21-01-2023 - SR - Super60 - NUCLEUS & ALL - BT - Jee-Main-GTM-11 - KEY & Sol'S
21-01-2023 - SR - Super60 - NUCLEUS & ALL - BT - Jee-Main-GTM-11 - KEY & Sol'S
CHAITANYA IIT ACADEMY, INDIA 21‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐11_KEY &SOL’S
CHEMISTRY
31) 4 32) 2 33) 3 34) 4 35) 3
36) 2 37) 3 38) 2 39) 4 40) 4
41) 1 42) 1 43) 2 44) 1 45) 2
46) 2 47) 3 48) 3 49) 4 50) 1
51) 80 52) 50 53) 0 54) 40 55) 200
56) 18 57) 3 58) 69 59) 3 60) 5
MATHEMATICS
61) 2 62) 1 63) 2 64) 3 65) 1
66) 1 67) 3 68) 1 69) 3 70) 1
71) 1 72) 2 73) 2 74) 3 75) 3
76) 2 77) 1 78) 1 79) 4 80) 1
81) 8 82) 1 83) 9 84) 1 85) 9
86) 3 87) 23 88) 166 89) 9 90) 24
SOLUTIONS
PHYSICS
1. No of divisions on main scale N
No of divisions on vernier scale N 1
Size of main scale division a
Let size of vernier scale division be b then we have
aN
aN b N 1 b
N 1
aN
Least count is a b a
N 1
N 1 N a
a N 1
N 1
2. 2u sin 300 2 10 1 / 2 2
t sec
g cos30 0 10 3/2 3
1
R 10cos300 t g sin300 t 2
2
10 3 2 1 14 10 20
10 10 m
2 3 2 23 3 3
3. Limiting friction between block and slab smAg 0.6 10 9.8 58.8N
But applied force on block A is 100 N. So the block will slip over a slab.
Now kinetic friction works between block and slab
Fk k mAg 0.4 10 9.8 39.2N
This kinetic friction helps to move the slab
39.2 39.2
Acceleration of slab 0.98 m / s 2
mB 40
4. 1
By conservation of energy mg 3h mg 2h mv 2 ( v velocity at B)
2
1
mgh mv2 ; v 2 gh
2
From free body diagram of block at B
mv 2
B h
N mg
mv2
N mg 2mg; N mg
h
5. By Maxwell’s law, time varying electric field produce time – varying magnetic field
C
and vice-versa. So statement I is correct and, V . So statement II is
r r
incorrect.
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 2
SRI CHAITANYA IIT ACADEMY, INDIA 21‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐11_KEY &SOL’S
6. GMm 1 1
P.E RR dr GMm
0
r2 R R0
1 2
The K.E. acquired by the body at the surface mv
2
1 2 1 1
mv GMm
2 R R0
1 1
v 2GM
R0 R
7. The volume flow rate (Q) of an incompressible fluid in steady flow remains constant
From equation of continuity,
av constant
1
Q a v constant or, a v
Where a area of cross-section and v velocity
If v decreases a increases and vice – versa.
When stream of water moves up, its speed decreases and therefore ' a ' increases
v
i.e. the water spreads out as a fountain. When stream of water from hose pipe moves
down, its speed increases and therefore area of cross-section decreases.
8. Vertical distance covered by water before striking ground H h . Time taken is,
t 2H h / g :
Horizontal velocity of water coming out of hole at P,
u 2 gh
Horizontal range ut 2 gh 2 H h / g
2 h H h
9. The linear momenta given by,
p 2 mE 2 mqV E qV
p m q 4m p .2q p 4 2 2 2
pp m pq p m pq p 1 1 1
10. The wavelength of spectral line of the third member of Lyman series is given by
1 1 1 16
R 1 …………. (i)
1 1 16 15R
The wavelength of spectral line of the first member of paschen series is given by
1 1 1 144
R 2 …………. (ii)
2 9 16 7R
Dividing (ii) by (i) we get
1 16 7R 7
2 15 R 144 135
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 3
SRI CHAITANYA IIT ACADEMY, INDIA 21‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐11_KEY &SOL’S
11. For A 1/ 2 20 min, t 80 min, number of half lifes n 4
t
N
Nuclei remaining g 0 . Therefore nuclei decayed
4
2
N
N0 0
24
For B 1/ 2 40 min, t 80 min, number of half lifes n 2
t
N0
nuclei remaining . Therefore nuclei decayed
22
N
N0 0
22
N 0 40 1 1
N
Required ratio 2 16 15 4 5
N 1 16 3 4
N 0 20 1
2 4
12. As we know, current density,
vd
j E nevd ne ne
E
1 1
ne ee Resistivity
1
or 0.4 m
10 1.6 10 19 19 1.6
19
r1
B1 B2
r2
1 1
0.1 10 2 10 7 1
0.1 2 0.1
2 1
2 10 7 6
10 V
2 0.1
B1lV B2lV
Water
1.33
5 cm
1.5 1cm
Glass
d1 d2 5 1
Apparent depth 3.759 0.666
1 2 1.33 1.5
4.425 Shift 6 cm 4.425 cm 1.575 cm
So most appropriate option will be (c).
