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Test Paper (TNG32)

The document contains 20 multiple choice questions related to chemistry concepts such as equilibrium, gases, thermochemistry, bonding etc. The questions cover topics like dissociation equilibrium of solids, Boyle's temperature, Gibbs energy changes for reversible reactions, properties of real gases, hybridization, molecular geometry, orbital interactions, phase equilibria and properties of ideal gases.

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Ansh Gupta
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68 views3 pages

Test Paper (TNG32)

The document contains 20 multiple choice questions related to chemistry concepts such as equilibrium, gases, thermochemistry, bonding etc. The questions cover topics like dissociation equilibrium of solids, Boyle's temperature, Gibbs energy changes for reversible reactions, properties of real gases, hybridization, molecular geometry, orbital interactions, phase equilibria and properties of ideal gases.

Uploaded by

Ansh Gupta
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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DATE:-18/11/2022

TNG32
Single Correct (4 &-1)
Q.1 At a certain temperature solids NH4HS and NH2COOHN4 are introduced into an
evacuated vessel. Consider the dissociation equilibrium of the species

NH2COONH4(s) 2NH3(g) + CO2(g). 𝐾𝑃1

NH4HS(s) NH3(g) + H2S(g). 𝐾𝑃1

They are allowed to simultaneously come to equilibrium. Select the correct statement

1. The ratio of amount NH3 produced by the species is equal to the ratio of their 𝐾𝑝 .
2. Total pressure exerted by NH3 is greater than the total pressure exerted by CO2 and
H2S.
3. Mole fraction NH3 cannot be greater than 1/3.
4. Pressure exerted by CO2 is twice the pressure exerted by H2S
𝑎
Q.2 A real gas obey Berthelot equation of gas that is (𝑃 + 𝑇𝑉 2 ) (𝑉𝑚 − 𝑏) = 𝑅𝑇
𝑚

The Boyle’s temperature for this is (a and b are constant)

𝑎 𝑎 2𝑎 2𝑎
1. 2. √𝑅𝑏 3. 𝑅𝑏 4. √𝑅𝑏
𝑅𝑏

Q.3 For a reversible reaction at 270C, change in Gibbs energy at standard state (∆𝐺 0 ) is-
690.9 R. If rate constant of forward reaction is 4 × 10−3 unit then value of Kb is [Kf and Kb
have same unit, R is gas constant]

1. 4 × 10−4 unit 2. 4 × 10−3 unit

3. 4 × 10−2 unit 4. 4 × 10−1 unit

Q.4 The following reaction was studied at 250C with initial amount of N2O3 equal 1 mol
N2O3(g) NO2(g) + NO(g)

At equilibrium the extent of reaction is found to be 0.3 mol for a total pressure of 1 bar then
1 1
∆𝑟 𝐺 0 for reaction is approximately (𝑇𝑎𝑘𝑒 10.1 = 10)

1. 0.099 J 2. 4281 J 3. 5706 J 4. 2016 J

Q.5 PClxF5–x molecule will be polar and non-polar for what values of x respectively?
Polar Non-polar Polar Non-polar
(A) 2, 3, 5 and 0, 4, 1 (B) 0, 2, 5 and 3, 1, 4
(C) 4, 3, 0 and 2, 0, 4 (D) 2, 1, 4 and 3, 0, 5
Q.6 Calculate the percentage of p character in the orbital occupied by the lone pair of
electrons in water molecule. [Given H_OH is 104.5° and cos (104.5°)
= -0.25]
1. 80% 2. 20% 3. 70% 4. 75%
DATE:-18/11/2022

Q.7 Consider the following statements and select the correct set of codes using T(True) and
F(False) in the given sequence.
(I) PI5(s) does not exist due to steric crowding.
(II) All possible angle in BF2Cl are 120°.
(III) In N(SiH3)3, lone pair of N is present in sp3 hybrid orbital.
(IV) d orbital used in hybridization of P in PBr5(s) is dz2
(A) T F T T (B) F T T T
(C) F F F F (D) T F T F

Q.8 Which of the following statements is correct for

1. It contains 𝑝𝜋 – 𝑝𝜋 and 𝑝𝜋 − 𝑑𝜋
2. It has regular tetrahedral geometry.
3. 𝜃1 > 𝜃3
4. Plane which contains maximum number of atom is 4.

