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SAFETY DATA SHEET

DEPOSITROL BL5313
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name or designation DEPOSITROL BL5313
of the mixture
Version number 6.2
Revision date 15/04/2020
Supersedes date 27/02/2018
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Deposit control agent
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
SUEZ Water Technologies & Solutions Belgium BV
Toekomstlaan 54
Industriepark Wolfstee
2200 HERENTALS
tel : +32 14 / 25 91 11
e-mail : [email protected]

1.4. Emergency telephone number

Multilingual emergency number (24/7)

Europe, Middle East, Africa, Israel (Europe and English

language speaking countries):
+44(0)1235 239670
Middle East & Africa (speaking Arabic):
+44(0)1235 239671

Official advisory body :

ANTIGIFCENTRUM
Bruynstraat 1
B-1120 BRUSSEL
+ 32 70 245 245

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 as amended
Health hazards
Serious eye damage/eye irritation Category 2 H319 - Causes serious eye
irritation.

2.2. Label elements

Label according to Regulation (EC) No. 1272/2008 as amended
Hazard pictograms

Signal word Warning

Hazard statements
H319 Causes serious eye irritation.

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Precautionary statements
Prevention
P280 Wear eye protection/face protection.
Response
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.
Storage Not available.
Disposal Not available.
Supplemental label information None.
2.3. Other hazards None known.

SECTION 3: Composition/information on ingredients

Mixtures
Chemical description Aqueous alkaline solution of organic salts and polymer
Chemical name % CAS-No. / EC REACH Registration No. Index No. Notes
No.

Tetrasodium 10 - < 25 3794-83-0 - -

(1-hydroxyethylidene)bisphosphonate 223-267-7
Classification: Acute Tox. 4;H302, Eye Irrit. 2;H319

The classification of the above substance(s) is given, including the hazard class, category code and hazard statements which are
assigned in accordance with their physicochemical, health and environmental hazards. Please refer to section 16 where the full text of
each relevant H-statement is listed.

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation Move to fresh air.
Skin contact Take off immediately all contaminated clothing.
Wash off immediately with plenty of water.
If skin irritation occurs: Get medical advice/attention.
Eye contact Keep eyelids apart.
Rinse immediately with plenty of water for at least 15 minutes.
Get medical attention if irritation persists after washing.
Ingestion Rinse mouth.
Do not give anything to eat or drink.
Do not induce vomiting.
4.2. Most important symptoms Irritant effects.
and effects, both acute and
delayed
4.3. Indication of any Not available.
immediate medical attention
and special treatment needed

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing Dry chemical, CO2, water spray or regular foam.
media
Unsuitable extinguishing None.
media
5.2. Special hazards arising Oxides of carbon and phosphorus evolved in fire.
from the substance or mixture

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5.3. Advice for firefighters
Special protective Self contained breathing apparatus. (CEN : EN 137)
equipment for firefighters Protective clothing (CEN : EN 469)
Protective gloves (CEN : EN 659)
Helmet (CEN : EN 443)
Special fire fighting Use standard firefighting procedures and consider the hazards of other involved materials.
procedures Prevent spillage and fire-fighting water from entering in public sewers or the immediate
environment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Wear protective clothing, gloves and safety goggles.
personnel
For emergency responders Use personal protection recommended in Section 8 of the SDS.
6.2. Environmental precautions Prevent from entering sewers or the immediate environment.
Accidental release of large quantities into the aquatic environment may harm aquatic organisms.
6.3. Methods and material for Absorb onto inert material and dispose of according to Hazardous Waste Regulations.
containment and cleaning up Remove small spills with plenty of water.
6.4. Reference to other Please refer also to section no. 8 'Exposure controls' for further information.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe Alkaline.
handling Do not mix with acidic material.
7.2. Conditions for safe Protect from freezing.
storage, including any Store containers closed when not in use.
incompatibilities
7.3. Specific end use(s) Only for professional and industrial users
Shelf life 720 Days

