686 Pans Gus vt (MART ies wt sow via (©) [Mad gabI; {Cole NHC Ceciecmer Maree ) Ash: (Cxelyn) Some more examples are [eacondaPs (Petipadal™s (Cx(on) KH OV.Ts (Pee), I 156 BONDING IN COORDINATION ‘eomrouNDe. ‘emer was fit dvarib the structures andthe exisience cf varius types of fomerian in coordination compounds. However, the nture of boning between cena metal atom, ‘and ligands in the coordination sphere hasbeen explined by {he ue wellAnown tories. These Gers are 1. Salone bond theory 2 Coys field theory 3, Ligand field or molecular orital theory (d) Valence bond theory: Is the simples ofthe tree ‘teoresand wat developed manly by Pasting desis the bonding in tors of hybrid erbale ofthe central metal som or in The theory mainly deals withthe eeometry (Ce shape) and magnetic properties ofthe completes. The Salen features ofthe theory re () The cenral meal loses a equsite numberof electrons 1s form the fon The numberof eloctone loi he valency ofthe esting cation In some cases, the metal stom doesnot lose electrons ) The central meal ion of atom (8 the case may be) smakzs valle numberof enpy yp amd ial ‘ultotacoonnation name These oval yore together ofr hybrid orbitals which are same in the number G.RB, Inorganie Chomisry for Competitions tn toe obits hybrdining tgethon Thy are vant ‘suivant in energy and have definite geometry, ‘Some of the common hybridized orbitals met in the coordination compound are listed below: (for dts se chapter zon valency.) Gort] pe of . aber deaton 7) | Doar Tea OT 3 | at | teamatpan | Heb el aca. were =r sip? | Seapine | (Ue, Cue ecw 5 | ae | rien | Fete fc Sori we | Stare (sr mit 6 | 4p | Se | ost wena, x | laner bia) | {FeO (MINHA ie | (owns otwa | (rerd™ (The nontonting eletos of he meal oecipy he inser eT ae roped in crac wih Rds ‘ls boweye, wk he rcs of some song ie tris nit Hunde Te din paring tis procet of hybridization may be ether (n=l) ap) ot _nsp’@. Ube complexes thus formed are referred to as inner or To in an cate ih pn compere epee “Tl hove tone ial cotnng ene pura lero. Vac bd Sas of the etl somo Eroveiapwitthes ais cong one pic eesres otter frm ean eons on ced Ceol bond (erp pot oat le pres Smale ammo forty Goi pone pdt Be magnet opie ofthe compli geometry ote npn eet) flown becomes Sona pare estoy ft permepe amt wie it drs tenn ped Som, aa pd he compro amore ature Coole avo piel cco ae esau “The numberof wired dcront sth peer of te congler en havng cea me on wi ogra The dpe nd eg nna ome oman cone of eal facts hve bmn bel on Ban of nce bond they he ule ne next abeCoordination Compounds and Organometallics or conan Och Terabe ren Golo: [mre | omer a oP e 1 1 1 Hi e 2 2 2 2 : 2 3 3 2 ‘ ‘ ‘ 2 ‘ “ ‘ 3 1 5 ‘ ‘ a ° ‘ (indigo ’ | 1 1 1 ‘cameo ero ten Linton of valence bond tery >The vas bend ory wes uly moan fe epg goon te Er ruber of atone (The tery does ot oer any expat sot te pote ones ey tnt tne toe “eysoneine cereal mans dices omcty we formation of cou on kes pce: The hen Urabe wy ate methine a reamnged Mame Fam ue whe oer ne he doe Ui Te ery dosnt oleran xan rbecxsece of aneroral od otro comple {Tethys tephra complexe we tative oes a ee (inthe formation of {Cu(NH}, oe electron ished fon 3d Spar, The esse south emeey rata fring shan cegon. Sch an eston cat rey Reyne ns [OHO AP