MATERIAL SAFETY DATA SHEET
DATE OF PREPARATION
865T604 Sep 22, 2013
18 00
SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
B65T604
PRODUCT NAME ""
ACROLONrm 218 HS Polyurethane - Gloss (Part A), Ultradeep/Clear Tint Base
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 Prospect Avenue N.W.
Cleveland, OH 44115
,.1.....,. ---- L.,.... •..........•........
Product Information (800) 524-5979
vvvrn.shenvin-vvilliarns.com
Regulatory Information (216) 566-2902
www.paintdocs.corn
Medical Emergency (216) 566-2917
Transportation Emergency' (800) 424-9300
`for Chemical Emergency ONLY (spill, leak, fire, exposure, or
accident)
SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
Units Vapor Pressure
% by Weight CAS Number Ingredient
0.4 100-41-4 Ethyibenzene
ACGIH TLV 20 PPM 7.1 mm
OSHA PEL 100 PPM
OSHA PEL 125 PPM STEL.
2 1330-20-7 Xylene
ACGIH TLV 100 PPM 5.9 mm
ACGIH TLV 150 PPM STEL
OSHA PEL 100 PPM
OSHA PEL 150 PPN1 STEL
1 64742-94-5 Medium Aromatic Hydrocarbons
ACGIH TLV Not Available 0.12 mm
OSHA PEL Not Available
0.2 91-20-3 Naphthalene
ACGIH TLV 10 PPM 1m
ACGIH TLV 15 PPM STEL
1•••
OSHA PEL 10 PPN1
OSHA PEL 15 PPM STEL PPI/Pr›,A
t17
4 78-93-3 Methyl Ethyl Ketone
ACGIH TLV 200 PPM tV
A11171
ACGIH TLV 300 PPM STEL
OSHA PEL 200 PPM
OSHA PEL 300 PPM STEL
10 123-86-4 n-Butyl Acetate
ACGIH TLV 150 PPM 10 mm
ACGIH TLV 200 PPM STEL
OSHA PEL 150 PPM
OSHA PEL 200 PPM STEL
6 108-65-6 1-Methoxy-2-Propanol Acetate
ACGIH TLV Not Available 1.8 mm
OSHA PEL Not Available
31 14808-60-7 Quartz
ACGIH TLV 0.025 mgim3 as Resp. Dust
OSHA PEL 0.1 mg/m3 as Resp. Dust
SECTION 3 — HAZARDS IDENTIFICATION
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B65T604
ROUTES OF EXPOSURE HIVIIS Codes
INHALATION of vapor or spray rnist.
Health 2'
EYE or SKIN contact with the product, vapor or spray mist.
Flammability 3
EFFECTS OF OVEREXPOSURE
EYES: Irritation. Reactivity O
SKIN: Prolonged or repeated exposure may cause irritaticn.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.
Prolonged overexposure to hazardous ingredients in Section 2 may cause adversa chronic effects to the following organs or systems:
• the liver
• thé urinary systern
• the hematopoietic (blood-forming) system
• the reproductive system
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
May cause allergic respiratory andlor skin reaction in susceptible persone or sensitization. This effect may be delayed severa; hours after
exposure.
Persone sensitive to isocyanates will experience increased allergic reaction on repeated exposure.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
SECTION 4 - FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes. Get medica! attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If any breathing problerns occur during use, LEAVE THE ARFA and get fresh air. problems remain or occur later;
IMMEDIATELY get medica' attention.
INGESTION: Do nct induce vomiting. Get medica! attention immediately.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT L EL UEL FU-,'MMABILITY CLASSIFICATION
55 °F FMCC 0.8 13.1 RED LAB=1 Flarmable. Flashbelow 100 'F (38 '0
EXTINGUISHING MEDIA
Carbon Dioxide. Dr! Chemical. Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately
apparent. Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus shcuid be used.
Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool re01.1containers vent pressure
build-up and possible autoignition or explosion when exposed to extreme heat. C.)
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASE D OR SPILLED
Remove all sources of ignition. Ventilate the ares.
Remove with inert absorbent.
SECTION 7 - HANDLING AND STORAGE
STORAGE CATEGORY
DOL Storage Class IB
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Contents are FLAMMABLE. Keep away from heat, sparks, and open fleme.
During use and until all vapore are gone: Keep area ventilated - Do not smoke - Extinguish al! flamee, pilot lights, and heaters - Turn off
stoves, electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Keep container closed when not in use. Transfer only to approved containers with complete and aporopriate labeling. Do not tape internally
Keep out of the reach of children.
page 2 of 5
B65T604
SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
NO PERSON SHOULD USE THIS PRODUCT, OR BE IN THE AREA WHERE IT IS BEING USED, IF THEY HAVE CHRONIC (LONG-
TERM) LUNG OR BREATHING PROBLEMS OR IF THEY EVER HAD A REACTION TO ISOCYANATES.
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous
listed in Section 2, the applicable limits for nuisance dusts
levels only during sanding or abrading of the dried film. If no specific dusts are-
mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 ring/m3 (respirable fraction).
are ACGIH TLV 10
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure
limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
Where overspray is present, a positive pressure air supplied respirator (TC19C NIOSH/MSHA approved) should be worn. If unavailable, a
properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2 may be
effective. Follow respirator manufacturera directions for use. Wear the respirator for the whole time of spraying and until all vapors and
NO PERSONS SHOULD BE ALLOWED IN THE AREA WHERE THIS PRODUCT IS BEING USED UNLESS
mists are gone.
