"wocte Rasa Reachio «Free Rabie) c) Re Tnternedite [fe QR-X+ No — ¢ Nox] # Bowd ROR: OT >C-& Del 2e-F. B 3° Rodicols Never combine. Hoey Disproportionate» ert ds A) conbinodion 8) Dis pro Pow tic voadion et. ute ZS (Rearmginel d= ee ote [ee ; = Pa eos bn jor Cis NOY OrOrn tt, Srey [Mita Co > Ce Wispropor bion ation). Fy oy ct Ne ey Gop Bthea—~ a) tL i aT tho No eta eat ia Na ee tho ie c F) eta Na HET “a Ani tho pet Aa Ph om Crafer) Short Notes. |R,—ese—e, + aalves of ed = 3+ (R-R, if B, Pr, Bu). i LA) trimer) . A) ae Grigor) 6] pu Lone | drogenos addition # concerted (MET: drogen adsorbed on rteted S01 foe. Meso o ee —/ £25 4) Treas Fer tala saobion, = |NK=WR [Hs0n AWHENH V's by jonobing eget (Balicy? tony c-e Lae eae te Redaced byib He Ro [itt does not do Ink Addisons _ 5) Soda Line Decorboxylahun » 4 7 . stobitrt easter Be Ree a aioe "dg 69-0 cook 1A Seon’ Sar Pa q AS cone’ — Ares coer Roo Me + 5 Eee, R-g +20, 2H, + .2Nob+20n0 # Free Redrcod Bees Sume.ug Wwvtz Coon 0) er ce© E, Elimmobyon Mechensrs: = orn bend < en, bee De ne + Corbocudion Pei (2- clef) # pole « [Reactor] ' Effect Shown * Flere feet sh = is required for Elirunohon a oe P should be nore: He previous ones: R=H isolopic: Tipntue? rH Alkyl > Alkyl: ates pa rich migrolos Firet- + The Wedge- Dash CoflFit of Migros * es ee aed Pe ban eee Sy-) Nu,foH Bijon [even Pron $pay: ner g Co) hing Ge oP OW G ie). is ond Intertedia a-Si, | #forrution of |G ae 5s RDS- free Shovld venain sone after robin 5 Conc. H,$0, JW3PO, i a[u© | KHs0,, Held, . | WP Fornoton of Corby cation —> R-P-s. # Saytre FE Alkene_*s_ For * ser gir ee ee oO Ge Se Sache i) FEC IU (ne rete Ea 1b. G ded td @ Elechrophillic Addition. Decth-t P= OK | 3 HI, HBr, Hel, O8r, », eHorpH® | Ho®, il-Hz8O,. 4 x( > XK ee € Red”)) NAA % Lane ae sex He. fee a a hat a loti Carbocotion- 0 eee Kno fr ongert ey y $ Ant; Additron ee (1-2 preduel) easels ¢ 84, £45, 522) Moet, HOGr, LA) Ai 8, Mego Na /-BE> Rocennic fleachon: A Aliene > Alkgne- Vx ae aN ( As 220) No reso gniki the Nucle where wore’ stoble c@ON ie ye (ars ee ee le) Todo lactiaobon. + [T, [2K] H Forretion of cyclic cster 2 9. A am 4q Ma ye t r ao fen bered ao nuost be horned: Bri Poche be tee US nite IT in port ee 2m, PPh; mM), 2nlPM)gcuy £29, 2n0 | ofFly 4 05¢c4), Tre no inforily, Cod Pen ee then — ai Dronl J = = ° Kon lone Wier v/s int Add Add bion eoaes Sy bee? wre (teA) 900 — er Xe). NAa wats ay Osep) 1) Tonic Alyes + a — Allon), + CH, i Be,0 +H,0 — > BeloH), + CH, Gg t¥s0 —> Mgvon), GH, “oe + Nz ——> WOW + coy, U, op cals +H,o ——> Calow), +e, wy Ip creonei fei via AlCl, A AN ts AE A te 1) Polymerisobion of Alicynes A cul AGI22) roerpers es as) (Bia) 4lcwecw) acca PF Via Free Radical mechanisi- | 17) Ozono Ozonolysiz_of ee ee aN 4 2NH, —> 2MaNH,! + WLP) R-C#0H + NaH, —» R~czcO a) This ts further used to increase Chapr, lea ght in ovgenit tee a1 ff = S BOLO 2 aos Ber O75 || aS gyidalion ¥ ' $ Terminol AlKp%8 forms Salt on air Reoebion wilh Wa/tig. WH a) ae no re” oor Arcot, Aresc-Ry > pb Bg A 18) Reduction of Arore Con pounds. 