Multiple Correct (4 & -1)


Q.9 Choose the incorrect statement (s) from the following.
1. HOMO for N2 molecule is 𝜋𝑏 MO.
2. LUMO for N2 ion is p* MO.
3. HOMO for CO molecule is NBMO from C-atom.
4. Among halogens, pale yellow colour of F2 only is not due to HOMO – LUMO transition.
Q.10 Which of the following is correct order for indicated bond length?

Q.11 Which of the following statements is/are not correct?


̂ in (SiH3)2O is larger than that of C–O–C in (CH3)2O.
(A) The bond angle 𝑆𝑖𝑂𝑆𝑖
(B) BF3 has more Lewis acidic nature than BI3.
(C) p𝜋 −d𝜋 bond electrons get delocalized between B and N atoms in B3N3H6.
(D) CH3NCS is linear, while SiH3NCS is bent structure.
Q.12 Consider the reaction at constant temperature 300K
A(g) + B(g) C(g) + D(g)

At any tome ‘t’ partial pressure of C, D, A and B are 3, 3, 1 and 1 atm respectively. The ∆𝐺
at time t is 12 kJ. Select the correct statement

1. Partial pressure of C at equilibrium is less than 3 atm


2. Partial pressure of A at equilibrium is less than 1 atm
3. ∆𝐺 0 of reaction at tome ‘t’ is 6.52 kJ (approx.)
4. At equilibrium ∆𝐺 0 and ∆𝐺 both are zero
DATE:-18/11/2022

Q.13 The correct relation is


8𝑎 𝑎 𝑃𝑐 𝑉𝑐 3
1. 𝑇𝑐 = 27𝑅𝑏 2. 𝑃𝑐 = 27𝑏2 3. Vc = 3b 4. =
𝑅𝑇𝑐 8

Integer Type (4 & 0)


Q.14 An equilibrium PCl5(g) PCl3(g) + Cl2(g) is maintained at given temperature in a
cylindrical system with movable piston. The concentration PCl5, PCl3 and Cl2 are found to be
0.01, 0.4 and 0.4 mol/L respectively. In this system 4 moles of Cl2, 8 moles of PCl5 are added
and 0.2 moles of PCl3 removed which changes the volume by x time. What will be value of
equilibrium constant at new condition?

Q.15 Consider the equilibrium.

PCl5(g) PCl3(g) +Cl2(g)

In initially 1 mol of PCl5 is present in 1 L vessel, vapour density of equilibrium mixture is


69.5 and degree of dissociation is x%. If equilibrium into a vessel of 2 L capacity and new
𝑦%−𝑥%
degree of dissociation is y%, then is (Take √5 = 2.2
2

𝑃
Q.16 If volume occupied by CO2 molecules is negligible, then calculate pressure (5.227)
exerted by one mole of CO2 gas at 300K. (a=3.592 atm L2 mol-2)

Q.17 An evacuated gas vessel weighs 50.0 g when empty, 148.0 g when filled with a liquid
of density 0.98 g mL-1 and 50.5 g when filled with an ideal gas at 760 mm Hg at 300K.
Determine the molar mass of the gas. (Use R = 0.082)

Q.18 Find the number of compounds of Xe which is/are associated with 180° bond angles.

Q.19 Find the total number of chemical species in which mentioned bond length decreases
due to back bonding.

Q.20 The number of triatomic molecules, which are nonplanar is ___________.


SnCl2, BF3, BeF2, OCl2

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