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring Not available.
procedures
Derived no effect levels Not available.
(DNELs)
Predicted no effect Not available.
concentrations (PNECs)
8.2. Exposure controls
Appropriate engineering Adequate ventilation to maintain air contaminants below exposure limits.
controls
Individual protection measures, such as personal protective equipment
Eye/face protection Safety goggles.
CEN : EN 166
Skin protection
- Hand protection Neoprene gloves (Protection against unintentional short-term contact)
Nitrile gloves (Protection against unintentional short-term contact)
Coating thickness: 0.5 mm
Penetration time: > 480 min
CEN : EN 374-1/2/3/4; EN 420
- Other Protective clothing.
CEN : EN ISO 13688; EN ISO 6529; EN 14605
Respiratory protection In case of insufficient ventilation, use a breathing mask with filter type: P2
CEN : EN 140; EN 143; EN 149
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Thermal hazards Not available.
Environmental exposure Prevent from entering in public sewers or the immediate environment.
controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Colour Yellow
Physical state Liquid
Odour Odourless.
Odour threshold Not available.
pH (concentrated product) 12,5 Neat
pH in aqueous solution 11,3 (5% Solution)
Melting point/freezing point -7 °C
Initial boiling point and boiling 104 °C
range
Flash point Not applicable.
Evaporation rate Not applicable.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Vapour pressure 18 mmHg
Vapour pressure temp. 21 °C
Vapour density <1
Relative density 1,26
Relative density temperature 21 °C
Solubility
Solubility (water) 100 %
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not applicable.
Decomposition temperature Not available.
Viscosity 32 mPa.s
Viscosity temperature 21 °C
Explosive properties Not available.
Oxidising properties Not available.
9.2. Other information
Pour point -4 °C
Shelf life 720 Days
VOC 0 % Estimated

SECTION 10: Stability and reactivity

10.1. Reactivity Not available.
10.2. Chemical stability Material is stable under normal conditions.
10.3. Possibility of hazardous Not applicable.
reactions
10.4. Conditions to avoid Protect from freezing.
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10.5. Incompatible materials Avoid contact with strong acids and oxidisers.
10.6. Hazardous Oxides of carbon and phosphorus evolved in fire.
decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Product Test Results
DEPOSITROL BL5313 (Mixture) Acute Dermal LD50 Rabbit: > 5000 mg/kg (Calculated
according to GHS additivity formula)
Acute Oral LD50 Rat: > 5000 mg/kg (Calculated according
to GHS additivity formula)
Components Test Results
Tetrasodium (1-hydroxyethylidene)bisphosphonate (3794-83-0) Acute Dermal LD50 Rabbit: > 5000 mg/kg
Acute Oral LD50 Rat: 990 mg/kg
Acute toxicity Based on available data, the classification criteria are not met.
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye Causes serious eye irritation.
damage/irritation
Respiratory or skin Based on available data, the classification criteria are not met.
sensitisation
Specific target organ toxicity - Based on available data, the classification criteria are not met.
repeated exposure
Specific target organ toxicity - Based on available data, the classification criteria are not met.
single exposure
Carcinogenicity Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
Information on likely routes of exposure
Ingestion May cause irritation of the gastrointestinal tract.
Inhalation Prolonged or excessive inhalation may cause respiratory tract irritation.
Skin contact May be irritating to the skin.
Eye contact Causes serious eye irritation.
Symptoms Not available.
Aspiration hazard Based on available data, the classification criteria are not met.
Mixture versus substance None known.
information
Other information Not available.

SECTION 12: Ecological information

12.1. Toxicity
Product Species Test Results
DEPOSITROL BL5313 (CAS Mixture)
Aquatic
Crustacea 0% Mortality Daphnia magna 1000 mg/l, Static Screen, 48 hour, (pH
adjusted)
80% Mortality Daphnia magna 2000 mg/l, Static Screen, 48 hour, (pH
adjusted)
Fish 0% Mortality Bluegill sunfish 2000 mg/l, Static Screen, 96 hour

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Product Species Test Results
Rainbow trout 2000 mg/l, Static Bioassay with 48-Hour
Renewal, 96 hour, (pH adjusted)
LC50 Fathead minnow > 5000 mg/l, Acute toxicity, 96 hour,
(Estimated)
NOEL Fathead minnow 3440 mg/l, Acute toxicity, 96 hour,
(Estimated)

