutions, which solution has
the highest hydrogen ion concentration?
(a) I (b) II (c) III (d) IV
20. Which one of the following is required to identify the gas evolved when dilute hydrochloric
acid reacts with zinc metal?
(a) blue litmus paper (b) red litmus paper (c) a burning slinter (d) lime water
21. Zinc reacts with an acid as well as with a base to liberate hydrogen. On the basis of this
what should be the nature of the zinc metal?
(a) basic (b) acidic (c) amphoteric (d) neutral
22. When you test the solutions of sodium bicarbonate, sodium hydroxide, hydrochloric acid
and acetic acid with universal indicator, in which case would you get a red colour?
(a) sodium bicarbonate (b) hydrochloric acid (c) sodium hydroxide (d) acetic acid
23. The pH of a sample of pure water is 7 at room temperature. What is its pH when a pinch of
solid sodium bicarbonate is dissolved in it?
(a) vary near to 7 (b) less than 7 (c) more than 7 (d) exactly 7
24. If an unknown solution turns blue litmus red, then the pH of the solution is more likely to
be (a) 12 (b) 10 (c) 7 (d) 4
28. An aqueous solution turns red litmus solution blue. Excess addition of which of the
following solution would reverse the change?
(a) Baking powder
(b) Lime
(c) Ammonium hydroxide solution
(d) Hydrochloric acid
29. During the preparation of hydrogen chloride gas on a humid day, the gas is usually passed
through the guard tube containing calcium chloride. The role of calcium chloride taken in
the guard tube is to
(a) absorb the evolved gas
(b) moisten the gas
(c) absorb moisture from the gas
(d) absorb Cl– ions from the evolved gas
30. Compounds such as alcohols and glucose contain hydrogen but are not categorized as
acids. Describe an activity to prove it.
31. Why does distilled water not conduct electricity, whereas rain water does?
32. Why do acids not show acidic behavior in the absence of water?
33. Five solutions A, B, C, D and E when tested with universal indicator showed pH as 4, 1,
11, 7 and 9, respectively, which solution is: a) neutral b) strongly alkaline? c) strongly
acidic d) weakly acidic e) weakly alkaline
Arrange the pH in increasing order of hydrogen ion concentration.
36. Equal lengths of magnesium ribbons are taken in test tubes A and B. Hydrochloric acid is
added to test tube A, while acetic acid is added to test tube B. The concentrations taken for
both the acids are same in which test tube the reaction occur more vigorously and why?
37. Fresh milk has a pH of 6. How does the pH change as it turns to curd? Explain your
answer.
38. A milkman adds a very small amount of baking soda to fresh milk.
a) Why does he shift the pH of the fresh milk from 6 to slightly alkaline?
b) Why does this milk take a long time to set as curd?
39. Why does tooth decay start when the pH of mouth is lower than 5.5?
40. How does the flow of acid rain water into a river make the survival of aquatic life in a river
difficult?
41. Dry hydrogen chloride gas does not turn blue litmus whereas hydrochloric acid does. Why?
43. Plaster of paris should be stored in a moisture – proof container. Explain why?
44. What is baking powder? How does it make the cake soft and spongy?
45. Give two important uses of washing soda and baking soda.
46. WHO AM I?
I can roughly measure pH value from 0-14.
I am called antichlor and am used to remove excess chlorine from clothes when treated
with bleaching powder.
I am a product of gypsum and am used to making chalks and fire proof materials.
I am a compound of calcium and can be used for disinfecting drinking water as well as
for decolourisation.
I give different smell in acid and base solution.
I am an oxide capable of showing properties for both acids and bases.
I am a covalent compound and conducts electricity in aqueous medium.
I am a salt of potassium hydroxide and nitric acid.
I am the term used when a solid becomes liquid when exposed to moist air.
I am derived from tomato and turn blue litmus into red.
