Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU    MAHARASTRA  DELHI    RANCHI 
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60 &All 2018_P2 Date: 17-08-22
Time: 02.30Pm to 05.30Pm GTA-32 Max. Marks: 180

KEY SHEET
PHYSICS
1 B,C 2 A,B 3 A,B,C 4 B,D 5 A,B 6 A,D

7 10 8 1.25 9 2 10 23.01 11 2.65 12 2

13 3.15 14 2 15 C 16 B 17 D 18 C

CHEMISTRY
19 B,D 20 A,D 21 A,B,C 22 ACD 23 A,C,D 24 A,C,D
25 9 26 6.59 27 4 28 5 29 3 30 9
-
6.95
31 6.00 32 5.00 33 A 34 B 35 D 36 A

MATHEMATICS
37 A,C,D 38 A,B,C,D 39 B,C,D 40 A,B,C,D 41 A,B,D 42 A,C,D

43 0 44 504 45 64 46 6 47 0 48 12

49 4.5 50 7 51 A 52 A 53 A 54 A
Sri Chaitanya IIT Academy 17-08-2022_Sr.Super60&All_Jee-Adv(2018-P2)_GTA-32_Key & Sol’s

SOLUTIONS
PHYSICS
1. For system remain in equilibrium, value of m can be decide in two limiting cases :
Case-I : m can take a maximum value such that 100kg block has tendency to move
upward. mg  100  g  sin 370   100  g  cos370
3 3 4
m  100    100   60  24  84
5 10 5
Case-II : m can take a minimum value such that 100kg block has tendency to move
downward. 100  g  sin 370  mg   100  g  cos370  m  36
So we got the range of m 36  m  84
In this range 37 and 83 lie.
2. The highest horizontal distance is for water coming from holes 3 and 4.
v  2 gh h is height of hole from top.
2 H  h
Horizontal distance x  vt  2 gh ; x  2 h H  h
g
3. Charge distribute over the surface of conductor in such a way that net field due to
this charge and outside charge q is zero inside. Field due to only q is non-zero.
4. 1 2    1 1 1 2    1
  and   
20 R 7 R / 2 R
280 20
Solving these equation, we get R  cm and  
13 13
5. dU Ke 2
F   4 .....1
dr r
Ke2 mv 2
 ..... 2 
r4 r
nh
and mvr  ..... 3
2
By (2) and (3)
Ke 2 4 2 m m
r 2 2
 K1 2 ..... 4 
h n n
1 Ke 2  Ke 2  Ke 2 n 6
Total energy  (potential energy)  3  3

2 6r  K1m  6 K13m3
6 2 
 n 
Total energy  n6
Total energy  m 3  (A) and (B) are correct.
6. vu 
Frequency received by the wall is n1  n0    272 Hz.
 vu 
Frequency of reflected waves received by the receiver is

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Sri Chaitanya IIT Academy 17-08-2022_Sr.Super60&All_Jee-Adv(2018-P2)_GTA-32_Key & Sol’s
vu 
n2    n1  289 Hz.  Bcat frequency  n2  n0  289  256  33 Hz
 v u 
v  v0 1 340 20
Wavelength of reflected waves, 1     m
n2 289 17
7. For the block of mass m2 , not to move, the maximum compression in the spring x0
should be such that kx0   m2 g .....1
Applying work energy theorem to block of mass m1 we get
1 1
m1u 2  kx02   m1 gx0 ..... 2 
2 2
1 1  2 m22 g 2  2 m1m2 g 2
From equation (1) and (2) we get m1u  2

