Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Jr.Super60 WTA-14 Date: 14-11-2021
Time: 09.00Am to 12.00 2019_P2 Max.Marks:180

KEY SHEET

PHYSICS
1 AB 2 ABC 3 ABCD 4 AD 5 ABCD 6 D
7 ABC 8 CD 9 1.15 10 20.00 11 3.50 12 5.00
13 7.00 14 1.13 15 A 16 A 17 A 18 A

CHEMISTRY
19 A 20 ACD 21 ABD 22 ABCD 23 AD 24 AD
25 AC 26 AB 27 0.00 28 800.00 29 20.00 30 32.00
31 10.00 32 30.00 33 A 34 D 35 A 36 C

MATHEMATICS
37 ACD 38 D 39 BCD 40 C 41 AC 42 AC
43 ABCD 44 AD 45 1.00 46 0.5 47 2.00 48 2.00
49 2.00 50 3.00 51 A 52 B 53 D 54 C
Sri Chaitanya IIT Academy 14-11-2021_Jr.Super60_Jee-Adv(2019-P2)_WTA-14_Key & Sol’s
SOLUTIONS
PHYSICS
1. Friction will act in upward direction
g tan 
 (For pure rolling)
MR 2
1
IC
2
For hollow sphere I  MR 2
3

g tan 
 
MR 2
1
IC
2
  tan 
 5 
2. L  r  MVcm  I cm

1
LB  m R  mR 2   r 
2
3
LB  m r
2
1 1
LA   m R  mR 2  m R
2 2
 LB 3 L ' A
As  LB 3 L ' A i.e., in (ACW) direction
LB  ve i.e., in (CW) direction
3. Conceptual
4. Conceptual
2
 L   ML 
5. Mg     
2  3 
3g
 
2L

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Sri Chaitanya IIT Academy 14-11-2021_Jr.Super60_Jee-Adv(2019-P2)_WTA-14_Key & Sol’s
 L 3g
 aCM  
2 4
 3g 
T  Mg  M  
 4 
g
T 
4

6. Conceptual
7. Conceptual
8. Conceptual
1 1
9. mgh  mvC2  I C 2
2 2
vC  R
R
10. mg    mR 2 ..... i 
2
f  mac ... ii 
aC  R ..... iii 
11. F  mac
2
F .R cos 600  f .R  mR 2
5
ac  R
N  mg  F
f  N
12. L final  0 (About a point on ground)
2
Liniital  mR 20  m0 R must also be zero
5
5
So, 0  0
2R
5 1
Or 0   5rad / sec
2   0.5 
13. By applying conservation of angular momentum

2 2 '
m0  mR 2  m ' R  mR 2
5 5 R

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Sri Chaitanya IIT Academy 14-11-2021_Jr.Super60_Jee-Adv(2019-P2)_WTA-14_Key & Sol’s
6 7
m0  m ' R
5 5
6
 '  0
7
14. T  f  mA a A
T .R  f .R  mA R 2 A
T  f   mB  mC  aB
mC g  T  mC .aC / B
aA  R A  aB
a A  R A  aB  aC / B
2H
T
aC / B
15. Conceptual
16. Conceptual
17. Conceptual
18. Conceptual

CHEMISTRY
dq
19.  T  0 is Clausius inequality
20. Conceptual
21. In H vs S graph, stage II to III is not correct

22.
23. In reversible cycle, heat rejected is minimum. For reversible cycle,
T 400
qrej  C  qabs   100  80 J
TH 500
q
24. dS  rev and  dS  0
T
25. For an isolated system, the entropy can never decrease
T P
26. a) For an ideal gas, S  nCP ln 2  R ln 1
T1 P2
T
At constant pressure: S  nC p ln 2  3  2.5R ln 2
T1

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Sri Chaitanya IIT Academy 14-11-2021_Jr.Super60_Jee-Adv(2019-P2)_WTA-14_Key & Sol’s
 43.22JK 1mol 1
T2
b) At constant volume: S  nCv ln  3  1.5R ln 2
T1
 25.93JK 1mol 1
qrev
27. For reversible adiabatic process, S 
T
qrev  0  Ssystem  0
T T
28.  1 2
T2
500  300 2
 
500 5
W
  W     qsource 
qsource
2
    2kcal   0.8kcal =800 cal
5
T T
29.  1 2
T1
375  300  75 
  
375  375 
 %  20 %
T P
30. S  n.CP ,m ln 2  nR ln 1
T1 P2
5 1200 1
0  1  R  ln  1 R  ln
2 300 P2
 P2  32bar
12000 12000
31. S  S A  S B     10 J / K
600 400
32. Heat transferred to surroundings by person per day = 86400  100 = 8640000 J/day.
The increase in entropy of surroundings
q 8640000
is S  rev   30000 JK 1  30 kJK 1
T 288
33. Thermodynamic processes application
34. Thermodynamic processes application
35. Conceptual
36. Ssurrounding  0 for Adiabatic free expansion of an ideal gas