51. A solution reacts with crushed egg-shells to give a gas that turns lime-water Milky, the
solution contains: ( )
a) NaCl b) HCl c) LiCl d) KCl
55. What colour would hydrochloric acid (pH=1) turn universal indicator. ( )
a) Orange b) purple c) yellow d) red
56. Which one of the following medicines is used for treating indigestion. ( )
a) Antibiotic b) analgesic c) antacid d) antiseptic
58. Which of the following is the most accurate way of representing neutralization? ( )
a) Acid + base → neutral solution
b) Acid + base → salt + water
c) Acid + base → sodium chloride + hydrogen
d) Acid + base → acidic solution
62. Which of the following salts does not contain water of crystallisation?
(a) Blue vitriol
(b) Baking soda
(c) Washing soda
(d) Gypsum
63. Sodium carbonate is a basic salt because it is a salt of
(a) strong acid and strong base
(b) weak acid and weak base
(c) strong acid and weak base
(d) weak acid and strong base
65. A sample of soil is mixed with water and allowed to settle. The clear supernatant solution
turns the pH paper yellowish-orange. Which of the following would change the colour of
this pH paper to greenish-blue?
(a) Lemon juice
(b) Vinegar
(c) Common salt
(d) An antacid
66. Which of the following gives the correct increasing order of acidic strength?
(a) Water <Acetic acid <Hydrochloric acid
(b) Water <Hydrochloric acid <Acetic acid
(c) Acetic acid <Water <Hydrochloric acid
(d) Hydrochloric acid <Water <Acetic acid
67. If a few drops of a concentrated acid accidentally spills over the hand of a student, what
should be done?
(a) Wash the hand with saline solution
(b) Wash the hand immediately with plenty of water and apply a paste of sodium
hydrogencarbonate
(c) After washing with plenty of water apply solution of sodium hydroxide on the hand
(d) Neutralise the acid with a strong alkali
68. Sodium hydrogencarbonate when added to acetic acid evolves a gas. Which of the
following statements are true about the gas evolved?
(i) It turns lime water milky
(ii) It extinguishes a burning splinter
(iii) It dissolves in a solution of sodium hydroxide
(iv) It has a pungent odour
(a) (i) and (ii) (b) (i), (ii) and (iii)
(c) (ii), (iii) and (iv) (d) (i) and (iv)
69. Common salt besides being used in kitchen can also be used as the raw material for making
(i) washing soda
(ii) bleaching powder
(iii) baking soda
(iv) slaked lime
(a) (i) and (ii) (b) (i), (ii) and (iv)
(c) (i) and (iii) (d) (i), (iii) and (iv)
70. One of the constituents of baking powder is sodium hydrogen carbonate, the other
constituent is
(a) hydrochloric acid
(b) tartaric acid
(c) acetic acid
(d) sulphuric acid
71. To protect tooth decay we are advised to brush our teeth regularly. The nature of the tooth
paste commonly used is
(a) acidic
(b) neutral
(c) basic
(d) corrosive
72. Which of the following statements is correct about an aqueous solution of an acid and of a
base?
(i) Higher the pH, stronger the acid
(ii) Higher the pH, weaker the acid
(iii) Lower the pH, stronger the base
(iv) Lower the pH, weaker the base
(a) (i) and (iii) (b) (ii) and (iii)
(c) (i) and (iv) (d) (ii) and (iv)
73. The pH of the gastric juices released during digestion is
(a) less than 7
(b) more than 7
(c) equal to 7
(d) equal to 0
74. Which of the following phenomena occur, when a small amount of acid is added to water?
(i) Ionisation
(ii) Neutralisation
(iii) Dilution
(iv) Salt formation
(a) (i) and (ii) (b) (i) and (iii)
(c) (ii) and (iii) (d) (ii) and (iv)
75. Which one of the following can be used as an acid–base indicator by a visually impared
student?
(a) Litmus
(b) Turmeric
(c) Vanilla essence
(d) Petunia leaves
76. Which of the following substance will not give carbon dioxide on treatment with dilute
acid?
(a) Marble
(b) Limestone
(c) Baking soda
(d) Lime
77. Which of the following is acidic in nature?
(a) Lime juice
(b) Human blood
(c) Lime water
(d) Antacid
83. Which of the following is(are) true when HCl (g) is passed through water?
(i) It does not ionise in the solution as it is a covalent compound.