2 2 K K
Putting the appropriate value we get u  10 m / s.
8. As the car travels at a fixed speed 1 m/s, hence tangential acceleration will be zero.
Therefore, there will be no component of friction along tangent.
mv 2
Case-I : If Mg  ; hence friction force on car of mass m will be outwards from
r
mv 2 m
the centre. T   mg  Mg   mg  .....1
rmax rmax

mv 2
Case-II : If Mg  ; hence friction force on car of mass m will be towards
r
mv 2 m
centre. T   mg  Mg   mg  ..... 2 
rmin rmin

rmax M   m 0.9  0.5  0.2 1.0

From equations (1) and (2)      1.25
rmin M   m 0.9  0.5  0.2 0.8
9. Conceptual
10. Change in internal energy for cyclic process (U )  0
For process a  b1  P  constant 
Wab  P.V  nRT  400 R
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Sri Chaitanya IIT Academy 17-08-2022_Sr.Super60&All_Jee-Adv(2018-P2)_GTA-32_Key & Sol’s
For process b  c T  constant 
Wbc  2 R  300  n2
For process c  d  P  constant 
Wcd  400 R
For process d  a T  constant  Wd a  2 R  500  n2
Net work  W   Wab  Wbc  Wcd  Wd a
W  400 Rn2  dQ  dU  dW , first law of thermady names.
 dQ  400 Rn 2.  400  87.3  0.6931  23.01
11. Applying conservation of energy
mAc 2  K A  mB c 2  K B  mcc 2  KC  excitation energy
 mA  mB  mC  c 2  K A  K B  KC 
excitation energy
4.65  5  3  K c  10 or kc  2.65 MeV
12. KEmax   5    eV
When these electrons are accelerated through 5V, they will reach the anode with
energy   5    5 eV 10    8   2eV .
13.  9
Least count  1    0.1  0.01 cm
 10 
Zero error  0.1  0.06  0.04 cm
Final reading  3.1  0.01 1  3.11 cm
So correct measurement  3.11  0.04  3.15 cm
14. L
 1  RC; 2   LC  t1t2  0.1sec
R
1
 T  2 LC  2  2sec
10
15. In situation A, B and C, shells I and II are not at same potential. Hence charge shall
flow from sphere I to sphere II till both acquire same potential.
If charge flows, the potential energy of system decreases and heat is produced.
In situations A and B charges shall divide in some fixed ratio, but in situation C
complete charge shall be transferred to shell I for potential of shell I and II to be
same. A-P,Q; B-P,Q; C-P,Q,S
In situation D both the shells are at same potential, hence no charge flows through
connecting wire.  D-R,S
16. 3 3
Torque about point of contact F  2 R   mR 2  mRa
2 2
3 3
2 F  ma F  ma  Friction should act to the right.
2 4
3 F
As F  ma, a  .
4 m
17. (A) If P  2V , from ideal gas equation we get
2

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Sri Chaitanya IIT Academy 17-08-2022_Sr.Super60&All_Jee-Adv(2018-P2)_GTA-32_Key & Sol’s
2V  nRT  with increase in volume
3

(i) Temperature increases implies dU  ve

(ii) dW  ve Hence dQ  dU  dW  ve
(B) If PV 2  constant, from ideal gas equation we get VT = K (constant)
Hence with increase in volume, temperature decreases
PK K
Now dQ  dU  PdV  nCv dT  2 dT [ dV   2 dT ]
T T
PV
 nCv dT  dT  n  Cv  R  dT
T
 with increase in temperature dT  ve
and since Cv  R for monoatomic gas. Hence dQ   ve as temperature is increased
(C) dQ  nCdT  nCv dT  PdV  n  Cv  2 R  dT  nCv dT  PdV
dV
 2nRdT  PdV    ve
dT
Hence with increase in temperature volume increases and vice versa.
 dQ  dU  dW  ve
(D) dQ  nCdT  nCv dT  PdV or n  Cv  2 R  dT  nCr dT  PdV
dV
or 2nRdT  PdV   ve
dT
 with increase in volume temperature decreases.
Also dQ  n  Cv  2 R  dT
With increase in temperature dT  ve but Cv  2 R for monoatomic gas.
Therefore dQ  ve with increase in temperature.
18. X L  X C resonance condition
10
In case (A) : i   1 VL  110,VC  110  In opposite phase;
10
VR  1 10