12.2. Persistence and degradability

- COD (mgO2/g) 137 (calculated data)
- BOD 5 (mgO2/g) 1 (calculated data)
- BOD 28 (mgO2/g) 3 (calculated data)
- Closed Bottle Test (% 2 (calculated data)
Degradation in 28 days)
- Zahn-Wellens Test (% 2 (calculated data)
Degradation in 28 days)
- TOC (mg C/g) 46 (calculated data)
12.3. Bioaccumulative potential Not available.
Partition coefficient Not available.
n-octanol/water (log Kow)
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil Not available.
12.5. Results of PBT and vPvB Not a PBT or vPvB substance or mixture.
assessment
12.6. Other adverse effects Nutrients: P : 45,7 mg/g, N : 0 mg/g

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Contaminated packaging According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 15 01 10

15 Waste packaging; absorbents, wiping cloths, filter materials and protective clothing not
otherwise specified.
15 01 Packaging (including separately collected municipal packaging waste).
15 01 10 Packaging containing residues of or contaminated by dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.
Disposal methods/information According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 16 03 05

16 Wastes not otherwise specified in the list.
16 03 Off-specification batches and unused products.
16 03 05 Organic wastes containing dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.

SECTION 14: Transport information

ADR
Not regulated as dangerous goods.
RID
Not regulated as dangerous goods.
ADN
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.

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SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Not listed.
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at
work, as amended.
Not listed.
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
Not listed.
National regulations Not available.
15.2. Chemical safety Not available.
assessment
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

SECTION 16: Other information

List of abbreviations
EC-No: European Commission Number
VME: Valeur moyenne d'exposition (Time weighted average)
COD: Chemical Oxygen Demand
IATA: International Air Transport Association
CAS: Chemical Abstract Service.
CLP: Classification, Labeling and Packaging REGULATION (EC) No 1272/2008 on classification,
labeling and packaging of substances and mixtures.
CEN: European Committee for Standardization (Comité Européen de Normalisation).

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TWA: Time Weighted Average.

STEL: Short-term Exposure Limit.
LD50: Lethal Dose 50%.
LC50: Lethal Concentration 50%.
EC50: Effective Concentration 50%.
NOEL: No observed effect level.
BOD: Biochemical oxygen demand.
TOC: Total Organic Carbon.
ADR: European agreement concerning the international carriage of dangerous goods by road
(Accord européen relatif transport des merchandises dangereuses par route).
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways (Accord européen relatif au transport international des marchandises dangereuses
par voies de navigation intérieures).
IMDG Code: International Maritime Dangerous Goods Code.
RID: Regulations concerning the international carriage of dangerous goods by rail (Règlement
International concernant le transport de marchandises dangereuses par chemin de fer).
References Safety data sheets of raw materials.
Information on evaluation The physical, health and environmental hazards of this mixture are assessed by applying the
method leading to the classification criteria for each hazard class or differentiation in Parts 2 to 5 of Annex I to Regulation
classification of mixture (EC) No 1272/2008 (CLP).
Full text of any H-statements
not written out in full under
Sections 2 to 15 H302 Harmful if swallowed.
H319 Causes serious eye irritation.
Revision information SECTION 2: Hazards identification: Supplemental label information
SECTION 3: Composition/information on ingredients: Composition comments
SECTION 6: Accidental release measures: For emergency responders
SECTION 8: Exposure controls/personal protection: - Hand protection
SECTION 11: Toxicological information: Acute toxicity
SECTION 11: Toxicological information: Carcinogenicity
SECTION 11: Toxicological information: Skin corrosion/irritation
SECTION 11: Toxicological information: Germ cell mutagenicity
SECTION 11: Toxicological information: Reproductive toxicity
SECTION 11: Toxicological information: Respiratory or skin sensitisation
SECTION 11: Toxicological information: Specific target organ toxicity - repeated exposure
SECTION 11: Toxicological information: Specific target organ toxicity - single exposure
SECTION 16: Other information: Further information
Training information Provide training on safe handling while considering the type of application and exposure scenarios.
Based on EC Directive / (EC) No 1907/2006 (REACH)
Regulations (EU) 2015/830
(EC) No 1272/2008
(EU) No 1357/2014

Further information Correction in Section: 8,11

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