EQUIPPED W1TH THE SAME RESPIRATOR PROTECTION RECOMMENDED FOR THE PAINTERS.
When sanding or abrading the dried film, wear a dust/mist respirator approved by N!OSH/MSHA for dust which may be generated from this
product, underlying paint, or the abrasive.
PROTECTIVE GLOVES
To present skin contact, wear gloves which are recommended by glove supplier for protection against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PROTECTIVE EQUIPMENT
Use barrier creara on exposed skir..
OTHER PRECAUTIONS
This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON
ALL COMPONENTS.
Intentional misuse by deliberately concentrating ard can be harmfui or fatal.
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT 10.64 Ib/gal 1275 gil
SPECIFIC GRAVITY 1.28
BOILING POINT 174 - 415 'F 73 - 212 'C
MELTING POINT Not Available
VOLATILE VOLUME 36%
EVAPORATION RATE Slower than
ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER Not Available
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
2.66 lb/gal 319 g/I Less Water and Federally Exempt Solvents
2.66 lb/gal 319 gil Emitted VOC
01181.4
SECTION 10 — STABILITY AND REACTIVITY
yo"
STABILITY — Stable
CONDITIONS TO AVOID ilNVIr"A
None known. r,' " LSA
'W itstr1z. kj?
INCOMPATIBILITY
‘ Cy
la
None known. '..: ‹)? o'r .
le...,
HAZARDOUS DECOMPOSITION PRODUCTS 's
i • ' -C'1 • tjc? '''s
By fire: Carbon Dioxide, Carbon Monoxide --... •0iMeiN.,
. C N‘-`
.-- 7
HAZARDOUS POLYMERIZATION
Will not occur
SECTION 11 — TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Methyl Ethyl Ketone may increase the nervous system effects of other solvents.
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.
Naphthalene is classified byilARC as possibiy carcinogenic te humans (2B) based on inadequate evidehce in humans and sufficient evidence
in laboratory animals.
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865T604
Ethylbenzene is classified by IARC as possibly'carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient
evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resultad in increases in
certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals
exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans.
Crystalline Sílice (Quartz, Cristobalite) is Usted by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film. may cause lung damage (silicosis) and possibly cancer.
TOXICOLOGY DATA
CAS No. Ingredient Name
100-41-4 Ethylbenzene
LC50 RAT 4HR Not Available
LD50 RAT 3500 mg/kg
1330-20-7 Xylene
LC50 RAT 4HR 5000 ppm
LD50 RAT 4300 mg/kg
64742-94-5 Mediurn Aromatic Hydrocarbons
LC50 RAT 4HR Not Available
LD50 RAT Not Available
91-20-3 Naphthalene
LC50 RAT 4HR Not Available
LD50 RAT Not Available
78-93-3 Methyl Ethyl Ketone
LC50 RAT 4HR Not Available
LD50 RAT 2740 mg/kg
123-86-4 n-Buty! Acetate
LC50 RAT 4HR 2000 ppm
LD50 RAT 13100 mg/kg
108-65-6 1-fsrlethoxy-2-Propanol Acetate
LC50 RAT 4HR Not Available
LD50 RAT 8500 mg/kg
14808-60-7 Quartz
LC50 RAT 4HR Not Available
LOSO RAT Not Available
SECTION 12 — ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
SECTION 13 — DISPOSAL CONSIDEP,ATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource Corservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.
incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
SECTION 14 — TP,ANSPORT INFORMATION
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping
description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of
transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicái)1e egstLtions is the sole
responsibility of the person offering the product for transport. u A:bí,
US Ground (DOT)
5 Liters (1.3 Gallons) and Less may be Classed as LTD. QTY. OR ORM-D C.J .1->
Larger Containers are Regulated as:
UN1263, PAINT, 3, PG II, (ERG#128)
DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities
Xylenes (isomers and mixture) 100 lb RQ
t cz211 It4 rz;i.ji, ,,,Ls,
c, la." c ,w,y.,
Bulk Containers may be Shipped as (check reportable quantities):
UN1263, PAINT, 3, PG II, (ERG#128)
50\ ..) /
Canada (TDG) .-. .
UN1263, PAINT, CLASS 3, PG II, (ERG#128) c4c,„_,
IMO
5 Liters (1.3 Gallons) and Less may be Shipped as Limitad Quantity.
UN1263, PAINT, CLASS 3, PG II, (13 C c.c.), EmS F-E, S-E
IATA/ICAO
UN1263. PAINT. 3. PG II
page 4 of 5
E3651-604
SECTION 15 - REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No. CHEMICALICOMPOUND % by WT % Element
100-41-4 Ethylbenzene 0.4
1330-20-7 Xylene 2
91-20-3 Naphthalene 0.2
r• A I ICr1171.11 A 00"W-te i-r.-soa ce
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are Usted, or are exempt from listing, en the TSCA Inventory.
SECTION 16 - OTHER INFORMATION
This product has been classified in accordance with the hazard criteria of the Canadían Controlled Prcducts Regulations (CPR) and the
MSDS ccntains all of the information required by the CPR.
The aboye information pertains this product as currently formulated, and is based on the information available at this time. Addition of reducers or cther
additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make nc
warranties, expresa or implied, and assume no liability in connection with any use of this information.
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page 5 of 5
