Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 1(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
Trade name
Cartasol Turquoise KRL liq
Material number: 101023
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Paper, pulp and board industry
Type of use : paper dye
1.3. Details of the supplier of the safety data sheet
Identification of the company
Clariant Produkte (Schweiz) AG
Rothausstrasse 61
4132 Muttenz
Telephone no. : +41 61 469 5111
Information about the substance/mixture
Textile, Leather & Paper Chemicals
Product Safety, ++41-(0)61-469-5121
e-mail: [email protected]
1.4. Emergency telephone number
00800-5121 5121 (24 h)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended)
The product does not require classification and labelling as hazardous according to
CLP/GHS.
Classification according EC Directive (67/548/EEC or 1999/45/EC, as amended)
The product is not classified as dangerous according to EC directives/the relevant national
laws.
2.2. Label elements
Labelling in accordance with EC-Directives (67/548/EEC or 1999/45/EC, as amended)
The product does not require a hazard warning label in accordance with EC Directives
Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 2(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
2.3. Other hazards
According to the present state of knowledge provided this product is handled correctly,there
is no danger to humans or the environment
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Chemical characterization
copper phthalocyanine dyestuff
cationic
Hazardous ingredients
Acetic acid
Concentration : 5 - 10 %
CAS number : 64-19-7
EC number: 200-580-7
Index Number 607-002-00-6
REACH - Registration 01-2119475328-30-0003
number according to
article 20(3):
Classification hazard substance EC
R 10
C Corrosive R 35
GHS classification EC
Flammable liquids Category 3 H226
Skin corrosion Category 1A H314
Concentration : 20 - 25 %
CAS number : 82864-55-9
Classification hazard substance EC
R 52/53
The text of the R-phrases is shown in section 16.
The text of the H-phrases is shown in section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
Seek medical assistance if discomfort continues
After inhalation
Immediately seek fresh air after inhaling of dust, vapour or aerosol.
After contact with skin
After contact with skin, wash immediately with plenty of water and soap.
Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 3(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
After contact with eyes
Immediately rinse eyes with running water and seek medical advice.
After ingestion
If swallowed seek medical advice immediately (treat symptomatically).
4.2. Most important symptoms and effects, both acute and delayed
Symptoms
No symptoms known currently.
Hazards
No hazards known at this time.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
compatible with all usual extinguishing media
Extinguishing media that must not be used for safety reasons
No restrictions
5.2. Special hazards arising from the substance or mixture
carbon oxides
copper oxides
nitrogen oxides
sulfur oxides
5.3. Advice for firefighters
Special protective equipment for firefighting
Use self-contained breathing apparatus
Further information
Large amounts of soot are formed in burning
Cool endangered containers with water spray jet.
Cool containers with water spray jet from the greatest possible distance
This product is not combustible
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear suitable personal protective equipment.
6.2. Environmental precautions
Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 4(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
Do not allow entry to drains,water courses or soil
6.3. Methods and material for containment and cleaning up
Clean equipment with water.
Pick up with absorbent material (eg sand, kieselgur, acid binder, universal binder, sawdust).
6.4. Reference to other sections
Additional information
Take up as such and consider recycling.
Do not let the liquid drain into rivers, ponds or sewer systems.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling
Avoid contact with skin, eyes, and clothing.
No special measures required.
Advice on protection against fire and explosion
No special measures required.
7.2. Conditions for safe storage, including any incompatibilities
Further information on storage conditions
Keep container tightly closed
7.3. Specific end use(s)
No further recommendations.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure limit values
Acetic acid
CAS number : 64-19-7
Directive on indicative exposure limits (amended)
EU OEL - Directive on indicative exposure limits
Revision : 29/05/1991
Threshold Limit Values
Values: 25 mg/m3 10 ppm
DNEL/DMEL values
DNEL/DMEL values are not available.
PNEC values
PNEC values are not available.
8.2. Exposure controls
Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 5(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
General protective measures
Observe the usual precautions for handling chemicals.
Hygiene measures
Wash hands before breaks and after work.
Remove soiled or soaked clothing immediately and clean thoroughly before using again.
Respiratory protection : In case of insufficient exhaust ventilation, or prolonged
exposure, use self-contained breathing apparatus.
Hand protection : Butyl rubber gloves
Neoprene gloves
Chemical resistant gloves
Observe the information of the glove manufacturers on
permeability and breakthrough times and other workplace
requirements
Eye protection : safety glasses
tightly fitting safety glasses
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : liquid
Form : aqueous-organic solution
Particle size : Not applicable
Colour : dark blue
Odour : yes
Odour threshold : not tested.
pH value : 3 - 4 (20 °C)
Melting point : not applicable
Boiling point : app. 100 °C
Sublimation point : not applicable
Flash point : no flash point up to the boiling point
Evaporation rate : not tested.
Flammability
Lower explosion limit : Not applicable
Upper explosive limit : Not applicable
Combustion number : Not applicable
Minimum ignition energy : not tested.
Burning rate : not applicable
Vapour pressure : Corresp. to vapour pressure of water
Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 6(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
Vapour density relative to air not tested.
:
Relative Density: not tested.
Solubility in water : (20 °C)
miscible
Octanol/water partition not tested.
coefficient (log Pow) :
Ignition temperature : not tested.
Thermal decomposition : not tested.
Viscosity (dynamic) : not tested.
