10th Class-AP-EM-Principles of Metallurgy
10th Class-AP-EM-Principles of Metallurgy
13
Principles of Metallurgy
Activity 1
Look at the following ores.
Identify the metal present in each ore.
Table - 1
• What metals can we get from the ores mentioned in the Table – 1?
• Can you arrange these metals in the order of their reactivity?
• What do you notice in Table – 2?
You will notice that the ores of many metals are oxides and sulphides.
This is why oxygen - sulphur (16th group) group is called chalcogen family
(chalco = ore; genus = produce)
The metals like K, Na, Ca, Mg and Al are so reactive that they are
never found in nature in free state.
The metals like Zn, Fe, Pb etc., are moderately reactive. They are found
in the earth crust mainly as oxides, sulphides and carbonates.
Metals like Au, Ag are least reactive and they are found even in free
state in nature.
Based on reactivity we can arrange metal in descending order of their
reactivity as shown below:
K, Na, Ca, Mg, Al Zn, Fe, Pb, Cu Ag, Au
––––––––––––––– ––––––––––––––– –––––––––––––
High reactivity Moderate reactivity Low reactivity
• Can you think how do we get these metals from their ores?
• Does the reactivity of a metal and form of its ore (oxides, sulphides,
chlorides, carbonates sulphates) has any relation with process of
extraction?
• How are metals extracted from mineral ores?
• What methods are to be used?
Let us find.
Extraction of metals from the ores:
The extraction of a metal from its ore involves mainly three stages.
They are:
I) Concentration or Dressing
II) Extraction of crude metal
III)Refining or purification of the metal.
288 X Class Principles of Metallurgy
Ore Hand picking
by Washing
Concentration of ore
Froth flotation
Magnetic Separation
Extraction of crude
metal from the ore
Sulphide ore
Oxides
Electrolysis of Calcination Roasting
molten ore
Reduction
Metal Oxide ofmetal Metal
(eg: Na, Mg, Al, etc.,)
Hand picking If the ore particles and the impurities are different in
one of the properties like colour, size etc., Using that
property the ore particles are handpicked separating
them from other impurities.
Washing Ore particles are crushed and kept on a slopy surface.
They are washed with controlled flow of water. Less
densive impurities are carried away by water flow,
leaving the more densive ore particles behind.
Froth floatation This method is mainly useful for sulphide ores which
have no wetting property whereas the impurities get
wetted. The ore with impurities is finely powdered and
kept in water taken in a flotation cell. Air under pressure
is blown to produce froth in water. Froth so produced,
takes the ore particles to the surface whereas impurities
settle at the bottom. Froth is separated and washed to
get ore particles.(see fig.1)
Magnetic separation If the ore or impurity, one of them is magnetic substance
and the other non-magnetic substance they are separated
using electromagnets. (see Fig.2)
Froth bubbles
carrying sulphide Powdered ore
ore particles Compressed
Air
Magnetic
wheel
Sulphide ore Non
particles Magnetic
wheel
Water Moving belt
containing
pine oil
Gangue Non Magnetic ore Magnetic ore
fig-2: Magnetic separation
fig-1: Froth floatation process for the
concentration of sulphide ores
There are some other methods also for dressing which you will learn at higher classes.
Metals Action of Reaction with Reaction with Reaction with dilute Reaction with
Oxygen cold water steam strong Acids chlorine on heating
291
Au
II Extraction of crude metal from the ore
Extraction of the metal from its ores depends on the reactivity of the
metal. To understand the order of reactivity of metals that are very familiar,
we study their chemical reactions with cold water, steam, dilute strong
acids and Cl2 and based on their vigorous activity order in these reactions
we frame out activity series. Arrangement of the metals in decreasing order
of their reactivity is known as activity series. (See table - 4)
Reduction of purified ore to the metal
The method used for a particular metal for the reduction of its ore to
the metal depends mainly on the position of the metal in the activity series.
A) Extraction of Metals at the top of the activity series
(K, Na, Ca, Mg and Al). Simple chemical reduction methods like
heating with C, CO etc to reduce the ores of these metals are not feasible.
The temperature required for the reduction is too high and more expensive.
To make the process economical, electrolysis methods are to be adopted.
Again the electrolysis of their aqueous solutions also is not feasible
because water in the solution would be discharged at the cathode in
preference to the metal ions.
The only method viable is to extract these metals by electrolysis of
their fused compounds. For example to extract Na from NaCl, fused NaCl
is electrolysed with steel cathode (-) and graphite anode (+). The metal
(Na) will be deposited at cathode and chloride liberated at the anode.
At Cathode 2Na+ + 2e– 2Na
At Anode 2Cl – Cl2 + 2e–
For the above electrolysis, a large quantity of electricity is required
to keep the ore in molten state. Suitable impurities are added to the ore to
decrease its melting point.
B) Extraction of metals in the middle of the activity series
(Zinc, iron, tin, lead and copper): The ores of these metals are generally
present as sulphides or carbonates in nature. Therefore prior to reduction
of ores of these metals, they must be converted into metal oxides.
Sulphide ores are converted into oxides by heating them strongly in
excess of air. This process is known as roasting. Generally the sulphide
The metal oxides are then reduced to the corresponding metal by using
suitable reducing agent such as carbon
i) Reduction of metal oxides with carbon: The oxides are reduced
by coke in a closed furnace which gives the metal and carbon monoxide
(CO).
at 1400 oC
Eg: PbO + C ––––––––––> Pb + CO
in blast furnace
Eg: Fe2O3 + 3CO ––––––––––––> 2Fe + 3CO2
850 oC
Eg: TiCl4 + 2Mg ––––––––––––>Ti + 2MgCl2
850 oC
TiCl4 + 4Na ––––––––––––> Ti + 4NaCl
Do you know?
Skip
car Fe2O3(s) + 3CO(g) ––––> 2Fe(l) + 3CO2(g)
haematite
Charge
hoppers
CaCO3(s) ––––> CaO(s) + CO2 (g)
Limestone(flux) lime
∼200 oC
Ore
Hearth
Fire
fig-7: Reverberatory box
furnace
298 X Class Principles of Metallurgy
Calcination: Calcination is a pyrochemical process in which the
ore is heated in the absence of air. The ore gets generally decomposed in
the process.
Eg: MgCO3(s) MgO(s) + CO2(g)
CaCO3(s) CaO(s) + CO2(g)
Flux: Flux is a substance added to the ore to remove the gangue from
it by reacting with the gangue. If the impurity (gangue) is acidic substance
like SiO2, basic substance like CaO is used as flux and if the impurity is of
basic nature like FeO acidic flux like SiO2 is added to the gangue.
CaO(s) + SiO2(s) ––––> CaSiO3(l)
flux silica(gangue) calcium silicate(slag)
Key words
Minerals, ores, froth flotation, Thermite process, distillation,
poling, liquation, electrolytic refining, smelting, roasting,
calcinations, blast furnace, reverberatory furnace.
ks
Fill in the blan
1. The method suitable to enrich the sulphide ores is………………………
2. Arranging metals in the decreasing order of their reactivity is called ………………
3. The method suitable for purification of low boiling metals is ……………………
4. Corrosion of iron occurs in the presence of ………….. and ……………..
5. The chemical process in which the ore is heated in the absence of air is called …
s
Multiple choice question