empl Snr chow ‘cing poperin {oi Thecungerin nerf mel ins nomaon of Sonpex edu eaele mabey. {@) Copel ed tory: Ctl ld tno wae apn Bae 199) nt Wn Vek (193 0 wt Crea soled a ne cyst explain te ope property and thei eld cya theory. Fever nether was ped othe sal of codon Couperin 950, Trees ond ery reps he Tiga etl onda covalent win eleton pi shared ‘eewen the mel and he Higand donor fom. his theory i ‘equ aed bu tis not adegat to explain properies of somo cach en and magneto. Carey the trading in coordination complexes is usually dseibed by cry ld theory or ligand eld theory. Tis theory acount ‘rinse sainivany eapnnnon te paieotconplens ‘speily esurand magncton. Thema pint ofthe they (According to ct fel theory, the boning in complex feos is purely electostatic. Thiv ony cepa the Tipe toms ofioniigande mach ae CI or CNT ar nega ot args (als called point charges) and if the igand molecules ‘renewal hese re regarded soit poles rsimply poe, the neg ed point toward ental mel on Sect fe Ne (rmeria eae) (i) Te compen regarded a «combination of este ‘met onsurounded by ligands which et point charge or int pls. The arangement of lgands sound the cena ‘el ion orator issih thatthe repalsion betwen these ‘mytve pin wuts nia {Gi Inerctone eneee postive charged naceas of the entra metal ion atom od the negatively charged ands are of two types:os GRB.Inorgante Chemistry for Competitions Geometry shape) and maenetie nature of some ‘Application of valence bond theory) the complenes ton ot] Gesmeny | Neal] Magne fee] CContguation by she” apni), “ne » ® ©| o [oe | o Me hew | gant 4 of 2 2 [Panag EERE © Er 12 | op | temtetat | 2 frum acne | EE ©) CEO 42 | apt [squire planar] 0 | Diamagnetic ho Tn © oD ° 2 | Parsmagnetic} eo, | IEEE) oTETH 0 | | rein | 0 | amg drape Pars sont] GIGI TEE 12 | ape | onatetnt | 2 [owamueni : bax oe ae aw mee | ETE O oe 2 5 |Poamants Ico | GEETET () 12 | er | oxtmaat | 1 frm Rearangement ip? toe lomwene | CLEC GET) v2 | ap | teateaat | 3 fraramagnee > low | EE O OO 2 1 fouamagsete locu | gE o co vz | om | rete | 1 frarmagnt Pp torons| GE © GT 2 dsp? | sqaure planar] 1 | raramagnett| a One dermis shite fom 3104p Coma.Coordination Compounds and Organometalcs o a [A rar cow | onto & oto 8 3 pwamense fccvsing) EEE) 2) GT) ts | a | oateta| > feeanagee ae = lcw.o| CEC © GE ooo) «3 COcthedeal | 3 [Pararagnetic EF & jcoma®) | tttititity LJ LLL) 8 + |raramaynene| fcora> | MOET GT] CECT | 13 | pie | oom | + fom ie 2, OOH”) CET ©) GEE ” asp | ovaeuat | 0 | Diamagnetic —=—_ % jor) Gmmmm oO OD a 1 [Paramagnetic| roano| HEE G) GG GET] + sit | Oetahedteal 1 |Paramaenetic| @ mae oe ey Rete) fmm O 2 4 [Paramagnetc| recog | HERE) ©) CLI ” dep | Cetahedral | 0 | Diamagnetic Rearrangement dsp" (nner) rrece,oyp*| EET GGUS) GETTT) | +2 | sp¥ | octahedral | 4 {Paramagneticl we (Outer) wing ee | se | oomern | “4: boro |(Fe(NHs) Sa eee nagne Fea) tim O OD ” 5 [Paramagnesi| lre(cN | IT) G) GEE) a Psp? | Ovtabedsal 1 |Paramagnetic| EE) @) GEE & |Fe fmm @ CO o 4 |Paramagnesi| reco, | EI ©) GETS) 0 | at | nigcon | 0 |oiameente a | tea60 (0) The stativ ore ane duet ptr la and the egaively charged ligands oth negative ead of 0 polar neutral molecules Fox example inthe cse of camlex ton, (FCN) the interactions ae between Fe” fon and ‘egalvely charged