4In 0 sgskn, MIDDLE Ring ' rrost Reockive « tx) De, -Ch= as ao con aaa Ketores. | too0] fie, mR ee oy, eae EE, Moe Tie k t 2 PP H-e-¢4 ep ey Po e) KAnd, Lal CO ca # The more e- rich ring 15 ox dreed first. Blar. 20 arene by v2.0, | 500% at i Leap, Arbydeide (8 Porned iS omdiredl Fo0%. wane bere y, oy wits i) Sees A to% VS °C) Seep on 526-6 ic ee " Coo a aoe =F oe POS [a ace 22) Birch Reduction of ay Cong #1 Bick — ee 2 roles. Me lig WM, OH Bin Reduction, fhe nore e~de ficvent Ring qt cen first Go 22) Electrophilic Arordic Sobelitylion. Ba) Fornobon of om coreplen is RDS. YP-H isotope Effect is not Shown excepi im reversible EAS- C)EWE > Meta Director E06 > 0-p Director ( Paro. > orthe) Rab of — 1 SSO > GO > @. ee Bi ai w°C=1). 4 Cen) EDs Friedel Craft Alkylahon 1d) Lewis Acids Like BF,, Alk,iFeX; are ») elem Re orrungerent. ¢) Rearrange nent a4 take plece. with UFe Ct; i Ce gee feds,von of Cyanide with Kea He wno, £23, = Hno, 2 M0, 10 ee as -Ne0, ir CC] Voz +0 Ae, a Fen, a CR le uch cer oo. a . ssible e336 Antlp, PR mnt Altaf ia Ry seal ay’ AAs 40] seal ay’ AAs 40] [eal E] Aley ws oO +c, 3 fly Phy Sa Hg th ond) Fr) oO eo Cesc cody AlC!z 90% Yor ce) Pheacls ond Aniline do not Cxve ; Friedel Craft Reae tons K Benzene Rings with Ewe alsode not | Reset Give FCA , inShead Nitmben zene ts usd &¢ Solvent for FCA- €) al Heglokion — De Attegshion x On Groft Acy lation. # no reortong erent, no Poly Acubtron- RIt is OT iaakh {2 a hohe "cy ahem Fi Ore x? @ cuegor) t fol for Atocking 1 ka pees Gen zene a 7 27) Phokohalygenahion of Alkones Tribvntion > 1 4% try2% (endo, ord AY beep? x? ole ch, + w( RDS) 79 or cn Pa cans LANE ater a Testo ex, ford) x +x —> 54 chy tty, —> Cry - 0 *P-H Ieotopic er Fee MESS Ci Br, (ere é 3 13-9:5 Ge fois shone > I vendo selective s 1: 9021600. 1 } 29> Su, Reaetrons: # carbocation 1s forred Fs) fae Mel x Ale Cai) oO #®6e1) Q TO} ae Sra Ceram? Bea oy # Friedel Crott A ee iis Reveesible. # ror ere ane ae Gos) Ovi £, a es pas ee 1 2 Dee ana * eat Invert product Dorineter aiodn Probie Solvent i's prefFered - Lee OTP > -ots} ee ate z § —ON, F oui CEN (Ne Fa Plate), ee aceetae Hence, Rate OF EAS: H, >GO>GT. “WP , cot oe, ye fer form hod by Renown,24> fN, Reactions. + Res AP ond 6 must be in Arty n NGP i's not observed ta tarpon With 2 and L-& in syn fos. feat | 4 Leno --* cf Us AP iN oie cid