JEE Main 29 January 2023 Shift 2 Memory-Based Questions

𝑡3
𝑥 6
1. lim 48 ∫0 1+𝑥 4𝑡 dx = ?
x→0

2. Find the coefficient of x301 in the binomial equation: x0 (1 + x)500 + x1 (1 + x)499 +

x2 (1 + x)498 + ... + x500
3. If tan150 + 1/tan1690 + 1/tan1050 + tan1950 = 2a, then find the value of a + 1/a.
4. Match the equations with their graphs.
5. Match the following ions with their lone pair of electrons.
IF7, ICl4-, XeF2, XeF4
6. Arrange the following ligands in the increasing order of their field strength: S2-, CO,
Ethylenediamine, C2O42-
7. Caprolactam when heated at high temperature gives which product?
8. The molarity of CO2 in a soft drink is 0.01 M. The volume of a soft drink is 300 ml.
Find the mass of CO2 in the soft drink.
9. During the qualitative analysis of SO3- using dilute H2SO4, the SO2 gas evolved turns
the K2CrO7 solution into which colour?
10. Which of the following is water soluble?
BeSO4, MgSO4, CaSO4, SrSO4, RaSO4
11. What is the shape of the OF2 molecule?
12. Which of the following compound acts as an inhibitor for cancer growth?
13. Bob P is released from its horizontal position of rest at the moment. If it collides
elastically with an identical bob Q hanging freely, then what will be the velocity of
bob Q after the collision? Take g = 10 m/s2 and the length of the strings to which the
bobs P and Q are attached as 20 cm.
14. Which of the following is an Antacid?
Answer - Ranitidine
15. Two conducting solid spheres A and B are placed at a very large distance Q1 and Q2.
The radius of A is R and the radius of B is 2R. When the key connecting the charges
is closed, find the ratio of the final charge densities.
16. NO2 in sunlight (UV) gives rise to A+B
A+O2 gives rise to C
B + C gives rise to NO2 + O2
Name the compounds A, B, and C.
17. For a system undergoing an isothermal process, heat energy is supplied to the system.
Then, which of the following are the correct statements?
Statement 1: Internal energy will increase.
Statement 2: Internal energy will decrease.
Statement 3: Work done by the system is positive.
Statement 4: Work done by the system is negative.
Statement 5: Internal energy remains constant.
18. Match the pairs.
Block Atomic Number
s-block 37
p-block 52
d-block 78
f-block 64
19. Which of the following can be used to prepare LiAlH4?
20. The heat passing through the cross-section of the conductor varies with time as Q(t) =
at - bt2 + ct3 where a, b, c are positive constants. What is the minimum heat current
through the conductor?
21. If the position-time graph of a particle is parabolic, what would be its corresponding
velocity-time graph? (Graph images given as options).
22. How many moles of electrons are required to reduce 1 mole of permanganate ion into
manganese oxide?
23. The speed of an electron in the 7th orbit is 3.6 x 106 m/s. What will be its speed in the
3rd orbit?
24. If frequency = 2 x1012 Hertz, calculate the energy for one mole.
25. Match the reactions with the diagrammatic representations of their products.
i. Wurtz Reaction
ii. Fittig Reaction
iii. Wurtz-Fittig Reaction
iv. Sandmeyer Reaction
26. The correct order of acidic strength of Ha, Hb, Hc and Hd. (A diagram of a compound
was given and the students will have to identify Ha, Hb, Hc and Hd to find the order of
the acidic strength.)
27. If the volume of an ideal gas is increased isothermally, then how will its internal
energy change?
28. If z = 1 + i and z1 = { [ i + z( 1 - i )] / [z ( 1 - z )]. Then find the value of [ (12/π)
arg(z1) ].
29. Assertion: Ketose gives seilwanoff test.
Reason: Ketose undergoes beta elimination to form furfural.
30. Let P(h, k) be any two points on x2 = 4y which is at the shortest distance from Q(0,
33), then what is the difference of distances of P (h, k) from the directrix of
y2 = 4 (x + y)?
1
31. If the coefficient of the expansion of x15 in expansion of (𝑎𝑥 3 + )15 is equal to
𝑏𝑥 1/3
1
the coefficient of x-15 in the expansion of (𝑎𝑥1/3 + )15, then | ab – 5 | = ?
𝑏𝑥 3
−2
32. If an = 4𝑛2 − 16n − 15 and a1 + a2 + a3 + ... + a25 = m/n, where m and n are coprime
numbers, then find the value of m + n.
33. If the height of capillary rise is 5 cm for a liquid, What is the rise in height if the
surface tension and density is doubled?
34. Capacitor of 400 uF is connected to a 100 V battery. Now the batter is removed and
the identical capacitor is connected. Find the change in the potential energy.
35. A particle moving in unidirectional motion travels half of the total distance with a
constant speed of 15 m/s. Now, it travels at 10 m/s for the first half of the remaining
journey and it travels at 5 m/s for the remaining half. What is the average speed of the
particle?
36. Electromagnetic wave beam of power 20 mW is incident on a perfectly absorbing
body for 300 ns. Find the total momentum transferred by the beam to the body.
37. If an insulator with an inductive reactance of XL = R is connected in series with
resistance R across an AC voltage, the power factor comes out to be P1. Now if a
capacitor with a capacitive reactance of XC = R is also connected in series with the
inductor and resistor in the same circuit, the power factor comes out to be P2. Find
P1/P2.
38. A bullet strikes a stationary ball of mass 200 g kept at a height of 20 m. After the
collision, the range of the bullet is 120 m and that of the ball is 30 m. Assuming that
the collision is along the horizontal direction and the g = 10 m/s2, find the initial
velocity of the bullet.
39. A coil A of radius 10 cm has NA number of turns and IA is the current flowing through
it. Another coil B is of radius 20 cm has NB number of turns and IB is the current
flowing through it. Assuming that the magnetic dipole moments of both coils is same,
find the value of IANA in terms of IB and NB.
40. An ideal gas undergoes a thermodynamic process following PT2 = Constant. The
symbols have their usual meaning. Find the volume expansion coefficient of gas.
41. 600 ml of 0.04 M HCl is mixed with 400 ml of 0.02 M H2SO4. Find the pH of the
resulting solution.
42. What is the role of SiO2 in Cu extraction?
43. A solution of 2 g of a non-electrolyte solute and 20 g of water has a boiling point of
373.52 K. If Kb =0.52 K kg/mole, find the molecular mass of the solute.
44. For first order kinetic rate constant 2.303 x 10-3 sec-1. The time taken for the
decomposition of substance from 7 g to 2 g will be how much? Use log7 = 0.845 and
log2 = 0.301
45. If Set A = {a, b, c}, R:A → A, R = {(a, b), (b, c)}. How many elements should be
added for making it symmetric and transitive?
46. If the area bounded by the larger part in the first quadrant by x = 4y2, x = 2, and y = x
is A, then find the value of 3A.
47. A die with the points (2, 1, 0, -1, -2, 3) is thrown 5 times. The probability that the
product of outcomes on all throws is positive is?
48. Let S = {1, 2, 3, 4, 5}. If f:S → P(S), where P(S) is the power set of S. Then the
number of one-one function f can be made is?
49. A line is cutting x-axis and y-axis at two points A and B respectively where OA = a,
OB = b. A perpendicular is drawn from O (origin) to AB at an angle of 𝜋/6 from
98√3
positive x-axis. If the area of triangle OAB = 3 sq. units, then √3𝑎 + 𝑏 is equal to?
50. The mean and variance of 7 observations are 8 and 16 respectively. If number 14 is
omitted, then a & b are the new mean and variance. Find a + b.