Material and safety Data sheet

Dissolved Acetylene

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

1.1 Product identifier
Product name ACETYLENE
Synonym(s) DISSOLVED ACETYLENE

1.2 Uses and uses advised against

Use(s) FUEL • INDUSTRIAL APPLICATIONS

1.3 Details of the supplier of the product

Supplier name: Ghani Global Group
Voice: +92 42 35161424-5
UAN: 111-ghani-1 (442-641)
Fax: +92 42 35160393
Email: [email protected]

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
GHS classification(s) Gases under Pressure: Dissolved gas
Flammable Gases: Category 1

2.2 Label elements

Signal word DANGER

Pictogram(s)

Hazard statement(s)
Extremely flammable gas.
Contains gas under pressure; may explode if heated.
Prevention statement(s)
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Response statement(s)
Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
Eliminate all ignition sources if safe to do so.
Storage statement(s)

Protect from sunlight. Store in a well-ventilated place

Disposal statement(s)
None allocated.
 PRODUCT NAME ACETYLENE
Other hazards
Asphyxiant. Effects are proportional to oxygen displacement.

3. COMPOSITION/ INFORMATION ON INGREDIENTS

3.1 Substances / Mixtures
Ingredient CAS Number EC Number Content (v/v)
ACETYLENE 74-86-2 200-816-9 >98%

4. FIRST AID MEASURES

4.1 Description of first aid measures
Eye Adverse effects not expected from this product.
Inhalation If inhaled, remove from contaminated area. To protect rescuer, use an Air-line respirator or Self Contained
Breathing Apparatus (SCBA). Be aware of possible explosive atmospheres. Apply artificial respiration if not
breathing. Give oxygen if available. For advice, contact a Poison Information Centre on 13 11 26 (Australia
Wide) or a doctor.
Skin Adverse effects not expected from this product.
Ingestion Ingestion is not considered a potential route of exposure.
First aid facilities No information provided.

4.2 Most important symptoms and effects, both acute and delayed
In high concentrations may cause asphyxiation. Symptoms may include loss of mobility / consciousness. Victim may not be aware of
asphyxiation. In low concentrations may cause narcotic effects. Symptoms may include dizziness, headache, nausea and loss of co-
ordination.

4.3 Immediate medical attention and special treatment needed

Treat for asphyxia.

5. FIRE FIGHTING MEASURES

5.1 Extinguishing media
Stop flow of gas if safe to do so, such as by slowly closing the cylinder valve. If the gas source cannot be isolated, do not extinguish
the flame, since re-ignition and explosion could occur. Await arrival of emergency services or manufacturer's advisor. Drench and cool
cylinders with water spray from protected area at a safe distance. If it is absolutely necessary to extinguish the flame, use only a dry
chemical powder extinguisher. Do not move cylinders for at least 24 hours. Avoid shock and bumps to cylinders.

5.2 Special hazards arising from the substance or mixture

Extremely flammable. Eliminate all ignition sources including cigarettes, open flames, spark producing switches/tools, heaters, naked
lights, pilot lights, mobile phones etc. when handling.

5.3 Advice for firefighters

Temperatures in a fire may cause cylinders to rupture and internal pressure relief devices to be activated. Cool cylinders or containers
exposed to fire by applying water from a protected location. Do not approach cylinders or containers suspected of being hot. This material
is capable of forming explosive mixtures in air.

5.4 Hazchem code

2SE
2 Fine Water Spray.
S Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Dilute spill and run-off.
E Evacuation of people in and around the immediate vicinity of the incident should be considered.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
If the cylinder is leaking, evacuate area of personnel. Inform manufacturer/supplier of leak. Wear self-contained breathing apparatus
when entering area unless atmosphere is proved to be safe. Ensure adequate air ventilation. Eliminate all sources of ignition. Consider
the risk of potentially explosive atmospheres.
6.2 Environmental precautions
Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous.

6.3 Methods of cleaning up

Carefully move material to a well ventilated remote area, then allow to discharge if safe to do so. Do not attempt to repair leaking valve
or cylinder safety devices.

6.4 Reference to other sections

See Sections 8 and 13 for exposure controls and disposal.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Use of safe work practices are recommended to avoid inhalation. Do not drag, drop, slide or roll cylinders. The uncontrolled release of
a gas under pressure may cause physical harm. Use a suitable hand truck for cylinder movement. Never open an acetylene cylinder
valve without the regulator attached. Gas regulator of suitable pressure and flow rating fitted to cylinder and manifold with low pressure
gas distribution equipment which controls fuel gas mixture and flame. The regulator and other equipment must be compatible with the
product and suited for the particular use. Never "sniff" acetylene as it may ignite spontaneously. Instead, carefully inspect the outlet
and if there are any signs of dirt, blow it out with a jet of clean compressed air or nitrogen.

7.2 Conditions for safe storage, including any incompatibilities

Do not store near incompatible substances and sources of ignition. Cylinders should be stored: upright, prevented from falling, in a secure
area; below 45°C, in a dry, well ventilated area constructed of non-combustible material with firm level floor (preferably concrete), away
from areas of heavy traffic and emergency exits. Post "No Smoking or Open Flames" signs in the storage areas.Refer to applicable
legislation on flammable storage quantity restrictions. Never transfer acetylene to another cylinder or other container.