a] Bite MSi, Om ow oe Buy tl : ? ef ave CM] Lsobstrate] | Nucteoprile | @) noi es Ag theese pe taction: TBS. ng ony sp OE “We p Hn x Ey & tncreape ROR oF Sw, Ce sides ygegee® >2*> 3°» concerted Mech”. | es wo. % Re defictency > Crowdin T PB Au ee eg # Polar A, paid solved d = ne # eee ba Neo (jes) AN, Doth 9 SNq foeney' (RA) yt sue A] Robeok a CHyael ° te oe, ae Bard. . yer ea Ht Necleophilistys TO>B/O>A® >f© Cfrobic). |e °° = FO 2L1@ >, rTeCAproti) | Fer, REP, beth moet be tn easel eepltee % i yn VeFrodad> fiw. K, Cévbstob) os Wc) Taet __K [Sebstrale ] Kdsvbstobe]f4)) + ce 30> Honsdiecker Reaction. Reagents Br, 20 Free Rodizal epee echo is [R-Foony 8, th Pb Finsetiiale) Ris We pret Sea Ves clectrophiie Made kren with 4, [el, A] “S37 8r bs, ne Pe yay * J spl Cor tatra Reach | Dd. + Iaistinte doch ac i Men force of Ag Br (J). # Ifwe use S/e,= A)is1 Ropiow — Norral Product Wz Ratio 7 peodtR— ReooR: since, cleavoge Of T, is foo Slow 31) Neighboring Group fartrcipation + Retention Froduct Doninckes- # (00-3000 times Paster tWinest Mv | # Polor Profi a re — Ihe Ke! c "0 g a 34 AIL-KOK, Ale. Mon, HOOKS, we don't vse chy/Z, of pelpbeipalis || 2M, manna, Dbu, OOM ee heppee | ces . am at Crd 82> E, Elminotion- 4 Rote « [Sobstrete ] [Gese] Peoncerled Mech, Anti Clinmotion # Elemental Effect Shown, P-H isebopre sek * HEAT Requived a(C-x @-3)'= (C-H B&S). XK RoR« Stobilily af Allcene Forrsed- IGelvest is pref TRON. CHOHsKON = OOK? | 0 BEY © Greek mG DX AT Phe, hie Roca (5H)1) Nucteo; +RMgX —>» #CMCTS is Forned. mee fn, 8 Ray | Bee it ¥ | Rsinw cing Flip is _ me Sud a ovat Fr tee > tata ~~ (Hof frien) “s Fe, Phe, By ioe, BH, MEY sue $88 o(' or van e] ie ees Seo R Ron wt oo Kok ere L-6). Gurls Reecin yer rts “he vt, Sat We St “Teves aes R- he ad ‘my ala) OO tp ret ¢ . PR. Balter ingey gris ae! ee No rx” (THFore) K Roh Sa OR ety ¥) DR be 2 Reon 33> Hoffmann Fiicties Me i Hp, fo tA". ot Cae, Ao at Pee wage ar es Sadly an aK KEE ad 4] to Bois K, * 748 ]eu a) N (he), + CHOW "Re Brie a 2 EN seseen 2) Nay iy Con ee ag Pat Fajen Cor), rae TI ped Gose A" 's Fosletl : =eyy “a Be +My 4) Ph—-Mg = a(Ph, ) Ph-Mg 2Be #4 Aon —> 2 Ph) _ Avo gfe $s) prmgaes weet — ML 24]) 17 x) PM eR cn pmel (es cola bt YORE ory fetch sts 05) RUBEN Ge R-% seg > Rae llg sg A 35 Preps of Sun Viewal Diol Fwe don} use polor fate Solvent ag Ta doll Aue Red, Raciaae enya? is Destroyed: 2 en |e] Ak + ftgs — 00 40% mur We, egies AAT ig Addit on 4 ipa ci ae ws tp CH=CH, GIO604 | 4 ote CY homey AyA CSRetatenne a mama te ett tee etter ere eran eee 36)Darzen's Reoetron. Ai) Caen Satis Act (Retention) *® R ao Reel ( Tryersion) & aye Sot, —e (emers) ! R-cony 22th » Reoct, # Phenol [Vinghe RON don!t reo. | “37> Clemmension Reduction H# Inoles (2H for bere! Cleneaaten u ; DAK, Bue Apes oth eee de ¢ 2 wl Sh 9 aie | “NX 24 38 wolfe Kish nerr aie : De oe, (ee (i) KOH Ri 4 eleven Reduction should nol be vsed Wik Acd Sensitive Hort Wolf —Kishaas Reduction shovtd not Ube dsed with Base. Beas Sensitive groups. 