In case (B) :
iC  iL  i  0 VR  0;VL  VC  10V
In case (C) : i  1,VL  VC  VR  10V

In case (D) :
VL  VC  10V
Net voltage across inductor and capacitor = 0
10
i   1 amp, VR  10
10

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Sri Chaitanya IIT Academy 17-08-2022_Sr.Super60&All_Jee-Adv(2018-P2)_GTA-32_Key & Sol’s

CHEMISTRY
19. Thermal stability of nitrates of alkali metals increases down group. MgO is basic
SnO is amphoteric and B2O3 is acidic oxides.
20. Cell reaction is : Tl  s   Cu 2  aq   Tl   aq   Cu  s 
Tl   0.0591
Reaction quotient Q  and Nernst equation is Ecell  Ecell
0
 log Q at
Cu 2
n
29 K, To increase Ecell Q should be decreased. Which is decreased by decreasing
[Tl  ] and increasing [Cu 2 ].
21.   
NNN
I II III
22. NCERT
23. Conceptual
24.

25.  10  103  58  103  T2  274 

  T2  283 K  10 C
0
log  3 
 
 4.5  10  2.303  8.314  274 T2 
 Rise in temperature  10  1  90 C
26. 10  105
 H     108
10,000
 H   108  from H 2 SO4   107  from water   1.1 107

total
pH  7  log1.1  6.94  7
27. 8a a PV 3 1.5
Tc  ,Vc  3b, Pc  2
Zc  C C  
27 Rb 27b RTC 8 4
28. Black sulphides are HgS, PbS, CuS, NiS, CoS.
29.

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Sri Chaitanya IIT Academy 17-08-2022_Sr.Super60&All_Jee-Adv(2018-P2)_GTA-32_Key & Sol’s
30.

31. Decapeptide + 9H 2O  X  Alanine + phenylanine

X is optically inactive i.e., glycine.
Total wt. of product after hydrolysis  796   9 18  958
n  75
No. of glycine   100  47; n  6.
958
32. NCERT
33. Le-chateliers principle is applicable and for ( R) Ptotal  PCO2 , which is equal to K p
for the given reaction.
34. NH 3 strong filled ligand, so dsp 2
MnO4 uses 3d xy ,3d yz ,3d zx orbitals and 4s orbitals to bond with four oxygen atoms.

3C – 4e bond so sp 3
35. Conceptual
36. Conceptual

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Sri Chaitanya IIT Academy 17-08-2022_Sr.Super60&All_Jee-Adv(2018-P2)_GTA-32_Key & Sol’s

MATHEMATICS
37.   1
 Z  2Z  1   Z 
 2    Contre    1 , 3 3   
Arg     arg    
 Z  Z  1  6  Z 1  6  4 4 
 
3 1 3 5 3 3 3 63 3
rad   Re  Z  max     ln  Z  max     
2 4 2 4 4 2 4

 
38.  X = no of dice showing even no. P = probability
5 5
3 1
0    
6 2
4
1 1 5
1 5
C1.  .   5
2
  2 2
5
 1  10
2 5
C2 .   5
2 2
5
 1  10
3 5
C3 .   5
2 2
5
1 5
4 5
C4 .    5
2 2
5 5
1 1
5      
2 2
5
5 10 10 5 1
  1. 5  . 5  3. 5  4. 5  5.   
2 2 2 2 2
1 25
 2  5  40  90  80  25   
25 4
  
39.  