Explosive properties : Explosive according to EU supply regulations : not explosive
Method : Expert statement
Oxidizing properties : Type of oxidizing effect : Not oxidizing
Method : Expert statement
9.2. Other information
Density : 1,08 g/cm3 (20 °C, 1.013 hPa)
Surface tension : not tested.
Specific resistance / electrical not tested.
conductivity :
SECTION 10: Stability and reactivity
10.1. Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2. Chemical stability
Under normal conditions the product is stable.
10.3. Possibility of hazardous reactions
When used and handled as intended, none.
10.4. Conditions to avoid
10.5. Incompatible materials
not known
10.6. Hazardous decomposition products
When used and handled as intended, none.
SECTION 11: Toxicological information
Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 7(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
11.1. Information on toxicological effects
Acute oral toxicity : LD50 > 2.000 mg/kg (rat)
Directive 1999/45/EC
Acute dermal toxicity : not tested.
Acute inhalation toxicity : not tested.
Irritant effect on skin : non-irritant (rabbit)
Directive 1999/45/EC
Irritant effect on eyes : non-irritant (rabbit)
Directive 1999/45/EC
Sensitization : not tested.
Repeated dose toxicity: not tested.
Genetic toxicity in vitro : not tested.
Assesment of mutagenicity : not available
Carcinogenicity : not tested.
Assessment of not available
carcinogenicity :
Developmental not tested.
toxicity/teratogenicity :
Toxicity to not tested.
reproduction/fertility :
Assessment of toxicity to not available
reproduction :
Assessment of teratogenicity not available
:
Specific target organ toxicity Remarks : not tested.
(STOT) - single exposure :
Specific target organ toxicity Remarks : not tested.
(STOT) - repeated exposure :
Remarks
Preparation has not been tested
The product was classified on the basis of the calculation procedure of the Dangerous
Preparations Directive (1999/45/EC).
SECTION 12: Ecological information
12.1. Toxicity
Fish toxicity : LC50 > 100 mg/l (48 h, rainbow trout (salmo gairdneri,
oncorhynchus mykiss))
Directive 1999/45/EC
Daphnia toxicity : not tested.
Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 8(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
Algae toxicity : not tested.
Bacteria toxicity : IC50 > 100 mg/l (activated sludge)
Method : test result of the active component according to
OECD 209
Toxicity to soil-dwelling not tested.
organisms :
Toxicity to terrestrial not tested.
organisms :
Toxicity to other not tested.
environmentally relevant
organisms :
12.2. Persistence and degradability
Physico-chemical not tested.
eliminability :
Photodegradation : not tested.
Biodegradability : > 90 % (TOC)
Method : SANDOZ internal test
Dissolved Organic carbon not available
(DOC) :
Chemical oxygen demand not available
(COD) :
Biochemical oxygen demand not available
(BOD5) :
12.3. Bioaccumulative potential
Bioaccumulation: not tested.
12.4. Mobility in soil
Behaviour in environmental compartments
No known data.
12.5. Results of PBT and vPvB assessment
No data available.
12.6. Other adverse effects
Additional ecotoxicological remarks
Product does not contain any organic bound Halogens which could lead to AOX-values.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 9(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
Product
Dispose of in accordance with local authority regulations
Dispose of in accordance with local authority regulations
Uncleaned packaging
Consider recycling.
Composition
C,
Cu ( 1,5 %) ,
H,
N,
O,
S,
SECTION 14: Transport information
Section 14.1. to 14.5.
ADR not restricted
ADNR not restricted
RID not restricted
IATA not restricted
IMDG not restricted
14.6. Special precautions for user
See sections 6 to 8 of this Safety Data Sheet.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No transport as bulk according IBC - Code.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
15.2. Chemical safety assessment
No Chemical Safety Assessment (CSA) is yet available for the component substances of this
preparation.
Safety Data Sheet in accordance with Regulation (EU)
No.453/2010
Cartasol Turquoise KRL liq Page 10(10)
Substance key: KS8904 Revision Date: 02.02.2011
Version : 2 - 5 / EU Date of printing : 15.02.2011
SECTION 16: Other information
Text of the R-phrases assigned to the ingredients/components mentioned in section
3:
10 Flammable.
35 Causes severe burns.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
List of the text of the hazard statements mentioned section 3 (H-phrases) :
H226 Flammable liquid and vapour.
H314 Causes severe skin burns and eye damage.
Decimal notation: "thousands" places are identified with a dot (for example, "2.000 mg/kg"
means "two thousand mg/kg"). Decimal places are identified with a comma (for example,
"1,35 g/cm3" means "one point three five g/cm3").
This information corresponds to the present state of our knowledge and is intended as a
general description of our products and their possible applications. Clariant makes no
warranties, express or implied, as to the information's accuracy, adequacy, sufficiency or
freedom from defect and assumes no liability in connection with any use of this information.
Any user of this product is responsible for determining the suitability of Clariant's products
for its particular application. Nothing included in this information waives any of Clariant's
General Terms and Conditions of Sale, which control unless it agrees otherwise in writing.
Any existing intellectual/industrial property rights must be observed. Due to possible
changes in our products and applicable national and international regulations and laws, the
status of our products could change. Material Safety Data Sheets providing safety
precautions, that should be observed when handling or storing Clariant products, are
available upon request and are provided in compliance with applicable law. You should
obtain and review the applicable Material Safety Data Sheet information before handling
any of these products. For additional information, please contact Clariant.