MATHEMATICS
2 2
37. Required locus is x  y  2 x  8 y  17  0

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Sri Chaitanya IIT Academy 14-11-2021_Jr.Super60_Jee-Adv(2019-P2)_WTA-14_Key & Sol’s
38. Equation of line is y  m( x  1)
Equation of pair of lines is  x  y  2  x  y  2   0
From above equation
Slope of line is undefine
39. Conceptual
1
40. Equation of AB = 2x+3y-1=0, equation of AC=x+2y-1=0, slope of AC=
2
 2
1
Slope of BO=2, equation of BO is y=2x.solving BO and AB we get B=  , 
8 8
1 3
Similarly we get C =  ,  substitute B,C in ax+by-1=0
4 8  
41.
P  cos ,sin  


O  

Q
cos     ,sin    

 
Q is obtained from P by reflection in the line through origin with slope tan    
 2
 
S is obtained from Q by reflection in the line through origin with the slope  tan  
2
42. It is clear that diagonals of the rhombus will be parallel to the
bisectors of the given lines and will pass through (1, 3).
Equations of bisectors of the given lines are
x  y 1  7x  y  5 
=  
2  5 2 
Or, 2x – 6y = 0, 6x + 2y = 5
Therefore, the equations of diagonals are x – 3y + 8 = 0 and 3x + y – 6 = 0. Thus
the required vertex will be the point where these lines meet the line
 8 16   6 12 
y = 2x. Solving these lines we get possible coordinates as  5 , 5  and  5 , 5  .
   
43. Let x 2  2hxy  y 2  0 be given by
y  m1 x & y  m2 x
m1  m2  2h
slope of y +x = -1

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Sri Chaitanya IIT Academy 14-11-2021_Jr.Super60_Jee-Adv(2019-P2)_WTA-14_Key & Sol’s
m1  1 m 1
tan   , tan   2
1  m1 1  m2
m1  1  m 1 
tan   & tan     2 
1  m1  1  m2 
(for +ve signs, in both gives the same value but m1  m2 ).
tan   1 tan   1
 m1  , m2 
tan   1 tan   1
m1  m2  2sec 2
 h  sec 2
1
cos 2 
h
1
2 cos2   1 
h
1
 1 h 2 h 1
 cos      cot  
 2h  h 1
44.

 3 9 1 1
G   ,   , D  1,1 , C  ,  , F 1,1
 2 4 2 4
3 1
     1 or   1
2 2
45. P is the incentre of triangle ABC
46. Hints: shifting origin to point 1,1
The equation becomes x  2 y  1  0 and 6 x 2  y 2  4 x  4 y  1  0
Now homogenizing the two
Coefficient of x 2 + Coefficient of y 2 =0
47. Image of A in x  2 y  1  0 lies on BC and image of A in x-y=0 is B
48. If x  (0, 1)
Then – 1  x + y < 0
And if x  [1, 2)
0x+y<1
1 
Required area  4  .1. 2 sin   2 sq. units
 2 4

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Sri Chaitanya IIT Academy 14-11-2021_Jr.Super60_Jee-Adv(2019-P2)_WTA-14_Key & Sol’s

1
1 2 3
0
–1
–1

x+y=1
x+y=0
x + y = –1

D C(1, 1)
q2

(0, 1) q 45°
1
Q(1, y)

A P B(1, 0)
(0, 0) (x, 0)
49.
tan q1 =x and tan q 2  1  y
Since, q1  q2 = 45°
tan q1  tan q2
 =1
1  tan q1 tan q2
x  (1  y) 2x
 =1  y …(i)
1  x(1  y) 1 x
Now, Perimeter= 1  x  y  (1  x)2  y 2
By using (i), we get
Perimeter=2
50. Let co-ordinate on x-axes be  h,0 
 Equation of line
4
y0  x  h .........1
2h
4h
y  int ercept 
h2
x  int ercept  h
1 4h
 Area of   h   16
2 h2
h2
8
h2
 h 2  8h  16  0 or h 2  8h  16  0
8  64  64
h4 h
2
8  8 2 8  8 2
 ,
2 2
h  4, 4  4 2, 4  4 2
51. Equation of line 3x  4 y  9
y  mx  1

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Sri Chaitanya IIT Academy 14-11-2021_Jr.Super60_Jee-Adv(2019-P2)_WTA-14_Key & Sol’s
5
On solving x 
3  4m
 3  4 m  1 or 3  4 m  5
 m  1 m  2
52. As a  3, b  2
Line y  mx  m 2 passing through  3, 2 
 m 2  3m  2  0
m  1, m  2
53. Given sides of triangle are y = 6
4x+3y=10
4x–3y+2=0  P.I are (1,2),(4,6),(–2,6)
consider reflections w.r.t to x =1
(1,2)  (1,2) (4,6)  ( 2,6) ( 2,6)  (4,6)
Find centroid, orthocentre ,incentre, circumcentre of triangle and
verify with column II
I  (Q)(T) B  (Q)(S) C  (Q)(R) D  (Q)(U)
54. Given sides of triangle are y = 6
4x+3y=10
4x–3y+2=0  P.I are (1,2),(4,6),(–2,6)
consider reflections w.r.t to x =1
(1,2)  (1,2) (4,6)  ( 2,6) ( 2,6)  (4,6)
Find centroid, orthocentre ,incentre, circumcentre of triangle and
verify with column II
I  (Q)(T) B  (Q)(S) C  (Q)(R) D  (Q)(U)

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