[Acid — Base Equilibrium Practice/Study Exam Answer Key, Part A: Multiple Choice 1° D 39 Oca) 40 3. OD 41 ae 42 sD 43 oD 44 7 2B 45 8 B 46 oc 47 10 BA 48 uD 49 2 B 50 13 OA 51 4 0A 52 sc 33 16 OC 54 7B 55 is 8) 56 19 =B 37 2 C 58 ai 2 59 22 A 60 23 ¢ 61 24 A 62 2 6C 63 - 6 &B 64 27 iB 65 280A 66 2 =D 67 30 =D 68 31 «=D 69 RA 70 33 0O«#&@ 1 24D) 72 35 OA 2B 36 C 74 bu 715 38 OA 16 POOCODUUPFOUUTO DUNS OD BA>H>RPOOWOBUS SUPA 1 B 79 80 81 82 83 84 85 86 87 88 89 2 92 93 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 ut 12 113 114 POU>rQANUPBMOFADUAOPOFAVAMwMAVROWNOOwWOANBAD 1s 116 17 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 PUWOF>>DOTOTORO>>OTT>TOFAPUOePOUTUMOFOS { 247248 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 71 172 173, 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 kp > e NATO UP >> OP TOP> DPOLOWU> > UHTONOTCVOIE ee v 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 21s 216 217 218 219 220 221 222 23 224 228 226 227 28 WOOUDAVOWOW> UNAOTH>DOOWOAUU>> kro ooawuo 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 oo) 261 262 263 264 265 266 PUP COWS USF O> DOOFOUUTODIUOTYOWO> TTA >> OP 267 268 269 270 an 272 273 214 278 276 217 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 | wUUArFTBrPOFUPaANwBwODGABTAATNADPart B: Written 1. HCOx@y) + H209 = COs*@g + HOw 2. a) CHjCOOH es) + H2Oy = CH3COO%Ga) + Hs0°(oq b) The [CHsCOOH] will increase while the [CHyCOO}] will decrease. The added 130” will react with the CHsCOO' to produce CHsCOOH ©) The pH will remain relatively constant. 3. pH=5.16 4, a) A pair of chemical species which differ by only one proton. b) H0* and HO 5. a) Ky Will increase as the equilibrium shifts right which cause the [H3O"] and [OH to increase. b) The pH will decrease ©) It will remain neutral as the [F,O"] still equals the [OH'] 6. pH = 2.67 7. a) HCNga + NHs(q) = CN + NEG") 'b) HCN and CN’ or NH; and NH," 8. a) H,PO, b) HPOS + F2Oy = HPOP Gy + HOG) 9. pH = 13.00 10. pH = 3.67 11. HF ag) + SO3*aq = HSOxeg + Feo “42, 8) Nisay + HhOp = NEM" ay + OH up - b) Ky = 18x10" 13, [H30°] = 6.3x10°M [OH] ~ 1.6x10°M 14, pH = 12.40 15. HaCeHsOeiaq) + H2Oy = HC6HsOe'ay + HO" ta) 16, pH = 1.43 249250 pH 7+-—— 17. a) CHsCOO%Gq + H2Og = CHs:COOH a + OH (aa) b) Ky = 56x10" 18. The acid must be benzoic acid because the K, values match. 19.8) Hindyg + L209) = India + HO" up b) The color would be amber 20. pH = 2.72 21. COn dissolves in water to make an acidic solution. HeCOsaq + HaOm = COs) + HsO"Gap 22. 2.50 g of NaOH 23. a) The stronger acid is HaTe 'b) The weaker base is HTe™ 24. Since Ky (2.3 x 10%) > K, for HCOs" (5.6 x 10"), the solution will be basic. 25. a) ’ t¢f——_— ~ B n Scshaped Saheped mark Equivalence Poin pl = 7-<— 25 mL of 0.10 M NOI for neutralization | — 1 mark ° 10 20 30 40 50 ‘Volume of NaOH(mL) ») Phenopthalein26, POR aq + F2Oy = HPOP a + OH ay 27. Transition point pH_= 2.90 28, 1.008 29. Unknown is an acid because it reacts with magnesium or bromthymol blue is yellow “. pH < 6.0 Unknown is a weak acid because it has poor electrical conductivity or indicators are both yellow which indicates a pH between 4.4 and 6.0 30. pH = 1.52 31, a) HsPOKay + H2Og = H2POs (ay + HsO%Wa b) A buffer solution forms and resists changes in pH. 32, HCsHsOyaq) + H20q) = CsHsOs'0q) + HsO% a) K, = [CsHs03][Hs0°] / [HsCsHsO3] 33.a) 2EOg + energy = HO" + OH a b) pH = 6.51 34.B>D>C>A 35. a) HCOs ay + H2Og) = COs) + 30%) HCOs(q) + HzO) = HeCOsq) + OH eq b) Key = 23x 10° 36. [H30*] = 6.0x10°M 37. pH = 1.70 = 38. a) HFey + H:0g = Fay + HsO%w — ») 1,0 and F - 39. Barbituric acid is stronger than propanoic acid. 40. Ky = 3.5x10* 41. pH = 1.10 42, a) HSOs) + HC20¢(aq) 2 H2SOsaq + C203? aap 1b) HaSOsaq is a stronger acid than HC20¢ 43. [H30°] = 6.2x10°M 2st252. 4, 45. 46. 47. 4B, 49, 50. 51. 52, 56. pH = 4.77 ‘Test: Use an indicator such as litmus. Result: Turns red. ‘Test: Add magnesium metal. H2 gas is given off. a) COs") + H2Oq = ACOs + OH Gn b) Ky = 18x 10% Ky = 14x 10* pH = 1.80 A strong Bronsted-Lowry acid is a species that donates a proton 100% to a receptive base. pH = 3.43 a) NaOH + HF — NaF + 120 b) OFag + Hay > 0m ©) NaF Fag + 09 = HFag + OM ap 8) A weak Bronsted-Lowry base is a proton acceptor that reacts with wate: less than 100%, b) NHS Ky = 14x 10* a) NaCNeg > Nate, + CNaa) b) CNiag + HaOg = HCNay + OH aa, . ©) Ky = [HCNJ[OH] / [CN] = 2.0x 10% . a) The ability to act as both a proton donor or proton acceptor. b) HCOs [OH] = 4.2x10°M57. a) The unknown is a weak acid. ‘The initial pH of 2.72 indicates that a weak acid is being titrated. ‘The equivalence or stoichiometric point has a pH of 8.88 which indicates that a basic salt is produced during this reaction. NaOH isa strong base and therefore the acid must be weak ) Thymol blue would be # green colour. or Phenolphthalein would be a faint pink colour. 58. 2) HCOs¢ag + HCOs‘) = C20. (aq + HzCOseaqp b) HC204 (eq and H2CO3 c) HC,Oy is a stronger acid than H,CO; 1x10 The unknown acid is citric acid. 59. K= 60, a) HSOsaq + H209) = SOs% aq + HO" any HSOs(q) + HO, = HaSOx + OH) b) Since K, (1.0x 107) > Ky (6.7x 10), the solution is acidic. 253