34y 4 Mechanism- | ox Ac eet eesty P RDS iS Kenetion oF brrst corbonity, Ve i ssf we a cee CES B8 hee Kee ont, 4 Age Ag ¥0, ye Wn re Acidic A seth Nonot Atteched . a Thy ticks 2 +o pice oa 4 F]cty-no, — cut, ih: 6] cH-czw vies # Net fe vealed “i |__Nebevoles T, —> 3 ime yt a a MoD,» OraAi-4 +Nucleophitic Hydride Doner- & TA eae F Electrephitic RA = OLGAL EE or al PIGAL-H Acts Irte L:AH,, FNaGHy POA =” De ee Meet See Cony Fe out, + HOCM. Woon ee Gives Holo fever abe won Tavtoner sation fore one trelone. x ee ay saat | ¥ a Ae ae ae false od Rede of Ral 2 -F >-c > -Br>-1 sees i) ee Me o Popo) A | ieeseu 2, 2 oy nes Nor Ea Roh] RM Non eh tron Mea Athy A-c 4 40) Holo farm Reaction. pte atts 7 a8 pea hie BL ant AS LA CCH, “Wao nen | @ R-cnza ATodoforns testig atest gn" FMF yg p [ran | | PE Ketones to ge gellow & CHE WRG eb Rew semede gare REN OM 4 42) Willianson's ¢ther_synKesiz. eee =P, © R-CPNe' taNu Sw2 AF i 44) Are $M ae ul or Fit Atteck Gill be on M085 crowd Koost Steble c@ leaues Fash nati zatyon 3 TAL Hy ae | A) << nae me 9 GEA H® ~_ OH. FA tire ” pce N Eat frie — NH, R-ceEN o fe Ale J. HO 8. ol 8) Acid + Snoles ie as om phe > legates | 4 Hp He H a@ orton Liat, al, R= neok td pide Cy > Bs an Bw Soe its Son IL? colle oon de, Kolone Irines icy Holide. cre thet fk NBGU, Reduces, Aldi Acid. Holide 182% r Meo, 0, 4 Al; [H0,0, [V9 Co 0s, CL” on_of Phenol from Conwe- O-0- HHP Ho nega TB Herth KY | ey Geox oe & a and +26, isn (4- Fm) Sip tee jes ex ! ARs oe oh Ally oy x —_—_ ee: crce) oot epee CXH) ON My 4» fbtrabes of Arenatic cong. | a Foning cre oO E 4350, [Meow , Mo 4s, = 4] > co (nee) ee & Corey Es 49) HofPrmonn Bronemide Degrodeion a “Reegents Kou 784.) dy Kon 0 KOM R- Emu, br, A-b= yu Be pO H,0.t co, + R-Ni, = R ¥ R055 is ce Cpa one F oo Rd to RB dees nok chenge During, | t A) R-coon NS. Fg) -c —F in, robs yu, MH, eA CN E ° (Double Oegrabkin)| 14) MeNe; ¢ NK,-NH, NaN, +2, 0 Ffroduction 651% 4) 6, n [FeBr, of BO For BAS c)br, s40 eal 1 ©) BKBrO, | HDF. vy £ wy MH y SWEATS CH, KOBe oe Ch u CH, C004, aaa Ss » Gua) Gobel Pholoride Synthesis. wy oe Sole ae 4 cept FR-cH, ee Y a fs a) i. Nis R-conn, #H,0, | SN, + Inversion vn con Fig 50> Corbarty| Test. # It is Given b, R-fin, Ae R-N=CO| PROS» Rar af 1° Amine wilt Grbeve # Zmoles of KOH ore used 51) Nitrotion by conc HNS 1 Avsines. Come. eT Comite N20, | me TD Y for) : as mn C Oy aie Ct act An Mol) Cary CH [Ee