15. The two springs are in parallel.
Effective spring constant, k k1 k2
Initial frequency of oscillation is given by
1 k1 k2
f ………. (i)
2 m
When both k1 and k2 are made four times their original values, the new frequency is
given by
1 4k1 4k2 1 4 k1 k 2 1 k1 k 2
f f ' 2 fv
2 m 2 m 2 m
16. We know that velocity in string is given by
T
v ……………. (i)
Where m mass of string
1 length of string
m
The tension T x g …………..(ii)
From (i) and (ii)
gx x 1/2dx gdt x 1/2 dx g dt
dx
2 1
dt 0 0
20
g t t2 2 2 2
g 10
l T
9.9 1015 10
3.3 1018 C
mg
q q
4
E 3 10
18. We have given two metallic hollow spheres of radii R and 4R having charges Q1 and
Q2 respectively.
kQ kQ
Potential on the surface of inner sphere (at A) VA 1 2
R 4R
Potential on the surface of outer sphere (at B)
kQ kQ 1
VB 1 2 Here, k
4R 4R 4 0
Potential difference, V V A V B 3 . kQ1 3 Q
. 1
4 R 16 0 R
Q2
Q1
R A
4R B
Capacitor blocks the DC current. So current will flow in lower loop only.
5
So, VPQ 4 4V
4 1
Charge on 4 F V ' C 4 4 4 2 4 8 C
44
20. Resistance of a metal conductor at temperature t0C is given by Rt R0 1 t ,
R0 is the resistance of the wire at 00 C and is the temperature coefficient of
resistance.
Resistance at 50 0 C , R50 R 0 1 50 ……….. (i)
Resistance at 100 0 C , R100 R0 1 100 ……….. (ii)
From (i), R50 R0 50 R0 …………. (iii)
From (ii), R100 R0 100 R0 ………… (iv)
Dividing (iii) by (iv), we get
R50 R0 1
R100 R0 2
Here, R50 5 and R100 6
22. D
d
D
d
d 3 105 103
0.6 106 600 109 m
d 5 102
600 nm
B 80 10 4 8 mT
30. For minimum impedance, we have
1
X L Xc L
c
1 1
L 0.01 101 103 H 100 mH
2 2
c 2 500
CHEMISTRY
31. Cu2S .Fe2S3 or CuFeS2
32. 2 Pb NO3 2 2H 2O O2
2 PbO2 4 HNO3
33. Si contains vacant d-orbtials so it accepts lone pair of H2O and gets hydrolysed. On
the other hand C in CCl4 can’t do so due to absence of vacant d-ortbials.
