MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK / GOA / BOKARO / PUNE
IIT – JEE: 2023 TW TEST (ADV) DATE: 23/01/22
TIME: 1 Hr. TOPIC: GOC MARKS: 80
SINGLE CORRECT ANSWER TYPE
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and
(D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
21. Which of the following resonating structures of 1-methoxy-1,3-butadiene is least stable?
(A)
(B)
(C)
(D)
22. Which statement is incorrect for the above reaction?
(A) Product is aromatic.
(B) Product has high dipolemoment.
(C) Product has less resonance energy.
(D) Product is diamagnetic in nature.
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23. Most acidic hydrogen is present in :
(A)
(B)
(C)
(D)
24. Steric inhibition of resonance can be expected in
(A)
(B)
(C)
(D)
25. Acyl cation has two resonating structures (I) and (II) :
Which statement is correct for (I) and (II)?
(A) (I) is more stable than (II)
(B) (II) is more stable than (I)
(C) Stability of (I) and (II) will be the same
(D) For some time (I) will be more stable and for remaining time (II) will be more stable
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26. Which order of acidic strength is wrong?
(A)
(B)
(C)
(D)
27. Which among the following pair is not a resonating structure?
(A)
(B)
(C)
(D) Both (B) & (C)
28. Resonance energy of these compounds will be in the order as :
(A) III > I > II
(B) I > II > III
(C) II > III > I
(D) I > III > II
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29. There are three canonical structures of naphthalene. Examine them and find correct statement among
the following :
(A) All C––C bonds are of same length
(B) C1––C2 bond is shorter than C2––C3 bond
(C) C1––C2 bond is larger than C2––C3 bond
(D) None of the above
30. Give the correct order of decreasing acidity :
(A) 2>1>3>4
(B) 3>2>1>4
(C) 1>2>3>4
(D) 3>4>2>1
MULTIPLE CORRECT ANSWER(S) TYPE
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONE OR MORE is/are correct. (+4, –2)
Partial Marks: +1 For darkening a bubble corresponding to each correct option. Provided NO
incorrect option is darkened. In all other cases, minus (–2) mark will be awarded in these parts.
For Example: If (A), (C)and (D)are all the correct options for a question, darkening all these
three will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening
(A) and (B) will result in –2 marks, as a wrong option is also darkened.
31. Which of the following group can participate in resonance with other suitable group?
(A)
(B)
(C)
(D)
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32. Which one of the followign pairs of structures represent the phenomenon of resonance?
(A)
(B)
(C)
(D)
33. Which of the following is true for stability between the two structures?
(A) PhCOO < PhSO3
(B) HCOO < CH3COO
CH3 CH3
(C) H3C H>
3C O
CH3 CH3
(D)
34. Correct order of +I effect.
(A) –O – > –COO – > –CMe3
(B) –CH2D > –CHD2 > –CD3
(C) –CH3 < –CH2Me < –CHMe2 < –CMe3
(D) –CH3 < –CD3 < –CT3
35. In which of the followign pairs IInd compound has less resonance enerngy?
(A)
(B)
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(C)
(D)
NUMERICAL VALUE TYPE
This section contains 5 questions. Each question is numerical value type. For each question, enter
the correct numerical value (e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
36. Find the number of compounds which are more acidic than H2O.
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37. Find the number of compounds which are aromatic.
38. How many of the following compounds have more stable than CH3––CH=CH––CH3?
39. Find the number of compounds having both localized and delocalised lone pair at N-atom.
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40. Consider the following groups :
How many groups can show –M effect when attached to a conjugated system?
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MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK / GOA / BOKARO / PUNE
IIT – JEE: 2023 TW TEST (ADV) DATE: 23/01/22
TOPIC: GOC
Answers Key
21. (D)
22. (C)
23. (C)
24. (C)
25. (B)
26. (C)
27. (D)
28. (B)
29. (B)
30. (C)
31. (A, B, C, D)
32. (A, B, C)
33. (A, D)
34. (A, C, D)
35. (A, B, D)
36. (8)
37. (7)
38. (2)
39. (5)
40. (3)
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