CN tons nec inthe, comple, {CHOI the intersstions ave Between CPion and eatielchired ends afsmmonia nalones Thee nmcve {Sind ead oh met The bn been, ‘mca an the surnding ind ae purely oe. This theory Senter my abt veg (6) The repulsive forces rz betwee the oe parson the ligands and lectons ithe dabalvo themetal oto The xt ld theory mainly fous on these repaive feces ‘ese foes re responsible for cusng a onterbe eet catherine deol fhe cent mela (i) In ee tansiion metal or fon. there ae. fve totals which are desgated diy dy and “The five orbs are vided into ost Sepending on the (@) The thre derbi dy dd) which ein nthe regions between the cordate es we desgntel a fp arbi (onooced trv rinse eed (©) The other wo ota (7) 2 which eet along theaxesareclled eos ororouned sso" ob talsaretwofolddeptnente These areal calle axilorbials. [ihe names fg and ete dened fom spectscope ene] ns fe transion melon rata alte five daha have same energy, ey they ar eens. However, when theligand approach the ental metal on or atom, he ectrons ore worots ote cenel mes ono wo re epi by lone pie ofthe ligands. As result of thee interactions the dopearcy oft ofthe metal on iat depending nthe erientation of ligands in pace. The dria ito tho sts of orials having diferent energies. This clled yrange bans fey el tiny. The ‘Met foltngdopnds on he mmo of Egnde ad tee Position aud th metal atom orion. The splting i aiflereat fnaifeentstractar. vith ilferent coordination numbers octahedra completes: Letus comlderan heel compe, [Linh heer treatin ie pice at the ean of ho vtaheion and a Sunouned by six Haun which seo the i ores a ihe octahedron a sown below, RB. Inorganic Chemis for Competitions “Te cows In dara of de mel enon ae repetica by negative pont charge or by the native end ofthe dipole ofthe ligands. This repulsion increases the enery of al the five dois. Iall the ligands approaching the metal caon seatanequl distance from each of davis (ce, he ligand elds spill syeametical, the oery ofeach ofthe five ‘orbital nernte bythe are smount a all the di remain degenerate, although they posess higher ener. However his isnot poeible sits only hypothetical station, Fig. 18.1 Tho shapes ef no fe eral ad se ‘anatlens with rane oan cetaheced ‘ory of charged gan _Sincethelobesoftwo cori icinhe path ofappeoshing ligands see, Fig. 15.1, the electrons in these evils ‘eapeiene greater force of repulsion than hose a es howe Iobes are dicted in pace hetwcen the pth ofthe Tiga re Fig 1610) £2, ong fa itl festa hile that of gba is decreas. ‘Thus, an energy diference exists between two set of combi. This energy alitfereceis called ey Meta sping sneray ad i roprvetel yo (he eben 0 and or ‘cthede.Kimeasures the crystal eld srength ofthe sa. ‘The cys eld pling oocurs in sucha way Ha average energy ofthe bias does not change.Coordination Compounds ond Orgonometatcs 3| Z gee a Gana ‘Sata o © ® ig. 182 Crs fot opting ot drial nan cabal (o) Spaning st cbse tvtar ne iene ogee “Tho ie hi itn cg ts Belo avout ogy ind wo ae ey 2 shove te meee ey The ne ne Eis wie domly Dy Bory os ‘Tbe fes nn to ype epee ate Sere ins ey soe om tye Sel Feri Tas nt nso ey el OFaret nos art nyse 985 89 we Cat a ping nearer: he cea arnt a pnts urn SIAM tone nen Fr 153 ay po foal ies 1008 ‘aa * i 189 el