34. It is Ionic compound. Remaining are only covalent.
35. 2XeF2 2H2O 2Xe 4HF O2
XeF6 H2O XeOF4 2HF
XeF6 2H2O XeO2F2 4HF
XeF6 3H2O XeO3 6HF
36. 3Hg 2HNO3 6HCl 3HgCl2 2NO 4H2O
37. 6 0
d 6 4s 0 4 p0
Co3 3d 7 4s2 t2 g eg 3
d 2 sp3
Fe3 W .L : t2 g 3eg 2
5
d
38. Mabcd 3 isomers (2 cis + 1 trans)
a ) Pt C l N O 2 N O 3 SN 3
b ) Pt cl NO 2 N O3 N CS 3
c ) Pt C l O N o N O 3 N C S 3
d ) Pt C l O N o N O 3 SC N 3
39. Intramolecular H-bond ortho effect are more acidic nature
40. Alternate double bonds with lone pair present in the compound.
41. Order of I effect.
42. K a1 K a2
I P P
P 6
2
43. Cl
SoCl2
A (Major product)
HO CH 2 OH
SoCl2 / P4
Cl CH 2Cl
Con.H SO
2 4
Aldol reaction H 3C CH 3
H in acidic medium
CH 3 H 2O
H 2CH C O H 2CH C CH 3
O
O C CH H2
CH 3
45. O O
NH 2 NH NH
NH 2
CH3CO 2 O / Py
3
KBrO / HBr
3 H O
Br Br
NaNO2 2 HCl
N 2 Cl 0 50 C
Br
Cu / HBr
Br Br
46. Ph NH 2 A
Ph Co NH 2
Br2 KOH
CHCl3 KOH
3 Ph N C H O
HCOOH Ph NH 2
B
(C)
47. Dinitrogen and dioxygen combine to form nitric oxide when the mixture is heated to
2273 – 3273 K in an electric arc.
48. Br Br Br
Br
Br2 / Fe
1,2-dibromobenzene
Br
1,4-dibromobenzene
49. p-hydroxy benzoic acid has higher b. pt. than o-hydroxybenzoic acid due to
intermoleucalr H-bonding.
50. Schotky in the pressure leads to increased collision frequency, missing from their
respective site.
51. For adiabatic process q 0 U Pext V2 V1 6 25 40 90L bar
Now H U PV 90 150 160 90 10 H 80 L bar
52.
For w.A & S.B OH K .C
Ka
53. For zero order reaction, the rate law is written as
x 0.25 x 0.06
KI 5 K II 5
t 0.05 t 0.12
54. 2 20 60 24
Eq. of OH produced
96500 965
CHO
CHCl3
NaOH
P Salicylaldehyde
60. N 2O3
N N
O O O
O
P
P
P4O6 O O O O
O P O P
P4O10
O P O P O
O
N O N O O O
O O
N 2O5
O P
P
O O
S
OH OH
O H 2 S2O3 HO S OH
P P
H 4 P2O5
h O O
O O OH
O O O S O
H 5 P3O10 HO P O P O P OH
H 2 S 2O5 HO S S OH
OH OH OH O
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 12
SRI CHAITANYA IIT ACADEMY, INDIA 21‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐11_KEY &SOL’S
MATHEMATICS
61. Given that f x 2 cos x which is continuous and differentiable every where
Also, f ' x sin x, f ' x 0 x n
There exists c t , t for t R such that f ' x 0
Statement – 1 is true.
Also f x being periodic 2 , statement – 2 is true, but statement – 2 is not a
correct explanation of statement – 1.
62. x2 x B 0 D 0 2 4 0 2 4
, 1,11,2.......1,6 , 2,2 , 2,3 , 2,4 , 2,5 , 26
3,3 , 3,4 , 3,5 , 3,6 , 4,5 , 4,6
63. A, D , I , K , M , N , N
M
A
N
K
I
N
D
6! 3 2 3! 1 2! 1! 0!
4 4!
Rank
2 2
1492
64. Mean + variance 24 np npq 24 …………. (i) np.npq =128 ……(ii)
33
p x 1 p x 2 32C1 pq31 32C2 p 2q30
228
65. Let PR x
15
tan 600 ………… (1)
AQ
x 15
tan 750
AQ
150 15 m
600
Q
(1)
(2)
2
2
71.
lim tan 2 x 2sin 2 x sin x 4 sin 2 x 6sin x 2
x
2
Rationalize the functions apply the limit in the denominator.
tan 2 x sin 2 x 3sin x 2 tan 2 x sin x 1 sin x 2
lim lim
9 9 6
x x
2 2
1 1 sin x 1 sin x 2
1
lim tan 2 x 1 sin x lim
6 x 6 x 1 sin x 1 sin x 12
2 2
72. Given statement is
p q p r ~ p q p r ~ p q r
p q r c is true.
Now, A p ~ r q
~ p ~ r q p r q
~ p r q p q r
From option (D).
p ~ q r p q r
73. For getting infinite solutions 0, 1 2 0 then check all the three equations
2 1 1
Let 1 3 2 0 3
1 4
7 1 1
And 1 1 3 2 0 K 6 K 3
K 3 4
74. x6
We have y
x 2 x 3
At y axis, x 0 y 1
On differentiating, we get
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 15
SRI CHAITANYA IIT ACADEMY, INDIA 21‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐11_KEY &SOL’S
dy
x 2 5 x 6 1 x 6 2 x 5
dx 2
x2 5x 6
dy
1 at point 0,1 Slope of normal 1
dx
Now equation of normal is y 1 1 x 0
y 1 x x y 1
1 1
, satisfy it.
