Chemistry L-1 Coaching

ATOMIC STRUCTURE
Single Correct Answer Type
1. The first use of quantum theory to explain the structure of atom was made by
(a) Heisenberg (b) Bohr (c) Planck (d) Einstein
2. Rutherford’s α-particle scattering experiment led to the conclusion that
(a) mass and energy are related
(b) the mass and the positive charge of an atom are concentrated in the nucleus
(c) neutrons are present in the nucleus
(d) atoms are electrically neutral
3. Which of the following statements is incorrect?
(a) The charge on an electron and on a proton are equal and opposite
(b) Neutrons has no charge
(c) Electrons and protons have the same mass
(d) The mass of a proton and a neutron are nearly identical
4. Cathode rays were discovered by
(a) Willam Crookes (b) J. Stoney (c) Rutherford (d) none of these
5. The nature of anode rays depends on
(a) nature of electrode (b) nature of discharge tube
(c) nature of residual gas (d) all of the above.
6. The proton and neutron are collectively called
(a) deuteron (b) positron (c) meson (d) nucleons
7. Cathode rays are produced when the pressure in the discharge tube is of the order of
(a) 76 cm of Hg (b) 10 −6 cm of Hg
(c) 1 cm of Hg (d) 10 −2 to 10 −3 mm of Hg
8. The average distance of an electron in an atom from its nucleus is of the order of
(a) 10 6 m (b) 10 −6 m (c) 10 −10 m (d) 10 −15 m
9. According to Bohr theory, the radius (r) and velocity (v) of an electron increases with the principal
quantum number ‘n’ as
(a) r increase, v decrease (b) r and v both increases
(c) r & v both decrease (d) r decrease, v increases
10. The most important short coming of Bohr’s model is that it :-
(a) Is unable to explain fine line of spectral line
(b) Combined the classical and quantum theories
(c) Did not consider the motion of nucleus
(d) Assumed the orbits be circular
11. The ratio of minimum wavelength of Lyman & Balmer series will be:-
(a) 1.25 (b) 0.25 (c) 5 (d)10

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Chemistry L-1 Coaching
12. The transition of electron in H-atom that will maximum energy is: -
(a) n3 n2 (b) n4 n3 (c) n5 n4 (d) All have same energy
13. Going from K-shell to N –shell in case of H-atom: -
(a) K.E. decreases (b) Total energy decreases
(c) Potential energy decreases (d) None of these
14. Angular momentum for P-shell electron: -
3h 2h
(a) (b)Zero (c) (d)None
π 2π
15. Which of the following, transition neither shows absorption or emission of energy:-
(a) 3px 3s (b) 3dxy 3dyz (c) 3s 3dxy (d) All the above
16. The ionization energy of excited hydrogen atom in eV will be:-
(a) 13.6 (b) Less than 13.6
(c) Greater than 13.6 (d) 3.4 or less
17. A photon of energy 12.75 ev is completely abosorbed by a hydrogen atom initially in ground state.
The principle quantum number of the excited state is:-
(a)1 (b) 3 (c) 4 (d) ∞
18. Which of the following electro magnetic radiation possesses highest amount of energy
(a) X –rays (b) Gamma ray (c) Radio waves (d) Cosmic rays
19. In an electronic transition atom cannot emit:-
(a) Visible light (b) γ -rays (c) Infra red light (d) Ultra violet light
20. Spin angular momentum for electron:-
h h h
(a) S(S + 1) (b) 2S(S + 1) (c) S(S + 2) (d) None
2π 2π 2π
21. A neutral atom of an element has 2K, 8 L 11 M and 2N electrons. The number of s-electron in the
atom are
(a) 2 (b) 8 (c)10 (d)6
22. n, ℓ and m values of an electron in 3py orbital are :-
(a) n = 3 ; l = 1 and m =1 (b) n =3 ; l and m= - 1
(c) Both 1 and 2 are correct (d) None of these
23. The explanation for the presence of the unpaired electron in the nitrogen atom can be given by :-
(a) Pauli’s exclusion principle (b) Hund’s rule
(c) Aufbau’s principle (d) Uncertainty principle
24. Remaining part of atom except outer orbit is called
(a) Kernel (b) Core (c) Empty space (d) None of these
25. The positron is as heavy as :-
(a) Electron (b) Neutron (c) Proton (d) Alpha particle
26. The configuration 1s , 2s , 2p , 3s shows:-
2 2 5 1