i ening of del ‘acura The teen danke 14 tag onal ae close to the pproschng ligands, Ara reso is he electrons sue tore repulsion than ey electrons. THe ner of obs on 153, “The eneay va between two sets of orbits designated as & (The subset ¢ indian teaheal complex) It is bverved that is considerably Tess than Oo. It has been found tha, “The ing fs Fi 4 ~§20 Spectrochemea series: Foray given etl ation. he magne of ens ld spliting reg depen one nae Ti igens The graterthe ese wih which the pm ean ‘Sfpoach the mel inthe gente wl be the ysl Feld ‘Shnne eausel by it Te ligands which affect ony Segre afer eld pling re termed wea eld igands SoBe ose hi tet 2 age sping ae elle seme ed gas ‘ah ian are angen rer ofthe mide ofc eld spliting. he rangement us, oie Is Sale spectrochemea sere. > Br < cr < NO} < F< OW < OX" < 140 The cyst eld siting teenie envionment 49 ta oe soca fag nt og tat bn “The dsiition of datecre in octahedral compleres tag tnd ey orbs takes place onthe basis of the nate of Tigands. Fo cases may ase {U Wnen we uganas wre weak: we ganda the every difference, Bo tween fg ae ‘ete reatively sal and hence al he ived-tbials may be Supposed tobe degenerate, Le. all the dois have nearly thesame energy and the distin electrons i ancy sets occurs accorsing 0 Huna's ue, Le, eectons Wi pa up only when each of the five dria io ot lst singly ‘cecupid. When the gan are weak the fst thre elections ‘umbered 1,23 got gst those numbered 4,5 go 10 set those munbeed 6,7, 6g 1 Set ad the enaining tv leerons mumbered 9, 10 wil oEcupy Se. Ths can be G.RB. Inorgonle Chemistry for Competitions Hence, te sompeaca uf mesh sl gan at call igh ‘pln complexes andthe compleres of song eld iands ae ‘leew spin complete, Calculations show thst coordination fates with four to seven d electrons are more stable for strong Held compared to weak eld cases. ‘Distribution of oestrone in fg and ep orbitals In tetrahedral omplenee The dette nf defect inthe ‘a! 22 sgh ugh aght® eps aa some i mc freak . Me #, ath tong ligands feldhas been shown in the following able: Inconvenient Pct sermg pig ery ees aed pes Scent ine ane oa) cota fale Spting reg, eds cet mony each =|] =a Siecle pevewaeckeron Byormieny thee Lome |. Lae [mmr | ce | spn (G) When the Uganda are omy’ Under he nfcoce [eran | uu | ewe | i ewieieng wee ee ‘sets is relatively high and thus the distribution of d electrons we inf and ey sets doesnot obey Hund's rule The istelestons a |i’? | 2 mL een ela [= qehatee yy “ For these complexes, io is higher than P. é 2 2 ae eee 7 + |e [strong tek (Low spiny | Weak etd Cigh spin | a 3 3 4 REET [Peete eet A cme 2 2 fi oat] Rot Fn conte| nod a 7 1 |m jw" lieca [tee] | ae eee] ole V fit dg ee| oP TARE agate saves Tete ava cng 2] a |agee) 2 1 ‘containing one or more unpaired electrons possess a definite 3_|s2]nre’| 3 [32] ce Valveofmagnetic moment. An unpired electron because ofits SPr pe <2 [ar ‘ahem mei net owns %, > set Met ees apes 1 fin|ng tls |s2 he ae moe epee o folate] « [2 frre t Seer, Sool a el hla aoe ye nglic= 921410 ep ers ott fare] afi] we te Bot Macon (BM) eset (ata) (a any gare sete of ct nee = 4S pts ere = voy op o jo fatet| o jo ‘The substances having magnetic moments are attracted in “Te fellowing conclsions ae derived pm he le {0 The ditto