te formohion af Aniliniver | 62> Diazokizabion. + ‘ino, Tate, FI? R-NH-N=O-S R-Wen-owe <— (tsa) Iv? 5 ce |4ITP Aliphatic, oR-Pew te wf) R-Ne, Diazoniyrs Sodt pet ett, : om papi se ren Hy o-ste nin, Ima NK, “oe Heo, 4am Nk ot 8) NM, be, Nay ae o-se mu 2] Tf Aromatic, [ th—-N= Pe i'g auth at O-S°C P-1-0 wage + Ry,apy Basic ey Acie Te rake a ihre hit a Diazmivn oop is Ewe on Diazonion sulk. hye Tollen’ 5 Test isco Basic Med "tes ond EDC on Rin TT] Necleophibic Subst fiasnivn | d oo Til, os ly etl or + Gy" F] ori & tay cr* pikes HS Eo Free -fedicel_, Sond niger, Faster wiih] > SoAe Mech > Galleon as 53) Reduction in Acidic or Slee tli ee ee Fe Re dnchontbyiRed PAT] B crm [Na-ey- eRe = aa Tollen's Reag yok ° d “EH, Ht om, CHCl, Cyd, lemjaxotol , oe ° J Ge Sool, ive olla oO Nee ~ * Tesh 1 Jon ee Kee, ee 7 v] opt Tolley me 55) The Fehlings Solution KT is a Basic Medina Test |x = Alioing + sere Pottogivre Tnbrole O,, (Proc lelles Salt) ion ea Soluhion). Paobin tty RE 2 44,05] Conipleg ed ppt) [fat have Cnoliable H] if forrmbion not) % Robe of Rx" K Rete of form ‘ ore ales give Febling!s Syhr"| (c Bape 10 cb | Aly Fem Geese eve Rehtingt| | ne y a ion soe ee Al | xed P is used to absorb I, Gos. 2 Molen lela f- “MH Riu, p- cu, tleie Coles) COW P/ur ae 3 coos FT ae $7) Aldol Condengafion Reagents: dil NaOH, dil KOM, Nal, Ba Cow), ae+ dol Sel Phos order 2 at low cone. 04 ond hos me at Raong cone. one ite Port no Aldol . Yes Aldol aA) 3% Q Retro aldo] + @+0 mise ehh Oe oH ' vehi anu 5 Connizzaro Reaction. po REACH of«. {no d-H). (Ros + Migration of 4.) # ae order + high es + ke Lenco) Lowe) Acidic hs See rm aa Me™: P ae fore “nee ar sani Asem tt Sire AOS = Br) Lay loy™>s, | 4. eae (enh MPMI Te Rove Ao aa |gtre Kiewond al “| FT, conn, ee bate 4 60) fer kin = ay mn Reoctron Rerietaae ts 6 mera ring. og we (B, ably AHeck on alleng ee 4) Selitinoff fest. " Victoses: give Red caw -Aldeses give Fink Colour: « ( pifF blw Aldose nd kelow) peer et 62> Re” with Pro /Pxs A] ROW + PX3 —» R-X +H5P0, + UX 8] ROR, + PX; —9 A,X #R,X t H3PO, 1 acoont kz —> Rcocl- 2 R, COR, He E alse J R,cook, Ss Ui mgt FIR coje(con,) £25 R,COx + R,COr- 6] 7 sem oe a A, Cle), R:- ® 63) Finkelshien ond-5 RF/ Act /RBe we ae + + MF Lde i PMaF/ Nec /Netby are Taceluble in aie # OOF, Hy Fa Soa Fs SbF, ES Meh Redetion O Kou, @40H $e eT’ "Ch eat der aw use is Swort2 Reach order * vu, Lone] + KLeusenc] Low’) rage] * ZF 6 is 4H the it Rt tAyF arcu | will - Show Cuunizorn. thy Benzoin eienien = 5 Bewzil Benzillic Rearronpenenr 5 Fee | fOr ee ore] ‘ ph nto 1 a : Korbon “of Attacker Renoing - 4 order of Reoction 62 2 R oeeiie tater ce. ee ¥ order of Reve tion pete,8S) Malaprade Reac hon: [rq n2%40 —> By