L1 : r   fg  gh  hf    i  2 j  3k   
  

  
L2 : r  iˆ  ˆj  kˆ   4i  5 j  6k   
L1 :  Shortest distance between  L1 & L2  is 
d  fg  2 gh  hf  
(A)  d  may be zero for some  ' x '  
(B)  d  0  fg  2 gh  hf  f  g ' h '  g  f ' 2h '  h  f ' 2 g '  0  
f '  g '  h'  0 

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Sri Chaitanya IIT Academy 17-08-2022_Sr.Super60&All_Jee-Adv(2018-P2)_GTA-32_Key & Sol’s
f g f ' h  fh ' f ' g  fg '
(C)  fg  hf  2 gh   2   0 
h g h2 g2
1 1 2 h' g ' 2 f '
(D)  fg  hf  2 gh       2  2  2  
h g f h g f
40.  d  x  y 1
Diffe  f |  x    x  y   1 
2
 dx   x c 
 x  y x y
2

1 1 1
Since  f  0   1  C  1   x 1 y   x y|  1 
x y 1 x 1  x 
2

41.   c 2b   2c b 
Let  A  0,0,  , B  0, b  , C  c,0  D  ,  E  ,   
3 3   3 3
C  4b
2 2
4c  b 2
2
 AD 2  , AE 2   
9 9
9 1 9 1
Now  AD 2  AE 2  1  b 2  c 2   BD   BD   
5 3 5 5
b2  c2 1 1
AG     
9 5 5
9 3
AB  AC  b  c  2b 2   b  c  , 
5 10
3 1 3 3 9
a   .   
5 2 10 10 20
2
1 2 2 1 3 3  3  9
R b c       area      20  
2 2 5 2 5 2 5
42.  A2  A; B 2  I  and  CC T  I  C T C  A  I  A1  AT ; B  B 1  and  C T  C 1  
(A)   ABC   C 1B 1  C T BAT   ABT C   
1 T

 
(B)  adj 2 AB 1C  64 adjC adjB adjA   64  
(C)  C 1B 1 A1  A1B 1C 1  C T B  BC T  BC  CB  
(D)  adj  3 A1BC 1   9adj  AT B 1C T   
43.  1  logx  x   2  but  logx  x   is   0  similarly  log x  x  1, 2  1 , 2  0  
44.  x3
We have  F  x     a  3 x 2  x  13  
3
 For  F  x   to have negative point to local minima, the equation  F '  x   0  must 
have two distinct negative roots. 
Now,  F '  x   x 2  2  a  3 x  1  
 Following condition(s) must be satisfied simultaneously. 
(i) Discriminat > 0; (ii) Sum of roots < 0; (iii) Product of roots > 0 
Now, D > 0 

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Sri Chaitanya IIT Academy 17-08-2022_Sr.Super60&All_Jee-Adv(2018-P2)_GTA-32_Key & Sol’s
 4  a  3  4   a  3  1  0   a  2  a  4   0  
2 2

 a   ,2    4,   ..... i   
Also  2  a  3  0  a  3  0  a  3 ..... ii   
And product of roots   s   1  0 R    i    ii   a   4,   ..... iii   
Hence sum of value(s) of  a  5  6  7  .....  100  5040  
45.  1 1  x 2  x  1 x 2  x  1 
We have  f    cot    dx .....1  
 2 x  3x 3  2x 
2
x
1

1  t  t  1 t 2  t  1   1 
2
1 1
x   dx   2 dt     
f   t cot    2  dt  
t t   2t  3 3 t 2
 2t  t 

1 1  t 2  t  1 t 2  t  1 
  cot   2  dt  
1 t  2t  3 3t  2t 


1  t 2  t  1 t 2  t  1 
    cot 1   2 
dt ..... 2   
1 
t  3  2t 2 t  3t 

On equation (1) + equation (2), we get 

   1 
2 f        ln   ln     2 ln   
1 t   


f     ln   
 
 x 2  3x  2   x  1 x  2 
ln  
Now  g       1 dx  
1 x 1  x 1 
ln

   
 Odd function i .e f   x  f  x  
ln 
1
g     1.dx  ln   ln    2ln   
1  
ln  
 

 
Now  f  200   g  50    ln  200    ln  50    ln 4  3. ln 4  
2 3
Hence  b  4  64  
a 3

46.  We have  Tr  3Tr 1  6r  

Tr Tr 1 n
 Tr Tr 1  n r
Dividing both sides by  3 , we get r  r 1  2    r  r 1    2  
r r

3 3 r 2  3 3  r 2
G.P.