of electrons of dd d?, dd? and 2 in ty and ey sets for bth tong and weak ocabedal Tigands Hels isthe ame. CH Foca ofa aan titre inte rangement af slevtone i weak an spe ian fel Gil) Weak field complexes of d*, d°,d® and d’ ions bave greater umber of unpaired electrons thn those of ston ld ‘omplexes and ths tereslan spins of weak Hed completes fave higher value ten arog eld complexes extemal magnetic fl Such substances are termed par _magnetle substances. Most ofthe coordination compounds ae paramagnetic The substances having no unpaited ele ‘or having only pied elecrons sbow zero magnetic momeot nd ae called dlamagaetiesubstanes. ‘The magnetic nature or magnetic moment ofa coordination ompound, tus, depend on the number of unpaired electrons ‘The magnetic moments approximately given by the relation, Magnetic moment, = atrr2} BM, where m # UE umber f unpaired clectonn. This rlaonship is wed toCoontnation Compounds and Orgenometalls (ane) Mtb = My ny el 2 (MLK) ML, + Lo My tel 1, Ks Ry are called stepwise stability constants, With a few exceptions, the values of successive Subiity Constants decrease regulary om A «Ky “The overall stability constant, i ven: MF AL My Lilla, oS ane ‘The hisher the oveall stability constant value of the comple, he more sable tis. Alteatively, 1K values called instability constant expan the dissociation ofthe comple ina metl om an ligand the solton. “The values bt conta for some ofthe complexes are uiven below: « Ka ‘Complex ‘Seay constant (Cust asx" (aatntnt 16% 10" (cots) Lips to (Cot) 50 10° Lane to? (acy GA. tnorgante Chem for Competitions (aera 12810 (ag(CN 10 « 102 fewer 20 « 10" (eecenn a? 769 «10° From the above values, some conclusion ae drawn (The values of stability constants fer widely depending on the nature ofthe metal ion and he and. in peer the charge deity om the central on, the greater ‘compleser, Le, the higher value of 1a the stable of ts com so Piss ene of the central len nce the a ese tibe we cesses at mal great as sey ef moon Meets mabe eer bar in ih item doe iret peo eso nd oto see aby ete cess 9 integer euin taraf ga be moe eS eee mie eer renee, ‘than Co jon and thus, [Co{NH:)4)"* is more stable than [Co(NHy)e}”. Similarly, [Fe(CN)g]” is more stable than [Fe(CN),)™. Sor, ns nt nme cone woe ne sn dae ey leone rete a at A CN rng ew be je camisole eons) of ses sis be wy roi Caton Ma Fe" og oN Stab ofthe comptes eee (©) Cheating ligands form more sable complees 95 ‘compared to monodentate ligands. 158 PREPARATION OF COORDINATION ‘COMPOUNDS CCoorination compounds are generally prepared by the spplieation of the fllowing methods Ligand substitution reactions: reaction involving tte feplacement ofthe igads atached tothe central mea 8 inthe comple by other ganda » gan subsiution reaction. Trarston metal ionsin aqueous soliton om comple fons by bonding with water molecules. These water malecles fare men repincea oy ligans fo Yorn ne aes comple. {ugonon) + #NHon) + (CoN ACag) + HO) [igs ton )+ 4 Lng NOUH a 4010, (Gre) ‘@uensie) INANE (on )H4CN (on)-1NiCN Aon )¥6NEY OR)ordination Compounds and Orgonometalis i, euanmunnccoyyn slate (CxO), )904. 8 fone ty alton of ammonia sltion to copper slat alton sad possum racyanonicklate( is csined bythe ation ofpoasium cyanide solution hexsaminenickel() spate setanon. 