(ii) It ionises in the solution
(iii) It gives both hydrogen and hydroxyl ion in the solution
(iv) It forms hydronium ion in the solution due to the combination of hydrogen ion with
water molecule
(a) (i) only (b) (iii) only
(c) (ii) and (iv) (d) (iii) and (iv)
84. Which of the following statements is true for acids?
(a) Bitter and change red litmus to blue
(b) Sour and change red litmus to blue
(c) Sour and change blue litmus to red
(d) Bitter and change blue litmus to red
85. Which of the following are present in a dilute aqueous solution of hydrochloric acid?
(a) H3O+ + Cl–
(b) H3O+ + OH–
(c) Cl– + OH–
(d) unionised HCl
86. Identify the correct representation of reaction occurring during chloralkali process
(a) 2NaCl(l) + 2H2O(l) → 2NaOH(l) + Cl2(g) + H2(g)
(b) 2NaCl(aq) + 2H2O(aq) → 2NaOH(aq) + Cl2(g) + H2 (g)
(c) 2NaCl(aq) + 2H2O(l) → 2NaOH(aq) + Cl2(aq) + H2 (aq)
(d) 2NaCl (aq) + 2H2O (l) → 2NaOH (aq) + Cl2(g) + H2(g)
87. What will be the action of the following substances on litmus paper? Dry HCl gas,
Moistened NH3 gas, Lemon juice, Carbonated soft drink, Curd, Soap solution.
88. Name the acid present in ant sting and give its chemical formula. Also give the common
method to get relief from the discomfort caused by the ant sting.
89. A student prepared solutions of (i) an acid and (ii) a base in two separate beakers. She
forgot to label the solutions and litmus paper is not available in the laboratory. Since both
the solutions are colourless, how will she distinguish between the two?
90. How would you distinguish between baking powder and washing soda by heating?
91. Salt - A commonly used in bakery products on heating gets converted into another salt B
which itself is used for removal of hardness of water and a gas C is evolved. The gas C
when passed through lime water, turns it milky. Identify A, B and C.
92. In one of the industrial processes used for manufacture of sodium hydroxide, a gas X is
formed as by product. The gas X reacts with lime water to give a compound Y which is
used as a bleaching agent in chemical industry. Identify X and Y giving the chemical
equation of the reactions involved.
93. What are strong and weak acids? In the following list of acids, separate strong acids from
weak acids. Hydrochloric acid, citric acid, acetic acid, nitric acid, formic acid, sulphuric
acid.
94. When zinc metal is treated with a dilute solution of a strong acid, a gas is evolved, which is
utilised in the hydrogenation of oil. Name the gas evolved. Write the chemical equation of
the reaction involved and also write a test to detect the gas formed.
95. In the following schematic diagram for the preparation of hydrogen gas as shown in below
Figure, what would happen if following changes are made?
(a) In place of zinc granules, same amount of zinc dust is taken in the test tube
(b) Instead of dilute sulphuric acid, dilute hydrochloric acid is taken
(c) In place of zinc, copper turnings are taken
(d) Sodium hydroxide is taken in place of dilute sulphuric acid and the tube is heated.
96. For making cake, baking powder is taken. If at home your mother uses baking soda instead
of baking powder in cake,
(a) how will it affect the taste of the cake and why?
(b) how can baking soda be converted into baking powder?
(c) what is the role of tartaric acid added to baking soda?
97. A metal carbonate X on reacting with an acid gives a gas which when passed through a
solution Y gives the carbonate back. On the other hand, a gas G that is obtained at anode
during electrolysis of brine is passed on dry Y, it gives a compound Z, used for disinfecting
drinking water. Identity X, Y, G and Z.
98. A dry pellet of a common base B, when kept in open absorbs moisture and turns sticky.
The compound is also a by–product of chloralkali process. Identify B. What type of
reaction occurs when B is treated with an acidic oxide? Write a balanced chemical equation
for one such solution.
99. A sulphate salt of Group 2 element of the Periodic Table is a white, soft substance, which
can be moulded into different shapes by making its dough. When this compound is left in
open for some time, it becomes a solid mass and cannot be used for moulding purposes.
Identify the sulphate salt and why does it show such a behaviour? Give the reaction
involved.
100. Identify the compound X on the basis of the reactions given below. Also, write the
name and chemical formulae of A, B and C.