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T2 T1 

32 3 

T3 T2 
 3 2
3 3  n r Tn T1
   2    n   4  2  1  
n 1

T T 3 3
 44  33  r 2

3 3 
G.P.

T T 
 nn  nn11 
3 3 
Tn 6
  4  2n1  1  T1  6   
3 3
n

 Tn  2.3n  4.3n.2n1  4.3n  2n1.3n  2.3n  Tn  2  6n  3n   

6 3  3
 2   6n  1   3n  1     S n   4.6n  5.3n  1  
5 2  5
Now on comparing, we get 
 n2  12n  39  4.6n  5.3n  1  3    4.6n  5.3n  1  
5 5  
 n 2  12n  39  3   n  6   0        Hence  n  6  
2

47.  sin x  1  sin x   1  cos x       No solution   M  0  

48. 
1  x  1  x  1  x     Coefficient of  x
4 4 13 8 13
 is  4  8  12.  
49.  Tangent to parabola is also tangent to hyperbola. 
4 1 3 9
 c 2  a 2 m 2  b 2  2  3  m   2  Area   .3.   
m 2 2 2
We have,    a 2  c 2  b 2  2ac  0   a  c   b 2  0  
2
50. 
  a  b  c  a  c  b   0  f 1 f  1  0  
So the equation  f  x   0  will have 2 distinct solution as exactly one root lie 
between   1,1  
51.  (P) Let A be given and let  P  p  , Q  q  , R  r   
2 2 2
pq  q r  r  p pq r
Let  K  3  2  kmax  3  
p q r
2 2 2
p  q2  r 2
35 35

1 6
5 6
 5  6 
(Q) Let  I 
60  3sin x  4cos x 
60  sin  x    dx  60  sin xdx  1 
0
 
6 6

 1
2 t 
1

 1  3t  2t   1  3t  2t   0 
2 t

(R) Let  L  lim   0   
 
t  t

 

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 1
3   1
3 

  1  3t  2t   e   1  3t  2t   e  
2 t 2 t

lim       L  L1  L2 .....1  

t  t t
   
   
5 13 3
Now,  L1  e3 & L2  e  L  L1  L2  4e3    4  
2 2

 
(S)  x  y  0  4  0  1  
x  y  1  4 1  
x  y  2  4 2 
x  y  99  4  99  
 number of solutions   1  4 1  2  3  .....  99   19801 
52.   1   2x   1   2x 
(A) As  sgn    1x  R  1 f  x     sgn      x  R  1  
  x       x   
4 2 x 4  2x  2x
As  x   2,2         is discontinuous when   1,0,1  
     
 
x ,0, , Clearly  f  x   is discontinuous and non‐derivable at 
2 2
 
x , 1,0,1,  i.e., 5 points 
2 2

 
 2x   1 
Graph of  y    sgn    in   2,2   
    x 

1
(D)  2 tan 1 x
  (or)   4  and  x  0  
4
53. 

 
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CD  directrix  

 
Apply power of points 
C. 

 
xy  2  x 2  y 2  4  ae   
2
 ab  2 ;
2ae  2, x2  y 2  4  
 x  y
2
ae  1,  xy  4  
x y2 2 
2 x  y   4 2  
54.  a b c  a b  b c  c a 
G1   .G2   .G3   .G1   
 3   3   3   3 
  
Volume of parallelepiped   G1G2 G1G3 G1G4   
     
 c a b a b c
       9 
 3 3 3 33

R) QP. i  j  k   0       x  y    y      z     0  

 
 PQ   9  x    y    z    9 
2 2 2 2

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Sec: Sr. Super60 & All Page 14