2 Direct mixing of reagent: Dichlow bir (ehyened- sine) platinum ie popared hy oding plain slo (Pech oehylenediamine, PIC + 2HN—CHl,—CHy—NHy—+ Pen) Ch] @ Sima hernminenike(l) clones candy det reason between solid nickel chloe (ic) and iui Nich, + 641,09 — Pio Ce 3. Redox reactions: In these reaction, ether oxidation credctin involved Cobalt) nate recs wih ques rumen tte and equine etna nme GO {eriicing nent to for pettammnentvsabah) tae Cate + BMH, 6 NHN, = HO, —> 2CaQNH)/NOSINO), + 2840 IMPORTANCE OF COORDINATION COMPOUNDS: ‘The complexes ar of immense imporance on acount oftheir Applicaton in various felts Dung complex formalin there tft erase changes i te propers ot mea som oo ane these change in propre aro made wo of tbe spltion ‘fetal complexes TL Analytical chemistry: Cootiaton compounds find ther applications in Both qualitative and quattatve methods ofanalyis {Te epantion of Ag fm Hein th fi ri of anayisis based onthe fact ta while avec sso in aqueous ammonia and HiClyfams a black isle aera AgCl + 281,01 —+ [ABN II+ 2840 159 Bagi, + NHOH —s Ho(NHACL+ H+ HCI+ HO aki (Tee separation of B group sulphides fom 1A group sulphides is based on the fact ta sulphides of B group form amples spider with yellow aamontum slp which are Soluble we slpdes of prop dot reset. S85 7 30et3S — ZIL9 ALEC] AnSe + 30MHgS —> 20H (ASS) SaSy + (NHS —> CNH QaLSHSs] (6) The detection of Cu" is bases onthe roman of = ‘uterine copper sulphate erplex which given ep (CuSO, + ANH —> [CulNt1804 os ato forms cocoate coloured pepe wi pousaans feiveyenide, 2EWSO, + KyFACNG + Cul FCN] + 2K80, (© Fe’ is detected by formation of «blood red coloured complex ith KSC, re" rRIEN—r_(reserg + KT (The detection and estimation of Ni” based on the formation ofa salt red complex with dimety plyoxime. (Ciiy C= NOH +2NH,oH enact (6) Many ign (organic reagents) are used for the gavimericetmition ofa numberof mel ios. ‘Meta fon to be estimatea™ Urganie reagent usea on ‘Benzoln oxime Be Diet giyoxtne re 1.10piendtine ap Pydonyguncie cat cso Pupil (a) EDTA is wed as colin nent voumetie sna of melons ike CM ind Za (0) The crortnatoncompoinds of te transition metals xh « saisty sour, Ths propery used la feline ay forthe enon of many tale () Other rales appiaions of cordnationconpoun ac inicreeacen ers esa of te ‘ai equsrng reagents an Solvent extacon. 2 Aectrgelopcraoors, Sur snl pedarvenated bye ef ele omation ire el ith lamejnie oon wih continous ping fa ‘son Sve diolver ars yn compen snd pu sie is reise by he ation sp se [ABS + INGCN w= ANG(AGlEN). Ns Ng Oy DHA Poesy ANH 38 Nal Aa(CN] + 22 —> Nu Za(CNl + 2A Naive Agan Ava dsolvein MCN ohitonnpreence of oxygen ofthe ae Ang BNACN+ 0, +210 ANALAQICN)] + N01 ‘Agand Av ar presptated by ation of sp an. rickel ems ye fenbon monoxide (nds rose).36 ‘The complan desompoes om heating again int wha and carbon monoxide, Ni + 4CO—+ Ni(COy, —Hetiag N+ 400 x In photogany, the image on the negatives fixed by disoving al the rerinig silver aids ‘wits hypo solution in the Yorm ofa solble comple. AgDe 1 2Nex6:05 —v NayfAu(S:Oyh] * Nab 4.Electroplting: Met complexes release metal slowly and ths give uniform coating in electroplating ofthe metal cn te deseo Cyana amples fave. rp, 5. Biologieal procesies: Coordination