Lect 34
Lect 34
Rayleigh scattering is a solution to the scattering of light by small particles. These particles
are assumed to be much smaller than wavelength of light. Then a simple solution can be found
by the method of asymptotic matching. This single scattering solution can be used to explain
a number of physical phenomena in nature. For instance, why the sky is blue, the sunset so
magnificently beautiful, how birds and insects can navigate without the help of a compass.
By the same token, it can also be used to explain why the Vikings, as a seafaring people,
could cross the Atlantic Ocean over to Iceland without the help of a magnetic compass.
339
340 Electromagnetic Field Theory
Figure 34.1: The magnificent beauty of nature can be partly explained by Rayleigh scattering
[182, 183].
When a ray of light impinges on an object, we model the incident light as a plane elec-
tromagnetic wave (see Figure 34.2). Without loss of generality, we can assume that the
electromagnetic wave is polarized in the z direction and propagating in the x direction. We
assume the particle to be a small spherical particle with permittivity εs and radius a. Essen-
tially, the particle sees a constant field as the plane wave impinges on it. In other words, the
particle feels an almost electrostatic field in the incident field.
where the dipole moment p = ql. The vector potential A due to a Hertzian dipole, after
substituting (34.1.1), is
µ J(r0 ) −jβ|r−r0 |
A(r) = dr0 e
4π V |r − r0 |
µIl −jβr
= ẑ e (34.1.3)
4πr
Near Field
From prior knowledge, we know that the electric field is given by E = −jωA − ∇Φ. From a
dimensional analysis, the scalar potential term dominates over the vector potential term in
the near field of the scatterer. Hence, we need to derive the corresponding scalar potential.
The scalar potential Φ(r) is obtained from the Lorenz gauge that ∇ · A = −jωµεΦ.
Therefore,
−1 Il ∂ 1 −jβr
Φ(r) = ∇·A=− e (34.1.4)
jωµε jωε4π ∂z r
When we are close to the dipole, by assuming that βr 1, we can use a quasi-static approx-
imation about the potential.1 Then
∂ 1 −jβr ∂ 1 ∂r ∂ 1 z 1
e ≈ = =− 2 (34.1.5)
∂z r ∂z r ∂z ∂r r rr
or after using that z/r = cos θ,
ql
Φ(r) ≈ cos θ (34.1.6)
4πεr2
1 This is the same as ignoring retardation effect.
342 Electromagnetic Field Theory
This dipole induced in the small particle is formed in response to the incident field. The
incident field can be approximated by a constant local static electric field,
so that Einc ≈ −∇Φinc = ẑEi , as ω → 0. The scattered dipole potential from the spherical
particle in the vicinity of it is given by
a3
Φsca = Es cos θ (34.1.9)
r2
The electrostatic boundary value problem (BVP) has been previously solved and3
εs − ε
Es = Ei (34.1.10)
εs + 2ε
Using (34.1.10) in (34.1.9), and comparing with(34.1.6), one can see that the dipole moment
induced by the incident field is that
εs − ε 3
p = ql = 4πε a Ei (34.1.11)
εs + 2ε
Far Field
In the far field of the Hertzian dipole, we can start with
1
E = −jωA − ∇Φ = −jωA − ∇∇ · A (34.1.12)
jωµε
But when we are in the far field, A behaves like a spherical wave which in turn behaves
like a local plane wave if one goes far enough. Therefore, ∇ → −jβ = −jβr̂. Using this
approximation in (34.1.12), we arrive at
ββ
E = −jω A − 2 · A = −jω(A − r̂r̂ · A) = −jω(θ̂Aθ + φ̂Aφ ) (34.1.13)
β
Consequently, using (34.1.11) for ql, we have in the far field that4
ω 2 µql −jβr εs − ε a3
∼
Eθ = −jωAθ = − e 2
sin θ = −ω µε Ei e−jβr sin θ (34.1.15)
4πr εs + 2ε r
r
ε 1
Hφ ∼
= Eθ = Eθ (34.1.16)
µ η
p
where η = µ/ε. The time-averaged Poynting vector is given by hSi = 1/2<e {E × H∗ }.