7.3 Specific end use(s)

No information provided.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters

Biological limits
No biological limit values have been entered for this product.

8.2 Exposure controls

Engineering controls Provide suitable ventilation to minimise or eliminate exposure. Confined areas (e.g. tanks) should be adequately
ventilated or gas tested. Flammable/explosive vapours may accumulate in poorly ventilated areas.

PPE
Eye / Face Wear safety glasses.
Hands Wear leather or cotton gloves.
Body Wear coveralls and safety boots.
Respiratory If using product in a confined area, wear an Air-line respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance COLOURLESS GAS
Odour GARLIC-LIKE ODOUR
Flammability EXTREMELY FLAMMABLE
Flash point < 23°C
Boiling point -84°C
Melting point NOT AVAILABLE
Evaporation rate NOT APPLICABLE
pH NOT APPLICABLE
Vapour density 0.906 (Air = 1)
Specific gravity NOT APPLICABLE
Solubility (water) SOLUBLE
Vapour pressure 4700 kPa @ 25°C
Upper explosion limit 80 % to 85 %
Lower explosion limit 2.5 %
Partition coefficient NOT AVAILABLE
Autoignition temperature 305°C
Decomposition temperature NOT AVAILABLE
Viscosity NOT AVAILABLE
Explosive properties NOT AVAILABLE
Oxidising properties NOT AVAILABLE
Odour threshold NOT AVAILABLE
9.2 Other information
Critical temperature 36.3°C (dissolved in acetone and porous medium)
Cylinder pressure (when full) 1550 kPa @ 15°C
% Volatiles 100 %
Critical pressure 6,242 kPa

10. STABILITY AND REACTIVITY

10.1 Reactivity
Forms explosive acetylides with copper, silver and mercury. Do not use alloys containing more than 65% copper.

10.2 Chemical stability

Stable under recommended conditions of storage. However, sensitive to heat or shock and may become explosive.

10.3 Possibility of hazardous reactions

Polymerizes with evolution of heat. Avoid contact with curing agents, accelerators, and/or initiators.

10.4 Conditions to avoid

Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials

Incompatible with oxidising agents (e.g. hypochlorites), copper, copper alloys (>70% copper), silver and mercury to form explosive
acetylides. May decompose violently at high temperatures and/or pressures or in the presence of a catalyst. Hazardous by-products may
be produced when this gas/gas mixture is used in welding, cutting and associated processes.

10.6 Hazardous decomposition products

May evolve toxic gases if heated to decomposition.

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
Skin Not classified as a skin irritant.
Eye Not classified as an eye irritant.
Sensitization Not classified as causing skin or respiratory sensitisation.
Mutagenicity Not classified as a mutagen.
Carcinogenicity Not classified as a carcinogen.
Reproductive Not classified as a reproductive toxin.
STOT – single Asphyxiant. Effects are proportional to oxygen displacement. Over exposure may result in dizziness,
exposure drowsiness, weakness, fatigue, breathing difficulties and unconsciousness.
STOT – repeated Not classified as causing organ effects from repeated exposure.
exposure

Aspiration Not classified as causing aspiration.

12. ECOLOGICAL INFORMATION

12.1 Toxicity
No ecological damage is expected to be caused by this product.

12.2 Persistence and degradability

This product is not readily biodegradable.

12.3 Mobility in soil

Because of its high volatility, the product is unlikely to cause ground or water pollution.

12.4 Other adverse effects

No information provided.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Waste disposal Cylinders should be returned to the manufacturer or supplier for disposal of contents.
Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION

CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT

(ADG) (IMDG / IMO) (IATA / ICAO)

14.1 UN Number 1001 1001 1001

14.2 Proper ACETYLENE, DISSOLVED ACETYLENE, DISSOLVED ACETYLENE, DISSOLVED
Shipping Name

14.3 Transport 2.1 2.1 2.1

hazard class
14.4 Packing Group None Allocated None Allocated None Allocated
14.5 Environmental hazards No information provided
14.6 Special precautions for user
Hazchem code 2SE
GTEPG 2A1

EMS F-D, S-U

Other information Ensure cylinder is separated from driver and that outlet of relief device is not obstructed.

15. OTHER INFORMATION

Additional information The storage and handling of gases in cylinders. When using this gas/gas mixture for welding, cutting
and associated processes, additional hazards may be generated by the process such as radiation,
noise and fume. Risk assessments should be made for each activity to identify and quantify the
individual hazards involved. Please refer to the relevant Safety Data Sheets for the welding
consumables being used or, if available, the materials being welded.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:

The recommendation for protective equipment contained within this report is provided as a guide only.
Factors such as method of application, working environment, quantity used, product concentration and
the availability of engineering controls should be considered before final selection of personal
protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:

It should be noted that the effects from exposure to this product will depend on several factors including:
frequency and duration of use; quantity used; effectiveness of control measures; protective equipment
used and method of application. Given that it is impractical to prepare a ChemAlert report which would
encompass all possible scenarios, it is anticipated that users will assess the risks and apply control
methods where appropriate.

END OF DECUMENT