TO], #Vicinal Piols, Amine, “4L19.2°) Ketone, Cost, Epoxides ure oxidised ow WR Step op agiat : iy Is) la Mofa) in Ne Tatele, a) € FArwnes, ie =“ cheers are nob. sad Nf mel ders [O89 Grea oy on ! nf ry 8) Se Phen Reduce peat teh Ree wey R-cH= wy On PS 67) are GSrignoed Rec R-Na, R= Li —> Mord Caer de. RaCobiy Ryd —> Soft. Nudeophile coon Bra / Hi0 wo Syn (ences) Lge S200 10, 72> willion sons Estenification Reaction RBC Pyar mea ° ee ena: ea 8 gr) [Rote of Eaten ) Size pes pire Ester Beton *) Sinnons Sritk Reection 8 5-eR, + Reon SEER -c~ok, #poly SS tay xy A Thies Ram Ve Pas erin Ace Med 5 TERY alRE Renton Fe fens >. 7) Riemer =Weroen Reset on === ST a are! onda, pro a Lor fee i oat cy CHiner) J Boge g 2, Rajon Bio (Gf Defeuit) K Cor 5) > > iss Teese Pare! (ice) ates okey @ ceed # Vicor i] EKO FE 60'e < TeIscte—sorhle ter) A] ens, iy Cock 7? Ise —9 Fora. (4 bond brenta) sy Nao ns j ' [Tx 50%]? KON —> Farr. |) yo i, ¢ize i of a ae Mu0K—> oro 5 ol LiOW > para | oF Litcog) "7 on ¢ 41 Jo tah er < ; or Ho) Base | Ass oe = 70) NBS hy. | ¥ Pore NASis inert Bt usually contoins 75) oxidation by MnO,, Inporities of (6r,, HBr.) > Sovree- FTA onls onidises Allylic ond benzglic Br ea Aon ES Reig | Aldehydes to Ketones Mnoz, ie Mas, A- ay Zuo Snes, Zaye8S) Malaprade Reac hon: [rq n2%40 —> By TO], #Vicinal Piols, Amine, “4L19.2°) Ketone, Cost, Epoxides ure oxidised ow WR Step op agiat : iy Is) la Mofa) in Ne Tatele, a) € FArwnes, ie =“ cheers are nob. sad Nf mel ders [O89 Grea oy on ! nf ry 8) Se Phen Reduce peat teh Ree wey R-cH= wy On PS 67) are GSrignoed Rec R-Na, R= Li —> Mord Caer de. RaCobiy Ryd —> Soft. Nudeophile coon Bra / Hi0 wo Syn (ences) Lge S200 10, 72> willion sons Estenification Reaction RBC Pyar mea ° ee ena: ea 8 gr) [Rote of Eaten ) Size pes pire Ester Beton *) Sinnons Sritk Reection 8 5-eR, + Reon SEER -c~ok, #poly SS tay xy A Thies Ram Ve Pas erin Ace Med 5 TERY alRE Renton Fe fens >. 7) Riemer =Weroen Reset on === ST a are! onda, pro a Lor fee i oat cy CHiner) J Boge g 2, Rajon Bio (Gf Defeuit) K Cor 5) > > iss Teese Pare! (ice) ates okey @ ceed # Vicor i] EKO FE 60'e < TeIscte—sorhle ter) A] ens, iy Cock 7? Ise —9 Fora. (4 bond brenta) sy Nao ns j ' [Tx 50%]? KON —> Farr. |) yo i, ¢ize i of a ae Mu0K—> oro 5 ol LiOW > para | oF Litcog) "7 on ¢ 41 Jo tah er < ; or Ho) Base | Ass oe = 70) NBS hy. | ¥ Pore NASis inert Bt usually contoins 75) oxidation by MnO,, Inporities of (6r,, HBr.) > Sovree- FTA onls onidises Allylic ond benzglic Br ea Aon ES Reig | Aldehydes to Ketones Mnoz, ie Mas, A- ay Zuo Snes, Zaye76) Oxidaty a Gy suas ¢r ver CHoro, chronate « 8, 3, + Nuon ‘su THE) on eu) ad, Aid oP Rebschin’ Aci > EUR > Akg rl CAs _ikis an Electvephitiic