Therefore, the total scattered power is
π 2π
1
Ps = r2 sin θdθ dφEθ Hφ∗ (34.1.17)
2 0 0
2 π
a6
1 4 εs − ε 3
= β |Ei |2 r2 sin θdθ 2π (34.1.18)
2η εs + 2ε r2 0
But
π π π
3 2
sin θdθ = − sin θd cos θ = − (1 − cos2 θ)d cos θ
0 0 0
−1
4
=− (1 − x2 )dx = (34.1.19)
1 3
Therefore
2
4π εs − ε
Ps = β 4 a6 |Ei |2 (34.1.20)
3η εs + 2εs
The scattering cross section is the effective area of a scatterer such that the total scattered
power is proportional to the incident power density times the scattering cross section. As
such it is defined as
2
8πa2 εs − ε
Ps
Σs = 1 2
= (βa)4 (34.1.21)
2η |Ei |
3 εs + 2ε
In other words,
Ps = hSinc i × Σs
It is seen that the scattering cross section grows as the fourth power of frequency since
β = ω/c. The radiated field grows as the second power because it is proportional to the
acceleration of the charges on the particle. The higher the frequency, the more the scattered
power. this mechanism can be used to explain why the sky is blue. It also can be used to
explain why sunset has a brilliant hue of red and orange. The above also explain the brilliant
glitter of gold plasmonic nano-particles as discovered by ancient Roman artisans. For gold,
4 The ω 2 dependence of the following function implies that the radiated electric field in the far zone is
the medium resembles a plasma, and hence, we can have εs < 0, and the denominator can be
very small.
Furthermore, since the far field scattered power density of this particle is
1
hSi = Eθ Hφ∗ ∼ sin2 θ (34.1.22)
2η
the scattering pattern of this small particle is not isotropic. In other words, these dipoles ra-
diate predominantly in the broadside direction but not in their end-fire directions. Therefore,
insects and sailors can use this to figure out where the sun is even in a cloudy day. In fact,
it is like a rainbow: If the sun is rising or setting in the horizon, there will be a bow across
the sky where the scattered field is predominantly linearly polarized.5 Such a “sunstone” is
shown in Figure 34.3.
Figure 34.3: A sunstone can indicate the polarization of the scattered light. From that, one
can deduce where the sun is located (courtesy of Wikipedia).
These two dipolar components have electric fields that cancel precisely at certain observation
angle. This gives rise to deep null in the bi-static radar scattering cross-section (RCS)6 of a
PEC sphere as illustrated in Figure 34.4.
Figure 34.4: RCS (radar scattering cross section) of a small PEC scatterer (courtesy of Sheng
et al. [185]).
When the size of the dipole becomes larger, quasi-static approximation is insufficient to
approximate the solution. Then one has to solve the boundary value problem in its full glory
usually called the full-wave theory or Mie theory [186, 187]. With this theory, the scattering
cross section does not grow indefinitely with frequency. For a sphere of radius a, the scattering
cross section becomes πa2 in the high-frequency limit. This physical feature of this plot is
shown in Figure 34.5, and it also explains why the sky is not purple.
6 Scattering cross section in microwave range is called an RCS due to its prevalent use in radar technology.
346 Electromagnetic Field Theory
Figure 34.5: Radar cross section (RCS) calculated using Mie scattering theory [187].
Figure 34.6: A particle scatters increasingly more in the forward direction as the frequency
increases.Courtesy of hyperphysics.phy-astr.gsu.edu.
∂2
1 ∂ 2 ∂ 1 ∂ ∂ 1 2
r + sin θ + + β Ψ(r) = 0 (34.2.1)
r2 ∂r ∂r r2 sin θ ∂θ ∂θ r2 sin2 θ ∂φ2
Noting the ∂ 2 /∂φ2 derivative, by using separation of variables technique, we assume Ψ(r) to
be
∂ 2 jmφ
where ∂φ2 e = −m2 ejmφ . Then (34.2.1) becomes
m2
1 ∂ 2 ∂ 1 ∂ ∂ 2
r + sin θ − + β F (r, θ) = 0 (34.2.3)
r2 ∂r ∂r r2 sin θ ∂θ ∂θ r2 sin2 θ
Again, by using the separation of variables, and letting further that
F (r, θ) = bn (βr)Pnm (cos θ) (34.2.4)
where we require that
m2
1 d d
sin θ + n(n + 1) − Pnm (cos θ) = 0 (34.2.5)
sin θ dθ dθ sin2 θ
when Pnm (cos θ) is the associate Legendre polynomial. Note that (34.2.5) is an eigenvalue
problem, and |m| ≤ |n|.
Consequently, bn (kr) satisfies
1 d 2 d n(n + 1) 2
r − + β bn (βr) = 0 (34.2.6)
r2 dr dr r2
The above is the spherical Bessel equation where bn (βr) is either the spherical Bessel function
(1)
jn (βr), spherical Neumann function nn (βr), or the spherical Hankel functions, hn (βr) and
(2)
hn (βr). The spherical functions are related to the cylindrical functions via [34, 43] 9
r
π
bn (βr) = B 1 (βr) (34.2.7)
2βr n+ 2
It is customary to define the spherical harmonic as
s
2n + 1 (n − m)! m
Ynm (θ, φ) = P (cos θ)ejmφ (34.2.8)
4π (n + m)! n
9 By a quirk of nature, the spherical Bessel functions needed for 3D wave equations are in fact simpler than
cylindrical Bessel functions needed for 2D wave equation. One can say that 3D is real, but 2D is surreal.
10 In a nutshell, a set of basis functions is complete in a subspace if any function in the same subspace can
359
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