compounds play ‘many imporant roles in aia and plants. They ae eset in storage and anspor of oxygen, as electron transfer agents, 2 setts a i pg Toe agin aps te given blow (@) Haemorlobin: Hacmoalbin is protein which is present inblod. Te man function of haemoglobin isto cary frygen in the blood fom the lungs t te sues where i ‘slvertheonygen molecleso mjolabin The qurddenate ‘mocmevcic esed the porphine maleeule i a important Be et hacmoglsbin str. The two H* ions bonded to itogenstoms are Gepaced andthe metal on coordinate Simultaneously wil the four irogen atoms. The complet. Tomed fom porphine called porphyria. The Fe-complex CBedheme femme sel cont ourhewe Boe Sotsaded na prt melee The tna tthe hee ron ins the ouiaton number #2. 1 is coord fo the four nirogn door atoms in the prpine group and als 10 « niogen donor atom na igand group whch is arached ithe protein, The sinh ian ia water molecule, which binds {he Fe” ion on the ther side ofthe rng i complete te ‘ciahdrl complex, Unde tes conditions, the haemoglobin ‘toes is called deoryhsemoplcbin and as Bue colour {Ta water ian cn be replaced realy by mele Een termed seeured xphsemgain Tisheonlain owt fom ngs wo tmves whee iis aan deoxygenated, “The tombeme conpiex is preset in ether cass of proteins, ele eytoenromes. Crotromes ect as eecron Fenian nlch le pley on ees petin meets prosvns GRB. Inorganic Chemistry for Competitions a a fe eee een sin en ti See a paieniereere neeesteal Seine 604+ 0 —aabtg? Caln04+ 60> 99 O. om G -doo Pe coor, Tree Sac of Corgi Armlacle of cloropyl ca dl one or two molecules of water ail. These coord water molersey tog Iycregen bonding hep the other cilorophyll molecules to ‘cite wih exch eer vr {H) Vila By ine comple of cota with gia dentate gnc wha to porphyrin gan of hee loin. Las been observed ta vitamin Bi is active eal” then cobalt is preset inl oxation state Kisarederysaline sane wih sgh oben wate it din Ps wane epCoordination Compounds and Orgenometallice ——————— hand Rael eer terme Sura ciaieeenes pierre cere sare Dineeepine man meraecs Senators Suite Nh noc eee Ren birenraset arer Shoetmcenemane siete econ ney Vinca il Gg conical sat finally eliminated from the body in urine. m Gi) The platinum complex cis (PYNH);Ch] known as sons Sana oie Tei enatoure couraie oes er Sectmmanscote te Siryemeraeiee eet pe ee ae eaet Sint ih tesa po ee ee say" te ht te ee eee Soe Sm ore a oe Tieceenitenitaracpemts Screamer oo SE a il 6 = FG ota Tipigarceam pebbles 2 oa tat a hte en aeeeeateatay gale elena steerer nar eee Sige ges ag aces eo ‘group and X's a halogen. ST oo ne A errr th tian hs ewe LO ais pent ite Re leer on toe mel roupe et a eign between fe a x aK Eareas opaerneaas spore Tiare compounds of ras with alkenes allyoee,benzreand other fing sompounde In these complexes. the metal and and form a bond tat involves the x electrons ofthe ligand. Thee ‘common examples are Zeit’ sal feocene and dibenzene ‘tromiuo. These are shows here zoe ste Famocane Danze chemin MPICK— CHa) Felt —Cahe art — CaM ‘Tee numberof carbon some bow tthe wal ia these cemmpounds i inficated by the Grek eter ye) witha ‘number. The prefixes n,m and indiat tat 2 Sond 6 ‘atom ators ae bound oto eee ior coera eens ieee rece irate ames Jo cm vagal RR « \ ‘a bo & eng ett