Redocing Ageat) Memes phen ante. Ay Ing ne ian Hess crowded post is AHoc Kel Capit] i lS ieptteny Oe 13) Protechian es Corben. P Udi aA cos Oi Dadupk 84) Bouveaul F-Bloac - Reduction A] R ¢] 8, ow * R,-OH. © Hd ney we ~OR, $tOH ° ow i ea ov Rem thon, Sot ER, . pe OxyMercuration Renerevrabron, ain ees Roe bu, ~« Poke Magn 10 Brig Sq | eg es Be 1) he ee ee Koy, (ierevredon is Antt. Bk He dversll | 95) Hell Vollard Zelinsky Reaction R 12S = Peete OW Red. R,—cW —e~ OM. 74 Kochin action + cH cy Hgso, $0, 80). E,CB_ glininakion ¥ Sane Mech as Aldol Rxt. fT. \ 4 bad be2(8u, Pe), high T Strong base Ewe ot P-pos” eater eon Bes No, Fen Sea Mis sO? Of; ar 5 Happens, with or without 450 AI R,—cnj-e-et Red R,—cH— cob. Seba ee 86) E; Eléninoten tony heot reqd , S cope Blinnohia “~M ce phn * Oech gS mes " od action. la) fare rs { of ae ers. a) oi 22) aReroxide £F fect / Khar yah heh H Free Radfeat Mech, And; - ~ Mar komi Kev bod97) WolPF Rear Aecktts R=EnN= gba g Me eo 7 R-N2C=O Cisocynok. R-Nzcx0 Hs, (uw, RATS £O{T) R=MH, + NA (1) + cofr) [sechnidl Degragatoay st So 8) pce oe at fe eae CU] Peo Me on! fe Hl X= NK, [P= NHR x2 —WHR, 2 ROH x= OR | be ciycook > xs — occ T/A. , Mamet aa we =——> lo R-N=C=0 g -t;~¢-oy E me | eee Gals i vc LArdat -Gishert Re] 91) Claisen Reo were saeT So oe | or” 2 ae Donets] 910) Rosenmurd Reduction. ony tod g80 3 adel ie R-e-H F Also Reduces triple end to Double bed t NO, to WH, Also Redyces > Coney house spaviest Rex a1ifeo —9 R-Li SS KCL Chia 742 [ 92) Debydretion bag Ale, 1THOp | Eu. » bg Ale, Aw; ou va oN THO; hekf, Th, Hoffnoan: a a hue I O ¥ ALO; 1 43> wi wittig Reaction za f, oR “ 1s z GETS, = rhhy Hees ¥ 1 @) Pht ra H Rese Ne 4) Diels Alder Reaction- ic ace 4 pees ed for pienes: takched to dienoplile- ° h , le, HK EDG Should be A Ewe shold be At BE eT Gt Ck, SL, Oa ao t only Poa Alkenes Give viels Aidep.Singlet carbene IC +SSth Cs4n Addit) en, et ¢ se plete Triplet cobens | +» paretee Mon * ~Sterenepel ii) a ye venilah sp 96> ae Mechanism - Def iy ax e meth eC KM Pe oe Ben2ane e erp! ge + iy Br. & s Pos ue ey 7 82°: © Should be Skbuhi'sed ye or Ae oF fect fre eed cosy Su lie = Ra A ore ®> ¢, Corbene Addition Rew lien A cy at ¥ oe Oxo, uf) Fett +6cv—e [Fecew),) + (' frossim Ble) fe, Teco, Oe Le dco opeenl LIP bol N,$ —9 Khoon! lal ae Taber + 460 ¢ Agt —» Ay ld) Tent for 3 HzPo, + 12 (MH, ), MoO, & UHR Phasphoros Hy), FO, « a@HoO, 2) Cemry Hele) Ct2000 —42y + COFEF Oy t CutoW), ——> CalO{4) 4,2 2) Petection of C, H+ ) 2H t%O —» ty th,O Wso, 22 io rare CvS0, -5Hz0 (blue). WH, — NM, WH;~oOn, HN, fee ete | do not 9 ive lasseuyne's tect 8 bcoz Z dont Wwe conbor # Ph-Ben e@ also does not give Lassac nets Test of on heatin: Sa aX ay