(a) Ground state of Flourine (b) Excited state of Flourine

2−
(c) Excited state of Neon atom (d) Excited state of O ion
27. Which of the following relations is not correct?
hc h h
(a) K.E. = h ( v − v 0 ) (b) E = (c) ∆x × ∆p ≤ (d) λ =
λ 4π mv
28. If E is the kinetic energy of the particle then which of the following expression is correct for de
Broglie wavelength of the particle :
h h h 2mE
(a) λ = (b) λ = (c) λ = (d) λ =
2mE 2mE 3mE h
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Chemistry L-1 Coaching
29. The electrons identified by quantum numbers n and l (i) n = 4, l = 1, (ii) n = 4, l =0 (iii) n = 3 , l=2
(iv) n = 3, l =1 can be placed in order of increasing energy.
(a) (iv) < (ii) < (iii) < (i) (b) (ii) < (iv) < (i) < (iii)
(c) (i) < (iii) < (ii) < (iv) (d) (iii) < (i) < (iv) < (ii)
30. Spliting of spectrum lines in magnetic field is
(a) Stark effect (b) Raman effect (c) Zeeman effect (d) Rutherford effect
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31. The wavelength of a spectral line emitted by hydrogen atom in the Lyman series is cm. What
15R
is the value of n 2 ? (R=Ryberg constant)
(a) 2 (b) 3 (c) 4 (d) 1
32. The incorrect statement is
(a) circumference of electron orbit (2πr) = nλ (n – an integer)
h
(b) de-Broglie equation : λ =
mv
 h 2 πr h  h
(c) angular momentum of an electron  = or mvr = n  is an integral multiple of
 mv n 2π  2π
(d) angular momentum of the electron is not quantised
33. ψ2 = 0 represent
(a) node (b) orbital
(c) angular wave function (d) wave functions
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34. The radius of 13 Al will be
−15
(a) 1.2 × 10 m (b) 27 × 10 −15 m (c) 10.8 × 10 −15 m (d) 3.6 × 10 −15 m
35. The density of the nucleus of an atom is
(a) 2.4 × 10 15 kg m −3 (b) 2.4 × 10 19 kg m −3 (c) 2.4 × 10 17 kg m −3 (d) 2.4 × 10 14 kg m −3
36. The heaviest sub-atomic particle is
(a) meson (b) neutron (c) proton (d) electron.
37. Which of the following is an arrangement of increasing value of e/m?
(a) n<α<p<e (b) e<p<α<n (c) n<p<e<α (d) p<n<α<e
38. When atoms are bombarded with α-particles, only a few in million suffer deflection, others pass
out undeflected. This is because:
(a) the force of repulsion on the moving alpha particle is small
(b) the force of attraction on the alpha particle to the oppositely charged electrons is very small
(c) there is only one nucleus and large number of electrons
(d) the nucleus occupies much smaller volume compared to the volume of the atom.
39. The specific charge for positive rays is much less than the specific charge for cathode rays. This is
because:
(a) positive rays are positively charged
(b) charge on positive rays is less
(c) positive rays comprise ionized atoms whose mass is much higher
(d) experimental method for determination is wrong
40. When α-particles are sent through a thin metal foil, most of them go straight through the foil
because.
(a) alpha particles are much heavier than electrons
(b) alpha particles are positively charged
(c) most part of the atom is empty space
(d) alpha particles move with high velocity
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