2 2
75. dx
ecos x sin x
Let I ……………… (i)
2
0 1 cos x ecos x e cos x
b b
Applying identity f x dx f a b x dx
a a
cos x
e sin x
I ……………. (ii)
dx
2 cos x
0 1 cos x e ecos x
Add equations (i) and (ii), we get
sin x
2I dx
2
0 1 cos x
On putting cos x t , we get
0 4
1 dt 1
2I 2 tan 1 t
2
01 t
76. 3 2
13 11 13 11 5
3x 2x 3x 2x 3
x x
I dx dx I dx
2x
4 4 4
4
3x 1 2 3 1 3 1
x16 2 2 4 2 2 4
x x x x
3 1 3 2
Let 2 t , 2 dx dt
x2 x4 x3 x5
dt
1 t 41 1 1 1
Then, I 2 C, I C
t4 2 4 1 2 3 3 1
3
2 2
4
x x
1 x12
I C
2x
6 4 2 3
3x 1
4 3 x 12 3 x 2
Required area dx
2 4
2
4
3x2 x3
6x
4 4
2
12 24 16 3 12 2 20 7 27
84. For circle, x 2 y 2 10 x 10 y 41 0
Centre C1 5,5 and radius, r1 3
For circle, x 2 y 2 24 x 10 y 160 0
Centre C2 12,5 and radius, r2 3
C1C2 7 r1 r2 Circles are separated
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 18
SRI CHAITANYA IIT ACADEMY, INDIA 21‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐11_KEY &SOL’S
Required minimum possible distance, p1 p2
7 3 3 1
85. If the line cuts the circle, then
CP r. ……….. (i)
Since, equation of circle is x 2 y 2 2 x 4 y 4 0
Centre 1,2 and radius 1 4 4 1
Also, the equation of line is 3x 4 y k .
38k
Using (i), 1
9 16
11 k
1 11 k 5
5
11 k 5 and 11 k 5
k 6 and 11 k 5 k 16 k 6,16
Integral values of k 7,8,9,10,11,12,13,14,15
Thus, number of integral values of k is 9.
86. Equation of straight line passes through P 3,2, 1 and parallel to given line is
x 3 y 2 z 1
……………. (i)
2 2 1
Q 2 3, 2 2, 1 be any point in line (i) and it is also lies on given plane.
3 2 3 2 2 4 1 1 0
4 4 0 1
87. 100 a
Here d
n 1
Now, A1 a d and, An 100 d
A 1 ad 1
So, 1 7 a 8d 100
An 7 100 d 7
100 a
7a 8 100 ……….. (i)
n 1
a n 33 ……….. (ii)
Now, by Eq. (i) and (ii)
7 n 2 132n 667 0
29
n 23 and n reject.
7
88. 10 k m
Given expression is
4 2
k 1 k k 1 n
2
2
1 10 k k 1 k k 1
2 k 1 k 2 k 1 k 2 k 1
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 19
SRI CHAITANYA IIT ACADEMY, INDIA 21‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐11_KEY &SOL’S
1 10 1 1 55 m
2 k 1 k 2 k 1 k k 1
2
111 n
m n 166
89. x2 y 2
Given ellipse is 1
16 9
So equation of tangent to the ellipse is,
y mx a 2m2 b2
y mx 16m2 9 ……………. (i)
Now, given circle is
x 2 y 2 12
So equation of tangent to the circle is
ymx 12 1 m2 ……………… (ii)
For common tangent on equating equations (i) and (ii)
16m 2 9 12 1 m 2
16m2 12m2 3 4m 2 3 12m 2 9
90. Given , roots of equation 3 x 2 x 1 0
1
So, ,
3 3
According to given relation of roots,
1 1 2 2
15 2 9 3
2 2 2 2
2
2 3 2 5
Now, 2
2 2 2 2
3 3 3
2
Take, 6 3 3 6 2 2
3 5 1 2 2
6 6 1 2 6 4 24 .
3 3 3